CN207738487U - A kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device - Google Patents

A kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device Download PDF

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Publication number
CN207738487U
CN207738487U CN201721503045.6U CN201721503045U CN207738487U CN 207738487 U CN207738487 U CN 207738487U CN 201721503045 U CN201721503045 U CN 201721503045U CN 207738487 U CN207738487 U CN 207738487U
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waste water
pump
water tank
room
low
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李向南
陈雪
陈文婷
赵焰
韩买良
徐志清
腾东玉
杨东
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Guoneng Water Environmental Protection Co.,Ltd.
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Beijing Lucency Enviro Tech Co Ltd
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Abstract

The utility model discloses a kind of desulfurization wastewater zero discharge treatment devices, more particularly to a kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device, it is mainly provided with heat source room, vaporization chamber, waste water tank, cooling chamber, low-temperature receiver room, heat exchanger plates, distillation film, cold plate, influent waste water pump, waste water small pump, solenoid valve, vacuum pump, condensed water suction pump, strong brine suction pump, PLC control cabinet.The present apparatus runs concentrated water outer circulation, and the uniform waste water quality of agitation is played in big flow cycle water inlet, the effect for cleaning distillation film film surface is washed away, distillation film service life is extended, improves impact resistance, it is designed using Zigzag type flow passage, improves heat exchanger effectiveness, crust of the device, flow passage components and distillation film are non-metallic material, acid and alkali-resistance, it is corrosion-resistant, modularized design, integration degree height, high degree of automation, it is stable efficient.

Description

A kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device
Technical field
The utility model patent is related to a kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device, belongs to waste water Zero-discharge technology field.
Background technology
For power plant desulfurization wastewater due to its high concentrtion, high rigidity, high salinity, pollutant kind are more, and different power plant water quality The features such as big is fluctuated, ingredient complexity, the maximum industrial wastewater of intractability the most in coal-burning power plant is become.
Vacuum membrane distillation technology, it is using dewatering microporous film as medium, in film both sides under the action of steam pressure difference, is waved in feed liquid Hair property component penetrates fenestra in vapour form, to realize the purpose of separation.With isolate and purify it is efficient, free from environmental pollution, It is easy to operate, low energy consumption, convenient for couple with other decontamination process and be integrated the advantages that.In the concentration of heat-engine plant desulfurized waste water There is huge application prospect in terms of decrement treatment.
But the presence of the temperature difference polarization and concentration polarization, lead to the thermal efficiency of membrane flux reduction and one way at high concentrations It is very low, become and restricts the bottleneck that the technology develops in heat-engine plant desulfurized wastewater zero discharge processing process of industrialization.Traditional vacuum Distillation device is susceptible to the dirty stifled problem of film infiltration in long-term operation, and the stability of system cannot be protected effectively Card needs the use lasting stability for solving membrane distillation.
If in terms of being therefore applied to heat-engine plant desulfurized Waste water concentrating decrement treatment, also need further to change its technology Into improving the stability and high efficiency of system operation.
Invention content
The utility model aim is to provide a kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device, it is intended to Solve the problems, such as above-mentioned background technology.The utility model overcomes existing technical problem, by Zigzag type flow passage, external circulating device with Vacuum membrane distillation is combined, and is proposed a kind of novel stabilising efficiently heat-engine plant desulfurized Waste water concentrating decrement processing apparatus, is applied In the processing of heat-engine plant desulfurized waste water, realizes wastewater zero discharge, guidance is provided for engineering design and engineering practice.
