CN206051788U - A kind of Bulbus Allii processing waste water recycling treatment system - Google Patents
A kind of Bulbus Allii processing waste water recycling treatment system Download PDFInfo
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- CN206051788U CN206051788U CN201620979103.1U CN201620979103U CN206051788U CN 206051788 U CN206051788 U CN 206051788U CN 201620979103 U CN201620979103 U CN 201620979103U CN 206051788 U CN206051788 U CN 206051788U
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- bulbus allii
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- 239000002351 wastewater Substances 0.000 title claims abstract description 53
- 238000012545 processing Methods 0.000 title claims abstract description 34
- 238000004064 recycling Methods 0.000 title claims abstract description 26
- 238000001914 filtration Methods 0.000 claims abstract description 32
- 235000004611 garlic Nutrition 0.000 claims abstract description 25
- 239000012466 permeate Substances 0.000 claims abstract description 25
- 239000012528 membrane Substances 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 238000001179 sorption measurement Methods 0.000 claims abstract description 21
- 239000000047 product Substances 0.000 claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 16
- 238000001764 infiltration Methods 0.000 claims abstract description 15
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- 230000008569 process Effects 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 7
- 240000002234 Allium sativum Species 0.000 claims description 24
- 238000000108 ultra-filtration Methods 0.000 claims description 19
- 238000004140 cleaning Methods 0.000 claims description 18
- 238000001728 nano-filtration Methods 0.000 claims description 17
- 239000000919 ceramic Substances 0.000 claims description 7
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- 239000011148 porous material Substances 0.000 claims description 4
- 238000005374 membrane filtration Methods 0.000 claims description 3
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
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- 206010054949 Metaplasia Diseases 0.000 description 1
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- 238000012356 Product development Methods 0.000 description 1
- JZRWCGZRTZMZEH-UHFFFAOYSA-N Thiamine Natural products CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N JZRWCGZRTZMZEH-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
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- 235000001014 amino acid Nutrition 0.000 description 1
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- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
This utility model provides a kind of Bulbus Allii processing waste water recycling treatment system, including：Effluent settling chamber, for storing the waste water produced in the production process of garlic products；Pre-filtration system, for carrying out pre-filtering process to the Bulbus Allii processing waste water from effluent settling chamber；Filtration system, for carrying out deep filtration treatment to the permeate from pre-filtration system；Special Resin adsorption system, for the high-selectivity adsorption of garlicin is carried out to the permeate from filtration system；Counter-infiltration system, for carrying out reverse-osmosis treated to the water outlet from Special Resin adsorption system；And biochemical system, for carrying out biochemical treatment to the concentrated solution from counter-infiltration system.Membrane technology and Special Resin adsorption technology are applied to Bulbus Allii production waste water reclaiming and are processed by Bulbus Allii processing waste water recycling treatment system provided by the utility model, so as to the low cost and the high stability that are truly realized required by industrialized production, while also improving product quality and reducing production cost.
Description
Technical field
This utility model belongs to garlic food manufacture field, more particularly, to a kind of Bulbus Allii processing waste water recycling treatment system
System.
