CN207276417U - A kind of ceramic membrane aeration and micro-positive pressure ozone film reused water processing device - Google Patents

A kind of ceramic membrane aeration and micro-positive pressure ozone film reused water processing device Download PDF

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Publication number
CN207276417U
CN207276417U CN201721135865.4U CN201721135865U CN207276417U CN 207276417 U CN207276417 U CN 207276417U CN 201721135865 U CN201721135865 U CN 201721135865U CN 207276417 U CN207276417 U CN 207276417U
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membrane
ozone
aeration
film
solenoid valve
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龙日军
吴汉阳
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Jiangxi Boxin Environmental Protection Technology Co ltd
Jiangxi Mufu New Materials Co ltd
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Jiangxi Boxin Refined Ceramics Environmental Protection Technology Co Ltd
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Abstract

The utility model discloses a kind of ceramic membrane aeration and micro-positive pressure ozone film reused water processing device,Including regulating reservoir,Pretreatment pool,Membrane cisterna,Water purifying tank,Ozone generator and air compressor machine,Pretreatment pool is provided with nano ceramics film aeration membrane,Ozone generator, which by ozonation aerated solenoid valve and ozone washes film solenoid valve and washes membrane tube with ozonation aerated pipe and ozone respectively, to be connected,Ozonation aerated pipe is connected with nano ceramics film aeration membrane,Ozone washes membrane tube and is connected with appendix,It is connected between oxygen aeration tube and appendix with compressed air rinsing aeration tube,Compressed air rinsing aeration electromagnetic valve is provided with compressed air rinsing aeration tube,Appendix one end is connected by air compressor machine solenoid valve I with air compressor machine,The other end is connected by air compressor machine solenoid valve II with membrane module outlet pipe,It is aerated using micro-positive pressure,Form the oxygen bubbles more than fine uniform quantity,Make full use of source of oxygen,Preferably oxygen is dissolved into water,Improve oxygen utilization rate,Strengthen biochemical effects,Reduce energy waste.

Description

A kind of ceramic membrane aeration and micro-positive pressure ozone film reused water processing device
Technical field
The utility model is related to method for treating water and water treatment facilities, and in particular to a kind of ceramic membrane aeration and it is critical it is micro- just Ozone is pressed to carry out the regenerated water treatment facilities of film.
Background technology
Earthenware slab membrane bioreactor is as a kind of new and effective sewage disposal technology, it has also become sanitary sewage, industry Waste water(The particularly waste water containing aromatic hydrocarbon)With extreme environment waste water(Such as butcher and breeding wastewater)It is indispensable in processing Treatment technology.
Ceramic membrane becomes sewage-treatment plant core component, and good result is achieved in practice.But system Because organic matter and inorganic matter absorption are in membrane surface in filtering operation, particularly bacterium and microbe metabolite be easily and metal Ionic interaction forms layer of gel layer in film surface, or bacterium in ceramic membrane surface implantation and can be tightly adhered to film surface On, coating layer is formed, causes diaphragm channel blockage flux to decline.Filtering just needs to divide diaphragm progress backwash 1 for 10 ~ 30 minutes Clock, and backwash water and pressure will be increased to 2 times, cause equipment work efficiency there was only 70% or so, equipment operating cost carries Height, cost of investment increase;And the time has grown bacterium and easily bred, further result in dirty stifled, it is necessary to be washed with solvent medicine, further Reduce filtration time and reduce total filter efficiency.And all salts containing soda acid and oxidant and the medicament of enzyme detergent class are equal Other salts substances can be generated, or even has partial salts material to form gel group in film surface with bacterium colloid group and brings gold into Belong to ion, cause secondary accumulation pollution, and pH value can be changed, derive other problem of environmental pollution.For these problems, state Interior useful ozone and back-flushing and the method for solution mixing backwash, but because ozone utilization rate is low, probably only 5%-20%, is caused Cost of use is expensive, and the ozone for causing part not utilize is discharged into air and causes air pollution and the harm to human body.
In addition the existing boring aeration largely used and aeration plate are aerated using macropore, and there are the utilization rate pole of oxygen The shortcomings of low, waste of energy, filling is uneven, is aerated head material in extreme circumstances and is easily corroded decomposition, short life.