The technical solution of the utility model is realized in the following way:A kind of Zigzag type outer circulation vacuum membrane distillation is useless Water concentrates reducing device, including heating device, vaporising device, cooling device and PLC device;The heating device includes heat source room (The heat sources such as hot water, exhaust steam can be accommodated), heat source room water inlet(Gas)Pipe, heat source room's water outlet(Gas)Pipe, heat exchanger plates;The evaporation dress It sets including vaporization chamber, waste water tank, waste water tank water inlet pipe, waste water tank outlet pipe, waste water small pump, influent waste water pump, influent waste water Pipe, electromagnetic valve I, waste water outlet pipe, electromagnetic valve II, vacuum pump, distillation film, strong brine suction pump;The cooling device includes cold But room, cold plate, condensed water outlet pipe, condensed water suction pump, low-temperature receiver room(The low-temperature receivers such as circulating cooling water of power plant can be accommodated), low-temperature receiver Room water inlet pipe, low-temperature receiver room outlet pipe;The PLC device includes PLC control cabinet;If the wastewater inlet pipe is in setting in vaporization chamber Dry influent waste water runner;The waste water outlet pipe is connected with the influent waste water runner other end in vaporization chamber;Heat source room's setting Thermometer I;The vaporization chamber setting vacuum meter, thermometer II;The low-temperature receiver room setting thermometer III;The waste water tank setting TDS sensors, liquid level sensor and submersible agitator.
Particularly, the heat source room, vaporization chamber, cooling chamber and low-temperature receiver room are built jointly, it is characterised in that heat source room and vaporization chamber Completely separated by heat exchanger plates, vaporization chamber is completely separated by distillation film with cooling chamber, cooling chamber and low-temperature receiver room by cold plate completely every It opens;The condensed water suction pump water inlet is connected with cooling chamber;The strong brine suction pump water inlet is connected with vaporization chamber;It is described Air-inlet of vacuum pump is connected with vaporization chamber.
Particularly, waste water external circulating system is arranged in the vaporising device, it is characterised in that waste water tank is discharged by waste water tank Pipe, influent waste water pump, electromagnetic valve I, wastewater inlet pipe are connected with influent waste water runner, and waste water tank passes through waste water tank water inlet pipe, electricity Magnet valve II, waste water outlet pipe are connected with influent waste water runner;The waste water tank water inlet pipe and waste water tank outlet pipe are respectively positioned on waste water Below low liquid level set by case.
Particularly, the influent waste water runner designs for Zigzag type flow passage, and is uniformly distributed in heat exchange plate surface;It is described useless Water water inlet pipe is symmetrical in both ends with waste water outlet pipe.
Particularly, the thermometer I, vacuum meter, thermometer II, thermometer III, TDS sensor, liquid level sensor, latent Water blender, electromagnetic valve I, electromagnetic valve II, influent waste water pump, waste water small pump, strong brine suction pump are connected with PLC control cabinet.
Particularly, the distillation film is plate membrane, material PTFE;The heating device, vaporising device and cooling device Shell and flow passage components be non-metallic material.
Utility model device operating procedure is as follows:
The heat sources such as hot water or exhaust steam are intake by heat source room(Gas)Pipe enters heat source room, and thermometer I, heat is arranged in heat source room Source indoor temperature control in the energy transfer to desulfurization wastewater of heat source, will carry out heating at 50 DEG C~80 DEG C, using heat exchanger plates and rise Temperature, the heat source after cooling are then discharged by heat source room(Gas)Pipe is discharged, and fresh heat source is intake by heat source room(Gas)Pipe is mended again Enter heat source room, carries out laser heating;The low-temperature receivers such as recirculated cooling water enter low-temperature receiver room, low-temperature receiver room setting temperature by low-temperature receiver room water inlet pipe Table III is spent, low-temperature receiver indoor temperature is controlled at 30 DEG C or so, and the energy transfer of vapor is arrived recirculated cooling water etc. using cold plate In low-temperature receiver, cooling condensation is carried out, the low-temperature receiver after heating is then discharged by low-temperature receiver room outlet pipe, and fresh low-temperature receiver is intake by low-temperature receiver room (Gas)Pipe fills into low-temperature receiver room again, carries out continuous cooling;Meanwhile vaporization chamber and cooling chamber are become by the swabbing action of vacuum pump Thermometer II, vacuum meter is arranged in vacuum state, vaporization chamber, and it is 30mbar~100mbar that vacuum degree, which is arranged, in vaporization chamber.
