Utility model content
The purpose of this utility model is to provide a kind of Based Intelligent Control dispensing piece-rate system suitable for silicon factory, is realized a kind of
By electronic technology automatic mixing iron powder and the weight of watery hydrochloric acid, primary dcreening operation is carried out to the silicon in white residue using ferrous acid mixed liquor,
The collection rate to the silicon in white residue is improved, while the iron in ferrous acid mixed liquor reclaim the purpose of collection, existing skill is solved
Efficiency is low by the way of manual sorting sorts to white residue in art, human cost big, and ferrosilicon in industrial waste is mixed
Iron in compound can not be recycled, and the iron powder after white residue is separated especially with iron powder can not be recovered, and cause resource
Waste the problem with environmental pollution.
The utility model is achieved through the following technical solutions:
A kind of Based Intelligent Control dispensing piece-rate system suitable for silicon factory, including be sequentially connected by pipeline Weighing module,
Stirring pool, cyclone, retort, sedimentation basin, filtering ponds, magnetic separator, also including being respectively connected by pipeline with Weighing module
Iron powder bucket, watery hydrochloric acid bucket, described iron powder bucket, watery hydrochloric acid bucket are located at Weighing module top, in iron powder
Drive control module is provided with bucket and watery hydrochloric acid bucket;
Iron powder wherein in iron powder bucket by pipeline to Weighing module, in Weighing module weigh by iron powder, when
When iron powder weight information reaches the preset value of Weighing module, Weighing module sends stop signal and is opened to iron powder bucket, transmission
To watery hydrochloric acid bucket, the drive control module on iron powder bucket stops signal after receiving the stop signal of Weighing module transmission
Conveying iron powder, the iron powder after then weighing is by pipeline to stirring pool;Drive control module on watery hydrochloric acid bucket is received
After the open signal sent to Weighing module, watery hydrochloric acid is delivered in Weighing module and is weighed, when watery hydrochloric acid weight information reaches
During the preset value of Weighing module, Weighing module sends stop signal to watery hydrochloric acid bucket, and the watery hydrochloric acid after weighing passes through pipeline
It is delivered to stirring pool;Also include water supply module, the water supply module is connected by water pipe with stirring pool;
Wherein the mixed liquor containing iron powder, white residue is pipelined to cyclone by stirring pool, and cyclone is by underflow opening
To retort, the mixed liquor in retort is delivered to sedimentation basin precipitation to the mixed liquor of discharge, and the sediment conveying in sedimentation basin is deposited
In storage tank, the liquid in sedimentation basin is delivered to filtering ponds filtering, the liquid after filtering is delivered to magnetic separator, the solid after filtering
It is delivered in bucket, the solid particle of magnetic separation is delivered to bucket by magnetic separator.
Further, the utility model improvement compared to existing technology is as follows:
1st, using the density of the density more than silicon of iron powder, silicon is separated from white residue:By watery hydrochloric acid, iron powder, water by certain
Weight ratio weigh and be then sent to stirring pool and stir together, then again toward white residue is added in stirring pool, in being stirred continuously, silicon
Silicon and density in slag will float over the surface of ferrous acid mixed liquor less than the material of ferrous acid mixed liquor, and now staff can
Salvaged with the silicon mixture that will float on surface, reaching carries out primary dcreening operation to the silicon in white residue, improve the collection to the silicon in white residue
The purpose of rate;The density of iron powder is 7.86g/cm3, the density of silicon is 2.42g/cm for the density of watery hydrochloric acid3, mass fraction is
The density of 30% watery hydrochloric acid is 1.1492g/cm3Although adding watery hydrochloric acid to reduce the close of mixed liquor in iron powder mixed liquor
Degree, but to reduce the iron powder taken away when salvaging, suitably add watery hydrochloric acid to be reacted part iron powder by a certain percentage,
The iron powder part in mixed liquor is become ferric ion, be distributed evenly in mixed liquor, while to mixing
The density of liquid does not result in too big influence, and the density of the density still above silicon of ferrous acid mixed liquor reaches the mesh for carrying out primary dcreening operation silicon
, compared to existing technology by the way of manual sorting sorts to white residue, the utility model greatly improves sorting effect
Rate, has saved human cost.
2nd, realize further separating silicon from white residue, while reclaiming the iron in mixed liquor:Floated in stirring pool
The silicon on mixed liquor surface has salvaged the primary dcreening operation realized to silicon by artificial, and stirring pool will contain iron ion, part iron powder, on a small quantity
White residue is pipelined to cyclone containing sour mixed liquor, and under the high speed rotation of cyclone, liquid-solid mixture is in centrifugal force
In the presence of separated, the big component of mixture Midst density is axially simultaneously moved downward in the presence of eddy flow field, along footpath
To moving out, moved downward along wall cone segments are reached, and discharged by underflow opening, i.e., density it is larger containing the molten of iron ion
Liquid, part iron powder and fraction white residue just flow out from underflow opening;The small component of density is moved to central axial direction, and in axis
An inside vortex for moving upwards is centrally formed, is then discharged by overfall, i.e., most of silicon and fraction solution are just from overfall
Outflow;The silicon filtering that will be flowed out from overfall is collected, and realizes the purpose further separate from white residue to silicon.
