CN205951007U - Sodium -sulfur cell solid electrolyte ceramic pipe forming device - Google Patents

Sodium -sulfur cell solid electrolyte ceramic pipe forming device Download PDF

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Publication number
CN205951007U
CN205951007U CN201620889962.1U CN201620889962U CN205951007U CN 205951007 U CN205951007 U CN 205951007U CN 201620889962 U CN201620889962 U CN 201620889962U CN 205951007 U CN205951007 U CN 205951007U
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China
Prior art keywords
station
sodium
solid electrolyte
sebific duct
ceramic pipe
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Active
Application number
CN201620889962.1U
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Chinese (zh)
Inventor
徐小刚
徐培敏
陈福平
周日生
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Shanghai Electric Enterprise Development Co., Ltd
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Shanghai Electric Sodium Sulfur Energy Storage Technology Co Ltd
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Abstract

The utility model discloses a sodium -sulfur cell solid electrolyte ceramic pipe forming device, including the carousel, be equipped with on the top surface of carousel and center on reinforced station, pressure equipment station and the demoulding station of the circumference distribution of carousel, just reinforced station the pressure equipment station with demoulding station is last all to be equipped with a forming die, forming die including be used for with forming die with the fixed base of carousel on the base top surface with the coaxial fixed plug of base and cup jointing the base with the rubber tube in the radial outside of plug, the rubber tube with form the die cavity that corresponds with sodium -sulfur cell solid electrolyte ceramic pipe shape between plug radial, the pressure equipment station includes a main pressure container, the main pressure container includes that one can cup joint the main bag in the radial outside of rubber tube, and be used for main bag bottom will the bottom closing cap of rubber tube locking, main pressure container and a force pump intercommunication.