Utility model content
In order to solve flat ceramic membrane module in the prior art, easily the deficiency of simultaneously frequent clean is blocked up in dirt in application process, The problem of ozone utilization rate is too low and causes running efficiency of system to reduce, and operating cost is high.To solve problem above, this practicality is new Type provides a kind of ceramic membrane aeration and critical micro-positive pressure ozone carries out the regenerated water treatment facilities of film.
The ozone generator uses air source ozone occurrence of equipment, and cost is controllable.The ozone generator outlet is divided into Two-way, enters pretreatment pool by solenoid valve all the way and carries out microvesicle aeration, main oxidation decomposes the organic matter of most of difficult degradation And reduce COD indexs etc..New process of employing new technology is handled, and ozone decomposed oxidation is fully carried out, is greatly improved The effective rate of utilization of ozone and the time with waste water.Using new product nano ceramics aeration membrane as aeration board, increase Aeration area and increase micropore quantity, and use critical micro-positive pressure, ozone is gradually formed microvesicle, and slowly increase, arrive Depart from aeration membrane surface, next bubble slowly produces again, so circulation.Whole bubble from formed to departing from all and around Organic matter carry out oxygenolysis, and because using nano ceramics film aeration membrane as hole substrate, the bubble of generation is non- Chang Wei little, considerably increases the quantity of bubble and the surface area with waste water.The overcompression when PC-MBR systems use Air carries out the micro- continuous-pressure breathing gas of microvesicle, there is provided ultra-fine source of oxygen bubble, makes full use of source of oxygen, reduces unnecessary energy wave Take;Another way enters membrane cisterna by other solenoid valves and exports back flush to the stifled ceramic membrane of dirt, uses critical micro-positive pressure Microvesicle is slowly produced, after oxygenolysis rapidly and efficiently is carried out using ozone, used air compressor machine departs from pollutant purging hollow Flat ceramic diaphragm surface, plays the purpose for recovering flux, reduce that solvent washes costly and causes asking for secondary pollution Topic.The hollow ceramic tablet diaphragm uses high purity aluminium oxide as carrier extrusion forming, single with 30-90 on its cross section Arrangement and the hollow hole of up/down perforation.Set inside the hollow ceramic flat membranes piece with 0.5~5 μm of micropore, outer surface There are transition zone, transition layer surface plating 0.01~0.2um microporous barriers.
The nano ceramics film aeration membrane makes of high purity aluminium oxide, corrosion-resistant and extreme environment, particularly organic molten Agent is with the obvious advantage, thus it is preferable used in high dangerous waste place aeration effect, and service life extension several times, reduce the later stage and replace the frequency.Institute Different pore size ceramic membrane can be made as requested by stating(Aperture can be used for being aerated from 0.1um ~ 100um), easy to corresponding different The requirement of aeration form(Such as boring aeration, aeration plate aeration, micro-pore aeration etc.), nano ceramics film aeration membrane can be tablet Ceramic membrane, pillar honeycomb ceramic body, the microporous inorganic material ceramics of DPF diesel particulate filters ceramic monolith or other shapes Body.The aperture of micropore is the plurality of specifications such as 1 μm ~ 50um in the hollow ceramic flat membranes, and porosity is 20%~75%.This Sample adapts to the place of different requirements.The aeration membrane can be placed with individual layer or multilayer is placed, and further improve ozone utilization Rate, so that the thrifty energy and space.The length of the nano ceramics film aeration membrane is 150-1000mm;Set in parallel or series Put, the Ullage of adjacent two nano ceramics film aeration membrane is 2-200mm;The nano ceramics film aeration membrane uses high pure oxygen It is carrier extrusion forming to change aluminium or kaolin or other viscous materials, and appearance and size is wide by 110,150mm, 250mm thickness 3-8mm, length 150-1000mm is spent, upper and lower end face is by 32-60 hollow hole single-row arrangement and up/down perforation, and the aperture of micropore is on sintering carrier 1-50 μm, centre plating transition zone, and distribution of pores is narrow.