Start the removal process to iron in mixed liquor:The utility model is added with ammoniacal liquor and compressed air in retort.
The solution containing iron ion, part iron powder and the fraction white residue that underflow opening is flowed out are by pipeline to retort, retort
In be connected with ammoniacal liquor, the mixed liquor in retort can occur following reaction, 2NH3H2O+FeCl2==2NH4Cl+Fe (OH) 2 ↓,
2NH3H2O+Fe2+==2NH4++Fe (OH) 2 ↓, 4Fe (OH) 2+O2+2H2O==4Fe (OH) 3 ↓, it is now molten in retort
Liquid color can be shifted gradually to yellowish-brown, bronzing, and the mixed liquor in retort now is delivered into sedimentation basin precipitation, now be precipitated
Chi Zhonghui is gradually layered, and lower floor is iron precipitate yellowish-brown, russet, and upper strata is mixed containing white residue and unreacted iron powder
Close liquid, then by the iron precipitate in sedimentation basin by artificially collecting conveying bucket in, liquid in sedimentation basin is by pipe
Road is delivered to filtering ponds filtering, and screen pack will not precipitate complete iron precipitate and stop in filtering ponds, and artificially collecting to precipitate
Thing is delivered in bucket, and few white residue and unreacted iron powder are contained in the filtrate after filtering, and mixed liquor is defeated by pipeline
Deliver to magnetic separator.Magnetic separator utilizes magnetic absorption principle, and the part iron powder in mixed liquor and some iron containing compoundses are adsorbed,
And be carried over Disengagement zone, with scraper scraping off magnetic drum and falling into bucket along chip leading plate the iron powder of absorption and some iron containing compoundses
In.Can not be recycled by solving with upper type the iron in the ferrosilicon mixture in industrial waste, especially with iron
Iron powder after powder separates white residue can not be recovered, and cause the problem of the wasting of resources and environmental pollution.
3rd, using Electronic Control realize to watery hydrochloric acid, iron powder, water automatic blending process:Because to the primary dcreening operation process of white residue
The big and lasting process of a workload, the ferrous acid mixed liquor in stirring pool white residue is carried out primary dcreening operation it is multiple after, ferrous acid
Material in mixed liquor can become extremely complex, now be accomplished by by the mixed liquor discharge in stirring pool, then by watery hydrochloric acid, iron
Powder, water, than dispensing, primary dcreening operation are carried out to the new white residue for adding by certain weight.Mode according to artificial dispensing every time wastes people
Power and trouble, so the utility model is tangled iron powder bucket, watery hydrochloric acid bucket using support, Weighing module is located at iron powder
Bucket, watery hydrochloric acid storage bottom of the barrel, realization is in communication with each other to iron powder and dilute using drive control module and Weighing module
The purpose of hydrochloric acid weighing and proportioning successively.
Described Weighing module includes the weight sensor being arranged in weighing hopper, microprocessor, first communication module, holds
Row mechanism, wherein:
Weight sensor:The weight of iron powder is gathered, iron powder weight information is then transferred to microprocessor;Collection watery hydrochloric acid
Weight, watery hydrochloric acid weight information is then transferred to microprocessor;
Microprocessor:Receive weight sensor transmission iron powder weight information, when iron powder weight information reach it is default heavy
During value, stop signal and open signal to first communication module are sent, while sending drive signal to executing agency;Receive weight
The watery hydrochloric acid weight information of quantity sensor transmission, when watery hydrochloric acid weight information reaches default gravimetric value, sends stop signal
To first communication module, while sending drive signal to executing agency;
First communication module:Stop signal and open signal that microprocessor sends are received, stop signal is sent to iron
Powder bucket, watery hydrochloric acid bucket is sent to by open signal;The stop signal that microprocessor sends is received, and by stop signal
It is sent to watery hydrochloric acid bucket;
Executing agency:Receive the drive signal of microcontroller transmission, the valve opening of control weighing hopper bottom or closing.
Further, existing weighing procedures are incorporated in the microcontroller in Weighing module, iron powder and watery hydrochloric acid is set
Gravimetric value, the gravimetric value of first time is iron powder, and the gravimetric value for being for the second time is watery hydrochloric acid, is claimed by procedure described above
Weight.Weighing hopper bottom is provided with valve, after first communication module has sent signal, microprocessor control is connected with valve
By valve opening, after iron powder or watery hydrochloric acid have all flowed, executing agency is automatically by valve closing for executing agency.
Drive control module on described iron powder bucket includes second communication module, microcontroller, executing agency, its
In:
Second communication module:The stop signal that Weighing module sends is received, and stop signal is transferred to microcontroller;
Microcontroller:The stop signal that second communication module sends is received, and stop signal is transferred to executing agency;
Executing agency:Receive the stop signal of microcontroller transmission, the valve closing on control iron powder bucket.
