CN206497044U - A kind of device of packaged type space constraint laser induced plasma - Google Patents

A kind of device of packaged type space constraint laser induced plasma Download PDF

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Publication number
CN206497044U
CN206497044U CN201720149335.9U CN201720149335U CN206497044U CN 206497044 U CN206497044 U CN 206497044U CN 201720149335 U CN201720149335 U CN 201720149335U CN 206497044 U CN206497044 U CN 206497044U
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China
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sample
chamber
space constraint
constraint
fixture
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CN201720149335.9U
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Inventor
李祥友
郝中骐
熊佛关
杨新艳
李嘉铭
郭连波
陆永枫
曾晓雁
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WUHAN NEW RESEARCH AND DEVELOPMENT LASER Co Ltd
Huazhong University of Science and Technology
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WUHAN NEW RESEARCH AND DEVELOPMENT LASER Co Ltd
Huazhong University of Science and Technology
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Abstract

The utility model belongs to LIBS detecting instrument correlative technology field, it discloses a kind of device of packaged type space constraint laser induced plasma, it includes coaxial optical path connecting rod, constraint chamber fixture, space constraint chamber, sample clamping component and travel mechanism.The coaxial optical path connecting rod is connected to coaxial collection LIBS system, so as to realize both coaxial positioning;The space constraint chamber fixture is connected to the coaxial optical path connecting rod, and the space constraint chamber activity is connected to the constraint chamber fixture;The sample clamping component is arranged in the travel mechanism, and it is set with the space constraint chamber relative spacing;The sample clamping component is used to clamp sample, the travel mechanism is by moving to drive the sample to move in the horizontal direction, to change the position that the laser beam of the laser condensing lens from the coaxial collection LIBS system is radiated at the sample surfaces.

Description

A kind of device of packaged type space constraint laser induced plasma
Technical field
The utility model belongs to LIBS detecting instrument correlative technology field, more particularly, to one kind The device of packaged type space constraint laser induced plasma.
Background technology
LIBS (Laser-induced Breakdown Spectroscopy, LIBS) is a kind of to swash Light is the plasma emission spectrometry technology of excitaton source, and because laser pulse action time is short, plasma lifetime is short, hair Penetrate spectral intensity to decay rapidly, the decline of the intensity of spectral line makes elementary analysis sensitivity decrease.Current LIBS spectrum Enhancement Method masters There is dipulse to excite, resonant excitation, microwave radiation technology, electric spark auxiliary, space constraint etc., due to space constraint technical costs Low, full spectrum enhancing effect is good, can not only improve the intensity of spectral line, also have to quantitative analysis performance improves to a certain degree.However, existing Space constraint chamber can only be fixed on sample surfaces, with the increase of accumulation laser pulse number, laser is anti-to sample same position Resintering erosion can produce deeper rhegmalypt, and then influence LIBS analysis precisions.
At present, relevant technical staff in the field has done some researchs, and such as Application No. 201520089462.5 is special Profit discloses a kind of LIBS space Enhancement test device, and the space enhancing diaphragm that the device is used includes three layers The concentric round platform being added together to eight stackings, is evenly equipped with the diaphragm of different pore size, space enhancing diaphragm on each concentric round platform Sample support is installed, sample is arranged on the upper back of maximum round platform with one heart, it is seen that the device can be flexible on support Different pore size space enhancing diaphragm is changed, but sample is relatively fixed during plasma exciatiaon, and sample and constraint chamber connect firmly Touch, sample is immovable, it is impossible to avoid to same position repeatedly ablation produce dell the problem of.And for example Application No. 201610045515.2 disclose a kind of LIBS systems of the micro heavy detection based on plasma confinement chamber, the LIBS System includes sample stage, laser, plasma confinement chamber, spectrometer and data processor, and it is set on sample surfaces Plasma confinement chamber, plasma radiant light serves humidification, but sample still can not be moved relative to constraint chamber It is dynamic.Correspondingly, this area has the technical need for developing the device that a kind of sample can be moved relative to space constraint chamber.