The ozone generator uses air source ozone occurrence of equipment, and the ozone generator outlet is divided into two-way, all the way By solenoid valve enter pretreatment pool carry out microvesicle aeration, whole bubble from is being formed to departing from all and around organic matter progress Oxygenolysis, and as hole substrate, the bubble produced is very small, greatly increases because using nano ceramics aeration membrane The quantity of bubble and the surface area with waste water;Another way blocks sewage into membrane cisterna by other solenoid valves hollow After flat ceramic diaphragm carries out oxygenolysis rapidly and efficiently, used air compressor machine purging departs from hollow ceramic flat membranes piece surface, Play the purpose for recovering flux.Reduce costly and the problem of causing secondary pollution that solvent is washed.
Air compressor machine outlet is equipped with efficient air filter 61, ensures the air purity that reverse air-blowing is washed.
Ceramic membrane aeration described in the utility model and critical micro-positive pressure ozone, which carry out the regenerated water treatment facilities of film, to be included adjusting Pond, pretreatment pool, membrane cisterna, water purifying tank, ozone generator and air compressor machine are saved, immersible pump, regulating reservoir are provided with the regulating reservoir It is connected with pretreatment pool with regulating reservoir outlet pipe, the pretreatment tank is provided with nano ceramics film aeration membrane, in the membrane cisterna Membrane module is provided with, pretreatment pool is connected with pretreatment pool outlet pipe with membrane cisterna, and the ozone generator passes through ozonation aerated electricity Magnet valve and ozone, which wash film solenoid valve and washes membrane tube with ozonation aerated pipe and ozone respectively, to be connected, and ozonation aerated pipe is exposed with nano ceramics film Air film piece is connected, and ozone washes membrane tube and is connected with appendix, is exposed between the ozonation aerated pipe and appendix with compressed air rinsing Tracheae is connected, and compressed air rinsing aeration electromagnetic valve is provided with compressed air rinsing aeration tube, and described appendix one end passes through Air compressor machine solenoid valve I is connected with air compressor machine, the other end is connected by air compressor machine solenoid valve II with membrane module outlet pipe, the film group Filtering outlet pipe is connected between part outlet pipe and water purifying tank, filter electromagnetic valve is provided with the filtering outlet pipe and self-priming increases Press pump.
The course of work of processing unit described in the utility model:After first adjusting concentration of wastewater in regulating reservoir, start diving Pump starts ozone generator 5 by sewage transport to pretreatment pool, closes ozone and washes film solenoid valve 55 and compressed air rinsing exposure Pneumoelectric magnet valve 56, opens ozonation aerated solenoid valve 52, and ozone enters pretreatment by ozone outlet pipe 51 and ozonation aerated pipe 53 In nano ceramics film aeration membrane in pond, formation ozone microbubbles come into full contact with sewage in sewage.When being adopted in pretreatment pool During with PC-MBR process, ozone generator is closed, starts air compressor machine, and closes air compressor machine solenoid valve II 63, ozonation aerated Solenoid valve 52 and ozone wash film solenoid valve 55, open compressed air rinsing aeration electromagnetic valve 56, compressed air is exposed by ozone Tracheae 53 enters in the nano ceramics film aeration membrane in pretreatment pool, and air micro-bubbles are formed in sewage and are fully connect with sewage Touch.Enter membrane cisterna when after the sewage of pretreatment pool reach a certain height, start roots blower 31 and be aerated, it is electromechanical to close pneumatics Magnet valve II 63, opens filtering solenoid valve 41 and spontaneous imbibition booster pump 42, the water purification after being handled in membrane cisterna out is through membrane module water outlet 33 enter in water purifying tank 4 with filtering outlet pipe 43.When needing to be rinsed membrane module, start air compressor machine 6, open air compressor machine Solenoid valve I 62 and air compressor machine solenoid valve II 63, close ozone and wash film electromagnetism 55, compressed air rinsing aeration electromagnetic valve 56 and mistake Solenoid valve 41 is filtered, compressed air is entered the recoil carried out in membrane module to diaphragm by appendix 64 and membrane module outlet pipe 22 Wash, after backwash, close air compressor machine, start ozone generator, close air compressor machine solenoid valve I 62, ozonation aerated solenoid valve 52, pressure Contracting air douche aeration electromagnetic valve 56 and filter electromagnetic valve 41, open air compressor machine solenoid valve II 63 and ozone washes film solenoid valve 55. Make ozone that the gel layer on diaphragm be decomposed and dissolved into membrane module by appendix and membrane module water outlet, go membrane removal The gel layer of on piece.Or ozone is directly compressed to inside air compressor machine and is mixed with air, mixed gas is directly from membrane module Backwashed in the diaphragm that water outlet enters in membrane module, being passed through ozone in the diaphragm into membrane module in critical micro-positive pressure mixes Gas is closed, the gel layer of difficult degradation on membrane surface is decomposed and dissolved using ozone, removes the gel layer on diaphragm.
