CN205856615U - A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system - Google Patents

A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system Download PDF

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Publication number
CN205856615U
CN205856615U CN201620317461.6U CN201620317461U CN205856615U CN 205856615 U CN205856615 U CN 205856615U CN 201620317461 U CN201620317461 U CN 201620317461U CN 205856615 U CN205856615 U CN 205856615U
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anode
negative electrode
storage tank
connecting tube
ozone
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方琦
方锦
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Jinhua Runda Environmental Protection Technology Co Ltd
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Jinhua Runda Environmental Protection Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The utility model discloses a kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system, including negative electrode storage tank, anode storage tank, electrolytic module and constant-current switch power source, described electrolytic module is connected with described negative electrode storage tank and anode storage tank respectively by pipeline, described electrolytic module includes catholyte assembly and anode electrolysis assembly, described constant-current switch power source is connected with catholyte assembly and the anode electrolysis assembly of electrolytic module respectively by wire, and described negative electrode storage tank and anode storage tank are respectively positioned on above described electrolytic module.A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system simple in construction of the present utility model, can need to produce hydrogen rich water and Ozone Water according to difference, hydrogen and ozone enter bottom storage tank, improve mixed effect, use pure water or deionized water as raw material, security performance is good, ozone does not contains by-product carcinogen etc., comprehensive use cost is low, and water itself is as cooling medium, electrolytic module improves the luminous efficiency of hydrogen and ozone without other cooling device, the cathod catalyst of employing Particular craft manufacture and anode catalyst.

Description

A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system
Technical field
This utility model belongs to technical field of electrochemistry, particularly relates to a kind of PEM membrane low-voltage electrolysis hydrogen, smelly oxygen evolution system System.
Background technology
Hydrogen molecule can remove human free radical, and the acute and chronic diseases causing old and feeble and multiple reason free radical has very Good therapeutical effect." modern medicine thinks that the corruption of material is the process of acidifying (oxidation), and Smoking And Drinking, environmental pollution etc. are all A large amount of peroxy radicals are produced in human body during meeting, its meeting vandalism cell tissue, causes genopathy and body aging, activity Hydrogen can effectively dispel internal free radical, and it is known that hydrogen rich water has all mankind such as exceeding vitamin C, carotene, lecithin The non-oxidizability of polyphenoils, to allergic dermatitis, constipation, hypertension, diabetes, cancer etc. by free radical cause all kinds of Symptom has powerful protective action, often drinks hydrogen rich water, it is possible to well enhance metabolism, and makes each cell to protect Hold the state of health, dispel body rust, slow down aging ".
Ozone has broad-spectrum sterilization, easy to use a, feature without any residual and instantaneously sterilising, and completely avoid Learn the harm that disinfectant is brought to environment, be a kind of preferably sterilization material, the most permitted in the U.S., Japan, Europe Many countries are widely used in public water system, food pharmaceutical, industrial processes, health care, particularly agricultural product produce, processing and Storage and transport process has fairly large application.
Existing ozone generating-device there is also in produced ozone and includes carcinogen etc., the low work of ozone concentration containing by-product Making environmental requirement high, comprehensive use cost is high, there is the shortcomings such as potential safety hazard, and yet there are no and can produce hydrogen, smelly simultaneously The report that the generating means of oxygen is relevant.
Utility model content
It is low that technical problem to be solved in the utility model is to provide a kind of simple in construction, efficiency PEM membrane high, low cost Pressure electrolysis hydrogen, ozone generation system.
For solving above-mentioned technical problem, this utility model provides a kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system, Including negative electrode storage tank, anode storage tank, electrolytic module and constant-current switch power source, described electrolytic module by pipeline respectively with institute The negative electrode storage tank stated connects with anode storage tank, and described electrolytic module includes catholyte assembly and anode electrolysis assembly, institute The constant-current switch power source stated is connected with catholyte assembly and the anode electrolysis assembly of electrolytic module respectively by wire, described Negative electrode storage tank and anode storage tank are respectively positioned on above described electrolytic module, and the hydrogen that electrolysis produces is directly entered negative electrode water storage Case, the ozone that electrolysis produces is directly entered anode storage tank, can produce high-concentration ozone water, and the ozone concentration of output is up to 25% (accounting for ozone and the percentage ratio of oxygen gross weight).
Further, described negative electrode storage tank upper end is provided with the first gas outlet, and lower end is provided with the first connecting tube With the second connecting tube;Described anode storage tank upper end is provided with the second gas outlet, and lower end is provided with the 3rd connecting tube and Four connecting tubes.
