CN207097970U - A kind of lithium ion battery containing Soft Roll three-electrode structure in situ - Google Patents

A kind of lithium ion battery containing Soft Roll three-electrode structure in situ Download PDF

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Publication number
CN207097970U
CN207097970U CN201720962685.7U CN201720962685U CN207097970U CN 207097970 U CN207097970 U CN 207097970U CN 201720962685 U CN201720962685 U CN 201720962685U CN 207097970 U CN207097970 U CN 207097970U
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CN
China
Prior art keywords
lug
lithium
ion battery
lithium ion
situ
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Expired - Fee Related
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CN201720962685.7U
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Chinese (zh)
Inventor
赵家兴
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Fujian City Rui Min Amperex Technology Ltd
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Fujian City Rui Min Amperex Technology Ltd
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Priority to CN201720962685.7U priority Critical patent/CN207097970U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

The utility model discloses a kind of lithium ion battery containing Soft Roll three-electrode structure in situ, including housing, it is characterised in that also includes:Positive pole ear, negative lug and the battery core being packaged in the housing, the side of the housing is provided with airbag, lithium reference electrode is provided with the housing, the lithium reference electrode, which is provided with, draws lug, the extraction lug is packaged on the airbag, and the lithium reference electrode and lug Surface coating have barrier film.Through the above way, interracial contact between electrode when the utility model can not interfere with lithium ion battery chemical conversion, so as to carry out in-situ test to lithium ion battery, more accurately lithium ion battery positive and negative electrode current potential can be monitored, and then rationally design battery NP ratios, avoid battery anodic potentials in charge and discharge process too high and negative terminal surface lithium separates out, improve lithium ion battery safety performance.