Pending desulfurization wastewater is promoted to waste water tank by waste water small pump, then passes through waste water tank outlet pipe, electromagnetic valve I It is promoted in vaporization chamber by influent waste water pump with wastewater inlet pipe, desulfurization wastewater is in the influent waste water stream for depending on heat exchanger plates setting It is heated up in flow process in road, under vacuum conditions, generates a large amount of vapor, the concentrated water after evaporation passes through wastewater effluent Pipe, electromagnetic valve II and waste water tank water inlet pipe return to waste water tank, and influent waste water runner is designed using Zigzag type flow passage in vaporization chamber, Heat-exchange time is extended, heat exchanger effectiveness is improved;The setting of electromagnetic valve I and electromagnetic valve II, it is right when effectivelying prevent stopping intaking The destruction of device vacuum degree.
Liquid level sensor measures the liquid level of waste water tank, and high liquid level and low liquid level number in waste water tank is arranged by PLC control cabinet Value, when liquid level is less than low liquid level in waste water tank, PLC control cabinet controls waste water moisturizing pump operation, and liquid level reaches high liquid in waste water tank When position, PLC control cabinet controls waste water small pump and stops;When liquid level is higher than low liquid level less than high liquid level in waste water tank, and temperature Table I, thermometer II, thermometer III and vacuum meter numerical value be entirely located in the numberical range being arranged in PLC control cabinet, PLC controls Cabinet control electromagnetic valve I and electromagnetic valve II processed are opened, influent waste water pump operation;When liquid level is less than low liquid level, and temperature in waste water tank Table I, thermometer II, thermometer III and vacuum meter numerical value be entirely located in the numberical range being arranged in PLC control cabinet, PLC controls Cabinet control electromagnetic valve I and electromagnetic valve II processed are closed, and influent waste water pump is out of service, if liquid level is always below low liquid in five minutes Position, PLC control cabinet alarm;When liquid level is higher than high liquid level, and thermometer I, thermometer II, thermometer III and vacuum in waste water tank The numerical value of table is entirely located in the numberical range being arranged in PLC control cabinet, if liquid level is always above high liquid level in five minutes, PLC control cabinet controls electromagnetic valve I and electromagnetic valve II is closed, and influent waste water pump is out of service and alarms;When thermometer I, thermometer Any value of II, thermometer III and vacuum meter are less than or beyond the numberical range being arranged in PLC control cabinet, PLC control cabinet controls Electromagnetic valve I and electromagnetic valve II processed are closed, and influent waste water pump is out of service and alarms.
TDS sensors measure the dissolvability solid amount of waste water in waste water tank, as water quality TDS >=200g/L in waste water tank, PLC control cabinet controls electromagnetic valve I and electromagnetic valve II is closed, and influent waste water pump is out of service, and PLC control cabinet controls strong brine suction Pump operation, when liquid level reaches low liquid level in waste water tank, it is out of service that PLC control cabinet controls strong brine suction pump, waste water tank setting Submersible agitator plays the role of stirring evenly water quality.
Vapor enters cooling chamber by distilling film fenestra, and the low-temperature receivers such as vapor and cooling water carry out hot friendship at cold plate It changing, vapor exothermic condensation converges at cooling indoor condensed water runner at water droplet, due to being vacuum state in cooling chamber, Therefore condensed water is extracted out using condensed water suction pump.
By using preceding solution, the utility model has the advantage that and good effect:
(1)The utility model includes concentrated water external circulating device, and the uniform waste water quality of agitation is played in big flow cycle water inlet, The effect for cleaning distillation film film surface is washed away, impact caused by change of water quality can be largely resistant to, to improve processing The ability of desulfurization wastewater extends distillation film service life, fundamentally solves bottle caused by temperature difference polarization and concentration polarization Neck restricts, and can handle the desulfurization wastewater of higher concentration.
(2)Influent waste water runner is designed using Zigzag type flow passage in vaporization chamber, is extended heat-exchange time, is improved heat exchange Efficiency solves the problems, such as that big flow water inlet heat transfer effect is poor.
(3)Heating device, the shell of vaporising device and cooling device and flow passage components are non-metallic material, and distillation film is Plate membrane, material PTFE have many advantages, such as acid and alkali-resistance, high temperature resistant, corrosion-resistant and high mechanical properties.