Background technology
Bulbus Allii also known as giant garlic, DUSUAN, calabash, single clove garlic, are the bulb of Liliaceae allium Bulbus Allii.Bulbus Allii is mankind mouth Chang Sheng
Indispensable flavoring agent in work, has for enhancing flavor effect of deodorization when fish, meat, birdss and vegetable is cooked, particularly in cold vegetable dish in sauce,
Both can flavour enhancing, can sterilize again.Traditionally, people described at ordinary times " Bulbus Allii ", for referring to Bulbus Allii.Bulbus Allii be divided into purple garlic with
Two kinds of Rhizoma Euonymus Bulbus Allii, the garlic clove of purple garlic is few and big, and acid is dense, and yield is high, is distributed in the ground such as North China, northwest more, and cold-hartliness is weak,
It is many to sow in spring, evening in period of maturation；Rhizoma Euonymus Bulbus Allii has two kinds of big lobe and valvula, and acid is thin, and more cold-resistant than purple garlic, many autumns are broadcast
Kind, the period of maturation is slightly early.The Garlic yield of China is very high, and long-term cultivated area is 20.0 ~ 26.7 ten thousand hectares, and yield is 4,000,000
Ton, occupies first place in the world, accounts for the 1/4 of Gross World Product.Bulbus Allii directly to eat raw as most, nutritive value highest, physiological function
Substantially.But, Bulbus Allii after the rest period of 60 ~ 80 d terminates, when natural environment is suitable, can be sprouted rapidly and consume and stored
Nutrient substance, quality can drastically deteriorate and can not eat.Therefore, Bulbus Allii can be processed into various products.This respect can be developed
Product it is a lot, such as dewatered garlic flake, garlic tablet, Bulbus Allii powder are substantially all to export to all over the world；It is further processed into serial product
Product, such as health food, cosmetics, feed additive etc. are up to tens kinds of products.Bulbus Allii this be considered as treasure by world many countries
The produce of product, but fail really to be formed industry development in China always.Garlic nutrition very abundant, every 100 g are fresh
70 g of Bulbus Allii moisture content, 4.4 g of protein, fatty 0.2 g, 23 g of carbohydrate, 0.7 g of crude fibre, 1.3 g of ash, calcium 5
Mg, 44 mg of phosphorus, 0.4 mg of ferrum, 0.24 mg of thiamine, 0.03 mg of riboflavin, 0.9 mg of nicotinic acid, 3 mg of ascorbic acid.Greatly
Contain 17 kinds of aminoacid in Bulbus Allii, wherein 8 kinds is needed by human.Additionally, Bulbus Allii also contain garlicin and trace element-selenium, zinc,
Germanium etc., the germanium and Se content particularly with notable physiologically active extremely enrich.
Bulbus Allii with its abundant nutritional labeling, excellent health-care effect, significant curative effect, cheap price, it is abundant from
So resource, the huge market demand, cause the extensive concern of people.China is one of Bulbus Allii major country of production, and resource is very rich
Richness, the country such as garlic product main exit Association of South-east Asian Nations, Japan, Korea, the U.S., Russia and Africa, Latin America, be mainly used in medicine,
The industries such as food, in recent years international market Bulbus Allii demand be continuously increased, export market becomes more diversified, and main problem is such as
Under：Bulbus Allii processing technique is delayed, and scientific and technological content is low;Outlet Bulbus Allii remains in pickles, cuts into slices, dry etc. and simply process, attached
Value added low, follow-up new product development is weak.Domestic enterprise's Bulbus Allii section production technology is mainly：It is immersion after Bulbus Allii is sliced, clear
Wash and in centrifugal process, generate Bulbus Allii section waste water, COD concentration is higher in its waste water, and the garlicin for containing has antibacterial killing
The effect of bacterium so that the waste water becomes the difficult waste water of high concentration.Research both at home and abroad to Bulbus Allii section waste water is less, without effectively
Ripe this kind of waste water of PROCESS FOR TREATMENT, it is directly outer after most enterprise dilution to enter surrounding water, it is larger to water environmental impact.
Membrane technology is just gradually widely applied in industrial every field in recent years, and membrane separation technique is using tool
Have and certain select the classification of material, separation, concentration, purification etc. are carried out through the filter medium of characteristic.After the sixties in 20th century,
Various membrane separation techniques are developed rapidly, occupy increasingly consequence in various isolation technics.Film has in separation process
Following function：The identification of material and transmission；Interface；Reacting field.The identification of material and through being to make in mixture between each component
Realize detached intrinsic factor；As interface, film will transmit through liquid and retain liquid be divided into it is mutually unmixed biphase；As reacting field film
Surface and internal surface of hole contain the functional group for having interaction ability with specific solute, by physical action, chemical reaction or
Biochemical reaction improves the selectivity and separating rate of membrance separation.Membrane separating process has under room temperature to be carried out, without phase change, energy consumption
Low, equipment is simple, convenient operation and control the features such as, be applied to the neck such as chemical industry, medicine, light industry, food, weaving, electronics, metallurgy
Domain.According to the difference of retention component, membrane process can be divided into microfiltration (Microfiltration, MF), ultrafiltration
(Ultrafiltration, UF), reverse osmosiss (Reverse osmosis, RO), dialysis (Dialysis, DS), electrodialysis
(Electrodialysis, ED) and seepage slope (Pervaporation, PV) etc..
