CN205790074U - A kind of compacted zone uniform planar structure perovskite solaode - Google Patents

A kind of compacted zone uniform planar structure perovskite solaode Download PDF

Info

Publication number
CN205790074U
CN205790074U CN201520800298.4U CN201520800298U CN205790074U CN 205790074 U CN205790074 U CN 205790074U CN 201520800298 U CN201520800298 U CN 201520800298U CN 205790074 U CN205790074 U CN 205790074U
Authority
CN
China
Prior art keywords
compacted zone
planar structure
conducting base
uniform planar
utility
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201520800298.4U
Other languages
Chinese (zh)
Inventor
王镜喆
何早阳
张继远
吴聪萍
邹志刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Yanchang sanglaite new energy Co.,Ltd.
Kunshan Innovation Institute of Nanjing University
Original Assignee
KUNSHAN SUNLAITE NEW ENERGY CO Ltd
Kunshan Innovation Institute of Nanjing University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KUNSHAN SUNLAITE NEW ENERGY CO Ltd, Kunshan Innovation Institute of Nanjing University filed Critical KUNSHAN SUNLAITE NEW ENERGY CO Ltd
Priority to CN201520800298.4U priority Critical patent/CN205790074U/en
Application granted granted Critical
Publication of CN205790074U publication Critical patent/CN205790074U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Abstract

The utility model discloses a kind of compacted zone uniform planar structure perovskite solaode, including: conducting base, the titanium dioxide dense layer being grown on conducting base, it is applied to the calcium titanium ore bed on titanium dioxide dense layer, the Hole transporting layers being formed on calcium titanium ore bed, the metal electrode layer being formed on Hole transporting layers.This utility model provides a kind of compacted zone uniform planar structure perovskite solaode and preparation method thereof, the voltage of the pure titanium that this utility model is plated on conducting base by regulation anodic oxidation and anodizing time, thus regulate dense layer thickness and consistency, reduce the compacted zone uneven phenomenon that spin coating brings, the compacted zone arrangement of preparation in order, can preferably be collected and conduct electronics.

