CN206003891U - A kind of new single cell of thermo battery - Google Patents

A kind of new single cell of thermo battery Download PDF

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Publication number
CN206003891U
CN206003891U CN201621040160.XU CN201621040160U CN206003891U CN 206003891 U CN206003891 U CN 206003891U CN 201621040160 U CN201621040160 U CN 201621040160U CN 206003891 U CN206003891 U CN 206003891U
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China
Prior art keywords
restrictor ring
negative plate
composite sheet
single cell
flow collection
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CN201621040160.XU
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Chinese (zh)
Inventor
田千秋
夏文涛
张勇
王建勇
吴展强
伍宏明
赵洪楷
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Guizhou Meiling Power Supply Co Ltd
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Guizhou Meiling Power Supply Co Ltd
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Abstract

The utility model discloses a kind of new single cell of thermo battery, including flow collection sheet, negative plate, the composite sheet containing positive pole and barrier film, and the restrictor ring made of isolation material, wherein, restrictor ring is bonded on flow collection sheet, and negative plate is placed in restrictor ring inner bottom part, and contact with flow collection sheet, the composite sheet is placed in restrictor ring, and is located above negative plate, leaves gap between restrictor ring inwall and composite sheet and negative plate outer wall.The utility model can effectively prevent the barrier film trickling occurred under high overload or under hot environment or negative pole trickling, it is also possible to prevent from being thinned the overlap joint short circuit phenomenon that occur between cell.

