CN207061913U - A kind of desulfurization wastewater zero discharge treatment flue and processing system - Google Patents
A kind of desulfurization wastewater zero discharge treatment flue and processing system Download PDFInfo
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- CN207061913U CN207061913U CN201720732949.XU CN201720732949U CN207061913U CN 207061913 U CN207061913 U CN 207061913U CN 201720732949 U CN201720732949 U CN 201720732949U CN 207061913 U CN207061913 U CN 207061913U
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- 239000002351 wastewater Substances 0.000 title claims abstract description 86
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 69
- 230000023556 desulfurization Effects 0.000 title claims abstract description 68
- 208000028659 discharge Diseases 0.000 title claims abstract description 27
- 230000007704 transition Effects 0.000 claims abstract description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 43
- 239000003546 flue gas Substances 0.000 claims description 43
- 230000003009 desulfurizing effect Effects 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 4
- 206010022000 influenza Diseases 0.000 claims 1
- 238000001704 evaporation Methods 0.000 abstract description 21
- 230000008020 evaporation Effects 0.000 abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000428 dust Substances 0.000 abstract description 7
- 238000013517 stratification Methods 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 abstract description 4
- 239000003643 water by type Substances 0.000 abstract description 3
- 238000005373 pervaporation Methods 0.000 abstract description 2
- 238000000889 atomisation Methods 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 5
- 239000002253 acid Substances 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000004094 preconcentration Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 102000010637 Aquaporins Human genes 0.000 description 1
- 108010063290 Aquaporins Proteins 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010026 decatizing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000001640 fractional crystallisation Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
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- Treating Waste Gases (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
Abstract
The utility model discloses a kind of desulfurization wastewater zero discharge treatment flue and processing system, including horizontal connection section, vertical section and at least two branch roads, one end of horizontal connection section is provided with the first connector for being connected with air preheater, the least significant end connection of the other end and vertical section;One end connection of the most significant end branch road of vertical section, the other end of branch road are provided with the second connector being connected with deduster;The first straight section being sequentially connected, curve transition section and the second straight section are provided with every branch road, the other end of the first straight section is connected with the most significant end of the vertical section, and the other end of the second straight section sets second connector;Each section of junction is rounding off.Can make desulfurization wastewater that all exhausted waters be dripped off into pervaporation within the as far as possible short time, and be unlikely to so that liquid water droplets enter follow-up equipment, at the same ensure evaporation along journey flue occur without burn into dust stratification and fouling the problem of.
Description
Technical field
The utility model belongs to desulfurization wastewater process field, and in particular to a kind of desulfurization wastewater zero discharge treatment flue and place
Reason system.
Background technology
Technique that existing desulfurization wastewater zero-emission engineering is applied, particularly domestic and international zero discharge of industrial waste water in recent years
Engineer applied, mainly using MVR vertical falling-films evaporation+fractional crystallization forced circulation salt manufacturing crystallizer+salt manufacturing dewaterer+drying+
Automatically the technical scheme packed.Desulfurization wastewater accomplishes 180000ppm after film is reduced, by the TDS of desulfurization wastewater, then highly concentrated
Salt solution enters evaporative crystallization technique, and according to heterogeneity in salt solution, the different of solubility crystallize out salinity at different temperature
Come, produce mixed salt, realize the zero-emission of waste water.The operation of this kind of desulfuration waste water treatment process is complicated, operating cost is high, technique not into
It is ripe, and salt caused by the process is NaCl and Na2SO4Crystal salt, purity is 98% or so, it is difficult to secondary use, can also be to ring
Secondary pollution is caused in border, belongs to dangerous waste, the processing cost of dangerous waste per ton is about 3000 yuan.
Although attempting desulfurization wastewater being sprayed onto in flue in the prior art, desulfurization wastewater is carried out using the waste heat of flue gas
Heating is evaporated, and remaining flying dust is caught by deduster and removed.But due to containing substantial amounts of moisture in desulfurization wastewater, if desulfurization
Waste water is evaporated not in time in flue, and when liquid is dropped in flue inner wall, burn into dust stratification or fouling are caused to flue inner wall, or greatly
The evaporation of amount moisture makes flue gas cool-down obvious, and low-temperature corrosion is caused to flue inner wall.If the drop of evaporation not in time is with flue gas
Into in follow-up equipment, in deduster, inevitably harm can be produced to follow-up equipment, influence equipment uses the longevity
Life.Also in order to solve the problem, attempt to carry out pre-concentration to desulfurization wastewater, then desulfurization wastewater be sprayed onto in flue again
Evaporation, still, the heat of one side desulfurization wastewater pre-concentration can expend certain energy, on the other hand, desulfurization wastewater pre-concentration
System be also required to larger investment, and then improve the processing cost of desulfurization wastewater.