Description

A kind of compacted zone uniform planar structure perovskite solaode
Technical field
A kind of solaode and preparation method, particularly a kind of compacted zone uniform planar structure perovskite solaode and preparation method thereof.
Background technology
Planar structure perovskite solar battery structure is simple, but requires higher to compacted zone, needs the good space of compactness little.But the compacted zone of perovskite solaode is to have the organic solution presoma of spin coating titanium or thermal spraying to make in prior art;Spin coating brings compacted zone uneven phenomenon, collection that compacted zone structure can not be orderly and conduction electronics;The most unresolved such problem of prior art.
Utility model content
For solving the deficiencies in the prior art, the purpose of this utility model is to provide a kind of compacted zone uniform planar structure perovskite solaode, by regulation voltage and anodizing time regulation dense layer thickness and consistency, the compacted zone arrangement of preparation in order, can preferably be collected and conduct electronics.
In order to realize above-mentioned target, this utility model adopts the following technical scheme that:
A kind of compacted zone uniform planar structure perovskite solaode, including: conducting base, the titanium dioxide dense layer being grown on conducting base, it is applied to the calcium titanium ore bed on titanium dioxide dense layer, the Hole transporting layers being formed on calcium titanium ore bed, the metal electrode layer being formed on Hole transporting layers.
Aforesaid a kind of compacted zone uniform planar structure perovskite solaode, conducting base is FTO electro-conductive glass, TCO electro-conductive glass or conducting PET.
Of the present utility model have the beneficial effect that this utility model provides a kind of compacted zone uniform planar structure perovskite solaode, the voltage of the pure titanium that this utility model is plated on conducting base by regulation anodic oxidation and anodizing time, thus regulate dense layer thickness and consistency, reduce the compacted zone uneven phenomenon that spin coating brings, the compacted zone arrangement of preparation in order, can preferably be collected and conduct electronics.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of embodiment of this utility model;
The implication of reference in figure:
1 conducting base, 2 titanium dioxide dense layers, 3 calcium titanium ore beds, 4 Hole transporting layers, 5 metal electrodes.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, this utility model made concrete introduction.
A kind of compacted zone uniform planar structure perovskite solaode, including: conducting base 1, the titanium dioxide dense layer 2 being grown on conducting base 1, the calcium titanium ore bed 3 being applied on titanium dioxide dense layer 2, the Hole transporting layers 4 being formed on calcium titanium ore bed 3, the metal electrode being formed on Hole transporting layers 45 layers;Preferred as one, conducting base 1 is FTO electro-conductive glass, TCO electro-conductive glass or conducting PET.The material of calcium titanium ore bed 3 includes: CH3NH3PbI3、CH3NH3PbClXI3-x;The material of hole conduction is Spiro-OMeTAD;The material that metal electrode is 5 layers is golden or silver-colored.Calcium titanium ore bed 3 thickness is 200-500nm, and Hole transporting layers 4 thickness is 70-200nm nm, and the thickness of metal electrode 5 is 70-150nm.
The preparation method of a kind of compacted zone uniform planar structure perovskite solaode, comprises the steps:
(1) pre-treatment of conducting base 1, processes 15min with UVO after using acetone, ethanol, the most ultrasonic 10min of deionized water, 80 DEG C of drying;
(2) pure titanium is plated on the conducting base 1 that step (1) processes;
(3) conducting base 1 containing titanium film obtained through step (2) is prepared titanium dioxide dense layer 2 by organic electrolyte anodizing;
(4) 500 DEG C of annealings 30min, then furnace cooling in horse expense stove are put into after being cleaned by the titanium dioxide dense layer 2 obtained through step (3);
(5) use perovskite spin coating liquid spin coating or one layer of calcium titanium ore bed 3 of evaporation on titanium dioxide dense layer 2;
(6) 5 layers of layer of metal electrode will be deposited with on above-mentioned calcium titanium ore bed 3.
Step 2 is further: titanium film thickness 20nm~100nm, evaporates power 150-250A, evaporation rate 5-10nm/min;
The further environment of step 3 is: anodic oxygenization 1~60min between anodic oxidation voltage 50~60V, obtains compacted zone;The voltage of the pure titanium being i.e. plated on conducting base 1 by regulation anodic oxidation and anodizing time, thus regulate dense layer thickness and consistency so that the compacted zone arrangement of preparation in order, can preferably be collected and conduct electronics.
This utility model provides a kind of compacted zone uniform planar structure perovskite solaode and preparation method thereof, the voltage of the pure titanium that this utility model is plated on conducting base 1 by regulation anodic oxidation and anodizing time, thus regulate dense layer thickness and consistency, reduce the compacted zone uneven phenomenon that spin coating brings, the compacted zone arrangement of preparation in order, can preferably be collected and conduct electronics.
Of the present utility model ultimate principle, principal character and advantage have more than been shown and described.Skilled person will appreciate that of the industry, above-described embodiment limits this utility model, the technical scheme that the mode of all employing equivalents or equivalent transformation is obtained the most in any form, all falls within protection domain of the present utility model.

Claims (2)

1. a compacted zone uniform planar structure perovskite solaode, it is characterized in that, including: conducting base, the titanium dioxide dense layer being grown on above-mentioned conducting base, it is applied to the calcium titanium ore bed on above-mentioned titanium dioxide dense layer, it is formed on the Hole transporting layers on above-mentioned calcium titanium ore bed, is formed on the metal electrode layer on above-mentioned Hole transporting layers.
A kind of compacted zone uniform planar structure perovskite solaode the most according to claim 1, it is characterised in that above-mentioned conducting base is FTO electro-conductive glass, TCO electro-conductive glass or conducting PET.
CN201520800298.4U 2015-10-13 2015-10-13 A kind of compacted zone uniform planar structure perovskite solaode Active CN205790074U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201520800298.4U CN205790074U (en) 2015-10-13 2015-10-13 A kind of compacted zone uniform planar structure perovskite solaode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201520800298.4U CN205790074U (en) 2015-10-13 2015-10-13 A kind of compacted zone uniform planar structure perovskite solaode

Publications (1)