Further, described catholyte assembly includes negative electrode water tank and the minus plate being arranged in negative electrode water tank, institute The minus plate side stated is provided with negative pole connecting portion, and described negative pole connecting portion is by wire with described constant-current switch power source even Connecing, described first connecting tube is connected with the hydrogen air vent of negative electrode water tank upper end, described second connecting tube and negative electrode water tank lower end Negative electrode water inlet connects;Described anode electrolysis assembly includes anode water tank and the positive plate being arranged in anode water tank, described Positive plate side be provided with positive pole connecting portion, described positive pole connecting portion is by wire and described constant-current switch power source even Connect;It is noble metal electrode room between described minus plate and positive plate, described 3rd connecting tube and the ozone of anode water tank upper end Air vent connects, and described 4th connecting tube is connected with the anode water inlet of anode water tank lower end.
Further, described minus plate includes negative electrode clamping plate, and described negative electrode clamping plate one side surface is the most successively It is provided with cathode micro porous plate, cathode catalyst layer, negative electrode silica gel tetrafluoro cushion and negative electrode, anode intermediate material proton exchange;Institute The positive plate stated includes that anode clamp, described anode clamp one side surface are disposed with anode micro porous plate, sun from inside to outside Electrode catalyst layer, anode gel tetrafluoro cushion and negative electrode, anode intermediate material proton exchange;Described minus plate and positive plate phase To the setting that keeps at a certain distance away, it is electrode chamber between the two.It is on-consumable type during the core component operation work of electrolytic module, Having only to ensure that the electrical conductivity of electrolyte (pure water or deionized water) meets the requirements, equipment can be stabilized operation.Described Minus plate and positive plate share same negative electrode, anode intermediate material proton exchange, in its both sides respectively added with silica gel tetrafluoro cushion, To guarantee that negative electrode, anode intermediate material proton exchange do not damage.
Further, the composition of described cathode catalyst layer comprises following raw material: chloroplatinic acid 0.02-3.1 part, activated carbon 0.07-11 part and isopropanol 2-22 part, manufacture method is by formula mix and blend by each for cathod catalyst component, obtains mixture; Use the mixture described in 40-100 DEG C of pure water sucking filtration cleaning;Dry the described mixture after sucking filtration;The system of rolling or compacting are dried After described mixture, to obtain final product.
Further, the composition of described anode catalyst layer comprises following raw material by weight percentage: plumbi nitras 190-600 part, copper nitrate 7-42 part, nitric acid 1-17 part, sodium fluoride 0.08-1.7 part, chlorization high tin 0.07-8 part, Butter of antimony. 0.06-10 part, hydrochloric acid 0.6-13 part and butanol 5-49 part, manufacture method is for enter chlorization high tin, Butter of antimony., hydrochloric acid and butanol The anti-Passivation Treatment of row, afterwards with plumbi nitras, copper nitrate, nitric acid and sodium fluoride mix and blend, then in the melting pan of 50-100 DEG C It is electrolysed, uses the unidirectional current of 30A-40A;By the material 70 DEG C drying after electrolysis, grind and get final product.
Further, it is provided with relay between the described wire between positive pole connecting portion and described constant-current switch power source Device, during to ensure to close power work switch, device is completely in off-position.
Further, described the first connecting tube, the second connecting tube, the 3rd connecting tube and the 4th connecting tube are all by high by third The connecting tube that alkene nitrile NBR/PVC oil resistant, resistance to ozone material are made, prevents corrosive pipeline.
Further, described cathode micro porous plate and anode micro porous plate are POROUS TITANIUM PLATE.
Beneficial effect: a kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system simple in construction of the present utility model, can basis Difference needs to produce hydrogen rich water and Ozone Water, hydrogen and ozone and enters bottom storage tank, improves mixed effect, hydrogen and ozone Luminous efficiency is high, uses pure water or deionized water as raw material, and security performance is good, does not contains by-product carcinogen etc. in ozone, Comprehensive use cost is low, and water itself is as cooling medium, and electrolytic module, without other cooling device, uses uniqueness The cathod catalyst of technique manufacture and anode catalyst improve the luminous efficiency of hydrogen and ozone.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model;
Fig. 2 is the structural representation of this utility model electrolytic module;
Fig. 3 is the structural representation of this utility model minus plate;
Fig. 4 is the structural representation of this utility model positive plate.