(4)Utility model device uses modularized design, and integration degree is high, reduces occupation area of equipment, automatically Change degree is high, avoids security risk caused by artificial non-standard operation, easy to operate, stable efficient.
Description of the drawings
Fig. 1 is Zigzag type outer circulation vacuum membrane distillation device schematic diagram described in the utility model;
Fig. 2 is Zigzag type flow passage schematic device described in the utility model.
In figure:1-heat source room, 1.1-thermometer I, the water inlet of 2-heat source room(Gas)Pipe, the water outlet of 3-heat source room(Gas)Pipe, 4-heat exchanger plates, 4.1-influent waste water runners, 5-vaporization chambers, 5.1-thermometer II, 5.2-vacuum meters, 6-waste water tanks, 6.1-TDS sensors, 6.2-liquid level sensors, 6.3-submersible agitators, 7-waste water tank water inlet pipes, the water outlet of 8-waste water tanks Pipe, 9-waste water small pumps, 10-influent waste waters pump, 11-wastewater inlet pipes, 12-electromagnetic valve Is, 13-waste water outlet pipes, 14-electromagnetic valve IIs, 15-vacuum pumps, 16-distillation films, 17-strong brine suction pumps, 18-cooling chambers, 19-cold plates, 20-low-temperature receiver rooms, 20.1-thermometer III, 21-condensed water outlet pipes, 22-condensed water suction pumps, the water inlet of 23-low-temperature receiver rooms Pipe, 24-low-temperature receiver room outlet pipes, 25-PLC switch boards.
Specific implementation mode
Below in conjunction with the accompanying drawings 1-2 and embodiment the utility model is described in further detail.
As shown in Figure 1, a kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device carrying out practically step is:
The heat sources such as hot water or exhaust steam are intake by heat source room(Gas)Pipe(2)Into heat source room(1), heat source room(1)Setting Thermometer I(1.1), heat source room(1)Interior temperature control utilizes heat exchanger plates at 50 DEG C~80 DEG C(4)The energy transfer of heat source is arrived In desulfurization wastewater, heat temperature raising is carried out, the heat source after cooling is then discharged by heat source room(Gas)Pipe(3)Discharge, fresh heat source are logical Cross heat source room's water inlet(Gas)Pipe(2)Heat source room is filled into again(1), carry out laser heating;The low-temperature receivers such as recirculated cooling water pass through low-temperature receiver Room water inlet pipe(23)Into low-temperature receiver room(20), low-temperature receiver room(20)Thermometer III is set(20.1), low-temperature receiver room(20)Interior temperature control At 30 DEG C or so, cold plate is utilized(19)By in the low-temperature receivers such as the energy transfer of vapor to recirculated cooling water, cooling condensation is carried out, Low-temperature receiver after heating then passes through low-temperature receiver room outlet pipe(24)Discharge, fresh low-temperature receiver are intake by low-temperature receiver room(Gas)Pipe(23)It mends again Enter low-temperature receiver room(20), carry out continuous cooling;Meanwhile vaporization chamber(5)And cooling chamber(18)Pass through vacuum pump(15)Swabbing action Become vacuum state, vaporization chamber(5)Thermometer II is set(5.1), vacuum meter(5.2), vaporization chamber(5)Vacuum degree, which is arranged, is 30mbar~100mbar.
For vacuum membrane distillation system, film both sides vapor pressure differential is as mass transfer driving force, and hydrophobic microporous membrane is as biography Pass medium, due to the hydrophobicity of film, salinity and solution water cannot through film and vapor can carry out mass transfer by fenestra, therefore Only vapor can penetrate fenestra, can the TDS of industrial high slat-containing wastewater be concentrated into 200g/L or more.