In summary, existing processing cost is high during desulfurization wastewater zero discharge treatment in the prior art, easily produces
Dangerous waste, the problem of corroding easily is produced to flue and follow-up equipment, still lack effective solution.
Utility model content
For technical problem present in above-mentioned prior art, the purpose of this utility model is to provide a kind of desulfurization wastewater zero
Emission treatment flue and processing system.It can make desulfurization wastewater that all exhausted waters be dripped off into pressure decatizing within the as far as possible short time
Hair, and be unlikely to so that liquid water droplets enter follow-up equipment, while ensure that evaporation occurs without burn into dust stratification and fouling along journey flue
The problem of.
In order to solve the above technical problems, the technical solution of the utility model is:
A kind of desulfurization wastewater zero discharge treatment flue, including horizontal connection section, vertical section and at least two branch roads, level is even
The one end for connecing section is provided with the first connector for being connected with air preheater, and the least significant end of the other end and vertical section connects;
One end connection of the most significant end branch road of vertical section, the other end of branch road are provided with the second connector being connected with deduster;
Be provided with the first straight section being sequentially connected, curve transition section and the second straight section on every branch road, the first straight section it is another
One end is connected with the most significant end of the vertical section, and the other end of the second straight section sets second connector;
Each section of junction is rounding off.
Desulfurization wastewater is sprayed in flue in horizontal connection section, and sprays to the vertical section of flue, desulfurization wastewater droplet
As flue gas enters the vertical section of flue, vertical section provides bigger vertical height for the evaporation of desulfurization wastewater drop, and
For flue gas when flowing through horizontal connection section and vertical section, the flue gas flow rate close to turning inwall is slow, close to corner-centric opening position
The flow velocity of flue gas is fast, and during rounding off, the speed of the flue gas in flue, pressure and temperature etc. tend to be steady, and can avoid desulfurization
Exhausted water is dropped in flue inner wall, is solved and is not evaporated complete desulfurization wastewater drop and easily fall asking on the inwall of flue
Topic.In vertical section, desulfurization wastewater water droplet will not fall in the flue inner wall of the lowermost end of vertical section, and vertical section have compared with
Big height, can provide evaporates desulfurization wastewater droplet compared with plenty of time, ensure that the evaporation efficiency of desulfurization wastewater.
The desulfurization wastewater of preliminary evaporation by vertical section has been realized in most of evaporation, when flowing through downstream leg, branch
Straight section and bending section are set on road, on the one hand the setting of bending section can increase the length in flow of flue gas path, that is, extend mist
The evaporation time of drop, can evaporating completely becomes vapor before deduster is entered, on the other hand can be to flow of flue gas
Stroke optimize, the waste water particle suspension after atomization is not rebuffed or is bottomed out in flue, flue inner wall will not be produced
Raw corrosion.
Further, the vertical section and the length of branch road ratio are 1:1-1.5.It is more beneficial for the evaporation of desulfurization wastewater.
Length herein is the length of flue centerline path.
Further, the distance between described first connector and the second connector are 32-43m.
Further, extension diameter section is connected between the vertical section and branch road, the miner diameter end and vertical section of extension diameter section are most
High-end connection, the bigger diameter end of extension diameter section connect with branch road.
Further, the second linkage section, the cross section of the second linkage section are also associated between the extension diameter section and branch road
Cross-sectional area of the product more than the bigger diameter end of extension diameter section.