Ceramic membrane is with loose structure with 1600 DEG C of high temperature sinterings of the Jing such as aluminium oxide, titanium oxide, zirconium oxide
High technology ceramics filtering material.It is by the ceramic monolith of porosity 30% ~ 50%, aperture 50nm ~ 15 μm, using sol-gel process
Or the asymmetric compound film that other techniques are made.Its structure is usually " sandwich " formula：Supporting layer（Also known as carrier layer）、
Transition zone（Also known as intermediate layer）, film layer（Also known as function stratum disjunctum）.Wherein the aperture of supporting layer is generally 1 ~ 20 μm, and porosity is
30% ~ 65%, its effect is to increase the mechanical strength of film；The aperture of the aperture ratio supporting layer in intermediate layer is little, and its effect is to prevent film
Infiltration of the granule to porous support layer in layer preparation process, about 20 ~ 60 μm of thickness, porosity are 30% ~ 40%；Film layer has divides
From function, from 0.8 nm ~ 1 μm, about 3 ~ 10 μm of thickness, porosity are 40% ~ 55% in aperture.The pore-size distribution of whole film by
Supporting layer is gradually reduced to film layer, forms asymmetric structure distribution.Ceramic membrane can be divided into microfiltration according to aperture（Aperture is more than 50
nm）, ultrafiltration（2 ~ 50 nm of aperture）, nanofiltration（Aperture is less than 2 nm）Etc. species.Ceramic membrane filter is a kind of " cross flow filter " form
Fluid separation process：Material liquid flow at high speed in the membrane tube, the clarified permeation liquid edge containing small molecule component under pressure-driven
With face vertical direction（Radially）Film is passed through outwards, the muddy concentrated solution containing macromolecular components is rejected by, so that fluid reaches
To separate, concentration, purification purpose.
The retention characteristic of ultrafilter membrane is the usual molecular cut off scope characterizing with to the molecular cut off of standard Organic substance
In 1000-300000 Da, therefore ultrafilter membrane can be to larger molecular organicses（Such as protein, antibacterial）, colloid, suspended solid etc. carry out
Separate, be widely used in the clarification of feed liquid, the isolating and purifying of larger molecular organicses, except thermal source.The retention characteristic of NF membrane be with
To MgSO4Characterizing, corresponding molecular cut off scope is in 150-1000 Da, therefore NF membrane can be right for rejection Deng standard solution
Small organic molecule etc. is separated with water, inorganic salt, is made desalination and is carried out while concentration.
The content of the invention
The purpose of this utility model is, there is provided a kind of Bulbus Allii processing waste water recycling treatment system.
For this purpose, this utility model provides following solution：
A kind of Bulbus Allii processing waste water recycling treatment system, the Bulbus Allii processing waste water recycling treatment system is for big
The waste water produced in the production process of Bulbus Allii product carries out recycling treatment, the Bulbus Allii processing waste water recycling treatment system bag
Include：
- effluent settling chamber, the effluent settling chamber are used for the waste water produce in the production process for store garlic products；
- pre-filtration system, the pre-filtration system is for carrying out pre- mistake to the Bulbus Allii processing waste water from effluent settling chamber
Filter is processed；
- filtration system, the filtration system is for carrying out deep filtration treatment to the permeate from pre-filtration system；
- Special Resin adsorption system, the Special Resin adsorption system is for carrying out to the permeate from filtration system
The high-selectivity adsorption of garlicin；
- counter-infiltration system, the counter-infiltration system is for carrying out reverse osmosiss to the water outlet from Special Resin adsorption system
Process；And
- biochemical system, the biochemical system is for carrying out biochemical treatment to the concentrated solution from counter-infiltration system.
