CN206692497U - A kind of bitter recycling treatment system - Google Patents

A kind of bitter recycling treatment system Download PDF

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Publication number
CN206692497U
CN206692497U CN201720120588.3U CN201720120588U CN206692497U CN 206692497 U CN206692497 U CN 206692497U CN 201720120588 U CN201720120588 U CN 201720120588U CN 206692497 U CN206692497 U CN 206692497U
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China
Prior art keywords
bitter
pool
sun
exposed
outlet
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CN201720120588.3U
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Chinese (zh)
Inventor
谈宾宾
黄传敏
任秉康
朱元红
李文扬
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Hangzhou Top Environmental Polytron Technologies Inc
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Hangzhou Top Environmental Polytron Technologies Inc
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Abstract

The utility model discloses a kind of bitter recycling treatment system, including:Bitter regulating reservoir, desalter, reaction tank, filter-pressing device;Divide salt device, divide the entrance of salt device to be connected with the supernatant outlet of reaction tank;First is exposed to the sun the pool, and the first entrance for being exposed to the sun the pool is connected with dividing the permeate of salt device to export, and the first outlet for being exposed to the sun the pool is connected with the first MVR evaporation and crystallization systems;And second be exposed to the sun the pool, second be exposed to the sun the pool entrance with dividing the concentrated solution outlet of salt device to be connected, the second outlet for being exposed to the sun the pool is connected with the 2nd MVR evaporation and crystallization systems.The utility model reduces the requirement of system influent quality, reduces the cost of investment and operating cost of reaction tank by setting desalter;By dividing salt device to carry out a point salt to the concentrate of bitter, it is possible to achieve solventing-out, be the NaCl and Na for subsequently obtaining high-purity2SO4Offer condition, realize the recycling of chemical substance in bitter.