Publication Number Publication Date
CN205790074U true CN205790074U (en) 2016-12-07

Family

ID=57413543

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201520800298.4U Active CN205790074U (en) 2015-10-13 2015-10-13 A kind of compacted zone uniform planar structure perovskite solaode

Country Status (1)

Country Link
CN (1) CN205790074U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105140403A (en) * 2015-10-13 2015-12-09 南京大学昆山创新研究院 Planar structure perovskite solar cell with uniform dense layer and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105140403A (en) * 2015-10-13 2015-12-09 南京大学昆山创新研究院 Planar structure perovskite solar cell with uniform dense layer and preparation method thereof

Similar Documents

Publication Publication Date Title
Park et al. Low-temperature solution-processed Li-doped SnO2 as an effective electron transporting layer for high-performance flexible and wearable perovskite solar cells
Yoshida et al. Unveiling the origin of unusual pseudocapacitance of RuO2· n H2O from its hierarchical nanostructure by small-angle x-ray scattering
Zhang et al. Fabrication and supercapacitive performance of long anodic TiO2 nanotube arrays using constant current anodization
Zhang et al. Preparation of Ni nanoparticle–TiO2 nanotube composite by pulse electrodeposition
Xia et al. Fabrication and electrochemical capacitance of polyaniline/titanium nitride core–shell nanowire arrays
JP2013225494A5 (en)
JP2013082606A5 (en)
Oury et al. Oxygen evolution on alpha-lead dioxide electrodes in methanesulfonic acid
Deshmukh et al. Supercapacitive performance of hydrous ruthenium oxide (RuO 2· n H 2 O) thin films synthesized by chemical route at low temperature
Alberti et al. Efficiency enhancement in ZnO: Al-based dye-sensitized solar cells structured with sputtered TiO2 blocking layers
CN101162739B (en) ZnO electrode of dye sensitization solar cell and method for producing the same
CN103710738B (en) A kind of composite film preparation method improving Mg-based hydrogen storage surface corrosion resistance performance
CN105206751A (en) Perovskite solar cell taking titanium dioxide nanotube as mesoporous layer and preparation method of perovkite solar cell
CN107833969B (en) A kind of high efficiency planar heterojunction perovskite thin film solar battery and preparation method
Momeni et al. Fabrication of tungsten decorated titania nanotube arrays as electrode materials for supercapacitor applications
CN205790074U (en) A kind of compacted zone uniform planar structure perovskite solaode
Ghani et al. Polypyrrole thin films decorated with copper nanostructures as counter electrode for dye-sensitized solar cells
Low et al. A gold-coated titanium oxide nanotube array for the oxidation of borohydride ions
CN103500836A (en) Roughened copper-foil current collector for lithium ion battery and method for manufacturing roughened copper-foil current collector
CN103956272A (en) Composite plane electrode based on super capacitor diaphragm, and preparation method thereof
CN205092270U (en) No hole transport layer's perovskite solar cell
CN108878660A (en) A kind of Ag/ZnO nuclear shell structure nano rod array electrode material preparation method
Qin et al. Surface destruction and performance reduction of the ZnO nanowire arrays electrode in dye sensitization process
CN205645888U (en) Titanium dioxide nanotube is perovskite solar cell on mesoporous layer
CN108010741B (en) A kind of electrode material of high-energy density and preparation method thereof

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
CP01 Change in the name or title of a patent holder

Address after: Zuchongzhi road Kunshan city 215347 Suzhou City, Jiangsu province No. 1699 comprehensive building A room 803

Co-patentee after: Jiangsu Yanchang sanglaite new energy Co.,Ltd.

Patentee after: KUNSHAN INNOVATION RESEARCH INSTITUTE OF NANJING University

Address before: Zuchongzhi road Kunshan city 215347 Suzhou City, Jiangsu province No. 1699 comprehensive building A room 803

Co-patentee before: KUNSHAN SUNLAITE NEW ENERGY Co.,Ltd.

Patentee before: KUNSHAN INNOVATION RESEARCH INSTITUTE OF NANJING University

CP01 Change in the name or title of a patent holder