Description

A kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus
Technical field
The utility model is related to a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus.
Background technology
Sodium-sulphur battery is using solid electrolyte ceramic pipe as electrolyte and barrier film, metallic sodium as negative material, non-gold Belong to sulphur as the secondary cell of positive electrode.It has the advantages that capacity is big, small volume, life-span length, efficiency high, can be applicable to electricity The fields such as net peak load shifting, emergency power supply, new forms of energy access, electric energy quality optimizing.
Isostatic pressing is Na- β "-Al2O3The committed step of solid electrolyte ceramic pipe prepared by powder.In traditional handicraft In, solid electrolyte ceramic pipe adopts wet type isostatic pressing method, and its main flow is that powder adds mould, i.e. gum cover In mould, put in pressure vessel after sealing, degasification, inject pressurization between pressure vessel and gum cover mould with high-pressure pump and be situated between Matter, the such as liquid such as water or oil, compressing.The material of gum cover mould is quality of rubber materials, such as polyurethane etc., compacting be divided into pressurization, Pressurize and stress-relief process, Na- β "-Al2O3Powder is compressing in the die cavity of mould.
The feature of wet type isostatic pressing method is that gum cover mould is contacted with pressure medium in pressing process.This side Method is difficult to automation mechanized operation, low production efficiency, is not suitable for producing in enormous quantities;Meanwhile, operating personnel need in the demoulding with Pressure medium contacts, and working condition is poor.
But sodium-sulphur battery will enter merchandized handling it is desired to solid electrolyte ceramic pipe is for the energy produced in enormous quantities Power.
Utility model content
The purpose of this utility model is to overcome the deficiencies in the prior art, providing a kind of sodium-sulphur battery solid electrolyte pottery Porcelain tube shaped device, it is avoided that traditional wet isostatic pressing is difficult to automation mechanized operation, the shortcoming of low production efficiency, reality Show the automatic continuous production of sodium-sulphur battery solid electrolyte ceramic pipe green compact, effectively increase production efficiency.
A kind of technical scheme realizing above-mentioned purpose is:A kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus, bag Include rotating disk it is characterised in that:
The top surface of described rotating disk is provided with the charging station of the circle distribution around described rotating disk, press-fits station and stripper Position, and described charging station, described press-fit a mould is equipped with station and described demoulding station;
Described mould includes for the base that described mould is fixing with described rotating disk, in described base top surface The co-axially fixed plug of upper and described base and be socketed in described base and the sebific duct of described plug radial outside, described sebific duct Form die cavity corresponding with sodium-sulphur battery solid electrolyte ceramic tube shape between the radial direction of described plug;
Described press-fit station and include a principal pressure container, described principal pressure container includes one and can be socketed in described sebific duct The main bag of radial outside, and the bottom cover for locking described sebific duct in described main bag bottom, described principal pressure container Connect with a compression pump.
Further, described press-fit station also include one be located at described rotating disk below press-fit lowering or hoisting gear.
Further, described press-fit station also include one connect described in press-fit lowering or hoisting gear, described bottom cover and Described compression pump press-fit sensor.
Further, in described mould, the top of described sebific duct is provided with charge door, and described charge door passes through sebific duct plug Closing.
Further, described charging station includes feeding machine arm, the charging lowering or hoisting gear below described rotating disk, Nozzle corresponding with described charge door position, and it is located at the horizontal vibration device at described charging lowering or hoisting gear top.
Further, described charging station also includes shaking with described nozzle, described charging lowering or hoisting gear and described level The charging sensor that dynamic device connects.
Further, described demoulding station include demoulding mechanical arm, rubber tube clip, green compact folder, cleaning brush, and with described The demoulding sensor that demoulding mechanical arm, described rubber tube clip, described green compact folder and described cleaning brush are simultaneously connected with.
Further, the radially facing surface between described sebific duct and described sebific duct plug is inverted cone surface.
Further, the contact surface between the outer circumference surface of the inner peripheral surface of described sebific duct and described base is the conical surface, and The outer circumference surface of described base is provided with the between outer land terrace that a bottom surface to described sebific duct is supported, the inner circle of described sebific duct Side face is provided with a top plane-plane contact with described base, makes the top surface of described base support the interior step surface of described sebific duct.
Further, the top surface of described rotating disk is additionally provided between described demoulding station and described charging station etc. Treat station, described wait station is provided with described mould.
