A kind of system for improving high basic metal coal and staiing coking
Technical field
The utility model is related to coal-burning boiler fields, are more particularly, to what a kind of improvement high basic metal coal stain coking
System.
Background technology
The higher coal of alkali metal content alkali metal elements such as contained sodium potassium in burning are changed into gaseous state at high temperature, when
When encountering the lower heat convection face of temperature, it can be deposited on heat convection surface in solid form.Because it is with higher stickiness
Heat-transfer surface can be caused to stain after absorption flying dust, and be not easy to be removed by soot blower, heat-transfer surface heat exchanged thermoresistance will be caused to increase, pot
Stove, which is contributed, to be reduced.
The existing technology to solve the contamination problems of high basic metal coal is broadly divided into three classes, and the first kind is before combustion to combustion
Material is pre-processed, and is recycled after carrying out dealkalize metal to raw coal:Such as Chinese patent CN202671513U uses slurrying system
System, heating compression system and piece-rate system remove sodium, and Chinese patent CN106701234A prepares low sodium coal using microwave, this kind of
Processing method system complex, high energy consumption and floor space are larger, and inconvenience is used in combination with coal-fired power station boiler.Second class is to fire
When burning in fuel blast blending by chemical action come the generation of inhibitory activity alkali metal salt:Such as Chinese patent
CN105670732A changes the composition ratio for mixing each ash content of ash sample by the ash fusion point conditioning agent of cooperation different proportion,
The ratio for having adjusted various elements content makes the ash fusion point of mixing ash sample increase, sodium element is made to migrate to sodium metasilicate and aluminosilicate
It is arranged with outside cinder in sodium, which needs special outfit additive, there is relatively high requirement, additive to its Composition Control
Cost is higher;Chinese patent CN104371790A proposes what alkali metal in a kind of high basic metal coal combustion of inhibition quasi- east discharged
Additive and its implementation, the additive can effectively inhibit 70% or more alkali metal to discharge with coal blending burning, and significantly
Improve the coal ash meltbility of coal, which equally needs to require to prepare according to certain to additive component, and implementation method and coal
Powder is ground together in coal pulverizer, can occupy the output of coal pulverizer, boiler input fuel quantity is influenced, to influence boiler output.
Third class is to be recycled for reducing contamination using flue gas or flying dust after fuel combustion:Chinese patent CN202813354U is utilized
Flue gas recirculation introduces cold flue gas in flue appropriate location by recirculation blower, by the region behind cold flue gas chilling screen bottom or screen
High-temperature flue gas, and then reduce high basic metal coal and stain activity, and it is made to be attached in fly ash granule, to avoid or mitigate tail
The problems such as contamination, abrasion and corrosion that portion heat convection face occurs, this method need to increase circulating fan, and can reduce boiler heat-transfer
Efficiency;CN103615714B proposes a kind of method recycled using abrasion-proof materiel and flying dust, is solved by wearing high-alkali
The problem of metal coal stains, this method need to add flying dust recycling and the circulator of a set of complexity, and abrasion-proof materiel and flying dust exist
Repeatedly physicochemical properties can change after cycle, and wearing character can be drastically reduced as the time increases, to influence
Its using effect.
Utility model content
To solve the above problems, the utility model provides a kind of method and system of improvement high basic metal coal contamination coking.
Technical solution adopted by the utility model to solve its technical problems is:A kind of improvement high basic metal coal contamination coking
Method, it is characterised in that:One or both of silicon oxide particles and al oxide granule mixture are sent by strength
Enter in the burner hearth of boiler and mixed with flue gas, adsorb the gaseous alkali metal salt in flue gas and generate chemical reaction generation property and is more steady
One or both of fixed alkali silicate and alkali metal silicate aluminium salt mixture, reduce flue gas in alkali metal content to
Mitigate heat-transfer surface in burner hearth to stain;Wash away what heat-transfer surface removing had adhered to by silicon oxide particles or al oxide granule simultaneously
Flying dust is hard burnt;Particle and flying dust enter dust-extraction unit with flue gas, and above-mentioned granulate mixture is not recycled.
Further, the silicon oxide particles or al oxide granule are sent by the Secondary Air in Secondary Air Nozzle of Boilers
Enter burner hearth;Particle spout is provided in the Secondary Air Nozzle of Boilers.