In figure, 1, negative electrode storage tank, the 101, first connecting tube, the 102, second connecting tube, the 103, first gas outlet, 2, sun Pole storage tank, the 201, the 3rd connecting tube, the 202, the 4th connecting tube, the 203, second gas outlet, 3, electrolytic module, 301, negative electrode water Case, 3011, negative pole connecting portion, 3012, minus plate, 3012a, negative electrode clamping plate, 3012b, cathode micro porous plate, 3012c, cathode catalysis Oxidant layer, 3012d, negative electrode silica gel tetrafluoro cushion, 3012e, negative electrode, anode intermediate material proton exchange, 3013, hydrogen air vent, 3014, negative electrode water inlet, 302, anode water tank, 3021, positive pole connecting portion, 3022, positive plate, 3022a, negative electrode clamping plate, 3022b, anode micro porous plate, 3022c, anode catalyst layer, 3022d, anode gel tetrafluoro cushion, 303, electrode chamber, 4, constant current Switching Power Supply, 5, relay.
Detailed description of the invention
As employed some vocabulary in the middle of description and claim to censure specific components.Those skilled in the art should It is understood that hardware manufacturer may call same assembly with different nouns.This specification and claims are not with name The difference claimed is used as distinguishing the mode of assembly, but is used as the criterion distinguished with assembly difference functionally.As logical " including " mentioned in the middle of piece description and claim is an open language, therefore should be construed to " include but do not limit In ".Description subsequent descriptions is for implementing better embodiment of the present utility model, and right described description is that this utility model is described Rule for the purpose of, be not limited to scope of the present utility model.Protection domain of the present utility model is when regarding appended power Profit requires that defined person is as the criterion.
Below in conjunction with accompanying drawing, this utility model is described in further detail, but not as to restriction of the present utility model.
A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system, including negative electrode storage tank 1, anode storage tank 2, electrolytic module 3 and constant-current switch power source 4, described electrolytic module 3 is by pipeline respectively with described negative electrode storage tank 1 and anode storage tank 2 even Logical, described electrolytic module 3 includes that catholyte assembly and anode electrolysis assembly, described constant-current switch power source 4 are divided by wire It is not connected with catholyte assembly and the anode electrolysis assembly of electrolytic module 3, described negative electrode storage tank 1 and anode storage tank 2 It is respectively positioned on above described electrolytic module 3.
Particularly preferred, described negative electrode storage tank 1 upper end is provided with the first gas outlet 103, and lower end is provided with first Connecting tube 101 and the second connecting tube 102;Described anode storage tank 2 upper end is provided with the second gas outlet 203, and lower end is arranged There is the 3rd connecting tube 201 and the 4th connecting tube 202.
Particularly preferred, described catholyte assembly includes negative electrode water tank 301 and the moon being arranged in negative electrode water tank 301 Pole plate 3012, described minus plate 3012 side is provided with negative pole connecting portion 3011, and described negative pole connecting portion 3011 is by leading Line is connected with described constant-current switch power source 4, described first connecting tube 101 and the hydrogen air vent 3013 of negative electrode water tank 301 upper end Connecting, described second connecting tube 102 is connected with the negative electrode water inlet 3014 of negative electrode water tank 301 lower end;Described anode electrolysis group Part includes anode water tank 302 and the positive plate 3022 being arranged in anode water tank 302, and described positive plate 3022 side is provided with Positive pole connecting portion 3021, described positive pole connecting portion 3021 is connected with described constant-current switch power source 4 by wire;Described the moon It is electrode chamber 303 between pole plate 3012 and positive plate 3022, described 3rd connecting tube 201 and the ozone of anode water tank 302 upper end Air vent 3023 connects, and described 4th connecting tube 202 is connected with the anode water inlet 3024 of anode water tank 302 lower end.As entering One step is preferred, it is possible to negative electrode storage tank 1 and/or anode storage tank 2 are set to two the most independent water tanks, respectively It is connected with water inlet, gas outlet.As it is further preferred that can also directly use pure water to pass through electrolytic module 3 produce richness Hydrogen water and Ozone Water are without arranging negative electrode storage tank 1 and anode storage tank 2.
Particularly preferred, described minus plate 3012 includes negative electrode clamping plate 3012a, described negative electrode clamping plate 3012a side Surface is disposed with cathode micro porous plate 3012b, cathode catalyst layer 3012c, negative electrode silica gel tetrafluoro cushion 3012d from inside to outside With negative electrode, anode intermediate material proton exchange 3012e;Described positive plate 3022 includes anode clamp 3022a, described anode Clamping plate 3022a mono-side surface is disposed with anode micro porous plate 3022b, anode catalyst layer 3022c, anode gel from inside to outside Tetrafluoro cushion 3022d and negative electrode, anode intermediate material proton exchange 3012e;Described minus plate 3012 and positive plate 3022 phase To the setting that keeps at a certain distance away, it is electrode chamber 303 between the two.