Employ a kind of technical scheme of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model, including Rotating disk, the top surface of described rotating disk is provided with the charging station of the circle distribution around described rotating disk, press-fits station and demoulding station, And described charging station, described press-fit a mould is equipped with station and described demoulding station;Described mould bag Include for the base that described mould is fixing with described rotating disk, co-axially fixed with described base on described base top surface Plug and be socketed in described base and the sebific duct of described plug radial outside, shape between the radial direction of described sebific duct and described plug Become die cavity corresponding with sodium-sulphur battery solid electrolyte ceramic tube shape;Described press-fit station and include a principal pressure container, institute State principal pressure container and include a main bag that can be socketed in described sebific duct radial outside, and in described main bag bottom by institute State the bottom cover of sebific duct locking, described principal pressure container is connected with a compression pump.It has the technical effect that:Which obviate tradition Wet type isostatic pressing is difficult to automation mechanized operation, and the shortcoming of low production efficiency is it is achieved that sodium-sulphur battery solid electrolyte is made pottery The automatic continuous production of porcelain tube green compact, effectively increases production efficiency.
Brief description
Fig. 1 is a kind of rotating disk schematic diagram of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model.
Fig. 2 is that a kind of mould of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model is illustrated Figure.
Fig. 3 is that a kind of charging station of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model is illustrated Figure.
Fig. 4 is that a kind of station that press-fits of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model is illustrated Figure.
Fig. 5 is that a kind of demoulding station of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model is illustrated Figure.
Specific embodiment
Refer to Fig. 1 to Fig. 5, inventor of the present utility model is in order to be able to preferably enter to the technical solution of the utility model Row understands, below by specifically embodiment, and combines accompanying drawing and is described in detail:
Refer to Fig. 1, a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model, including a water The rotating disk 900 of flat setting, the top surface of rotating disk 900 is evenly equipped with four stations, is followed successively by charging station 2, press-fits station 3, the demoulding Station 4 and wait station 5.One one-tenth for the shaping of sodium-sulphur battery solid electrolyte ceramic pipe is designed with each described station Pattern tool 1.
Fig. 2 is mould 1, including base 11, plug 12, sebific duct 13 and sebific duct plug 14.The bottom surface of base 11 and rotating disk 900 top surface is fixed.Plug 12 is coaxially fixed on the top surface of base 11, by positioned at base 11 between plug 12 and base 11 The fixing pin 111 of end face center is fixing.Sebific duct 13 bottom surface opening, sebific duct 13 is coaxially socketed in base 11 and the footpath of plug 12 is outside Side.Contact surface between the outer circumference surface of the inner peripheral surface of sebific duct 13 and base 11 is the conical surface.Set on the outer circumference surface of base 11 There is a between outer land terrace 112 that sebific duct 13 bottom surface is supported.The inner peripheral surface of sebific duct 13 is provided with one and base 11 top surface Face contact, make base 11 top surface support the interior step surface 131 of sebific duct 13.
Formed and sodium-sulphur battery solid electrolyte ceramic tube shape between the outer circumference surface of plug 12 and top surface, and sebific duct 13 Corresponding die cavity 15, base 1 be used for plug 12 and sebific duct 13 positioned it is ensured that obtained with sodium-sulphur battery solid electrolyte The wall thickness of earthenware is uniform.The top of sebific duct 13 is provided with a charge door 132, and charge door 132 is closed by sebific duct plug 14. Radially facing surface between sebific duct plug 14 and charge door 132 is an inverted cone surface, to prevent sebific duct plug 14 in pressure process from coming off.
Charging station 2 includes feeding machine arm 21, is located at the charging lowering or hoisting gear 22 of rotating disk 900 lower section, rises positioned at charging Falling unit 22 top, can make horizontal vibration device 23, the nozzle 24 of mould 1 horizontal vibration, and charging sensor 25.When Do not load Na- β "-Al2O3When the mould 1 of powder runs to charging station 2, charging sensor 25 sends a signal first To feeding machine arm 21, feeding machine arm 21 is made to take sebific duct plug 14 away, due to charging sensor 25 and charging lowering or hoisting gear 22 Between be provided with buffer, therefore charging sensor 25 time delay after sebific duct plug 14 is taken away by feeding machine arm 21 send a signal To charging lowering or hoisting gear 22, lift mould 1, make the charge door 132 of mould 1 be directed at nozzle 24.Due to charging sensing It is equipped with buffer between device 25 and nozzle 24 and horizontal vibration device 23, and the time delay of this two buffers is identical but be longer than Buffer between charging sensor 25 and charging lowering or hoisting gear 22, therefore after mould 1 is promoted to specified altitude assignment, charging Sensor 25 sends signal to nozzle 24 and horizontal vibration device 23 simultaneously, and nozzle 24 feeds to die cavity 15, horizontal vibration Device 23 carries out horizontal vibration to mould 1.Because the contact surface between sebific duct 13 and base 11 is improved, can prevent Shift between sebific duct 13 and plug 12 in vibration processes, thus ensureing the equal of sodium-sulphur battery solid electrolyte ceramic thickness of pipe wall Even property, during charging, Na- β "-Al2O3Powder enters die cavity 15 from charge door 132, and fills die cavity 15 by gravity fall.Pass through The aperture of adjustment nozzle 24 and opening time can control charging rate;By adjusting the vibration frequency energy of horizontal vibration device 23 Enough control Na- β "-Al2O3The bulk density of powder.After charging finishes, that is, after being fed to specified altitude, charging sensor 25 sends Signal, makes charging lowering or hoisting gear 22 control mould 1 to decline, makes the bottom surface of mould 1 contour with the top surface of rotating disk 900, Sebific duct plug 14 is reinstalled charge door 132 by feeding machine arm 21.