Preferably, effluent settling chamber bottom sediment is delivered to boiler room after drying and carries out burning disposal.
Preferably, the pre-filtration system includes：Self-cleaning filter and purpose ceramic-film filter, the self-cleaning filter
For coarse filtration being carried out to the Bulbus Allii processing waste water from effluent settling chamber and permeate meets the water inlet water of purpose ceramic-film filter
Matter requires, the purpose ceramic-film filter is for carrying out membrane filtration to the permeate from self-cleaning filter and permeate met
The influent quality of filter system is required.Effluent settling chamber supernatant by water pump be delivered to self-cleaning filter carry out coarse filtration so that
Mechanical impurity before membranous system must being entered, reduces the pollution and damage of membranous system, extends the service life of film.
Preferably, the concentrated solution for producing in the self-cleaning filter and purpose ceramic-film filter is delivered to effluent settling chamber.
Preferably, the pore size filter of the self-cleaning filter is 50 ~ 70 μm.
Preferably, the pore size filter of the purpose ceramic-film filter is 30 ~ 50 nm.
Preferably, the crossflow velocity of the purpose ceramic-film filter is 3 ~ 4 m/s.
Preferably, the membrane flux of the purpose ceramic-film filter is 340 ~ 400 LMH.
Preferably, the filtration system includes：The filtration system includes：Ultrafiltration system and nanofiltration system, the ultrafiltration
, for hyperfiltration treatment is carried out to the permeate from pre-filtration system, the nanofiltration system is for from the saturating of ultrafiltration system for system
Crossing liquid carries out nanofiltration process.The main component of the concentrated solution of ultrafiltration system and nanofiltration system is garlic polysaccharide, can be refined place
Reason production garlic polysaccharide.
Preferably, the molecular cut off of the ultrafilter membrane of the ultrafiltration system is 80000 ~ 100000 Da.
Preferably, the membrane flux of the ultrafiltration system is 35 ~ 40 LMH.
Preferably, the molecular cut off of the NF membrane of the nanofiltration system is 150 ~ 200 Da.
Preferably, the membrane flux of the nanofiltration system is 16 ~ 18 LMH.
Preferably, in the Special Resin adsorption system, resin is garlicin molecular cngram resin.
Preferably, the permeate of the counter-infiltration system is delivered to garlic products production workshop section.
Bulbus Allii processing waste water recycling treatment system provided by the utility model has the advantage that：
（1）Coarse filtration is carried out to waste water by self-cleaning filter, rigid impurity can be exempted to rear end film processing system
Mechanical damage；
（2）Clarification filtration is carried out by purpose ceramic-film filter to waste water, floor space is reduced, and the yield of filter progress is carried
It is high；
（3）By the concentrated solution of self-cleaning filter and purpose ceramic-film filter is delivered to effluent settling chamber so that waste water sinks
Suspended sediment concentration in the pond of shallow lake is improved, so that the sedimentation effect in effluent settling chamber is notable；
（4）Garlic polysaccharide is concentrated by ultrafiltration system and nanofiltration system so that in permeate, content of organics subtracts
Few, viscosity is reduced, and has also reclaimed the garlic polysaccharide in waste water, the utility being extracted in waste water；
（5）The high-selectivity adsorption of garlicin is realized by Special Resin adsorption system, valuable source has both been reclaimed, and
The biodegradability of waste water is improve, and treatment conditions is provided for subsequent biochemical process；
（6）The water outlet of Special Resin adsorption system carries out concentration minimizing process by counter-infiltration system and realizes middle water time
With, save industrial water amount, reduce biochemical system scale again, save construction and operating cost.