Particularly preferred, the composition of described cathode catalyst layer 3012c comprises following raw material: chloroplatinic acid 0.02-3.1 Part, activated carbon 0.07-11 part and isopropanol 2-22 part, manufacture method is by formula mix and blend by each for cathod catalyst component, Obtain mixture;Use the mixture described in 40-100 DEG C of pure water sucking filtration cleaning;Dry the described mixture after sucking filtration;Roll system or Described mixture after compacting drying, to obtain final product.
Particularly preferred, the composition of described anode catalyst layer 3022c comprises following raw material by weight percentage: Plumbi nitras 190-600 part, copper nitrate 7-42 part, nitric acid 1-17 part, sodium fluoride 0.08-1.7 part, chlorization high tin 0.07-8 part, three Antimony chloride 0.06-10 part, hydrochloric acid 0.6-13 part and butanol 5-49 part, manufacture method be by chlorization high tin, Butter of antimony., hydrochloric acid and Butanol carries out anti-Passivation Treatment, afterwards with plumbi nitras, copper nitrate, nitric acid and sodium fluoride mix and blend, then at 50-100 DEG C Melting pan is electrolysed, uses the unidirectional current of 30A-40A;By the material 70 DEG C drying after electrolysis, grind and get final product.
Particularly preferred, arrange between the wire between described positive pole connecting portion 3021 and described constant-current switch power source 4 There is relay 5.
Particularly preferred, first described connecting tube the 101, second connecting tube the 102, the 3rd connecting tube 201 and the 4th connects The connecting tube that pipe 202 is all made up of high acrylonitrile NBR/PVC oil resistant, resistance to ozone material.
Particularly preferred, described cathode micro porous plate 3012b and anode micro porous plate 3022b is POROUS TITANIUM PLATE.
PEM low tension solution generation system can produce hydrogen and two kinds of materials of ozone simultaneously, can obtain hydrogen rich water and smelly Oxygen water, principle is to use negative and positive the two poles of the earth electrolysis deionized water of low-voltage DC conductive polymers membrane electrode, and water is at solution interface On be separated by electrolysis with the form of proton exchange, hydrogen from cathode solution interface directly discharge generate hydrogen, oxygen molecule is at anode circle Obtain energy because of the electron excitation of high-density current generation on face, and aggregate into ozone molecule.
A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system simple in construction of the present utility model, can need system according to difference Take hydrogen rich water and Ozone Water, hydrogen and ozone to enter bottom storage tank, improve the luminous efficiency of mixed effect, hydrogen and ozone Height, uses pure water or deionized water as raw material, and security performance is good, does not contains by-product carcinogen etc., comprehensively use in ozone Low cost, and water itself is as cooling medium, and electrolytic module, without other cooling device, uses Particular craft manufacture Cathod catalyst and anode catalyst improve the luminous efficiency of hydrogen and ozone.
Described above illustrate and describes some preferred embodiments of the present utility model, but as previously mentioned, it should be understood that this Utility model is not limited to form disclosed herein, is not to be taken as the eliminating to other embodiments, and can be used for various Other combinations, amendment and environment, and can be in utility model contemplated scope described herein, by above-mentioned teaching or association area Technology or knowledge be modified.And the change that those skilled in the art are carried out and change are without departing from spirit of the present utility model and model Enclose, the most all should be in the protection domain of this utility model claims.

Claims (7)

1. a PEM membrane low-voltage electrolysis hydrogen, ozone generation system, it is characterised in that: include negative electrode storage tank (1), anode water storage Case (2), electrolytic module (3) and constant-current switch power source (4), described electrolytic module (3) is stored up with described negative electrode respectively by pipeline Water tank (1) connects with anode storage tank (2), and described electrolytic module (3) includes catholyte assembly and anode electrolysis assembly, described Constant-current switch power source (4) be connected with catholyte assembly and the anode electrolysis assembly of electrolytic module (3) respectively by wire, institute The negative electrode storage tank (1) stated and anode storage tank (2) are respectively positioned on described electrolytic module (3) top.
PEM membrane low-voltage electrolysis hydrogen the most according to claim 1, ozone generation system, it is characterised in that: described negative electrode storage Water tank (1) upper end is provided with the first gas outlet (103), and lower end is provided with the first connecting tube (101) and the second connecting tube (102);Described anode storage tank (2) upper end is provided with the second gas outlet (203), and lower end is provided with the 3rd connecting tube And the 4th connecting tube (202) (201).