Press-fit station 3 to include:Press-fit lowering or hoisting gear 31, principal pressure container 32, compression pump 33 positioned at mould 1 lower section With press-fit sensor 34.Principal pressure container 32 includes main bag 321 and is used for the bottom cover 322 of main bag 321 bottom lock. Main bag 321 is made with polyurethane or rubber.Compression pump 33 is connected with principal pressure container 32.Press-fit sensor 34 and filling is detected Na- β "-Al2O3The mould 1 of powder runs to when press-fiting station 3, sends signal, and triggering press-fits lowering or hoisting gear 31, will become Pattern tool 1 raises to specified altitude assignment, so that mould 1 is located in the main bag 321 of principal pressure container 32, that is, the footpath of sebific duct 13 is outside Side is socketed the main bag 321 of principal pressure container 32.After mould 1 lifting puts in place, press-fit sensor 34 to principal pressure container 32 Bottom cover 322 sends signal, after making the bottom cover 322 of principal pressure container 32 lock sebific duct 13, by press-fiting sensor 34 triggering compression pumps 33, compression pump 33 connects principal pressure container 32, and therefore compression pump 33 adds in the radial outside injection of main bag 321 Pressure medium, makes principal pressure container 32 start to Na- the β "-Al in die cavity 152O3Powder is suppressed, and compacting is divided into pressurization, pressurize And stress-relief process.Na-β″-Al2O3Powder is compressing in the die cavity 15 of mould 1.Pressing speed is 35MPa/s, highest Pressure is 200MPa, and the dwell time is 30s, and release is divided into three phases, and the release speed in 200~55MPa stage is 25MPa/ The release speed in s, 55~15MPa stage is 1.5MPa/s, and the release speed of 15MPa to standard atmospheric pressure stage is 0.25MPa/ S, manually controllable.After compacting finishes, press-fiting sensor 34 makes bottom cover 322 unlock, and synchronous press mounting sensor 34 sends one Individual signal, makes to press-fit lowering or hoisting gear 31 and declines, and makes the bottom surface of mould 1 parallel with the top surface of rotating disk 900.
Such design, by pressure medium injects the radial outside of main bag 321, using dry type isostatic pressing process Greatly improve the production capacity of sodium-sulphur battery solid electrolyte ceramic pipe, adapted to sodium-sulphur battery and will enter merchandized handling Require.Such design makes main bag 321 pressure medium be sealed in outside the main bag 321 of principal pressure container 32, in pressing process Mould 1 is not contacted with pressure medium.It is thus susceptible to realize oneself of sodium-sulphur battery solid electrolyte ceramic pipe green compact production Dynamicization operates, and production efficiency is high, is suitable for producing in enormous quantities.
Demoulding station 4 includes demoulding mechanical arm 41, rubber tube clip 42, green compact folder 43, cleaning brush 44 and demoulding sensor 45. Demoulding sensor 45 and green compact folder 43, be all connected with buffer between cleaning brush 44, demoulding sensor 45 and demoulding mechanical arm 41 it Between be connected with two-way circuit in parallel, a route road is provided with buffer, an in addition route road, and demoulding sensor 45 is directly connected to the demoulding Mechanical arm 41.It is connected with two-way buffer in parallel between demoulding sensor 45 and rubber tube clip 42, and the time delay of this two-way buffer It is different.When the mould 1 that demoulding sensor 45 detects equipped with sodium-sulphur battery solid electrolyte ceramic pipe green compact runs During to demoulding station 4, first trigger demoulding mechanical arm 41, then Time-delayed trigger rubber tube clip 42, green compact folder 43, cleaning brush 44, glue successively Pipe clamp 42 and demoulding mechanical arm 41, demoulding sensor 45 is for the first time after triggering demoulding mechanical arm 41, and demoulding mechanical arm 41 is by sebific duct Plug 14 is taken away.Demoulding sensor 45 triggers rubber tube clip 42, and sebific duct 13 is lifted by rubber tube clip 42, and after sebific duct 13 is removed, the demoulding passes Sensor 45 triggering green compact folder 43, described green compact are lifted by green compact folder 43, are put on blanking bench.Then, demoulding sensor 45 triggers Cleaning brush 44, cleaning brush 44 is cleaned to whole plug 12 and base 11, removes surplus material above.After cleaning finishes, take off Sebific duct 13 is placed back on base 11 by mould sensor 45 triggering rubber tube clip 42, finally, second triggering of demoulding sensor 45 Sebific duct plug 14 is resetted by demoulding mechanical arm 41.
Charging, press-fit and be fully completed with knockout course after, 90 ° of rotating disk 900 rotate counterclockwise, the shaping mould of charging station 2 Tool 1 goes to and press-fits station 3, and the mould 1 press-fiting station 3 goes to demoulding station 4.The mould 1 of demoulding station 4 goes to Treat station 5.The mould waiting station 5 goes to charging station 1, so circulates.
A kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus of the present utility model avoid traditional wet isostatic pressed Shaping is difficult to automation mechanized operation, and the shortcoming of low production efficiency is it is achieved that sodium-sulphur battery solid electrolyte ceramic pipe green compact Automatic continuous production, effectively increases production efficiency.
Those of ordinary skill in the art is it should be appreciated that above embodiment is intended merely to illustrate that this practicality is new Type, and be not used as being to restriction of the present utility model, as long as in spirit of the present utility model, to the above The change of embodiment, modification all will fall in Claims scope of the present utility model.