For convenience of Geldart-D particle, the grain size of the silicon oxide particles or al oxide granule is less than 2mm.
A kind of system for improving high basic metal coal and staiing coking, including be equipped in silicon oxide particles and al oxide granule
One or two kinds of mixtures particle warehouse, one group of particle spout being arranged in Secondary Air Nozzle of Boilers, with particle spout
The Pneumatic conveying pipeline of connection, the other end of Pneumatic conveying pipeline are connected with device for transporting objects, device for transporting objects with
Particle warehouse connects, and is also connected with and is provided with compressed air cylinder.
Further, the device for transporting objects include receiving warehouse, material issuing storehouse and material gas mixer, the receiving warehouse with
It is provided with warehouse outlet valve between grain warehouse, pressure is provided between the receiving warehouse, material issuing storehouse and material gas mixer and compressed air cylinder
Contracting air pipeline, and in receiving warehouse, material issuing storehouse and expect that the inlet end of gas mixer is respectively arranged with receiving warehouse intake valve, material issuing storehouse
Intake valve and conveyer regulating valve;Receiving warehouse outlet valve is provided between the receiving warehouse and material issuing storehouse, material issuing storehouse is mixed with material gas
Batcher is provided between device;
It is additionally provided with discharge duct in the receiving warehouse, air bleeding valve, the material issuing storehouse and exhaust are provided on discharge duct
Pipeline enclosure is provided with communicating pipe, is arranged on communicating pipe and balanced valve.Divider, divider are provided on the Pneumatic conveying pipeline
On be provided with one group with particle spout correspondingly export and connect with particle spout by pipeline.
As another mode of movement, the device for transporting objects includes the receiving warehouse being connected to particle warehouse, particle storage
Warehouse outlet valve is provided between storehouse and receiving warehouse, receiving warehouse is connected with one group and the one-to-one material issuing storehouse of particle spout,
It is provided with receiving warehouse outlet valve between material issuing storehouse and receiving warehouse, is connected by Pneumatic conveying pipeline between material issuing storehouse and particle spout;Institute
It states and is provided with compressed air pipe between receiving warehouse, material issuing storehouse and compressed air cylinder, and in the inlet end in receiving warehouse and material issuing storehouse point
It is not provided with receiving warehouse intake valve and material issuing storehouse intake valve.
As the third mode of movement, the device for transporting objects includes the mechanical transmission device being connected to particle warehouse,
It is provided with blocking valve between mechanical transmission device and particle warehouse, one group and particle spout one are provided with below mechanical transmission device
One corresponding surge bunker is provided with one group and the one-to-one discharge port of surge bunker on the mechanical transmission device;The buffering
Material gas mixer is connected with below storehouse, one end of material gas mixer is connect with Pneumatic conveying pipeline, the other end and compression
It is provided with compressed air pipe between air tank, conveyer regulating valve is provided on the compressed air pipe.
Preferably, the mechanical transmission device is pipe chain machine or screw conveyor.
For convenience of the contamination coking situation in real time monitoring burner hearth, included light is provided in the burner hearth or flue of the boiler
The high temperature resistant camera machine in source.
The beneficial effects of the utility model:The high basic metal coal that improves stains the system of coking using Geldart-D particle, knot
Structure is simple, efficient, and facilitates the feeding concentration for adjusting silicon oxide particles and al oxide granule, and conveying is at low cost.This reality
With novel chemical reaction generative nature is generated with the gaseous alkali metal salt in flue gas using silicon oxide particles and al oxide granule
The more stable alkali silicate of matter and alkali metal silicate aluminium salt, while constantly washing away what heat-transfer surface removing had adhered to by particle
The problem of flying dust is hard burnt, i.e., effective solution high basic metal coal stains coking, and do not interfere with the heating properties of boiler.Together
When, due to the deriving from a wealth of sources of Si oxide and/or aluminum oxide, cheap, and without completing additive according to certain formula
Configuration, can be the silicon ash waste material in other chemical processes, can also gather materials on the spot the sandstone materials such as river sand, Desert Sand.Its
Secondary, not stringent to particle size requirements, simple breakage is ground.Also need not particle coal pulverizer be sent into mix together with coal dust
Conjunction is ground, and is avoided the output for occupying coal pulverizer and is increased coal pulverizer power consumption, will not lead to fuel because of being limited by pulverizer capacity
Amount reduces the reduction so as to cause boiler output.In addition, being recycled without to particle, avoids particle and following
Property occurs in ring to change, avoids complicated recovery of circulatory system, it is simple and reliable.