Utility model content
For the defect of prior art, the utility model provides a kind of packaged type space constraint laser induced plasma The device of body, its work characteristics based on laser-induced breakdown spectroscopy device, for space constraint laser induced plasma The structure and part connecting relation of device are designed.The device of the packaged type space constraint laser induced plasma Travel mechanism is provided with, the travel mechanism drives sample to be moved relative to space constraint chamber so that laser action is in sample table The position in face changes, and then avoids same position of the laser to sample surfaces ablation produces dell repeatedly, improves LIBS points Analyse precision.In addition, the device volume of described packaged type space constraint laser induced plasma is smaller, cost is relatively low, And there is preferable compatibility relative to conventional laser induced breakdown spectroscopy system, be conducive to using space constraint enhanced spectrum The stability of spectrum is ensure that simultaneously.
To achieve the above object, the utility model provides a kind of packaged type space constraint laser induced plasma Device, it includes coaxial optical path connecting rod, constraint chamber fixture, space constraint chamber, sample clamping component and travel mechanism, its feature It is:
The coaxial optical path connecting rod is connected to coaxial collection LIBS system, so as to realize that both is same Axle is positioned;The constraint chamber fixture is connected to the coaxial optical path connecting rod, and being connected to for the space constraint chamber activity is described Constrain chamber fixture;The sample clamping component is arranged in the travel mechanism, and it sets with the space constraint chamber relative spacing Put;The sample clamping component is used to clamp sample, and the travel mechanism is by mobile to drive the sample in the horizontal direction Or vertical direction movement, to change the laser of the laser condensing lens from the coaxial collection LIBS system Beam is radiated at the position of the sample surfaces or changes the distance between the laser condensing lens and described sample.
Further, the constraint chamber fixture includes lid on constraint chamber fixture, connected with lid screw thread on the constraint chamber fixture The constraint chamber fixture lower cover that connects and compression spring on the constraint chamber fixture in lid and the constraint chamber lower cover is contained in, it is described Constraint chamber fixture top cap is connected to the coaxial optical path connecting rod.
Further, lid is stair-stepping cavity cylinder on the constraint chamber fixture, and it includes first step portion and solid Surely the first noumenon portion in the first step portion is connected to, the first step portion offers through hole, and the first noumenon portion is opened Provided with the first step trough being connected with the through hole, the through hole is provided commonly for supplying the laser beam with first step trough Pass through.
Further, the stepped cylinder of the constraint chamber fixture lower cover, it is offered and first step trough The second step trough being connected, second step trough is through the constraint chamber fixture lower cover;One end of the compression spring connects The bottom surface of first step trough is connected to, the other end stretches into second step trough and be connected to after passing through first step trough The space constraint chamber;The compression spring is used for the upper table face pressure by the lower surface of the space constraint chamber and the sample Tightly.
Further, the space constraint chamber is stair-stepping cylinder, and it includes second step portion and is fixedly connected on Second body in the second step portion, second body offers hemispherical chamber, and the second step portion is opened up There is the through hole being connected with the hemispherical chamber, the through hole is connected with second step trough;Described second Rank portion is resisted against on the cascaded surface of second step trough, and the cascaded surface is used to limit the space constraint chamber towards the movement The movement travel of mechanism.
Further, the laser beam sequentially passes through the through hole, first step trough, second step trough and institute State and enter the hemispherical chamber after through hole and be radiated on the surface of the sample set by the hemispherical chamber enclosure, with Sample described in ablation produces plasma, produces shock wave while the plasma exciatiaon, and the shock wave is to extending out Reflected in scattered process by the inwall of the hemispherical chamber, the shock wave of reflection passes through the plasma to expansion Enter row constraint to realize the increase of spectral intensity.
Further, the sample clamping component includes sample deck and sample clamping screw, and the sample deck is removable That unloads is connected in the travel mechanism;The sample clamping screw be engaged with the sample deck to clamp the sample and The sample is positioned.
Further, the travel mechanism includes Z-direction vertical displacement platform, X-direction horizontal position moving stage and Y-direction horizontal position Moving stage, the Z-direction vertical displacement platform, the X-direction horizontal position moving stage and the Y-direction horizontal position moving stage are movable from up to down Link together, and three formed three-shaft displacement platform.
Further, the Z-direction vertical displacement platform is used to drive the sample vertically mobile described to change The distance between sample and the laser condensing lens;The X-direction horizontal position moving stage and the Y-direction horizontal position moving stage are used for band The dynamic sample is moved in the horizontal direction acts on the position of the sample surfaces to change the laser beam, and then avoids described Laser beam produces dell to the sample ablation repeatedly in same position.
Further, the quantity of the coaxial optical path connecting rod is four, and four coaxial optical path connecting rods are around described The central shaft of space constraint chamber is uniformly arranged.