Description

A kind of bitter recycling treatment system
Technical field
The utility model belongs to bitter utilization of resources field, more particularly, to a kind of bitter recycling treatment system.
Background technology
China is the country of a serious water shortage, per capita water resources quantity about 2400m3, it is only whole world water per capita 1/4, and spatial and temporal distributions are uneven, and water environment pollution is more serious, and primary poor-quality water distribution area is wide, especially in northwest drought Land area, because precipitation is rare, evaporation is strong, and water resource is naturally deficient, as the underground water of main resource of water supply, generally contains Salt, fluorinated volume is high, and most area is again without alternative freshwater resources.Because water quality is inferior, mouthfeel extreme difference, or even can not drink With wherein many index does not meet or do not reached country《Sanitary standard for drinking water》, show as high salt concentration alkali composition, or even table It is now high rigidity, high fluorine, high arsenic, high ferrimanganic, low iodine, low selenium feature, has for many years had a strong impact on the life of the local people masses Bioplasm amount and body health level, it can be seen that diseases prevention changes the urgency and necessity of water.
The desalination of bitter is actually saline-water reclamation, brine desalination is desalinated or is reached after processing and drinks water gauge It is accurate.At present, domestic the Northwest's method for desalting brackish water mainly has the way of distillation, electric drive embrane method, hyperfiltration etc..Bitter is light Contain a large amount of salinities and mineral resources after change in strong brine, how to improve the economy of brackish water desalination engineering is in current industry One of research direction.
Electric drive membrane technology refers in the case where electric field force acts on ion by the membrane separating process of selective ion exchange membrane, its Core is anion and cation exchange membrane, i.e., only allows cation using cation-exchange membrane by the way that anion-exchange membrane is only permitted Perhaps the characteristic that anion passes through carries out the technology of Selective Separation to effects of ion.Under electric field force effect, the moon in solution Directional migration occurs for cation, and another part water body is moved to from a part of water body, so as to reach solution separation, purification and concentration Mesh.
Film evaporation is that one kind using Hollow-fibre membranes material was flow medium, improves gas-liquid two-phase contact area with this, carries A kind of technology of high-moisture evaporation rate.Unit volume strong brine can be substantially reduced using film evaporation technique by evaporation to reach The floor space needed for purpose is concentrated, can also reduce evaporation time to a certain extent, improve the efficiency of evaporation and concentration.
The content of the invention
The purpose of this utility model is, for the deficiencies in the prior art, there is provided at a kind of bitter recycling Reason system.
Therefore, above-mentioned purpose of the present utility model is achieved through the following technical solutions:
A kind of bitter recycling treatment system, the bitter recycling treatment system include:
- bitter regulating reservoir, bitter is passed through in the bitter regulating reservoir;
- desalter, the entrance of the desalter are connected with the outlet of bitter regulating reservoir;
- reaction tank, the reaction tank are connected with the concentrated solution outlet of desalter;
- filter-pressing device, the entrance of the filter-pressing device are connected with the precipitation outlet of reaction tank;
- divide salt device, it is described to divide the entrance of salt device to be connected with the supernatant outlet of reaction tank;
- the first is exposed to the sun the pool, and the described first entrance for being exposed to the sun the pool is connected with dividing the permeate of salt device to export, and described the One outlet for being exposed to the sun the pool is connected with the first MVR evaporation and crystallization systems;
And
- the second is exposed to the sun the pool, described second be exposed to the sun the pool entrance with dividing the concentrated solution outlet of salt device to be connected, described Two outlets for being exposed to the sun the pool are connected with the 2nd MVR evaporation and crystallization systems.
The utility model provides a kind of bitter recycling treatment system, by setting desalter, reduces system water inlet Water quality requirement, reduce the cost of investment and operating cost of reaction tank;By dividing salt device to carry out a point salt to the concentrate of bitter, Solventing-out can be realized, is the NaCl and Na for subsequently obtaining high-purity2SO4Premise is provided, realizes chemical substance in bitter Recycling, NaCl purity reach national two level Nacl standard(>97.5%), Na2SO4Purity reach national two class Grade As Standard(>98.0%).
While using above-mentioned technical proposal, the utility model can also be used or combined using further below Technical scheme:
The desalter is electric drive film device, and the desalination solution of electric drive film device is used as agricultural irrigation.
NaOH and Na are added in the reaction tank2CO3
The pressing filtering liquid outlet of the filter-pressing device is connected with bitter regulating reservoir.
Described point of salt device is nanofiltration device, and the NF membrane of the nanofiltration device is a multivalent ion seperation film.