Pending desulfurization wastewater passes through waste water small pump(9)It is promoted to waste water tank(6), then pass through waste water tank outlet pipe (8), electromagnetic valve I(12)And wastewater inlet pipe(11)It is pumped by influent waste water(10)It is promoted to vaporization chamber(5)It is interior, desulfurization wastewater according to Invest heat exchanger plates(4)The influent waste water runner of setting(4.1)It is heated up in interior flow process, under vacuum conditions, generates A large amount of vapor, the concentrated water after evaporation pass through waste water outlet pipe(13), electromagnetic valve II(14)With waste water tank water inlet pipe(7)It returns to Waste water tank(6);Vaporization chamber(5)Interior influent waste water runner(4.1)It is designed using Zigzag type flow passage, extends heat-exchange time, improved Heat exchanger effectiveness;Electromagnetic valve I(12)And electromagnetic valve II(14)Setting, effectively prevent stop intake when, to device vacuum degree Destruction.
Liquid level sensor(6.2)Measure waste water tank(6)Liquid level, pass through PLC control cabinet(25)Waste water tank is set(6)Middle height Liquid level and low liquid level numerical value, work as waste water tank(6)Middle liquid level is less than low liquid level, PLC control cabinet(25)Control waste water small pump(9)Fortune Row, waste water tank(6)When middle liquid level reaches high liquid level, PLC control cabinet(25)Control waste water small pump(9)Stop;Work as waste water tank(6) Middle liquid level is higher than low liquid level, and thermometer I less than high liquid level(1.1), thermometer II(5.1), thermometer III(20.1)With it is true Empty table(5.2)Numerical value be entirely located in PLC control cabinet(25)In the numberical range of interior setting, PLC control cabinet(25)Control electromagnetism Valve I(12)And electromagnetic valve II(14)It opens, influent waste water pump(10)Operation;Work as waste water tank(6)Middle liquid level is less than low liquid level, and temperature Spend Table I(1.1), thermometer II(5.1), thermometer III(20.1)And vacuum meter(5.2)Numerical value be entirely located in PLC control cabinet (25)In the numberical range of interior setting, PLC control cabinet(25)Control electromagnetic valve I(12)And electromagnetic valve II(14)Close, waste water into Water pump(10)It is out of service, if liquid level is always below low liquid level, PLC control cabinet in five minutes(25)Alarm;Work as waste water tank(6) Middle liquid level is higher than high liquid level, and thermometer I(1,1), thermometer II(5.1), thermometer III(20.1)And vacuum meter(5.2)'s Numerical value is entirely located in PLC control cabinet(25)In the numberical range of interior setting, if liquid level is always above high liquid level in five minutes, PLC control cabinet(25)Control electromagnetic valve I(12)And electromagnetic valve II(14)It closes, influent waste water pump(10)It is out of service and alarm; As thermometer I(1.1), thermometer II(5.1), thermometer III(20.1)And vacuum meter(5.2)Any value be less than or exceed PLC control cabinet(25)The numberical range of interior setting, PLC control cabinet(25)Control electromagnetic valve I(12)And electromagnetic valve II(14)It closes, Influent waste water pumps(10)It is out of service and alarm.
TDS sensors(6.1)Measure waste water tank(6)The dissolvability solid amount of interior waste water, works as waste water tank(6)Interior water quality TDS >=200g/L, PLC control cabinet(25)Control electromagnetic valve I(12)And electromagnetic valve II(14)It closes, influent waste water pump(10)Stop Operation, PLC control cabinet(25)Control strong brine suction pump(17)Operation, waste water tank(6)When middle liquid level reaches low liquid level, PLC controls Cabinet processed(25)Control strong brine suction pump(17)It is out of service, waste water tank(6)Submersible agitator is set(6.3), it is equal to play stirring The effect of even water quality.
Vapor is by distilling film(16)Fenestra enters cooling chamber(18), the low-temperature receivers such as vapor and cooling water are in cold plate (19)Place carries out heat exchange, and vapor exothermic condensation converges at cooling chamber at water droplet(18)Interior condensed water runner, due to cold But room(18)Interior is vacuum state, therefore utilizes condensed water suction pump(22)Condensed water is extracted out.