The PC-MBR or other treatment process are using -2 empty endless form for exposing the sky of -3 water backwashing -4 and exposing of 1 filtering.Adopt Small ozone is produced with the critical micro-positive pressure of new technology to steep, and is incrementally increased and departed from the technique of nanometer flat ceramic film surface, can The empty filtration time and efficiency for exposing two steps of -3 water backwashing, greatly increasing system of processing step 2 is reduced, and it is anti-using ozone Interior when 12 is small after flushing to be not easy growth and particle-bound bacteria and colloidal substance, water flux can further improve.Using PC-MBR Pretreatment pool ozone does not enter during technique, small using pore-size distribution, and transmembrane pressure is small, and the small nano ceramics film in aperture is exposed Gas, is aerated using micro-positive pressure, is formed the oxygen bubbles more than fine uniform quantity, is made full use of source of oxygen, preferably dissolve oxygen Into water, oxygen utilization rate is improved, strengthens biochemical effects, reduces energy waste.
Brief description of the drawings
Fig. 1 is the operation principle schematic diagram of the utility model.
In Fig. 1:1st, regulating reservoir 11, immersible pump 12, regulating reservoir outlet pipe 2, pretreatment pool 21, nano ceramics film Aeration membrane 22, pretreatment pool outlet pipe 3, membrane cisterna 31, roots blower 32, aeration tube 33, membrane module water outlet 34, film Component 4, water purifying tank, 41, filter electromagnetic valve 42, spontaneous imbibition booster pump 43, filtering outlet pipe 5, ozone generator 51, ozone Outlet 52, ozonation aerated solenoid valve 53, ozonation aerated pipe 54, ozone wash membrane tube 55, ozone washes film solenoid valve 56, pressure Contracting air douche aeration electromagnetic valve 57, compressed air rinsing aeration tube 6, air compressor machine 61, air filter, 62, pneumatics it is electromechanical Magnet valve I 63, air compressor machine solenoid valve II 64, appendix.
Embodiment
In Fig. 1, a kind of ceramic membrane aeration and critical micro-positive pressure ozone carry out the regenerated water treatment facilities of film and include adjusting Pond 1, pretreatment pool 2, membrane cisterna 3, water purifying tank 4, ozone generator 5 and air compressor machine 6, are provided with immersible pump 11 in the regulating reservoir, Regulating reservoir is connected with pretreatment pool regulating reservoir outlet pipe 12, and the pretreatment tank is provided with nano ceramics film aeration membrane 21, Membrane module 34 is provided with the membrane cisterna, membrane module lower part is provided with aeration tube 32, aeration tube and roots blower 31(Or it is centrifuged Wind turbine)It is connected, pretreatment pool is connected with pretreatment pool outlet pipe 22 with membrane cisterna, the ozone generator and 51 phase of ozone outlet pipe Even, ozone outlet pipe is washed film solenoid valve 55 by ozonation aerated solenoid valve 52 and ozone and is washed respectively with ozonation aerated pipe 53 and ozone Membrane tube 54 is connected, and ozonation aerated pipe is connected with nano ceramics film aeration membrane 21, and ozone washes membrane tube and is connected with appendix 64, described It is connected between ozonation aerated pipe and appendix with compressed air rinsing aeration tube 57, pressure is provided with compressed air rinsing aeration tube Contracting air douche aeration electromagnetic valve 56, described appendix one end is connected with air compressor machine, the other end by air compressor machine solenoid valve I 63 with Membrane module water outlet 33 is connected, and filtering outlet pipe 43 is connected between the membrane module water outlet and water purifying tank, described to filter out Filter electromagnetic valve 41 and spontaneous imbibition booster pump 42 are provided with water pipe.