Description

A kind of new single cell of thermo battery
Technical field
The utility model is related to a kind of new single cell of thermo battery, belongs to thermal cell technical field.
Background technology
Thermal cell is hot activation reserve cell, and it is to make electrolyte with fused salt, makes the one of its fusing and activation using thermal source Secondary property reserve cell.When thermal cell works, at 450 DEG C~550 DEG C, with output power, activationary time is short for internal temperature, storage Life-span length is deposited, the advantages of environmental suitability is strong.
Due to thermal cell export high-temperature molten salt battery, in working order under, electrolyte and negative material in barrier film(LiB is closed Gold)Semi-molten state is, with certain mobility.Mate with higher heat under the conditions of harsh high overload environmental mechanicses Under, the electrolyte in battery and negative material can trickle, and cause short circuit, and when serious, battery can occur combustion explosion etc. existing As.
In order to prevent the electrolyte in barrier film from trickling, in the thermal cell design in past, generally adopt and there is relatively strong absorption The magnesia of performance serves as electrolyte flow inhibitor, holds onto electricity with the capillarity that the loose structure using magnesia is produced Xie Zhi, while introducing restrictor ring in composite sheet, prevents its trickling.In addition to preventing the trickling of negative pole LiB alloy, generally adopt The trickling of LiB alloy is limited with insulation restrictor ring.
The trickling problem of electrolyte and LiB alloy is can solve the problem that although with above-mentioned measure, but when thermal cell is in high overload Under the conditions of environmental mechanicses, under such as more than 10000g impact or high heat design point, the electrolyte in barrier film and negative pole material Material LiB alloy still may overflow trickling, cause short circuit.
Traditional single cell of thermo battery structure is as shown in figure 1, its operation principle is:After thermal cell activation, in pyrotechnics In the presence of thermal source, electrolyte and negative pole Flashmelt, so as to electrochemical system is built, export electric energy.In activation, electricity Solution matter and negative material are changed into liquid phase from solid phase, volumetric expansion, and under higher stack pressure, the restrictor ring in conventional batteries is not Electrolyte and LiB alloy can be held onto completely, the two all may between barrier film and cathode contact face overflow and go out to cause short circuit(Figure Overfall 6 shown in 1).
Utility model content
The technical problems to be solved in the utility model is:A kind of new single cell of thermo battery is provided, by strengthening current limliting Ring thickness forms tubbiness semi-closed structure, is embedded in restrictor ring formation integration monomer battery by reducing compact size, with solution The technical barrier that certainly electrolyte and negative material trickle in thermal cell barrier film.
The technical solution of the utility model:A kind of single cell of thermo battery, including flow collection sheet, negative plate, containing positive pole and The composite sheet of barrier film, and the restrictor ring made of isolation material, wherein, restrictor ring is bonded on flow collection sheet, and negative plate is placed in Restrictor ring inner bottom part, and contact with flow collection sheet, the composite sheet is placed in restrictor ring, and is located above negative plate, in restrictor ring Gap is left between inwall and composite sheet and negative plate outer wall.
The current limliting ring thickness is 0.9 ~ 1.3 times of composite sheet and negative plate gross thickness.
The restrictor ring internal diameter is 0.5 ~ 2mm with the difference of composite sheet and negative plate diameter dimension.
The restrictor ring external diameter is identical with flow collection sheet outside dimension.
The isolation material is asbestos or mica.
The beneficial effects of the utility model are:Barreled semi-closed structure that the utility model is built by restrictor ring, embedded The integration monomer battery structure that pole piece is formed.Conventional thermoelectric pond monomer battery structure is compared, is had the advantage that:
1st, the tubbiness semi-closed structure that restrictor ring is formed eliminates overfall, not only limits the trickling of negative pole LiB alloy, And the trickling of the electrolyte in barrier film is limited, with higher reliability.
2nd, the single cell of thermo that the utility model is provided is semiclosed integral structure, is totally different from same size Composite sheet+semi-enclosed negative pole modular construction, reduce battery component quantity, more reliable in structure, be conducive to enhancing to exceed Carry lower environmental mechanicses performance.
3rd, the single cell of thermo that the utility model is provided has higher safe adaptability, as restrictor ring is present with pole piece Certain interval, not only can provide the tolerance existed when monomer is assembled, and can build electrolyte or barrier film under extreme condition Packing space in trickling.
4th, current limliting ring thickness and pole piece in the single cell of thermo that the utility model is provided(Composite sheet+negative plate)Gross thickness phase Closely, be not in the excessive situation of local pressure, the overlap joint that can be better protected between ultra-thin cell, widen monomer electricity The practical space in pond.
In sum, the utility model compared with prior art, can strengthen the security performance of battery, widen thermal cell heat Amount scope of design, can preferably meet hot environment and high overload thermal cell use requirement.
Description of the drawings
Fig. 1 is traditional single cell of thermo battery structural representation;
Fig. 2 is structural representation of the present utility model;
Fig. 3 is the structural representation of restrictor ring;
In figure:1 is flow collection sheet, and 2 is restrictor ring, and 3 is positive pole, and 4 is barrier film, and 5 is negative plate, and 6 is overfall.
Specific embodiment
For making the purpose of this utility model, technical scheme and advantage clearer, new to this practicality below in conjunction with accompanying drawing Type is described in further detail.
Embodiment 1:
The utility model single cell of thermo battery structure and preparation method as follows:By thick 0.5mm, ring width is 1mm, ring external diameter It is adhered on the flow collection sheet 1 of Φ 22 for the restrictor ring 2 made of asbestos ring of Φ 22,0.1mm thickness LiB alloy punching is become Φ 19.5 negative plate 5, using press prepare the composite sheet containing positive pole 3 and barrier film 4, composite sheet thickness 0.4mm, diameter of phi 19.5, Successively LiB negative plate 5 and composite sheet are embedded in and are stained with the flow collection sheet 1 of restrictor ring 2, obtain new single cell of thermo.Wherein single Body battery pole piece is Φ 19.5,2 width 1mm of restrictor ring, 2 external diameter Φ 22 of restrictor ring, and 2 internal diameter of restrictor ring with pole piece difference in diameter is 0.5mm, 2 thickness of restrictor ring are equal to LiB negative plate 5 and composite sheet gross thickness 0.5mm.
Embodiment 2:
By thick 0.8mm, ring width is 1.5mm, and ring external diameter is adhered to Φ's 72 for the restrictor ring 2 made of asbestos ring of Φ 72 0.2mm thickness LiB alloy punching, on flow collection sheet 1, is become the negative plate 5 of Φ 68, is prepared containing positive pole 3 and barrier film 4 using press Composite sheet, composite sheet thickness 0.50mm, diameter of phi 68, LiB negative plate 5 and composite sheet are successively embedded in the afflux for being stained with restrictor ring 2 In piece 1, new single cell of thermo is obtained.Wherein cell pole piece is Φ 68, restrictor ring 2 width 1.5mm, 2 external diameter Φ of restrictor ring 72,2 internal diameter of restrictor ring is 1mm with pole piece difference in diameter, 2 thickness of restrictor ring(0.8mm)Total equal to LiB negative plate 5 and composite sheet Thickness(0.70mm)1.15 times.
Embodiment 3:
By thick 1.2mm, ring width is 2mm, and ring external diameter is the afflux that the restrictor ring 2 made of mica of Φ 92 is adhered to Φ 92 0.3mm thickness LiB alloy punching, on piece 1, is become the negative plate 5 of Φ 86, is prepared containing the compound of positive pole 3 and barrier film 4 using press Piece, composite sheet thickness 1.05mm, diameter of phi 86, LiB negative plate 5 and composite sheet are successively embedded in the flow collection sheet 1 for being stained with restrictor ring 2 In, obtain new single cell of thermo.Wherein cell pole piece is Φ 86, restrictor ring 2 width 2mm, 2 external diameter Φ 92 of restrictor ring, limit 2 internal diameter of stream ring is 2mm with pole piece difference in diameter, 2 thickness of restrictor ring(1.20mm)Equal to LiB negative plate 5 and composite sheet gross thickness (1.35mm)0.9 times.
Above content be with reference to specific preferred embodiment further detailed description of the utility model, it is impossible to Identification is of the present utility model to be embodied as being confined to these explanations.Ordinary skill for the utility model art For personnel, without departing from the concept of the premise utility, some simple deduction or replace can also be made, should be all regarded For belonging to protection domain of the present utility model.