By the contemplated above technical scheme of the utility model, compared with prior art, what the utility model was provided can The device of portable space constraint laser induced plasma mainly has the advantages that:
(1) travel mechanism can drive the sample in the horizontal direction by mobile or vertical direction is moved, The sample is radiated at the laser beam for changing the laser condensing lens from the coaxial collection LIBS system The position on surface changes the distance between the laser condensing lens and described sample, it is to avoid laser beam is to sample surfaces Same position ablation repeatedly, improves LIBS analysis precisions, and small volume, and cost is relatively low, and compatibility is preferably;
(2) the second step portion of the space constraint chamber is resisted against on the cascaded surface of second step trough, the ladder Face is used to limit the space constraint chamber towards the movement travel of the travel mechanism, realizes the space constraint chamber and the constraint Chamber fixture lower cover realizes the travel limit of the space constraint chamber while flexible connection;
(3) lid is threadedly coupled with the constraint chamber fixture lower cover on the constraint chamber fixture so that the constraint chamber lower cover It can quickly cover and remove from the constraint chamber fixture, and then be easy to space constraint chamber described in quick-replaceable;
(4) inwall of the hemispherical chamber of the space constraint chamber returns shock reflection, and the shock wave of reflection is to swollen Swollen plasma enters row constraint so that its volume diminishes, and population density increases, so as to realize the increase of spectral intensity.
Brief description of the drawings
Fig. 1 is the dress for the packaged type space constraint laser induced plasma that the utility model better embodiment is provided Put the schematic diagram in use state.
In all of the figs, identical reference is used for representing identical element or structure, wherein:1- coaxial optical paths connect Extension bar, 2- laser condensing lens, 3- is focused on to be covered on mirror holder, 4- laser beams, 5- constraint chamber fixtures, 6- compression springs, 7- constraint chamber folders Has lower cover, 8- space constraint chambers, 9- plasmas, 10- samples, 11- sample decks, 12- sample clamping screws, 13-Z directions are hung down Straight displacement platform, 14-X directions horizontal position moving stage, 15-Y directions horizontal position moving stage.
Embodiment
In order that the purpose of this utility model, technical scheme and advantage are more clearly understood, below in conjunction with accompanying drawing and implementation Example, the utility model is further elaborated.It should be appreciated that specific embodiment described herein is only to explain The utility model, is not used to limit the utility model.
Referring to Fig. 1, the packaged type space constraint laser induced plasma that the utility model better embodiment is provided The device of body, described device can make sample during plasma exciatiaon relative to space constraint chamber level by travel mechanism Mobile, to be prevented effectively from repeatedly ablation of the laser beam to sample surfaces same position, and described device small volume, cost is low, with Conventional laser induced breakdown spectroscopy system has preferable compatibility, is conducive to ensureing while using space constraint enhanced spectrum The stability of spectrum.
The device of described packaged type space constraint laser induced plasma includes coaxial optical path connecting rod 1, constraint Chamber fixture, space constraint chamber 8, sample clamping component and travel mechanism, the coaxial optical path connecting rod 1 are connected to coaxial collection and swashed Photoinduction breakdown spectral system, so that the device of described packaged type space constraint laser induced plasma and original optical path system System (coaxial collection LIBS system) coaxial positioning.In present embodiment, in order to ensure positioning precision and connection Stability, the quantity of the coaxial optical path connecting rod 1 is four, four coaxial optical path connecting rods 1 around the space about The central shaft of beam chamber 8 is uniformly arranged;It is appreciated that in other embodiments, the quantity of the coaxial optical path connecting rod 1 can be with Increase according to actual needs or reduce.
The constraint chamber fixture is connected to the coaxial optical path connecting rod 1.The space constraint chamber 8 activity is connected to institute State constraint chamber fixture.The sample clamping component is arranged in the travel mechanism, and it is used to clamp sample 10, the sample 10 Positioned at the underface of the space constraint chamber 8.The travel mechanism is used to drive the sample 10 in the horizontal direction or vertically Direction is moved, with change laser beam 4 act on the sample 10 surface position or change the sample 10 and gather with laser The distance between burnt mirror 2.
One end of the coaxial optical path connecting rod 1 is connected to the constraint chamber fixture, and the other end is connected to focusing mirror holder 3. The focusing mirror holder 3 offers accepting hole, and the accepting hole is used to house the laser condensing lens 2.It is described in present embodiment The central shaft of the central shaft of laser condensing lens 2, the central shaft of the constraint chamber fixture and the space constraint chamber 8 is substantially overlapped.
