CN206616276U - A kind of electrolysis chlorine dioxide generator - Google Patents

A kind of electrolysis chlorine dioxide generator Download PDF

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Publication number
CN206616276U
CN206616276U CN201720248004.0U CN201720248004U CN206616276U CN 206616276 U CN206616276 U CN 206616276U CN 201720248004 U CN201720248004 U CN 201720248004U CN 206616276 U CN206616276 U CN 206616276U
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reaction vessels
plane
chlorine dioxide
anode chamber
inlet
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CN201720248004.0U
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朱文英
张鑫
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Weifang Shun Shun Environmental Protection Technology Co Ltd
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Weifang Shun Shun Environmental Protection Technology Co Ltd
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Abstract

The utility model proposes several electrolytic cells with hollow structure in a kind of electrolysis chlorine dioxide generator, including reaction vessels, reaction vessels;There are cathode chamber and anode chamber in electrolytic cell;Reaction vessels are provided with running water water inlet and electrolysed saline solution inlet;Bottom of electrolytic tank is with the first inclined-plane from centre to cathode chamber side and from centre to the second inclined-plane of anode chamber side;Lowest part on the inclined-plane of cathode chamber bottom first is provided with cathode chamber leakage fluid dram, and the lowest part on the inclined-plane of anode chamber bottom second is provided with anode chamber's leakage fluid dram;The reaction vessels bottom is exported provided with hydrogen outlet and sodium hydroxide.The utility model reasonable in design, it is safe and convenient to use, reliability is high, it is sufficiently stirred for merging electrolysed saline solution using circulating pump, ensure reaction efficiency, ion exchange resin soft water processor can effectively filter out the materials such as solubility calcium, the magnesium compound in running water, and the concentration into the chlorine dioxide of production has been effectively ensured.