Claims (5)

1. a kind of single cell of thermo battery, including flow collection sheet(1), negative plate(5), containing positive pole(3)And barrier film(4)Compound Piece, and the restrictor ring made of isolation material(2), wherein, restrictor ring(2)It is bonded in flow collection sheet(1)On, negative plate(5)Put In restrictor ring(2)Inner bottom part, and and flow collection sheet(1)Contact, it is characterised in that:The composite sheet is placed in restrictor ring(2)Interior, and position In negative plate(5)Top, in restrictor ring(2)Inwall and composite sheet and negative plate(5)Gap is left between outer wall.
2. single cell of thermo battery according to claim 1, it is characterised in that:The restrictor ring(2)Thickness is composite sheet And negative plate(5)0.9 ~ 1.3 times of gross thickness.
3. single cell of thermo battery according to claim 1, it is characterised in that:The restrictor ring(2)Internal diameter and composite sheet And negative plate(5)The difference of diameter dimension is 0.5 ~ 2mm.
4. single cell of thermo battery according to claim 1, it is characterised in that:The restrictor ring(2)External diameter and flow collection sheet (1)Outside dimension is identical.
5. single cell of thermo battery according to claim 1, it is characterised in that:The isolation material is asbestos or mica.
CN201621040160.XU 2016-09-07 2016-09-07 A kind of new single cell of thermo battery Active CN206003891U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201621040160.XU CN206003891U (en) 2016-09-07 2016-09-07 A kind of new single cell of thermo battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201621040160.XU CN206003891U (en) 2016-09-07 2016-09-07 A kind of new single cell of thermo battery

Publications (1)

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CN206003891U true CN206003891U (en) 2017-03-08

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107293763A (en) * 2017-06-16 2017-10-24 沈阳崇华电子科技有限公司 One kind carries the poroid filming switch-board thermoelectric pool preparation method in center
CN109761589A (en) * 2019-03-15 2019-05-17 沈阳君威新能科技有限公司 A kind of ceramics thermal battery inertia block ring and preparation method thereof
CN110890564A (en) * 2019-11-29 2020-03-17 贵州梅岭电源有限公司 Preparation method of co-heating multi-monomer for thermal battery
CN114094132A (en) * 2021-11-07 2022-02-25 西安北方庆华机电有限公司 Thin single battery capable of shortening thermal battery activation time and preparation method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107293763A (en) * 2017-06-16 2017-10-24 沈阳崇华电子科技有限公司 One kind carries the poroid filming switch-board thermoelectric pool preparation method in center
CN107293763B (en) * 2017-06-16 2019-03-26 沈阳崇华电子科技有限公司 One kind having the poroid filming switch-board thermoelectric pool preparation method in center
CN109761589A (en) * 2019-03-15 2019-05-17 沈阳君威新能科技有限公司 A kind of ceramics thermal battery inertia block ring and preparation method thereof
CN110890564A (en) * 2019-11-29 2020-03-17 贵州梅岭电源有限公司 Preparation method of co-heating multi-monomer for thermal battery
CN114094132A (en) * 2021-11-07 2022-02-25 西安北方庆华机电有限公司 Thin single battery capable of shortening thermal battery activation time and preparation method

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