One end of the constraint chamber fixture is connected to the coaxial optical path connecting rod 1, and the other end is connected to the space about Beam chamber 8.The constraint chamber fixture includes lid 5 on constraint chamber fixture, constrains the constraint chamber that lid 5 is threadedly coupled on chamber fixture with described Fixture lower cover 7 and it is contained in compression spring 6 on the constraint chamber fixture in lid 5 and the constraint chamber lower cover 7.The constraint chamber Lid 5 is connected to the coaxial optical path connecting rod 1 on fixture, and the activity of constraint chamber fixture lower cover 7 is connected to the space about Beam chamber 8.
Lid 5 is stair-stepping cavity cylinder on the constraint chamber fixture, and it includes first step portion and is fixedly connected on The first noumenon portion in the first step portion, the first step portion offers through hole, and the first noumenon portion is offered and institute The first step trough that through hole is connected is stated, the through hole is provided commonly for supplying to come from the laser condensing lens with first step trough 2 laser beam 4 is passed through.In present embodiment, the coaxial optical path connecting rod 1 is connected to the edge in the first step portion;Institute The first step trough is stated towards being formed with internal thread on one end inwall of the constraint chamber fixture lower cover 7.
The constraint chamber fixture lower cover 7 stepped cylinder substantially, it is offered is connected with first step trough The second logical step trough, second step trough is through the constraint chamber fixture lower cover 7.In present embodiment, the constraint chamber Fixture lower cover 7 towards being formed with external screw thread on the periphery of one end of lid 5 on the constraint chamber fixture, the external screw thread with it is described interior Screw thread is engaged, so that lid 5 is threadedly coupled with the constraint chamber fixture lower cover 7 on the constraint chamber fixture.The constraint chamber folder Tool lower cover 7 can be removed quickly from lid 5 on the constraint chamber fixture, in order to space constraint chamber 8 described in quick-replaceable.
One end of the compression spring 6 is connected to the bottom surface of first step trough, and the other end passes through first ladder Second step trough is stretched into after groove and the space constraint chamber 8 is connected to.The compression spring 6 is used for the space constraint The upper surface of the lower surface of chamber 8 and the sample 10 is compressed so that the lower surface of the space constraint chamber 8 and the sample 10 Upper surface forms soft contact.
The space constraint chamber 8 is stair-stepping cylinder, and it includes second step portion and is fixedly connected on described second Second body of stage portion, second body offers hemispherical chamber, the second step portion offer with it is described The through hole that hemispherical chamber is connected, the through hole is connected with second step trough.It is described to pass through in present embodiment The center overlapping of axles of the central shaft of perforation, the central shaft of the space constraint chamber 8 and the hemispherical chamber.The second step Portion is resisted against on the cascaded surface of second step trough, and the cascaded surface is used to limit the space constraint chamber 8 towards the shifting The movement travel of motivation structure.Second body passes through second step trough.The hemispherical chamber is located at described sharp Light beam 4 is acted on the region of the sample 10, and the laser beam 4 sequentially passes through the through hole, first step trough, described Enter the hemispherical chamber after second step trough and the through hole and described in being radiated at and being set by the hemispherical chamber enclosure On the surface of sample 10, the plasma 9 of HTHP is produced with sample described in ablation 10, it is same that the plasma 9 is excited When produce shock wave, the shock wave is during to external diffusion by the inwall of the hemispherical chamber of the space constraint chamber 8 Reflect, the shock wave of reflection enters row constraint so that its volume diminishes to the plasma 9 of expansion, and population is close Degree increase, so as to realize the increase of spectral intensity.The light of the plasma 9 is returned along laser beam optical path, is sequentially passed through described Collected on space constraint chamber 8, the constraint chamber fixture lower cover 7 and the constraint chamber after lid 5 by the laser condensing lens 2, finally Spectrometer, which is transferred to, after into coaxial collection light path carries out light splitting.