Further, the cross-sectional area of second linkage section is 70-80m2。
Further, the cross-sectional area of the horizontal connection section is minimum, is 30-35m2。
The setting that each section of flue is in order to which preferably desulfurization wastewater droplet is suspended in flue, is avoided and flue inner wall
Touching, while the risk of flue internal corrosion, dust stratification and fouling can be eliminated;Each section of set-up mode and annexation simultaneously, prolong
The evaporation time of desulfurization wastewater droplet has been grown, ensure that desulfurization wastewater droplet complete evaporation.At the same time it can also ensure along journey flue
Internal temperature is higher than dew point sour in flue gas, avoids producing low-temperature corrosion to flue.
A kind of desulfurization wastewater zero-discharge treatment system, including boiler, air preheater, deduster and desulfurizing tower, air are pre-
Hot device is connected with deduster by above-mentioned flue, in the flue gas air inlet preheater of boiler discharge, with air heat-exchange, desulfurizing tower
The horizontal connection section for the above-mentioned flue that caused desulfurization wastewater is sprayed between air preheater and deduster, dry ash after being evaporated with
Flue gas is captured removing into deduster;Flue gas after dedusting discharges after entering desulfurizing tower desulfurization.
Further, desulfurization wastewater is sprayed into flue by double fluid atomization nozzle.
Further, the double fluid atomization nozzle includes air duct, waste water tunnel and shower nozzle, and air duct is with giving up
Aquaporin is connected, and air duct is connected with air compressor, and waste water tunnel is connected with waste water pump.
Desulfurization wastewater can be atomized using pressure-air.
The beneficial effects of the utility model are:
The utility model is improved the structure of the flue between air preheater and deduster, desulfurization can be made to give up
All exhausted waters are dripped off pervaporation by water within the as far as possible short time, and are unlikely to so that liquid water droplets enter follow-up equipment,
Simultaneously ensure evaporation along journey flue occur without burn into dust stratification and fouling the problem of.
Brief description of the drawings
Fig. 1 is the structural representation of desulfurization wastewater zero-discharge treatment system of the present utility model;
Fig. 2 is the structural representation of double fluid atomization nozzle of the present utility model;
Fig. 3 is the structural representation of the shower nozzle of double fluid atomization nozzle of the present utility model;
Fig. 4 is the side view figure structure schematic representation of desulfurization wastewater zero discharge treatment flue of the present utility model;
Fig. 5 is the three-dimensional figure structure schematic representation of desulfurization wastewater zero discharge treatment flue of the present utility model;
Fig. 6 is speed vector figure of the flue gas in desulfurization wastewater zero discharge treatment flue;
Fig. 7 is the movement locus figure that exhausted water is dropped in flue;
Fig. 8 is along journey walling of flue temperature profile;
Fig. 9 is the temperature profile of deduster entrance.
Wherein, 1, boiler, 2, air preheater, 3, deduster, 4, desulfurizing tower, 5, filter press, 6, chimney, 7, waste water pump,
8th, air compressor, 9, waste water inlet, 10, air intlet, 11, flange, 12, shower nozzle, 13, extension diameter section, 14, tie point, 15,
Second branch road, 16, vertical section, 17, horizontal connection section.
Embodiment
It is noted that described further below is all exemplary, it is intended to provides further instruction to the application.It is unless another
Indicate, all technologies used herein and scientific terminology are with usual with the application person of an ordinary skill in the technical field
The identical meanings of understanding.
It should be noted that term used herein above is merely to describe embodiment, and be not intended to restricted root
According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singulative
It is also intended to include plural form, additionally, it should be understood that, when in this manual using term "comprising" and/or " bag
Include " when, it indicates existing characteristics, step, operation, device, component and/or combinations thereof.
As shown in figure 1, a kind of desulfurization wastewater zero-discharge treatment system, including it is boiler 1, air preheater 2, deduster 3, de-
Sulphur tower 4 and chimney 6, the flue after air preheater 2 is improved with deduster 3 by the utility model connect, the cigarette that boiler 1 is discharged
Cool in gas air inlet preheater 2 with air heat-exchange, flue gas after heat exchange, desulfurization wastewater caused by desulfurizing tower 4 sprays into empty
In flue between air preheater 2 and deduster 3, dry ash after being evaporated is captured removing with flue gas into deduster 3;After dedusting
Flue gas enter the desulfurization of desulfurizing tower 4 after discharged from chimney 6.Desulfurization wastewater caused by desulfurization takes off by sedimentation and the press filtration of filter press 5
After water, gypsum is obtained.