The regulating reservoir 1 inflow and concentration of wastewater are mixed well after by immersible pump 11 by the adjusted pond outlet pipe 12 of sewage Pump in pretreatment pool 2, it is described to be controlled into water management by the liquid level meter of membrane cisterna 3.The preprocessed pond initial filter device of sewage Initial filter is carried out, filters bulky grain inorganic matter or other bulky grain aggregates and excessive suspended matter or floating oily substance etc.. The initial filter device can be the pre-processing devices such as thin grid, pre-filter, air floatation machine, Oil scraper.The ozone generator 5 It is aerated through ozone outlet pipe 51 from the ozonation aerated solenoid valve 52 of left by ozonation aerated pipe 53 using new product nano ceramics film Ozone is formed many trickle approximations by ozone by diaphragm 21 using the ultra-fine aperture nano ceramics fenestra of the critical micro-positive pressure of new process In the microvesicle of zero pressure, fully and waste water, larger molecular organics and oil slick in oxygenolysis sewage etc. are carried out absolutely mostly The organic matter Quick Oxidation of number difficult degradation resolves into low or nontoxic small-molecule substance, or even directly resolves into CO2And H2O.Institute State pretreatment pool when using PC-MBR techniques and be added without ozone, close ozone generator, start air compressor machine, and close pneumatics electromechanics Magnet valve II 63, ozonation aerated solenoid valve 52 and ozone wash film solenoid valve 55, open compressed air rinsing aeration electromagnetic valve 56, make pressure Contracting air is entered in the nano ceramics film aeration membrane in pretreatment pool by ozonation aerated pipe 53, and it is micro- that air is formed in sewage Bubble come into full contact with sewage, directly use air-source progress micropore micro-positive pressure aeration, the aeration membrane can be ceramic membrane, The micropore ceramics body of pillar honeycomb ceramic body, DPF diesel particulate filters ceramic monolith or other shapes.The long-time uses Pollutant can cause nano ceramics aeration membrane surface to deposit, and influence to ozonize discomposing effect, system can close ozonation aerated electricity Magnet valve 52, opens air compressor machine solenoid valve I 62 and compressed air rinsing aeration electromagnetic valve 56 and aeration membrane is backwashed into horizontal high voltage, Remove aeration membrane surface contaminant.The preprocessed pond outlet pipe 22 of sewage decomposed through ozone oxidation is overflowed in membrane cisterna It is further processed, in the membrane cisterna, using activated sludge process and membrane separation technique, flocculation sediment and membrane separation technique, work Property charcoal absorption handled with membrane separation technique, electrolysis further sewage decomposed or is degraded and by receiving with membrane separation technique etc. Rice ceramic diaphragm 12 is separated by filtration.Pollutant is trapped within membrane cisterna, and water purification is by spontaneous imbibition booster pump 42 through on membrane module 34 Membrane module water outlet 33, filter electromagnetic valve 41 and filtering outlet pipe 43 flow into water purifying tank 4 collect, complete filtering.The film group Part has the aeration tube 32 of tape punching, and source of the gas is provided by roots blower 31.
During the nano ceramics film aeration membrane normal filtration, water purification is by hollow ceramic flat membranes piece gap by collector pipe Through spontaneous imbibition booster pump filter electromagnetic valve filtering outlet pipe enter water purifying tank, when work after a certain period of time flat ceramic diaphragm by micro- life When thing or Organic Material Blocking fenestra, resistance increase, when negative pressure increases to 0.04 ~ 0.05mpa, system will be automatically stopped into water and just Filter aeration and filtration system, by the compressed air in air compressor machine via air filter, air compressor machine solenoid valve I, air compressor machine electromagnetism Valve II, membrane module water outlet, which are transported in hollow ceramic flat membranes piece, carries out high pressure gas backwash, by hollow ceramic flat membranes piece table The attachment pollutant in face is separated from membrane surface, and the cross-flow steam-water mixing liquid band produced by bottom aeration tube is walked part dirt and blocked up. Close air filter solenoid valve I and open ozone and wash that ozone is washed membrane tube by film solenoid valve through ozone outlet pipe, ozone, membrane module goes out The mouth of a river is transported to inside membrane module, is dropped ozone under the effect of the pressure and is transferred to film surface quickly through fenestra, to organic matter or Bacterial body and other attachments carry out oxygenolysis, are then shut off ozone and wash film solenoid valve, open air filter solenoid valve I, The material of reverse blow oxygenolysis is carried out by big pressure compressed air.According to the different size of negative pressure value carry out different numbers and The ozone clean flat ceramic diaphragm of time.Diaphragm flux recovery is to more than 90%, and negative pressure, in below 0.01mpa, system is extensive Multiple operation.