The sample clamping component includes sample deck 11 and sample clamping screw 12, and the sample deck 11 is dismountable It is connected in the travel mechanism, in order to the quick regulation position of sample deck 11.In present embodiment, the sample card The quantity of seat 11 is two, and two relative spacings of sample deck 11 are set;One in two sample decks 11 is opened Provided with screwed hole, the sample clamping screw 12 is supported on the sample 10 after passing through the screwed hole, so that the sample 10 support on another sample deck 11, and the sample clamping screw 12 is engaged to clamp with the sample deck 11 The sample 10 and the sample 10 is positioned;It is appreciated that in other embodiments, the number of the sample deck 11 Amount can increase or reduce according to actual needs.
The travel mechanism includes Z-direction vertical displacement platform 13, X-direction horizontal position moving stage 14 and Y-direction horizontal position moving stage 15, the Z-direction vertical displacement platform 13, the X-direction horizontal position moving stage 14 and the Y-direction horizontal position moving stage 15 are successively from upper Downward movable links together.The Z-direction vertical displacement platform 13 is connected with the sample deck 11.Present embodiment In, the Z-direction vertical displacement platform 13, the X-direction horizontal position moving stage 14 and the row of Y-direction horizontal position moving stage 15 are into three axles Displacement platform.The Z-direction vertical displacement platform 13 is used to drive the sample 10 vertically to move to change the sample 10 The distance between with the laser condensing lens 2.In present embodiment, to prevent from focusing on laser breakdown air, the sample is adjusted 10 surfaces are located above laser spot at about 3~4mm.The X-direction horizontal position moving stage 14 and the Y-direction horizontal position moving stage 15 For driving the sample 10 to move in the horizontal direction to change the position that the laser beam 4 acts on the surface of sample 10, The laser beam 4 is avoided to produce dell to the ablation of sample 10 repeatedly in same position.In present embodiment, the X side Moved along the horizontal plane in " bow " shape to horizontal position moving stage 14 and the Y-direction horizontal position moving stage 15.
The device for the packaged type space constraint laser induced plasma that the utility model is provided, its travel mechanism can By mobile to drive the sample in the horizontal direction or vertical direction is moved, lured with changing from the coaxial collection laser The laser beam for leading the laser condensing lens of breakdown spectral system is radiated at the position of the sample surfaces or changes the laser and gathers The distance between sample described in Jiao Jingyu, it is to avoid same position repeatedly ablation of the laser beam to sample surfaces, improves LIBS Precision, and small volume are analyzed, cost is relatively low, compatibility is preferably;The second step portion of the space constraint chamber is resisted against institute On the cascaded surface for stating the second step trough, the cascaded surface is used to limit the space constraint chamber towards the motion row of the travel mechanism Journey, realize realizes the space constraint chamber while space constraint chamber is flexibly connected with the constraint chamber fixture lower cover Travel limit;Lid is threadedly coupled with the constraint chamber fixture lower cover on the constraint chamber fixture so that the constraint chamber lower cover can Quick covered from the constraint chamber fixture is removed, and then is easy to space constraint chamber described in quick-replaceable;The space constraint chamber The inwall of hemispherical chamber returns shock reflection, and the shock wave of reflection enters row constraint so that its body to the plasma of expansion Product diminishes, population density increase, so as to realize the increase of spectral intensity.
As it will be easily appreciated by one skilled in the art that the foregoing is only preferred embodiment of the present utility model, not To limit the utility model, all any modifications made within spirit of the present utility model and principle, equivalent substitution and change Enter, should be included within protection domain of the present utility model.

Claims (10)

1. a kind of device of packaged type space constraint laser induced plasma, it includes coaxial optical path connecting rod, constraint chamber Fixture, space constraint chamber, sample clamping component and travel mechanism, it is characterised in that:
The coaxial optical path connecting rod is connected to coaxial collection LIBS system, so as to realize that both is coaxial fixed Position;The constraint chamber fixture is connected to the coaxial optical path connecting rod, and the space constraint chamber activity is connected to the constraint Chamber fixture;The sample clamping component is arranged in the travel mechanism, and it is set with the space constraint chamber relative spacing;Institute Stating sample clamping component is used to clamp sample, and the travel mechanism is by mobile to drive the sample in the horizontal direction or perpendicular Nogata is irradiated to movement with the laser beam for changing the laser condensing lens from the coaxial collection LIBS system Distance between the position of the sample surfaces or the change laser condensing lens and the sample.
2. the device of packaged type space constraint laser induced plasma as claimed in claim 1, it is characterised in that:It is described Constraint chamber fixture includes lid on constraint chamber fixture, constraint chamber fixture lower cover and receipts with covering threaded connection on the constraint chamber fixture Lid and the compression spring constrained in chamber lower cover on the constraint chamber fixture are dissolved in, the constraint chamber fixture top cap is connected to institute State coaxial optical path connecting rod.