Description of the drawings
Fig. 1 is the system schematic that the utility model conveys particle using feed method pneumatic conveying mode.
Fig. 2 is the system schematic that the utility model conveys particle using air supply method pneumatic conveying mode.
Fig. 3 is the system schematic that the utility model conveys particle using machinery conveying with Geldart-D particle combination.
Specific implementation mode
The technical scheme in the embodiment of the utility model is described below in conjunction with the accompanying drawings, the embodiment described is only real
With novel a part of example.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creativeness
The every other embodiment obtained under the premise of labour, shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of system for improving high basic metal coal and staiing coking, including be equipped in silicon oxide particles and al oxide granule
One or two kinds of mixtures particle warehouse 1,2 particle spouts 17 being arranged in 18 overfire air port of boiler, with particle
The Pneumatic conveying pipeline 15 that spout 17 connects, the other end of Pneumatic conveying pipeline 15 are connected with device for transporting objects a, object
Material conveying device a is connect with particle warehouse 1 and compressed air cylinder 11 respectively.
Specifically, the device for transporting objects a includes receiving warehouse 3, material issuing storehouse 6 and material gas mixer 9, the receiving warehouse 3
Positioned at the lower section of particle warehouse 1, the feed opening of particle warehouse 1 is connect by warehouse outlet valve 2 with the feed inlet of receiving warehouse 3, is received
3 discharge port of feed bin is connect by receiving warehouse outlet valve 5 with the feed inlet in material issuing storehouse 6, and the discharge port in material issuing storehouse 6 passes through batcher 8
It is connect with material gas mixer 9.It is provided with compression between the receiving warehouse 3, material issuing storehouse 6 and material gas mixer 9 and compressed air cylinder 11
Air pipeline 14, and the inlet end of receiving warehouse 3, material issuing storehouse 6 and material gas mixer 9 be respectively arranged with receiving warehouse intake valve 4,
Material issuing storehouse intake valve 7 and conveyer regulating valve 10.It is additionally provided with discharge duct 23 in the receiving warehouse 3, is set on discharge duct 23
It is equipped with air bleeding valve 13, is provided with communicating pipe 24 between the material issuing storehouse 6 and discharge duct 23, is arranged on communicating pipe 24 and balanced valve
12.Divider 16 is provided on the Pneumatic conveying pipeline 15, be provided on divider 16 2 outlet and by pipeline respectively with
Two particle spouts 17 connect.
When system operation, one or both of silicon oxide particles and al oxide granule mixture are put into first
In grain warehouse 1.Receiving warehouse 3 is fed later, concrete operations are:Receiving warehouse outlet valve 5 is closed, receiving warehouse intake valve 4 is closed, opens
Air bleeding valve 13 is opened to 3 pressure release of receiving warehouse, opens warehouse outlet valve 2, particle enters receiving warehouse 3.Then material issuing storehouse is fed, specifically
Operating procedure is:The warehouse outlet valve 2 of particle warehouse 1 is closed, air bleeding valve 13 is closed, opens receiving warehouse intake valve 4 to receiving warehouse 3
Pressurising.After the completion of pressurising, receiving warehouse outlet valve 5 is opened, opens balanced valve 12, particle enters material issuing storehouse 6.Above-mentioned two process week
And renew, it remains and maintains material in material issuing storehouse 6.Particle is continuously expelled to material gas from material issuing storehouse 6 and mixed by pulverizer coal feeder 8
Clutch 9.Particle through Pneumatic conveying pipeline 15 and passes through divider 16 under the carrying of the compressed air of compressed air reservoir 11
It is equally divided into two-way, is entered in stove by two particle spouts 17 respectively.Above-mentioned particle is under the carrying of boiler secondary air, with stove
Interior flue gas is mixed, and reaching by chemical reaction with flue gas and with the physical contact of heating surface, which improves high basic metal coal, stains
The effect of coking.The batcher 8 can adjust the grain amount of input according to the contamination coking situation in 18 stove of boiler.