Description

A kind of lithium ion battery containing Soft Roll three-electrode structure in situ
Technical field
Lithium battery manufacturing technology field is the utility model is related to, contains Soft Roll three-electrode structure in situ more particularly, to one kind Lithium ion battery.
Background technology
Lithium ion battery can be divided into cylindrical lithium ion battery, square aluminum case lithium ion electricity according to its shape and sheathing material Pond, soft bag lithium ionic cell.At present, soft bag lithium ionic cell due to its light weight, energy density is high the advantages that be widely used In fields such as consumer electronics product, new-energy automobiles.
Three electrodes are the common methods of lithium ion battery chemical property research, but traditional soft bag lithium ionic cell three is electric Pole structure is melted into lithium ion battery(Charge)Before, reference electrode and both positive and negative polarity are separated using barrier film and are incorporated into battery Portion, but this mode, the easy fold of positive/negative plate when carrying out battery seal, both positive and negative polarity interface when causing the lithium ion battery to be melted into Loose contact, the accuracy of both positive and negative polarity potential test is influenceed, so as to rationally design the NP ratios of battery, NP ratios refer to unit Area capacity ratio;NP=negative pole surface density * active material ratio * active materials gram volume/(Positive pole surface density * active material ratios Rate * active material gram volumes), typically at least above 1.0 in design, general minimum value takes 1.02.
Utility model content
Technical problem to be solved in the utility model is:In view of the shortcomings of the prior art, there is provided one kind is containing in situ soft The lithium ion battery of bag three-electrode structure, both positive and negative polarity interracial contact is good when achievable lithium ion battery is melted into, and improves both positive and negative polarity electricity Bit test accuracy, improve the security performance of lithium ion battery.
In order to solve the above-mentioned technical problem, the technical solution adopted in the utility model is:One kind is provided and contains Soft Roll in situ The lithium ion battery of three-electrode structure, including housing, in addition to:Be packaged in positive pole ear in the housing, negative lug and Battery core, the side of the housing are provided with airbag, and lithium reference electrode is provided with the housing, and the lithium reference electrode, which is provided with, draws Lug, the extraction lug are packaged on the airbag, and the lithium reference electrode and extraction lug Surface coating have barrier film.
Wherein, after lithium ion battery chemical conversion, the airbag is provided with opening, and the lithium reference is placed by the opening Electrode is in the housing.
Wherein, the positive pole ear is aluminium pole ears, and negative lug is one kind in nickel lug, copper nickel plating lug.
Wherein, the lithium reference electrode is shaped as rectangle or circle, and the lithium reference electrode thickness is 0.1mm ~ 1.0mm.
Wherein, the lug of drawing is one kind in aluminium pole ears, nickel lug, copper nickel plating lug.
Wherein, the extraction lug is provided with lithium piece, the lithium piece thickness 0.5mm, long 2cm, wide 2cm.
Wherein, the housing is plastic-aluminum shell.
The beneficial effects of the utility model are:It is different from prior art, housing of the utility model in lithium ion battery Side is provided with airbag, and lithium reference electrode is provided with housing, and the extraction lug of its one end is packaged on airbag, and lithium reference electrode and Drawing lug Surface coating has barrier film.When lithium ion battery of the present utility model does not interfere with lithium ion battery chemical conversion between electrode Interracial contact, so as to carry out in-situ test to lithium ion battery, more accurately lithium ion battery positive and negative electrode current potential can be supervised Survey, and then rationally design battery NP ratios, avoid battery anodic potentials in charge and discharge process too high and negative terminal surface lithium separates out, carry High-lithium ion battery safety.
Brief description of the drawings
Fig. 1 is the structural representation of the lithium ion battery described in the utility model containing Soft Roll three-electrode structure in situ.
Embodiment
For detailed description technology contents of the present utility model, the objects and the effects, below in conjunction with embodiment and match somebody with somebody Accompanying drawing is closed to be explained.
Fig. 1 is refer to, the utility model provides a kind of lithium ion battery containing Soft Roll three-electrode structure in situ, including aluminium Plastic housing body 1, it is packaged in the housing 1 and is packaged with positive pole ear 2, negative lug 3 and battery core 4, the side of the housing 1 is pre- Airbag 5 is left, after lithium ion battery chemical conversion, airbag 5 is cut off to form an opening 6, by the opening 6 in the housing 1 Lithium reference electrode 7 is inside put into, the lithium reference electrode 7, which is provided with, draws lug 8, and the extraction lug 8 is packaged in the airbag 5 On, and the lithium reference electrode 7 and the extraction Surface coating of lug 8 have barrier film 9.
Wherein, the positive pole ear 2 is aluminium pole ears, and negative lug 3 is one kind in nickel lug, copper nickel plating lug.
Wherein, the lithium reference electrode 7 is rectangle or circle, and the thickness of lithium reference electrode 7 is 0.1mm ~ 1.0mm.
Wherein, the lug 8 of drawing is one kind in aluminium pole ears, nickel lug, copper nickel plating lug.
Wherein, the extraction lug 8 is provided with lithium piece, the lithium piece thickness 0.5mm, long 2cm, wide 2cm.
Specifically, the step of making lithium ion battery described in the utility model is mainly as follows:
The first step:Anode ear, negative electrode lug, battery core are packaged in soft bag lithium ionic cell plastic-aluminum shell, plastic-aluminum shell-side side is pre- Stay airbag.Electrolyte is injected from reserved airbag side in glove box and is open.It is melted into using traditional lithium-ion battery chemical synthesis technology, Lithium ion battery is vented after drying room will be melted into using vacuum-pumping equipment, and reserved airbag side, which is cut off, to be positioned in glove box.
Second step:Thickness 0.5mm, long a width of 2cm*2cm square lithium piece are coated on extraction lug in glove box Upper pressing, lithium piece and extraction lug cladding are prevented into internal short-circuit of battery with barrier film, then inserted by cutting off reserved airbag To the ready lithium ion battery of the first step, it is packaged in side and reserves airbag edge, the utility model is made.
The utility model is installed on three electrode test apparatus, detects both positive and negative polarity electricity in lithium ion battery charge and discharge process Position, you can determine whether that anodic potentials are too high or negative terminal surface lithium separates out, so as to go to adjust lithium ion battery NP ratios, improve lithium from The security performance of sub- battery.
Embodiment of the present utility model is the foregoing is only, not thereby limits the scope of the claims of the present utility model, it is every The equivalents made using the utility model specification and accompanying drawing content, or directly or indirectly it is used in the technology neck of correlation Domain, similarly it is included in scope of patent protection of the present utility model.