（7）Membrane technology and Special Resin adsorption technology are applied to Bulbus Allii production waste water reclaiming process and are truly realized industry
Metaplasia produces required low cost and high stability, while also improving product quality and reducing production cost.
Description of the drawings
Fig. 1 is the schematic diagram of Bulbus Allii processing waste water recycling treatment system provided by the utility model；
In figure：101- effluent settling chambers；201- self-cleaning filters；202- purpose ceramic-film filters；301- ultrafiltration systems；
302- nanofiltration systems；401- Special Resin adsorption systems；501- counter-infiltration systems；601- biochemical systems.
Specific embodiment
This utility model is described in further detail with specific embodiment referring to the drawings.
Bulbus Allii processing waste water recycling treatment system is provided for the waste water produced in the production process to garlic products
Sourceization process, Bulbus Allii processing waste water recycling treatment system include：
- effluent settling chamber 101, for storing the waste water produced in the production process of garlic products；
- pre-filtration system, for carrying out pre-filtering process to the Bulbus Allii processing waste water from effluent settling chamber 101；
- filtration system, for carrying out deep filtration treatment to the permeate from pre-filtration system；
- Special Resin adsorption system 401, for the high selectivity of garlicin is carried out to the permeate from filtration system
Absorption；
- counter-infiltration system 501, for carrying out reverse-osmosis treated to the water outlet from Special Resin adsorption system 401；With
And
- biochemical system 601, for carrying out biochemical treatment to the concentrated solution from counter-infiltration system 501.
Pre-filtration system includes：Self-cleaning filter 201 and purpose ceramic-film filter 202, it is right that self-cleaning filter 201 is used for
Coarse filtration is carried out from the Bulbus Allii processing waste water of effluent settling chamber 101 and permeate meets the water inlet water of purpose ceramic-film filter 202
Matter requires that purpose ceramic-film filter 202 is met for membrane filtration and permeate are carried out to the permeate from self-cleaning filter 201
The influent quality of filtration system is required.The concentrated solution of self-cleaning filter 201 and purpose ceramic-film filter 202 is delivered to wastewater sedimentation
Pond 101 carries out reprecipitation.
Filtration system includes：Ultrafiltration system 301 and nanofiltration system 302, ultrafiltration system 301 is for from ceramic membrane filter
The permeate of device 202 carries out hyperfiltration treatment, and nanofiltration system 302 carries out nanofiltration process for the permeate from ultrafiltration system 301.
The main component of the concentrated solution of ultrafiltration system 301 and nanofiltration system 302 is garlic polysaccharide, can be refined process for producing Bulbus Allii many
Sugar.
The permeate of counter-infiltration system 501 is delivered to garlic products production workshop section.
Above-mentioned specific embodiment be used for illustrate this utility model, preferred embodiment only of the present utility model and
, rather than to this utility model limit, in spirit of the present utility model and scope of the claims, to this reality
With new any modification, equivalent substitution and improvements made etc., protection domain of the present utility model is both fallen within.
Claims (10)
1. a kind of Bulbus Allii processing waste water recycling treatment system, it is characterised in that the Bulbus Allii processing waste water recycling treatment system
The waste water for producing in the production process to garlic products of uniting carries out recycling treatment, at the Bulbus Allii processing waste water resource
Reason system includes：
- effluent settling chamber, the effluent settling chamber are used for the waste water produce in the production process for store garlic products；
- pre-filtration system, the pre-filtration system is for carrying out at pre-filtering to the Bulbus Allii processing waste water from effluent settling chamber
Reason；
- filtration system, the filtration system is for carrying out deep filtration treatment to the permeate from pre-filtration system；
- Special Resin adsorption system, the Special Resin adsorption system is for carrying out Bulbus Allii to the permeate from filtration system
The high-selectivity adsorption of element；
- counter-infiltration system, the counter-infiltration system is for carrying out at reverse osmosiss to the water outlet from Special Resin adsorption system
Reason；And
- biochemical system, the biochemical system is for carrying out biochemical treatment to the concentrated solution from counter-infiltration system.