Described first, which is exposed to the sun in the pool, sets the first film evaporator, and first film evaporator sets hydrophobic doughnut Film.
Set on connecting pipe between the outlet of first film evaporator and the entrance of the first MVR evaporation and crystallization systems Put the first filter.
Described second, which is exposed to the sun in the pool, sets the second film evaporator, and second film evaporator sets hydrophobic doughnut Film.
Set on connecting pipe between the outlet of second film evaporator and the entrance of the 2nd MVR evaporation and crystallization systems Put the second filter.
The bitter recycling treatment system also includes freezing and crystallizing system, the entrance of the freezing and crystallizing system and Two outlets for being exposed to the sun the pool are connected, and the mother liquor outlet of the freezing and crystallizing system is connected with second pool of being exposed to the sun.
Bitter recycling treatment system provided by the utility model first by being exposed to the sun in the pool and second is exposed to the sun the pool First film evaporator and the second film evaporator are inside set respectively, the floor space on the pool of being exposed to the sun can be reduced, improves the steaming of water Send out efficiency;By setting freezing and crystallizing system, so as to which winter can realize Na2SO4Crystallization, reduce its production run cost;It is logical Electric drive film device+nanofiltration device+is crossed to be exposed to the sun the coupling of the pool/film evaporator+MVR evaporation and crystallization systems+freezing and crystallizing system Mode, which obtains bitter recycling treatment system, can realize to brackish water desalination and " zero-emission " processing, both obtain freshwater resources And can enough utilizes the chemical resource in bitter.
Brief description of the drawings
Fig. 1 is a kind of bitter recycling treatment system provided by the utility model;
In figure:101- bitter regulating reservoirs;201- electric drive film devices;301- reaction tanks;401- filter-pressing devices;501- receives Filter device;601- first is exposed to the sun the pool;The film evaporators of 602- first;611- second is exposed to the sun the pool;The film evaporators of 612- second; The MVR evaporation and crystallization systems of 701- the first;The MVR evaporation and crystallization systems of 711- the 2nd;The filters of 801- first;811- second is filtered Device;901- freezing and crystallizing systems.
Embodiment
The utility model is described in further detail with specific embodiment referring to the drawings.
A kind of bitter recycling treatment system, including:
- bitter regulating reservoir 101, bitter is passed through in bitter regulating reservoir 101;
- desalter, the entrance of desalter are connected with the outlet of bitter regulating reservoir 101;
- reaction tank 301, reaction tank 301 are connected with the concentrated solution outlet of desalter;
- filter-pressing device 401, the entrance of filter-pressing device 401 are connected with the precipitation outlet of reaction tank 301;
- divide salt device, divide the entrance of salt device to be connected with the supernatant outlet of reaction tank;
- the first is exposed to the sun the pool 601, and the first entrance for being exposed to the sun the pool 601 is connected with dividing the permeate of salt device to export, and first The be exposed to the sun outlet on the pool 601 is connected with the first MVR evaporation and crystallization systems 701;
And
- the second is exposed to the sun the pool 611, second be exposed to the sun the pool 611 entrance with dividing the concentrated solution outlet of salt device to be connected, second The be exposed to the sun outlet on the pool 611 is connected with the 2nd MVR evaporation and crystallization systems 711.
Desalter is electric drive film device 201, and the desalination solution of electric drive film device is used as agricultural irrigation.
NaOH and Na are added in reaction tank 3012CO3
The pressing filtering liquid outlet of filter-pressing device 401 is connected with bitter regulating reservoir 101.
It is nanofiltration device 501 to divide salt device, and the NF membrane of nanofiltration device 501 is a multivalent ion seperation film.
First, which is exposed to the sun in the pool 601, sets the first film evaporator 602, and the first film evaporator 602 sets hydrophobic hollow fibre Tie up film.
On connecting pipe between the outlet of first film evaporator 602 and the entrance of the first MVR evaporation and crystallization systems 701 First filter 801 is set.
Second, which is exposed to the sun in the pool 611, sets the second film evaporator 612, and the second film evaporator 612 sets hydrophobic hollow fibre Tie up film.
On connecting pipe between the outlet of second film evaporator 612 and the entrance of the 2nd MVR evaporation and crystallization systems 711 Second filter 811 is set.
Bitter recycling treatment system also includes freezing and crystallizing system 901, the entrance of freezing and crystallizing system 901 and second The be exposed to the sun outlet on the pool 611 is connected, and the mother liquor outlet of freezing and crystallizing system 901 is connected with second pool 611 of being exposed to the sun.
Above-mentioned embodiment is used for illustrating the utility model, preferred embodiment only of the present utility model, and It is not that the utility model is limited, it is new to this practicality in spirit of the present utility model and scope of the claims Any modification, equivalent substitution and improvements that type is made etc., both fall within the scope of protection of the utility model.