PEM membrane low-voltage electrolysis hydrogen the most according to claim 2, ozone generation system, it is characterised in that: described negative electrode electricity Solve assembly and include negative electrode water tank (301) and the minus plate (3012) being arranged in negative electrode water tank (301), described minus plate (3012) side is provided with negative pole connecting portion (3011), and described negative pole connecting portion (3011) is opened with described constant current by wire Closing power supply (4) to connect, described first connecting tube (101) is connected with the hydrogen air vent (3013) of negative electrode water tank (301) upper end, described Second connecting tube (102) is connected with the negative electrode water inlet (3014) of negative electrode water tank (301) lower end;Described anode electrolysis assembly bag Including anode water tank (302) and the positive plate (3022) being arranged in anode water tank (302), described positive plate (3022) side sets Being equipped with positive pole connecting portion (3021), described positive pole connecting portion (3021) is by wire with described constant-current switch power source (4) even Connect;It is electrode chamber (303) between described minus plate (3012) and positive plate (3022), described 3rd connecting tube (201) and sun The ozone air vent (3023) of pole water tank (302) upper end connects, described 4th connecting tube (202) and anode water tank (302) lower end Anode water inlet (3024) connect.
PEM membrane low-voltage electrolysis hydrogen the most according to claim 3, ozone generation system, it is characterised in that: described minus plate (3012) include that negative electrode clamping plate (3012a), described negative electrode clamping plate (3012a) side surface are disposed with negative electrode from inside to outside Microwell plate (3012b), cathode catalyst layer (3012c), negative electrode silica gel tetrafluoro cushion (3012d) and negative electrode, anode intermediate material Proton exchange (3012e);Described positive plate (3022) includes anode clamp (3022a), described anode clamp (3022a) It is soft that side surface is disposed with anode micro porous plate (3022b), anode catalyst layer (3022c), anode gel tetrafluoro from inside to outside Pad (3022d) and negative electrode, anode intermediate material proton exchange (3012e);Described minus plate (3012) and positive plate (3022) Relative spacing certain distance is arranged, and is electrode chamber (303) between the two.
PEM membrane low-voltage electrolysis hydrogen the most according to claim 3, ozone generation system, it is characterised in that: described positive pole is even Connect and between the wire between portion (3021) and described constant-current switch power source (4), be provided with relay (5).
PEM membrane low-voltage electrolysis hydrogen the most according to claim 3, ozone generation system, it is characterised in that: described first is even Adapter (101), the second connecting tube (102), the 3rd connecting tube (201) and the 4th connecting tube (202) are all by high acrylonitrile NBR/ The connecting tube that PVC oil resistant, resistance to ozone material are made.
PEM membrane low-voltage electrolysis hydrogen the most according to claim 4, ozone generation system, it is characterised in that: described negative electrode is micro- Orifice plate (3012b) and anode micro porous plate (3022b) are POROUS TITANIUM PLATE.
CN201620317461.6U 2016-04-07 2016-04-07 A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system Active CN205856615U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160076155A1 (en) * 2012-11-12 2016-03-17 Paino Inc. Apparatus for Preparing Hydrogen Water
CN105671586A (en) * 2016-04-07 2016-06-15 金华市润达环保科技有限公司 PEM membrane low-voltage hydrogen electrolysis and ozone generation system
CN106361492A (en) * 2016-09-30 2017-02-01 福州品行科技发展有限公司 Medical physical cooling device and use method thereof
CN107083557A (en) * 2017-02-21 2017-08-22 鑑道生命科技有限公司 A kind of equipment of utilization graphene high-efficiency oxygen and hydrogen-rich ionized water
CN113522206A (en) * 2021-08-03 2021-10-22 湖南新欧源环保科技有限公司 Multi-ion hydrolysis blue oxygen generator assembly

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160076155A1 (en) * 2012-11-12 2016-03-17 Paino Inc. Apparatus for Preparing Hydrogen Water
US9903025B2 (en) * 2012-11-12 2018-02-27 Paino Inc. Apparatus for preparing hydrogen water
CN105671586A (en) * 2016-04-07 2016-06-15 金华市润达环保科技有限公司 PEM membrane low-voltage hydrogen electrolysis and ozone generation system
CN106361492A (en) * 2016-09-30 2017-02-01 福州品行科技发展有限公司 Medical physical cooling device and use method thereof
CN107083557A (en) * 2017-02-21 2017-08-22 鑑道生命科技有限公司 A kind of equipment of utilization graphene high-efficiency oxygen and hydrogen-rich ionized water
CN107083557B (en) * 2017-02-21 2018-12-11 鑑道生命科技有限公司 A kind of equipment using graphene high-efficiency oxygen and hydrogen-rich ionized water
CN113522206A (en) * 2021-08-03 2021-10-22 湖南新欧源环保科技有限公司 Multi-ion hydrolysis blue oxygen generator assembly

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