2. according to the Bulbus Allii processing waste water recycling treatment system described in claim 1, it is characterised in that the pre-filtering system
System includes：Self-cleaning filter and purpose ceramic-film filter, the self-cleaning filter is for the Bulbus Allii from effluent settling chamber
Processing waste water carries out coarse filtration and permeate meets the influent quality requirement of purpose ceramic-film filter, and the purpose ceramic-film filter is used for
Membrane filtration is carried out to the permeate from self-cleaning filter and permeate meets the influent quality requirement of filtration system.
3. according to the Bulbus Allii processing waste water recycling treatment system described in claim 2, it is characterised in that the self-cleaning
The concentrated solution produced in filter and purpose ceramic-film filter is delivered to effluent settling chamber.
4. according to the Bulbus Allii processing waste water recycling treatment system described in claim 2, it is characterised in that the self-cleaning
The pore size filter of filter is 50 ~ 70 μm.
5. according to the Bulbus Allii processing waste water recycling treatment system described in claim 2, it is characterised in that the ceramic membrane mistake
The pore size filter of filter is 30 ~ 50 nm.
6. according to the Bulbus Allii processing waste water recycling treatment system described in claim 1, it is characterised in that the filtration system
Including：The filtration system includes：Ultrafiltration system and nanofiltration system, the ultrafiltration system is for from the saturating of pre-filtration system
Crossing liquid carries out hyperfiltration treatment, and the nanofiltration system carries out nanofiltration process for the permeate from ultrafiltration system.
7. according to the Bulbus Allii processing waste water recycling treatment system described in claim 6, it is characterised in that the ultrafiltration system
Ultrafilter membrane molecular cut off be 80000 ~ 100000 Da.
8. according to the Bulbus Allii processing waste water recycling treatment system described in claim 6, it is characterised in that the nanofiltration system
NF membrane molecular cut off be 150 ~ 200 Da.
9. according to the Bulbus Allii processing waste water recycling treatment system described in claim 1, it is characterised in that the Special Resin
In adsorption system, resin is garlicin molecular cngram resin.
10. according to the Bulbus Allii processing waste water recycling treatment system described in claim 1, it is characterised in that the reverse osmosiss
The permeate of system is delivered to garlic products production workshop section.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108041544A (en) * | 2017-12-19 | 2018-05-18 | 安徽国瑞食品有限公司 | A kind of processing method of the compound garlic powder of seasoning Seabuckthorn Oil |
| CN108147600A (en) * | 2017-10-18 | 2018-06-12 | 安徽国瑞食品有限公司 | A kind of method from dewatered garlic flake processing waste water effective component extracting |
| CN109467274A (en) * | 2018-12-20 | 2019-03-15 | 辽宁莱特莱德环境工程有限公司 | A kind of garlic processing waste water Zero discharging system |
| CN109970286A (en) * | 2019-04-29 | 2019-07-05 | 南京瑞轩环保科技有限公司 | A kind of processing method of garlic processing waste water |
-
2016
- 2016-08-29 CN CN201620979103.1U patent/CN206051788U/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108147600A (en) * | 2017-10-18 | 2018-06-12 | 安徽国瑞食品有限公司 | A kind of method from dewatered garlic flake processing waste water effective component extracting |
| CN108041544A (en) * | 2017-12-19 | 2018-05-18 | 安徽国瑞食品有限公司 | A kind of processing method of the compound garlic powder of seasoning Seabuckthorn Oil |
| CN109467274A (en) * | 2018-12-20 | 2019-03-15 | 辽宁莱特莱德环境工程有限公司 | A kind of garlic processing waste water Zero discharging system |
| CN109970286A (en) * | 2019-04-29 | 2019-07-05 | 南京瑞轩环保科技有限公司 | A kind of processing method of garlic processing waste water |
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