Description

A kind of electrolysis chlorine dioxide generator
Technical field
The utility model is related to electrolysis unit technical field, more particularly to a kind of electrolysis chlorine dioxide generator.
Background technology
Electrolysis chlorine dioxide generator is that the nineties introduce advanced production technology from the U.S., through production domesticization, series Change and upgrade by technological improvement and produce on the basis of former series of products, although have been achieved with automatically controlling and run now, energy According to the start, unused time automatic running being previously set, the temperature for cooling down electrolysis and timing can be operationally monitored automatically certainly Discharge spent lye is moved, but the electrolytic efficiency of electrolytic cell used has some limitations, and controllability is not high, and using effect is not Ideal, due to generally using Nacl for electrolysis raw material, the disinfection composition generated in anode chamber has chlorine dioxide, chlorine, ozone With hydrogen peroxide etc., therefore, the electrolysis chlorine dioxide generator that in the market is used, the purity for generating chlorine dioxide is not high, Its yield is relatively low, second-rate, while also there is spent lye discharges halfway defect.
The content of the invention
The utility model is intended to overcome the above-mentioned defect deposited in the prior art, proposes that a kind of electrolysis chlorine dioxide occurs Device.
What the technical solution of the utility model was realized in:
Several electricity with hollow structure in a kind of electrolysis chlorine dioxide generator, including reaction vessels, reaction vessels Solve groove;The electrolyte bath is separated into the cathode chamber and the sun of electrolysed saline solution for being loaded with running water after softening by barrier film Pole room;The reaction vessels are provided with running water water inlet and electrolysed saline solution inlet, and the cathode chamber of each electrolytic cell passes through soft Pipe is connected with running water water inlet, and anode chamber is connected by flexible pipe with the electrolysed saline solution inlet;The bottom of electrolytic tank With the first inclined-plane from centre to cathode chamber side and from centre to the second inclined-plane of anode chamber side;In the negative electrode The lowest part on the inclined-plane of room bottom first is provided with cathode chamber leakage fluid dram, and the lowest part on the inclined-plane of anode chamber bottom second is arranged provided with anode chamber Liquid mouthful;The reaction vessels bottom is exported provided with hydrogen outlet and sodium hydroxide.
Further, the sodium hydroxide outlet is below the hydrogen outlet.
Further, the reaction vessels bottom has inclined-plane, lowest part of the sodium hydroxide outlet positioned at the inclined-plane.
Further, it is respectively equipped with a metering on the running water water inlet and electrolysed saline solution inlet of the reaction vessels Pump.
Further, the reaction vessels are provided with ion exchange resin soft water processor, and its water inlet connection running water is supplied Water pipe, the running water water inlet of delivery port coupled reaction vessel.
Further, the reaction vessels are provided with dissolved salt device, and the dissolved salt device includes circulating pump and is loaded with chloride Change the flexible pipe connected on sodium and the salt box of sodium chlorite solution, the inlet and liquid outlet of the circulating pump and stretch into the salt box Below interior liquid level;The salt box is connected by pipeline with the electrolysed saline solution inlet, and its bottom is provided with sewage draining exit.
Above-mentioned technical proposal is employed, the beneficial effects of the utility model are:
The utility model reasonable in design, using conveniently, safely, reliably, fusion electrolysis is sufficiently stirred for using circulating pump Salting liquid, it is ensured that reaction efficiency, ion exchange resin soft water processor can effectively filter out solubility calcium, magnesium in running water The materials such as compound, have been effectively ensured the concentration into the chlorine dioxide of production.
Brief description of the drawings
, below will be to embodiment in order to illustrate more clearly of the utility model embodiment or technical scheme of the prior art Or the accompanying drawing used required in description of the prior art is briefly described, it should be apparent that, drawings in the following description are only It is some embodiments of the present utility model, for those of ordinary skill in the art, before creative labor is not paid Put, other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is structural representation of the present utility model.
Wherein:1- reaction vessels;2- electrolytic cells;3- barrier films;4- cathode chambers;5- anode chambers;6- running water water inlets;7- electricity Solve salting liquid inlet;The inclined-planes of 8- first;The inclined-planes of 9- second;10- cathode chamber leakage fluid drams;11- anode chambers leakage fluid dram;12- hydrogen Outlet;13- sodium hydroxides are exported;14- measuring pumps;15- water inlets;16- delivery ports;17- circulating pumps;18- salt box;19- blowdowns Mouthful.
Embodiment
Below in conjunction with the accompanying drawing in the utility model embodiment, the technical scheme in the utility model embodiment is carried out Clearly and completely describe, it is clear that described embodiment is only a part of embodiment of the utility model, rather than whole Embodiment.Based on the embodiment in the utility model, those of ordinary skill in the art are not under the premise of creative work is made The every other embodiment obtained, belongs to the scope of the utility model protection.
A kind of electrolysis chlorine dioxide generator, as shown in figure 1, having including several in reaction vessels 1, reaction vessels 1 The electrolytic cell 2 of hollow structure;Be separated into inside the electrolytic cell 2 by barrier film 3 be loaded with the cathode chamber 4 of running water after softening, with And the anode chamber 5 of electrolysed saline solution;The reaction vessels 1 are provided with running water water inlet 6 and electrolysed saline solution inlet 7, respectively The cathode chamber of electrolytic cell 2 is connected by flexible pipe with running water water inlet, and anode chamber passes through flexible pipe and the electrolysed saline solution feed liquor Mouth connection.
The bottom of electrolytic cell 2 has the first inclined-plane 8 from from centre to cathode chamber side and from centre to anode chamber one Second inclined-plane 9 of side;Lowest part on first inclined-plane of cathode chamber bottom 8 is provided with cathode chamber leakage fluid dram 10, anode chamber bottom The lowest part on the second inclined-plane 9 is provided with anode chamber's leakage fluid dram 11, and running water and electrolysed saline solution can be discharged more thoroughly, in electrolysis Trench bottom will not depositing contaminants, it is ensured that the chlorine dioxide concentration produced in course of reaction is higher.
In addition, the bottom of reaction vessels 1 is provided with hydrogen outlet 12 and sodium hydroxide outlet 13.Above-mentioned sodium hydroxide outlet 13 in the lower section of hydrogen outlet 12, and hydrogen density is small, is discharged from sodium hydroxide top.
It is pointed out that above-mentioned electrolytic cell is enclosed construction, produced disinfection by chlorine dioxide gas will not be let out Reveal in environment, environment will not be polluted, while cathode chamber is completely separable with air in electrolytic process, produced hydrogen The danger of blast is not present in gas, and security is greatly improved.
The above-mentioned bottom of reaction vessels 1 has inclined-plane, and the sodium hydroxide outlet 13 is located at the lowest part on the inclined-plane, hydroxide It is more thorough that sodium is discharged, easy to operate.
A measuring pump 14 is respectively equipped with the running water water inlet 6 and electrolysed saline solution inlet 7 of above-mentioned reaction vessels 1, The quantity delivered of running water and electrolysed saline solution can accurately be controlled.
Above-mentioned reaction vessels 1 are provided with ion exchange resin soft water processor, and its water inlet 15 connects tap water supply pipe, The running water water inlet 6 of the coupled reaction vessel of delivery port 16.Ion exchange resin soft water processor can effectively filter out running water In the material such as solubility calcium, magnesium compound, while improving electrolytic efficiency, be effectively ensured into the dense of the chlorine dioxide of production Degree.
Above-mentioned reaction vessels 1 are provided with dissolved salt device, and the dissolved salt device includes circulating pump 17 and is loaded with sodium chloride-containing With the salt box 18 of sodium chlorite solution, the flexible pipe connected on the inlet and liquid outlet of the circulating pump 17 stretches into the salt box Below interior liquid level;The salt box 18 is connected by pipeline with the electrolysed saline solution inlet 7, and its bottom is provided with sewage draining exit 19, Waste liquid is discharged by sewage draining exit timing.
Electrolytic cell is enclosed construction in the utility model, and produced disinfection by chlorine dioxide gas will not be leaked to environment In, environment will not be polluted, while cathode chamber is completely separable with air in electrolytic process, produced hydrogen is not present The danger of blast, security is greatly improved, therefore, and using conveniently, safely, reliably, fusion electrolysis is sufficiently stirred for using circulating pump Salting liquid, it is ensured that reaction efficiency, while the purity of chlorine dioxide of generation is high.
Preferred embodiment of the present utility model is the foregoing is only, it is all at this not to limit the utility model Within the spirit and principle of utility model, any modification, equivalent substitution and improvements made etc. should be included in the utility model Protection domain within.