3. the device of packaged type space constraint laser induced plasma as claimed in claim 2, it is characterised in that:It is described It is stair-stepping cavity cylinder to constrain lid on chamber fixture, and it includes first step portion and is fixedly connected on the first step portion The first noumenon portion, the first step portion offers through hole, and the first noumenon portion offers what is be connected with the through hole First step trough, the through hole is provided commonly for passing through for the laser beam with first step trough.
4. the device of packaged type space constraint laser induced plasma as claimed in claim 3, it is characterised in that:It is described The stepped cylinder of chamber fixture lower cover is constrained, it offers the second step trough being connected with first step trough, institute The second step trough is stated through the constraint chamber fixture lower cover;One end of the compression spring is connected to the bottom of first step trough Face, the other end stretches into second step trough and is connected to the space constraint chamber after passing through first step trough;The pressure Contracting spring is used to compress the upper surface of the lower surface of the space constraint chamber and the sample.
5. the device of packaged type space constraint laser induced plasma as claimed in claim 4, it is characterised in that:It is described Space constraint chamber is stair-stepping cylinder, and it includes second step portion and is fixedly connected on second of the second step portion Body portion, second body offers hemispherical chamber, and the second step portion is offered to be connected with the hemispherical chamber Logical through hole, the through hole is connected with second step trough;The second step portion is resisted against second ladder On the cascaded surface of groove, the cascaded surface is used to limit the space constraint chamber towards the movement travel of the travel mechanism.
6. the device of packaged type space constraint laser induced plasma as claimed in claim 5, it is characterised in that:It is described Laser beam, which is sequentially passed through, enters described half after the through hole, first step trough, second step trough and the through hole Spherical chamber and be radiated on the surface of the sample set by the hemispherical chamber enclosure, with described in ablation sample produce etc. from Daughter, produces shock wave, the shock wave is during to external diffusion by the hemisphere while plasma exciatiaon The inwall of shape chamber is reflected, and the shock wave of reflection enters row constraint to realize that spectrum is strong by the plasma to expansion The increase of degree.
7. the device of the packaged type space constraint laser induced plasma as described in claim any one of 1-6, its feature It is:The sample clamping component includes sample deck and sample clamping screw, and the sample deck is removably connected to institute State in travel mechanism;The sample clamping screw is engaged to enter the sample to clamp the sample with the sample deck Row positioning.
8. the device of the packaged type space constraint laser induced plasma as described in claim any one of 1-6, its feature It is:The travel mechanism includes Z-direction vertical displacement platform, X-direction horizontal position moving stage and Y-direction horizontal position moving stage, the Z side One is connected to vertical displacement platform, the X-direction horizontal position moving stage and the Y-direction horizontal position moving stage are movable from up to down Rise, and three forms three-shaft displacement platform.
9. the device of packaged type space constraint laser induced plasma as claimed in claim 8, it is characterised in that:It is described Z-direction vertical displacement platform be used to driving the sample vertically to move with change the sample and the laser condensing lens it Between distance;The X-direction horizontal position moving stage and the Y-direction horizontal position moving stage are used to drive the sample to move in the horizontal direction It is dynamic to act on the position of the sample surfaces to change the laser beam, and then avoid the laser beam repeatedly right in same position The sample ablation and produce dell.
10. the device of the packaged type space constraint laser induced plasma as described in claim any one of 1-6, its feature It is:The quantity of the coaxial optical path connecting rod is four, and four coaxial optical path connecting rods are around the space constraint chamber Central shaft is uniformly arranged.
CN201720149335.9U 2017-02-20 2017-02-20 A kind of device of packaged type space constraint laser induced plasma Active CN206497044U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112113952A (en) * 2020-10-19 2020-12-22 温州大学 Remote measuring device based on LIBS technology
CN112198149A (en) * 2020-10-19 2021-01-08 温州大学 Portable LIBS composition analyzer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112113952A (en) * 2020-10-19 2020-12-22 温州大学 Remote measuring device based on LIBS technology
CN112198149A (en) * 2020-10-19 2021-01-08 温州大学 Portable LIBS composition analyzer
CN112198149B (en) * 2020-10-19 2023-11-07 温州大学 Portable LIBS component analyzer

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