Claims (7)

1. a kind of lithium ion battery containing Soft Roll three-electrode structure in situ, including housing, it is characterised in that also include:Encapsulation In the positive pole ear in the housing, negative lug and battery core, the side of the housing is provided with airbag, is provided with the housing Lithium reference electrode, the lithium reference electrode, which is provided with, draws lug, and the extraction lug is packaged on the airbag, and the lithium is joined There is barrier film than electrode and lug Surface coating.
2. the lithium ion battery according to claim 1 containing Soft Roll three-electrode structure in situ, it is characterised in that lithium from After sub- Battery formation, the airbag is provided with opening, and the lithium reference electrode is placed in the housing by the opening.
3. the lithium ion battery according to claim 1 containing Soft Roll three-electrode structure in situ, it is characterised in that it is described just Pole lug is aluminium pole ears, and negative lug is one kind in nickel lug, copper nickel plating lug.
4. the lithium ion battery according to claim 1 containing Soft Roll three-electrode structure in situ, it is characterised in that the lithium Reference electrode is shaped as rectangle or circle, and the lithium reference electrode thickness is 0.1mm ~ 1.0mm.
5. the lithium ion battery according to claim 1 containing Soft Roll three-electrode structure in situ, it is characterised in that described to draw Go out lug for one kind in aluminium pole ears, nickel lug, copper nickel plating lug.
6. the lithium ion battery according to claim 1 containing Soft Roll three-electrode structure in situ, it is characterised in that described to draw Go out lug and be provided with lithium piece, the lithium piece thickness 0.5mm, long 2cm, wide 2cm.
7. the lithium ion battery according to claim 1 containing Soft Roll three-electrode structure in situ, it is characterised in that the shell Body is plastic-aluminum shell.
CN201720962685.7U 2017-08-03 2017-08-03 A kind of lithium ion battery containing Soft Roll three-electrode structure in situ Expired - Fee Related CN207097970U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720962685.7U CN207097970U (en) 2017-08-03 2017-08-03 A kind of lithium ion battery containing Soft Roll three-electrode structure in situ

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Application Number Priority Date Filing Date Title
CN201720962685.7U CN207097970U (en) 2017-08-03 2017-08-03 A kind of lithium ion battery containing Soft Roll three-electrode structure in situ

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108630980A (en) * 2018-05-09 2018-10-09 合肥国轩高科动力能源有限公司 Lithium ion three-electrode soft package battery and testing method thereof
CN110007245A (en) * 2019-03-19 2019-07-12 合肥国轩高科动力能源有限公司 Method for detecting N/P ratio design rationality of lithium ion battery by three electrodes
CN111366852A (en) * 2020-03-26 2020-07-03 上海电气集团股份有限公司 In-situ observation method and device for charging state of graphite electrode
CN111600077A (en) * 2020-05-29 2020-08-28 重庆金康新能源汽车有限公司 Battery cell with coated lithium reference electrode and method of providing
CN112730548A (en) * 2020-12-30 2021-04-30 傲普(上海)新能源有限公司 Lithium dendrite online monitoring method and system for lithium ion battery

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108630980A (en) * 2018-05-09 2018-10-09 合肥国轩高科动力能源有限公司 Lithium ion three-electrode soft package battery and testing method thereof
CN110007245A (en) * 2019-03-19 2019-07-12 合肥国轩高科动力能源有限公司 Method for detecting N/P ratio design rationality of lithium ion battery by three electrodes
CN110007245B (en) * 2019-03-19 2021-08-06 合肥国轩高科动力能源有限公司 Method for detecting N/P ratio design rationality of lithium ion battery by three electrodes
CN111366852A (en) * 2020-03-26 2020-07-03 上海电气集团股份有限公司 In-situ observation method and device for charging state of graphite electrode
CN111600077A (en) * 2020-05-29 2020-08-28 重庆金康新能源汽车有限公司 Battery cell with coated lithium reference electrode and method of providing
CN111600077B (en) * 2020-05-29 2021-07-06 重庆金康新能源汽车有限公司 Battery cell with coated lithium reference electrode and method of providing
CN112730548A (en) * 2020-12-30 2021-04-30 傲普(上海)新能源有限公司 Lithium dendrite online monitoring method and system for lithium ion battery

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GR01 Patent grant
GR01 Patent grant
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Zhao Jiaxing

Inventor after: Wang Haoran

Inventor after: Yang Yunjie

Inventor after: Zhang Yuxi

Inventor after: Han Wenyu

Inventor before: Zhao Jiaxing

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180313