Embodiment 2:
A kind of system for improving high basic metal coal and staiing coking, including be equipped in silicon oxide particles and al oxide granule
One or two kinds of mixtures particle warehouse 1,2 particle spouts 17 being arranged in 18 overfire air port of boiler, with particle
The Pneumatic conveying pipeline 15 that spout 17 connects, the other end of Pneumatic conveying pipeline 15 are connected with device for transporting objects a, object
Material conveying device a is connect with particle warehouse 1 and compressed air cylinder 11 respectively.
The device for transporting objects a includes that the feed opening for the 3 particle warehouse 1 of receiving warehouse being connected to particle warehouse 1 passes through storage
Warehouse discharging valve 2 is connect with the feed inlet of a receiving warehouse 3, and 3 discharge port of receiving warehouse passes through receiving warehouse outlet valve 5 and two material issuing storehouses
6 feed inlet connection.It is additionally provided with discharge duct 23 in the receiving warehouse 3, air bleeding valve 13 is provided on discharge duct 23.It is described
Receiving warehouse 3, material issuing storehouse 6 are connected to between compressed air cylinder 11 by compressed air pipe 14, and in receiving warehouse 3 and material issuing storehouse 6
Inlet end is respectively arranged with receiving warehouse intake valve 4 and material issuing storehouse intake valve 7.6 discharge port of material issuing storehouse passes through Pneumatic conveying pipeline 15
It is connect respectively with particle spout 17;Particle spout 17 is located in the overfire air port of boiler 18.
When system operation, one or both of silicon oxide particles and al oxide granule mixture are put into first
In grain warehouse 1.Then receiving warehouse is fed, and concrete operations are:Receiving warehouse outlet valve 5 is closed, receiving warehouse intake valve 4 is closed, is opened
Air bleeding valve 13 opens warehouse outlet valve 2, particle enters receiving warehouse to 3 pressure release of receiving warehouse.Then to one of material issuing storehouse into
Material, concrete operations are as follows:Warehouse outlet valve 2 is closed, air bleeding valve 13 is closed, opens receiving warehouse intake valve 4 to 3 pressurising of receiving warehouse.
After the completion of pressurising, one of receiving warehouse outlet valve 5 is opened, particle enters corresponding material issuing storehouse 6.The material issuing storehouse 6 charging is completed
Afterwards, another material issuing storehouse is fed, ensures each material issuing storehouse all in the state for having material always.Compressed air is continuously
By particle from material issuing storehouse 6, send to particle spout 17 and enter in stove through Pneumatic conveying pipeline 15.Above-mentioned particle is in boiler secondary air
It under carrying, is mixed with inner flue gas of the stove, it is high to reach improvement by chemical reaction with flue gas and with the physical contact of heating surface
Alkali metal coal stains the effect of coking.
Displacement can be adjusted by material issuing storehouse intake valve 7 to adjust pressure according to the contamination coking situation in 18 stove of boiler
The grain amount that contracting air is carried by.
Embodiment 3:
A kind of system for improving high basic metal coal and staiing coking, including be equipped in silicon oxide particles and al oxide granule
One or two kinds of mixtures particle warehouse 1,2 particle spouts 17 being arranged in 18 overfire air port of boiler, with particle
The Pneumatic conveying pipeline 15 that spout 17 connects, the other end of Pneumatic conveying pipeline 15 are connected with device for transporting objects a, object
Material conveying device a is connect with particle warehouse 1 and compressed air cylinder 11 respectively.
The device for transporting objects a includes the mechanical transmission device 20 being connected to particle warehouse 1, the blanking of particle warehouse 1
Mouth is connect by blocking valve 19 with mechanical transmission device 20, and the effect of blocking valve 19 is that the compressed air in surge bunker 21 is avoided to return
Enter in warehouse 1.The mechanical transmission device 20 can be that pipe chain machine can also be screw conveyor etc., and mechanical transmission device 20 is equipped with
Two or more discharge ports.Each discharge port is connect with the feed inlet of 2 surge bunkers 20.The discharge port and material of 2 surge bunkers 20
The feed inlet of gas mixer 9 connects.Compressed air reservoir 11 is connect by compressed air pipe 14 with conveying gas regulating valve 10, defeated
Regulating valve of supplying gas 10 is connect with the air inlet of material gas mixer 9.Expect the outlet of gas mixer 9 by Pneumatic conveying pipeline 15 with
Grain spout 17 connects.Particle spout 17 is located in the overfire air port of boiler 18.The position of surge bunker 21 is usually located at stokehold and leans on
The region of nearly particle spout 17.