Claims (6)

1. a kind of electrolysis chlorine dioxide generator, it is characterised in that:Including several with hollow in reaction vessels, reaction vessels The electrolytic cell of structure;The electrolyte bath is separated into the cathode chamber and electrolytic salt for being loaded with running water after softening by barrier film The anode chamber of solution;The reaction vessels are provided with running water water inlet and electrolysed saline solution inlet, the negative electrode of each electrolytic cell Room is connected by flexible pipe with running water water inlet, and anode chamber is connected by flexible pipe with the electrolysed saline solution inlet;The electricity Trench bottom is solved with the first inclined-plane from centre to cathode chamber side and from centre to the second inclined-plane of anode chamber side; The lowest part on the inclined-plane of cathode chamber bottom first is provided with cathode chamber leakage fluid dram, and the lowest part on the inclined-plane of anode chamber bottom second is provided with Anode chamber's leakage fluid dram;The reaction vessels bottom is exported provided with hydrogen outlet and sodium hydroxide.
2. a kind of electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:The sodium hydroxide outlet Below the hydrogen outlet.
3. a kind of electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:The reaction vessels bottom With inclined-plane, lowest part of the sodium hydroxide outlet positioned at the inclined-plane.
4. a kind of electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:The reaction vessels from A measuring pump is respectively equipped with water water inlet and electrolysed saline solution inlet.
5. a kind of electrolysis chlorine dioxide generator according to claim 1 or 4, it is characterised in that:The reaction vessels Be provided with ion exchange resin soft water processor, its water inlet connection tap water supply pipe, delivery port coupled reaction vessel from Water water inlet.
6. a kind of electrolysis chlorine dioxide generator according to claim 1 or 4, it is characterised in that:The reaction vessels Dissolved salt device is provided with, the dissolved salt device includes circulating pump and is loaded with sodium chloride-containing and the salt box of sodium chlorite solution, institute The flexible pipe connected on the inlet and liquid outlet of circulating pump is stated to stretch into the salt box below liquid level;The salt box passes through pipeline It is connected with the electrolysed saline solution inlet, its bottom is provided with sewage draining exit.
CN201720248004.0U 2017-03-15 2017-03-15 A kind of electrolysis chlorine dioxide generator Active CN206616276U (en)

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CN201720248004.0U CN206616276U (en) 2017-03-15 2017-03-15 A kind of electrolysis chlorine dioxide generator

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Application Number Priority Date Filing Date Title
CN201720248004.0U CN206616276U (en) 2017-03-15 2017-03-15 A kind of electrolysis chlorine dioxide generator

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CN206616276U true CN206616276U (en) 2017-11-07

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109055966A (en) * 2018-09-13 2018-12-21 北京化工大学 A kind of chemical combined method for preparing chlorine dioxide of electrochemistry-

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109055966A (en) * 2018-09-13 2018-12-21 北京化工大学 A kind of chemical combined method for preparing chlorine dioxide of electrochemistry-

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