Claims (10)

1. a kind of bitter recycling treatment system, it is characterised in that the bitter recycling treatment system includes:
- bitter regulating reservoir, bitter is passed through in the bitter regulating reservoir;
- desalter, the entrance of the desalter are connected with the outlet of bitter regulating reservoir;
- reaction tank, the reaction tank are connected with the concentrated solution outlet of desalter;
- filter-pressing device, the entrance of the filter-pressing device are connected with the precipitation outlet of reaction tank;
- divide salt device, it is described to divide the entrance of salt device to be connected with the supernatant outlet of reaction tank;
- the first is exposed to the sun the pool, and the described first entrance for being exposed to the sun the pool is connected with dividing the permeate of salt device to export, and described first is sudden and violent The outlet for shining the pool is connected with the first MVR evaporation and crystallization systems;
And
- the second is exposed to the sun the pool, described second be exposed to the sun the pool entrance with dividing the concentrated solution outlet of salt device to be connected, described second is sudden and violent The outlet for shining the pool is connected with the 2nd MVR evaporation and crystallization systems.
2. a kind of bitter recycling treatment system according to claim 1, it is characterised in that the desalter is electricity Drive film device.
3. a kind of bitter recycling treatment system according to claim 1, it is characterised in that added in the reaction tank NaOH and Na2CO3
A kind of 4. bitter recycling treatment system according to claim 1, it is characterised in that the pressure of the filter-pressing device Filtrate (liquid is connected with bitter regulating reservoir.
5. a kind of bitter recycling treatment system according to claim 1, it is characterised in that described to divide salt device to receive Device is filtered, the NF membrane of the nanofiltration device is a multivalent ion seperation film.
6. a kind of bitter recycling treatment system according to claim 1, it is characterised in that described first is exposed to the sun in the pool First film evaporator is set, and first film evaporator sets hydrophobic hollow fiber membrane.
A kind of 7. bitter recycling treatment system according to claim 6, it is characterised in that the first film evaporation dress The first filter is set on connecting pipe between the outlet put and the entrance of the first MVR evaporation and crystallization systems.
8. a kind of bitter recycling treatment system according to claim 1, it is characterised in that described second is exposed to the sun in the pool Second film evaporator is set, and second film evaporator sets hydrophobic hollow fiber membrane.
A kind of 9. bitter recycling treatment system according to claim 8, it is characterised in that the second film evaporation dress The second filter is set on connecting pipe between the outlet put and the entrance of the 2nd MVR evaporation and crystallization systems.
10. according to a kind of above bitter recycling treatment system described in any one claim, it is characterised in that described Bitter recycling treatment system also includes freezing and crystallizing system, and the entrance of the freezing and crystallizing system is exposed to the sun the going out of the pool with second Mouthful it is connected, the mother liquor outlet of the freezing and crystallizing system is connected with second pool of being exposed to the sun.
CN201720120588.3U 2017-02-09 2017-02-09 A kind of bitter recycling treatment system Active CN206692497U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110304778A (en) * 2019-07-17 2019-10-08 青岛沃赛海水淡化科技有限公司 A kind of bitter treatment process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110304778A (en) * 2019-07-17 2019-10-08 青岛沃赛海水淡化科技有限公司 A kind of bitter treatment process

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GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: Bitter resourceful treatment system

Effective date of registration: 20180621

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY CO.,LTD.

Registration number: 2018330000158

PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20190613

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY CO.,LTD.

Registration number: 2018330000158

PC01 Cancellation of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: Bitter resourceful treatment system

Effective date of registration: 20190617

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY CO.,LTD.

Registration number: 2019330000161

PE01 Entry into force of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20210724

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY Co.,Ltd.

Registration number: 2019330000161

PC01 Cancellation of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: A brackish water resource treatment system

Effective date of registration: 20210810

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY Co.,Ltd.

Registration number: Y2021330001089

PE01 Entry into force of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20220927

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY CO.,LTD.

Registration number: Y2021330001089

PC01 Cancellation of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: A resource treatment system for brackish water

Effective date of registration: 20221020

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY CO.,LTD.

Registration number: Y2022330002569

PE01 Entry into force of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY CO.,LTD.

Registration number: Y2022330002569

PC01 Cancellation of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: A Bitter Salt Water Resource Treatment System

Granted publication date: 20171201

Pledgee: China Everbright Bank Limited by Share Ltd. Hangzhou Yuhang sub branch

Pledgor: SUNUP ENVIRONMENTAL TECHNOLOGY CO.,LTD.

Registration number: Y2024980010904

PE01 Entry into force of the registration of the contract for pledge of patent right