Further, valve handle is additionally provided with drive control module, the valve handle is connected with valve, first people
Work Open valve handle, valve is opened, and then the iron powder in iron powder bucket carries out claiming in pipeline with regard to automatic using gravity principle
Weight.After the completion of weighing, by receiving the stop signal that Weighing module sends, the valve of bottom of the barrel is stored by actuating mechanism controls iron powder
Door is closed, and stops that Weighing module is continued to convey iron powder.
Drive control module on described watery hydrochloric acid bucket includes third communication module, microcontroller, executing agency,
Wherein:
Third communication module:The open signal that Weighing module sends is received, and open signal is transferred to microcontroller;Connect
The stop signal that Weighing module sends is received, and stop signal is transferred to microcontroller;
Microcontroller:Receive open signal or stop signal that third communication module sends, and by open signal or stopping
Signal transmission is to executing agency;
Executing agency:Receive the open signal or stop signal of microcontroller transmission, the valve on control watery hydrochloric acid bucket
Door is turned on and off.
Further, the valve in the weighing hopper in the watery hydrochloric acid bucket and Weighing module in the utility model is adopted
It is made of acidproof corrosion-resistant material.Drive control module on watery hydrochloric acid bucket is firstly received and receives what Weighing module sent
Open signal, control valve is opened, and watery hydrochloric acid is delivered in weighing hopper;The shutdown signal of Weighing module transmission is received afterwards,
Control valve is closed, and the transportation to watery hydrochloric acid is realized using gravity.
The water supply module includes the water flow meter measuring device, microcontroller, the executing agency that are arranged on water pump, wherein:
Water flow meter measuring device:Metering water pump flows to the flow information in stirring pool, and flow information is transferred into micro-control
Device processed;
Microcontroller:The flow information of water flow meter measuring device transmission is received, when flow information reaches default gravimetric value
When, send halt instruction to executing agency;
Executing agency:Receive the execute instruction of microcontroller transmission, the valve closing on control water pump.
Further, valve handle, the valve handle and valve are provided with the valve that water pump is connected with stirring pool
Connection;Manually opened by handle control valve, the water that water flow meter measuring device convection current goes out is measured, when flow information reach it is micro-
During the default gravimetric value of controller, microcontroller is closed by executing agency's autocontrol valve, is realized in mixed liquor to water
Proportioning course of conveying.
Also include hothouse, the hothouse is connected with bucket by conveyer belt.Further, by the utility model
Recovery to iron, has iron precipitate, iron powder and a small amount of water in bucket, bucket is put and is sent into drying on a moving belt
Room dries, and dried mixture is more conducive to preserve.
Also include heater and agitator, the heater be located at retort outside, agitator be located at retort inside and
It is connected with agitator.Further, the ammoniacal liquor in retort is relatively slow with ferrous ion or ferric ion reaction, in retort
One heater of outer setting, for being heated to retort, can promote the reaction of ammoniacal liquor and ferrous ion or ferric ion,
Agitator inside retort can be such that mixed liquor is reacted evenly with ammoniacal liquor, promote reaction.
The utility model compared with prior art, has the following advantages and advantages:
1st, a kind of Based Intelligent Control dispensing piece-rate system suitable for silicon factory of the utility model, using the different material meeting of density
The principle of AUTOMATIC ZONING, watery hydrochloric acid, iron powder, water are weighed by certain weight ratio to be then sent to stirring pool and stirs together, so
Afterwards again toward white residue is added in stirring pool, in being stirred continuously, silicon and density in white residue less than ferrous acid mixed liquor material just
The surface of ferrous acid mixed liquor can be being floated over, the silicon mixture that will float on surface is salvaged, and reach carries out primary dcreening operation to the silicon in white residue,
Improve the purpose to the collection efficiency of the silicon in white residue;
2nd, a kind of Based Intelligent Control dispensing piece-rate system suitable for silicon factory of the utility model, cyclone is using centrifugal force and close
The principle of difference is spent by the most of silicon removal in mixing, and the iron content mix acid liquor flowed out in cyclone is collected again then,
After the retort containing ammoniacal liquor is reacted, then iron precipitate is collected by sedimentation basin and filtering ponds, magnetic separator is to mixed
The iron powder closed in liquid is collected, and realizes the mode that a kind of iron in mixture to ferrosilicon is collected, in solving industrial waste
Ferrosilicon mixture in iron can not be recycled, the iron powder after white residue is separated especially with iron powder can not be recovered,
Cause the problem of the wasting of resources and environmental pollution;
3rd, a kind of Based Intelligent Control dispensing piece-rate system suitable for silicon factory of the utility model, in iron powder bucket and watery hydrochloric acid
It is provided with drive control module on bucket, drive control module and Weighing module are realized to iron powder and dilute by communication module
The automatic weighing and burden process of hydrochloric acid, is then sent to stirring pool, and then the water flow meter measuring device of water supply module is micro- to water flow measurement
Controller is controlled, and realizes the automatic gauge course of conveying to water, is realized a kind of by electronic technology automatic mixing iron powder and dilute
The weight of hydrochloric acid, the purpose of primary dcreening operation is carried out using ferrous acid mixed liquor to the silicon in white residue.