Claims (6)

1. a kind of ceramic membrane aeration and micro-positive pressure ozone film reused water processing device, it includes regulating reservoir(1), pretreatment pool(2)、 Membrane cisterna(3), water purifying tank(4), ozone generator(5)And air compressor machine(6), immersible pump is provided with the regulating reservoir(11), adjust Pond and pretreatment pool regulating reservoir outlet pipe(12)It is connected, it is characterised in that:The pretreatment tank is provided with the exposure of nano ceramics film Air film piece(21), membrane module is provided with the membrane cisterna(34), pretreatment pool pretreatment pool outlet pipe(22)It is connected with membrane cisterna, The ozone generator passes through ozonation aerated solenoid valve(52)Film solenoid valve is washed with ozone(55)Respectively with ozonation aerated pipe(53) Membrane tube is washed with ozone(54)It is connected, ozonation aerated pipe is connected with nano ceramics film aeration membrane, and ozone washes membrane tube and appendix (64)It is connected, compressed air rinsing aeration tube is used between the ozonation aerated pipe and appendix(57)It is connected, compressed air rinsing Compressed air rinsing aeration electromagnetic valve is provided with aeration tube(56), described appendix one end passes through air compressor machine solenoid valve I(62) With air compressor machine(6)It is connected, the other end passes through air compressor machine solenoid valve II(63)With membrane module water outlet(33)It is connected, the membrane module Water outlet(33)With water purifying tank(4)Between be connected with filtering outlet pipe(43), it is described filtering outlet pipe on be provided with filter electromagnetic Valve(41)And spontaneous imbibition booster pump(42).
2. a kind of ceramic membrane aeration according to claim 1 and micro-positive pressure ozone film reused water processing device, its feature exist In:The membrane module includes spaced hollow ceramic tablet diaphragm, organic or inorganic material plug and collector pipe.
3. a kind of ceramic membrane aeration according to claim 1 and micro-positive pressure ozone film reused water processing device, its feature exist In:The nano ceramics film aeration membrane(21)For ceramic membrane, pillar honeycomb ceramic body, DPF diesel particulate filters pottery Ceramic carrier or microporous inorganic material ceramic body.
4. a kind of ceramic membrane aeration according to claim 1 and micro-positive pressure ozone film reused water processing device, its feature exist In:The membrane module(34)Lower part is provided with aeration tube(32), aeration tube and roots blower(31)It is connected.
5. a kind of ceramic membrane aeration according to claim 1 and micro-positive pressure ozone film reused water processing device, its feature exist In:The ozone generator(5)With ozone outlet pipe(51)It is connected, ozone outlet pipe passes through ozonation aerated solenoid valve(52)With it is smelly Oxygen washes film solenoid valve(55)Respectively with ozonation aerated pipe(53)Membrane tube is washed with ozone(54)It is connected.
6. a kind of ceramic membrane aeration according to claim 1 and micro-positive pressure ozone film reused water processing device, its feature exist In:The air compressor machine(6)Outlet is equipped with air filter(61), ensure the air purity that reverse air-blowing is washed.
CN201721135865.4U 2017-09-06 2017-09-06 A kind of ceramic membrane aeration and micro-positive pressure ozone film reused water processing device Active CN207276417U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI717743B (en) * 2018-05-30 2021-02-01 日商三菱電機股份有限公司 Membrane clean device and method for cleaning membrane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI717743B (en) * 2018-05-30 2021-02-01 日商三菱電機股份有限公司 Membrane clean device and method for cleaning membrane

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Address after: 337253 Luxi Industrial Park, Pingxiang City, Jiangxi Province

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Patentee before: Jiangxi Boxin Environmental Protection Technology Co.,Ltd.

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