Claims (1)

1. a kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device, which is characterized in that including heating device, evaporation Device, cooling device and PLC device;The heating device includes heat source room(1), heat source room's water inlet pipe(2), heat source room's outlet pipe (3), heat exchanger plates(4);The vaporising device includes vaporization chamber(5), waste water tank(6), waste water tank water inlet pipe(7), waste water tank water outlet Pipe(8), waste water small pump(9), influent waste water pump(10), wastewater inlet pipe(11), electromagnetic valve I(12), waste water outlet pipe(13)、 Electromagnetic valve II(14), vacuum pump(15), distillation film(16), strong brine suction pump(17);The cooling device includes cooling chamber (18), cold plate(19), low-temperature receiver room(20), condensed water outlet pipe(21), condensed water suction pump(22), low-temperature receiver room water inlet pipe (23), low-temperature receiver room outlet pipe(24);The PLC device includes PLC control cabinet(25);The wastewater inlet pipe(11)In vaporization chamber (5)Interior several influent waste water runners of setting(4.1);The waste water outlet pipe(13)With vaporization chamber(5)Interior influent waste water runner (4.1)The other end is connected;The heat source room(1)Thermometer I is set(1.1);The vaporization chamber(5)Thermometer II is set(5.1)、 Vacuum meter(5.2);The low-temperature receiver room(20)Thermometer III is set(20.1);The waste water tank(6)TDS sensors are set (6.1), liquid level sensor(6.2)And submersible agitator(6.3);
The heat source room(1), vaporization chamber(5), cooling chamber(18)With low-temperature receiver room(20)It builds jointly, it is characterised in that heat source room(1)With Vaporization chamber(5)By heat exchanger plates(4)It is completely separated, vaporization chamber(5)With cooling chamber(18)By distillation film(16)It is completely separated, cooling chamber (18)With low-temperature receiver room(20)By cold plate(19)It is completely separated;The condensed water suction pump(22)Water inlet and cooling chamber(18)Phase Even;The strong brine suction pump(17)Water inlet and vaporization chamber(5)It is connected;The vacuum pump(15)Air inlet and vaporization chamber(5) It is connected;
Waste water external circulating system is arranged in the vaporising device, it is characterised in that waste water tank(6)Pass through waste water tank outlet pipe(8), it is useless Water intake pump(10), electromagnetic valve I(12), wastewater inlet pipe(11)With influent waste water runner(4.1)It is connected, waste water tank(6)Pass through Waste water tank water inlet pipe(7), electromagnetic valve II(14), waste water outlet pipe(13)With influent waste water runner(4.1)It is connected;The waste water tank Water inlet pipe(7)With waste water tank outlet pipe(8)It is respectively positioned on waste water tank(6)Below set low liquid level;
The influent waste water runner(4.1)It is designed for Zigzag type flow passage, and is uniformly distributed in heat exchanger plates(4)Surface;The waste water Water inlet pipe(11)With waste water outlet pipe(13)It is symmetrical in both ends;
The thermometer I(1.1), thermometer II(5.1), vacuum meter(5.2), TDS sensors(6.1), liquid level sensor (6.2), submersible agitator(6.3), waste water small pump(9), influent waste water pump(10), electromagnetic valve I(12), electromagnetic valve II(14)、 Strong brine suction pump(17), thermometer III(20.1)With PLC control cabinet(25)It is connected;
The distillation film(16)For plate membrane, material PTFE;The heating device, vaporising device and cooling device shell and Flow passage components are non-metallic material.
CN201721503045.6U 2017-11-13 2017-11-13 A kind of Zigzag type outer circulation vacuum membrane distillation Waste water concentrating reducing device Active CN207738487U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112777690A (en) * 2021-01-31 2021-05-11 东莞飞霸净水科技有限公司 Large-flow reverse osmosis water purifier
CN115259286A (en) * 2022-09-03 2022-11-01 南华大学 Low-energy-consumption high-efficiency tubular membrane distillation system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112777690A (en) * 2021-01-31 2021-05-11 东莞飞霸净水科技有限公司 Large-flow reverse osmosis water purifier
CN115259286A (en) * 2022-09-03 2022-11-01 南华大学 Low-energy-consumption high-efficiency tubular membrane distillation system

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