When system operation, one or both of silicon oxide particles and al oxide granule mixture are put into first
In grain warehouse 1.Mechanical transmission device 20 is opened, particle is sent into surge bunker 21.Particle is in gravity or the work of compressed air injection
Into pan feeding gas mixer 9 under, and in the case where being carried from the compressed air of compressed air reservoir 11, through Pneumatic conveying pipeline 15
Entered in stove by particle spout 17.Above-mentioned particle is mixed under the carrying of boiler secondary air with inner flue gas of the stove, by with
The chemical reaction of flue gas and have the function that improving high basic metal coal stains coking with the physical contact of heating surface.
The contamination coking situation in 18 stove of boiler is monitored by the high temperature resistant camera machine 22 of automatic light source, is conveyed by machinery
The rotating speed of device 19 adjusts the grain amount into surge bunker 21, to adjusting into the grain amount in boiler 18.
A method of improving high basic metal coal and stain coking, by one kind in silicon oxide particles and al oxide granule
Or two kinds of mixtures are sent into the burner hearth of boiler by strength and mix, adsorb the gaseous alkali metal salt in flue gas and produce with flue gas
Biochemical reaction generates one or both of the more stable alkali silicate and alkali metal silicate aluminium salt of property mixture, subtracts
Alkali metal content stains to mitigate heat-transfer surface in burner hearth in few flue gas;Pass through silicon oxide particles or al oxide granule simultaneously
It washes away heat-transfer surface and removes the flying dust adhered to and hard coke;In burner hearth in a part of silicon oxide particles and al oxide granule
Generate alkali silicate, alkali metal silicate aluminium salt after the reaction of one or two kinds of mixtures, another part silicon oxide particles and
One or both of al oxide granule mixture washes away heat-transfer surface, and silicon oxide particles, alumina are obtained after the completion of reaction
The hybrid particles of composition granule and alkali silicate, alkali metal silicate aluminium salt, particle are filled with flue gas into dedusting with flying dust
It sets.
The silicon oxide particles or al oxide granule are sent into burner hearth by the Secondary Air in Secondary Air Nozzle of Boilers;Institute
It states and is provided with particle spout in Secondary Air Nozzle of Boilers;The silicon oxide particles or the dosage of al oxide granule are according to boiler
Heat-transfer surface recepts the caloric to be adjusted with heat-transfer surface contamination degree.
The grain size of the silicon oxide particles or al oxide granule is less than 2mm, by simple crushing and can grind
It realizes, it is made to meet Geldart-D particle or mechanical transport condition.
It is as follows:
Step 1:Raw material containing one or both of silicon oxide particles and al oxide granule mixture is carried out
Simple process makes it meet Geldart-D particle or mechanical transport condition at graininess.The ingredient of above-mentioned particle need not be controlled strictly,
The percentage that the quality for ensureing Si oxide and/or aluminum oxide accounts for gross mass is only needed to be not less than 50%.Its grain size should be not more than
1mm by simple crushing and can grind realization.
Step 2:It is conveyed one kind or two in silicon oxide particles and al oxide granule using Geldart-D particle or machinery
Kind mixture is sent directly into burner hearth by the particle spout in Secondary Air Nozzle of Boilers.Carrying of the above-mentioned particle in Secondary Air
Under, it is mixed with the flue gas in stove, adsorbs the gaseous alkali metal salt in flue gas and generate the more stable alkali of chemical reaction generation property
Metal silicate and alkali metal silicate aluminium salt reduce alkali metal content in flue gas and are stain to mitigate heat-transfer surface.With gaseous state sodium salt
And SiO2For:
2NaCl+n SiO2+H2O→Na2O.nSiO2+2HCl
Na2SO4+3SiO2→Na2O.3SiO2+SO2+1/2O2
Step 3:It monitors low melting point alkali metal salt heat-transfer surface in stove and adheres to contamination, preferably by with light source
Contamination coking situation in camera surveillance boiler furnace adjusts and enters silicon oxide particles and al oxide granule in burner hearth
Grain amount changes dust, and washing away for particle is utilized to carry out physical removal to staiing layer.
Step 4:Particle after reaction enters dust-extraction unit with flue gas and by separation removal, handles, do not have to together with coal ash
Other recycling or circulator is separately provided.