Claims (10)

1. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus, including rotating disk it is characterised in that:
The top surface of described rotating disk is provided with the charging station of the circle distribution around described rotating disk, press-fits station and demoulding station, And described charging station, described press-fit a mould is equipped with station and described demoulding station;
Described mould includes for the base that described mould is fixing with described rotating disk, on described base top surface with The co-axially fixed plug of described base and be socketed in described base and the sebific duct of described plug radial outside, described sebific duct and institute State formation die cavity corresponding with sodium-sulphur battery solid electrolyte ceramic tube shape between the radial direction of plug;
Described press-fit station and include a principal pressure container, described principal pressure container includes one and can be socketed in described sebific duct radially The main bag in outside, and the bottom cover for locking described sebific duct in described main bag bottom, described principal pressure container and Individual compression pump connection.
2. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 1 it is characterised in that:Described Press-fit station also include one be located at described rotating disk below press-fit lowering or hoisting gear.
3. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 2 it is characterised in that:Described Press-fit station also include one connect described in press-fit lowering or hoisting gear, described bottom cover and described compression pump press-fit sensor.
4. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 1 it is characterised in that:Described In mould, the top of described sebific duct is provided with charge door, and described charge door is closed by sebific duct plug.
5. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 4 it is characterised in that:Described Charging station includes feeding machine arm, and the charging lowering or hoisting gear below described rotating disk is corresponding with described charge door position Nozzle, and it is located at the horizontal vibration device at described charging lowering or hoisting gear top.
6. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 5 it is characterised in that:Described Charging station also includes the charging sensor being connected with described nozzle, described charging lowering or hoisting gear and described horizontal vibration device.
7. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 4 it is characterised in that:Described Demoulding station include demoulding mechanical arm, rubber tube clip, green compact folder, cleaning brush, and with described demoulding mechanical arm, described rubber tube clip, The demoulding sensor that described green compact folder is simultaneously connected with described cleaning brush.
8. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 4 it is characterised in that:Described Radially facing surface between sebific duct and described sebific duct plug is inverted cone surface.
9. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 1 it is characterised in that:Described Contact surface between the outer circumference surface of the inner peripheral surface of sebific duct and described base is to set on the conical surface, and the outer circumference surface of described base There is the between outer land terrace that a bottom surface to described sebific duct is supported, the inner peripheral surface of described sebific duct is provided with one and described base Top plane-plane contact, make the top surface of described base support the interior step surface of described sebific duct.
10. a kind of sodium-sulphur battery solid electrolyte ceramic pipe forming apparatus according to claim 1 it is characterised in that:Institute The wait station being additionally provided between described demoulding station and described charging station, described wait station are stated on the top surface of rotating disk It is provided with described mould.
CN201620889962.1U 2016-08-17 2016-08-17 Sodium -sulfur cell solid electrolyte ceramic pipe forming device Active CN205951007U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106863579A (en) * 2017-03-13 2017-06-20 上海电气钠硫储能技术有限公司 A kind of sodium-sulphur battery solid electrolyte ceramic pipe shaping mould positioner

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106863579A (en) * 2017-03-13 2017-06-20 上海电气钠硫储能技术有限公司 A kind of sodium-sulphur battery solid electrolyte ceramic pipe shaping mould positioner

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Legal Events

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C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20200917

Address after: Room 1201, no.1346 Gonghe Xin Road, Jing'an District, Shanghai 200070

Patentee after: Shanghai Electric Enterprise Development Co., Ltd

Address before: 201815 Shanghai Jiading District City Jia Zhu Road No. 1997

Patentee before: SHANGHAI ELECTRIC SODIUM SULFUR ENERGY STORAGE TECHNOLOGY Co.,Ltd.

TR01 Transfer of patent right