Desulfurization wastewater zero discharge treatment flue, including horizontal connection section 17, vertical section 16, the branch road of tie point 14 and second
15, one end of horizontal connection section 17 is provided with the first connector for being connected with air preheater 2, the other end and vertical section 16
Least significant end connection;The most significant end of vertical section 16 is connected with the miner diameter end of extension diameter section 13, the bigger diameter end of the extension diameter section of extension diameter section 13
It is connected with the second linkage section, the cross-sectional area of the second linkage section is more than the cross-sectional area of the bigger diameter end of extension diameter section, the second linkage section
Cross-sectional area be 74m2, the cross-sectional area of horizontal connection section 17 is minimum, is 31m2.The other end of second linkage section and first
The branch road 15 of road 14 and second connects, and the other end of the branch road 15 of tie point 14 and second is provided be connected with deduster 3
Two connectors.
As shown in Figure 4 and Figure 5, it is straight that the first straight section being sequentially connected, curve transition section and second are provided with every branch road
Section, the other end of the first straight section are connected with the most significant end of the vertical section, and the other end of the second straight section sets second connection
Part;Each section of junction is rounding off.The length ratio of vertical section 16 and branch road is 1:1-1.5.First connector and second
The distance between connector is 32-43m.As, the length of the flue centerline path between air preheater 2 and deduster 3
For 32-43m.
As shown in Figures 2 and 3, desulfurization wastewater is sprayed into flue by double fluid atomization nozzle, double fluid atomization nozzle bag
Air duct, waste water tunnel and shower nozzle 12 are included, air intlet 10 is provided with air duct, being provided with waste water on waste water tunnel enters
Mouth 9, air duct is connected with waste water tunnel, and air duct is connected with air compressor 8, and waste water tunnel is connected with waste water pump 7, is given up
Water pump 7 connects with waste water tank caused by desulfurizing tower 4.
CFD sunykatuib analyses are carried out to flue gas using the system after improvement, analysis result is as shown in table 1.
Table 1
Sequence number | Project | Numerical value | Unit |
1 | Along journey flue gas peak flow rate (PFR) | 32.8 | m/s |
2 | Along journey flue gas lowest speed | 0.163 | m/s |
3 | Air preheater exports mean flow rate | 5.83 | m/s |
4 | Deduster entrance mean flow rate | 11.864 | m/s |
As shown in fig. 6, the structure of flue is optimized the utility model, that is, flue interior flow field is optimized, makes cigarette
Road internal speed, pressure and temp region are steady, avoid waste water spray into after due to the turbulent flow of flue gas, cause waste water droplet to touch flue
Inwall, eliminate the risk of flue internal corrosion, dust stratification and fouling.
As shown in fig. 7, atomization, desulfurization wastewater direction are sprayed in the horizontal connection section 17 of flue of the desulfurization wastewater after improvement
Vertical section 16 is sprayed, and the drop after atomization accelerates in vertical section 16, and is heated and evaporates most of moisture, when atomized drop enters
When entering extension diameter section 13, the amount of droplets in flue gas significantly reduces, the base into the flue gas in the branch road 15 of tie point 14 and second
Originally atomized drop is not contained, shows that the drop in flue gas is evaporated completely.
Fig. 8 is along journey walling of flue temperature profile, in horizontal connection section 17 and vertical section 16, atomized drop in flue gas
Content is larger, and now the temperature of the flue gas near flue inner wall is very high, and flue inner wall can be avoided to produce low-temperature corrosion, the
In one branch road 14 and the second branch road 15, the temperature of flue gas has declined, but more than the sour dew point in flue gas, and now cigarette
There is no drop substantially in gas, can avoid the inwall of flue that corrosion and scale formation occurs.
As shown in figure 9, the temperature of the flue gas entered by two branch roads in deduster 3 is uniform, and temperature is higher,
The dew point higher than acid along journey flue internal temperature is may insure, avoids flue that low-temperature corrosion occurs, as shown in below table data.
Table 2
Unit load | Flue gas flow | Flue-gas temperature | Flue-gas temperature reduction amount | Flue-gas temperature after evaporating waste water |
BMCR | 2968018m3/h | 137℃ | 6.25℃ | 130.75℃ |
75%THA | 2073525m3/h | 128℃ | 7.29℃ | 120.71℃ |
40%THA | 1359073m3/h | 121℃ | 7.65℃ | 113.35℃ |
Table 3
Load | Flue gas volume flow | Flue gas volume flow after evaporating waste water |
BMCR | 2968018m3/h | 2922790m3/h |
75%THA | 2073525m3/h | 2035843m3/h |
40%THA | 1359073m3/h | 1332695m3/h |
Table 4
Load | Deduster inlet flue gas flow velocity | Deduster inlet flue gas flow velocity after evaporating waste water |
BMCR | 11.684 | 11.506 |
75%THA | 8.163 | 8.015 |
40%THA | 5.350 | 5.247 |
Table 5
Load | Humidity of flue gas | Humidity of flue gas after evaporating waste water |
BMCR | 9.23% | 9.61% |
75%THA | 9.23% | 9.68% |
40%THA | 9.23% | 9.71% |
Table 6
Coal | Acid dew point | Acid dew point after evaporating waste water |
BMCR | 101.57℃ | 109.50℃ |
75%THA | 101.57℃ | 109.65℃ |
40%THA | 101.57℃ | 109.71℃ |
The preferred embodiment of the application is the foregoing is only, is not limited to the application, for the skill of this area
For art personnel, the application can have various modifications and variations.It is all within spirit herein and principle, made any repair
Change, equivalent substitution, improvement etc., should be included within the protection domain of the application.
Claims (10)
- A kind of 1. desulfurization wastewater zero discharge treatment flue, it is characterised in that:Including horizontal connection section, vertical section and at least two branch Road, one end of horizontal connection section are provided with the first connector for being connected with air preheater, and the other end and vertical section are most Low side connects;One end connection of the most significant end branch road of vertical section, the other end of branch road are provided with second be connected with deduster and connected Fitting;The first straight section being sequentially connected, curve transition section and the second straight section, the other end of the first straight section are provided with every branch road It is connected with the most significant end of the vertical section, the other end of the second straight section sets second connector;Each section of junction is rounding off.
- 2. desulfurization wastewater zero discharge treatment flue according to claim 1, it is characterised in that:The vertical section and branch road Length ratio is 1:1-1.5.
- 3. desulfurization wastewater zero discharge treatment flue according to claim 1, it is characterised in that:First connector and The distance between two connectors are 32-43m.
- 4. desulfurization wastewater zero discharge treatment flue according to claim 1, it is characterised in that:The vertical section and branch road it Between be connected with extension diameter section, the miner diameter end of extension diameter section connects with the most significant end of vertical section, and the bigger diameter end of extension diameter section connects with branch road.
- 5. desulfurization wastewater zero discharge treatment flue according to claim 4, it is characterised in that:The extension diameter section and branch road it Between be also associated with the second linkage section, the cross-sectional area of the second linkage section is more than the cross-sectional area of the bigger diameter end of extension diameter section.
- 6. desulfurization wastewater zero discharge treatment flue according to claim 5, it is characterised in that:The horizontal stroke of second linkage section Sectional area is 70-80m2。
- 7. desulfurization wastewater zero discharge treatment flue according to claim 6, it is characterised in that:The horizontal stroke of the horizontal connection section Sectional area is minimum, is 30-35m2。
- A kind of 8. desulfurization wastewater zero-discharge treatment system, it is characterised in that:Including boiler, air preheater, deduster and desulfurization Tower, air preheater and deduster are connected by any flues of claim 1-7, and the flue gas air inlet of boiler discharge is pre- In hot device, the level of the flue sprayed into air heat-exchange, desulfurization wastewater caused by desulfurizing tower between air preheater and deduster Linkage section, dry ash after being evaporated are captured removing with flue gas into deduster;Flue gas after dedusting enters desulfurizing tower desulfurization heel row Put.
- 9. desulfurization wastewater zero-discharge treatment system according to claim 8, it is characterised in that:Desulfurization wastewater passes through two-fluid Atomizer is sprayed into flue.
- 10. desulfurization wastewater zero-discharge treatment system according to claim 9, it is characterised in that:The twin spray Mouth includes air duct, waste water tunnel and shower nozzle, and air duct connects with waste water tunnel, and air duct connects with air compressor Connect, waste water tunnel is connected with waste water pump.
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