CN205740468U - The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly - Google Patents

The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly Download PDF

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Publication number
CN205740468U
CN205740468U CN201620638183.4U CN201620638183U CN205740468U CN 205740468 U CN205740468 U CN 205740468U CN 201620638183 U CN201620638183 U CN 201620638183U CN 205740468 U CN205740468 U CN 205740468U
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China
Prior art keywords
hydrogen
hollow
rich water
preparation facilities
hydrogen rich
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Withdrawn - After Issue
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CN201620638183.4U
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Chinese (zh)
Inventor
高鹏
张玉鹏
邹建洲
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BEIJING ZHONGQINGYUAN ENGINEERING TECHNOLOGY Co.,Ltd.
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Shanghai Purple Box Biotechnology Co Ltd
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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

This utility model relates to being filled with hydrogen in liquid to the device of over-saturation state.nullA kind of removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly,The hollow-fibre membrane group that this hydrogen rich water preparation facilities sets in including shell body and shell body,The SPE electrolysis bath with special pure water tank it is additionally provided with in described shell body,Described doughnut module is the miniature Triafol T CTA hollow fiber polymer membrane of class ECMO,It is located in an independent inner housing,Shell body is provided with water inlet and hydrogen rich water outlet,The snap joint connection corresponding with the gateway of hydrophilic Triafol T CTA hollow-fibre membrane that they utilize water pipe to pass through on inner housing,The hydrogen outlet of described SPE electrolysis bath also utilizes pipeline to be passed through hydrophilic Triafol T CTA hollow-fibre membrane by the snap joint on inner housing,The thickness of described hydrophilic Triafol T CTA hollow-fibre membrane is 15 μm.The thin intensity of membrane module thickness that this utility model uses is high, and the life-span is longer.

Description

The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly
Technical field
This utility model relates to being filled with hydrogen in liquid to the device of over-saturation state, particularly relates to a kind of online hydrogen The preparation facilities of solution.
Background technology
Hydrogen solution refers to the gas-liquid mixture that hydrogen is formed after being dissolved in water, adds hydrogen and does not change the pH value of former water. The biological effect of hydrogen aqueous solution is gradually accepted by people and approves.Wherein, over-saturation hydrogen solution is because preparation is difficult Degree height and applied range, biological medical effect is especially pronounced.It is current most widely used general by drinking hydrogen water intake hydrogen Method, be also hydrogen health-oriented products forms the safest, modal.
The preparation method drinking hydrogen water includes being electrolysed water, hydrogen dissolves the type such as water, magnesium metal reaction water.
Electrolysis water is the earliest for the hydrogen water of human body, and the electrolysis water of drinking for the purpose of health care originates from Japan the earliest. The equipment of preparation electrolysis water is referred to as electrolysis bath, can be containing a small amount of hydrogen by the isolated alkaline water of semipermeable membrane after electrolysis Gas, the deficiency of electrolysis water is owing to drinking water is directly electrolysed by electrolysis bath, and electrolysis of adulterating in drinking water produces Chlorine residue and ozone, the pH value of water will change, and the metal electrode of electrolysis bath directly acts on water, have the metal of trace from Son separates out, if being used for drinking, then metal ion can enter in human body with water, and more important point is, electrolysis water mode obtains Aqueous solution of hydrogen efficiency is the lowest and dissolubility is low, does not far reach hydrogen saturation in aqueous.
CN102730895A discloses a kind of Household hydrogen-rich water production device, and described preparation facilities includes housing and hollow Fibrous membrane group, wherein said housing be provided with connect with fluid supply inlet, for the air inlet connected with hydrogen source and row Liquid mouth, described hollow-fibre membrane group includes many hollow fiber film tubes and is contained in described housing, described hollow-fibre membrane group Arrival end connect with described inlet thus liquid can be in the internal flow of described hollow fiber film tube, and from described hydrogen The hydrogen of source of the gas can from the fenestra of described hollow fiber film tube flow into described hollow fiber film tube inside and and liquid mixing, And the port of export of described hollow-fibre membrane group connects with described leakage fluid dram.Wherein, hollow fiber film tube is by hydrophobe dual-property membrane Material is made.Here, hydrophobe dual-property membrane material refers to by polysulfones (PS), polyamide (PA), polypropylene fine (PAN), poly-first The hydrophobic materials such as base acrylic acid methyl ester. (PMMA), polyether sulfone (PES) are main, and doping polyvinylpyrrolidone (PVP) etc. is hydrophilic Property material after formed while possess the material of hydrophilic and hydrophobic character.Further, it is thought relative to hydrophobe dual-property membrane The hollow-fibre membrane of material prepares 5.9ppm, and pure hydrophobic film is prepared saturated solution concentration and substantially reduced.
Additionally, the thickness of above-mentioned various film is big, and intensity is not enough, and under the effect of hydrogen pressure and hydraulic pressure, the life-span is the longest;Make Used time Hydrogen Vapor Pressure is higher, there is certain potential safety hazard.
Summary of the invention
This utility model is intended to overcome the drawbacks described above of prior art, it is provided that a kind of molten hydrogen assembly is removable online low Pressure hydrogen rich water preparation facilities.This utility model can be connected directly between in water purification end, and the thin intensity of membrane module thickness of employing is high, hydrogen Pressure is lower, and the life-span is longer.
A kind of removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly of this utility model, this hydrogen rich water preparation dress Put the hollow-fibre membrane group set in including shell body and shell body, in described shell body, be additionally provided with the SPE with special pure water tank Electrolysis bath, described doughnut module is located in an independent inner housing, and shell body is provided with connection pipeline or pipeline is drunk The water inlet of water and hydrogen rich water outlet, they utilize the snap joint and the gateway of hollow-fibre membrane that water pipe passes through on inner housing Corresponding connection, the hydrogen outlet of described SPE electrolysis bath also utilizes pipeline to be passed through doughnut by the snap joint on inner housing Film.
The removable online low pressure hydrogen rich water preparation facilities of described molten hydrogen assembly, described doughnut module uses parent The miniature Triafol T CTA hollow fiber polymer membrane of class ECMO of aqueous, thickness is 15 μm.
The removable online low pressure hydrogen rich water preparation facilities of described molten hydrogen assembly, is provided with in described special pure water tank Liquid level sensor.
The removable online low pressure hydrogen rich water preparation facilities of described molten hydrogen assembly, described SPE electrolysis bath is also associated with Waste discharge mouth outside shell body.
The removable online low pressure hydrogen rich water preparation facilities of described molten hydrogen assembly, the hydrogen outlet of described SPE electrolysis bath Pipeline be provided with relief valve and pressure transducer.
The removable online low pressure hydrogen rich water preparation facilities of described molten hydrogen assembly, the hydrogen that described SPE electrolysis bath decomposes Gas air pressure is 0.025-0.045Mpa, and the hydrogen rich water rate of outflow is 2100-3000ml/min each doughnut module, and it is dense Degree is 2-3.5ppm.
Described molten hydrogen assembly removable on-line continuous high concentration hydrogen rich water preparation facilities, the pressure of supply water of tolerance can Reach the limiting pressure i.e. 1.08MPa of country's domestic pipe-line drinker testing standard.
This utility model is as water purification end prod, it is ensured that long-term hygienic safety, and replaceable is essential condition.Therefore institute Stating inner housing all uses snap joint and external pipe to connect, can quickly dismounting and change inner housing and hollow fiber film assembly; The water inlet of inner housing can be directly connected to water purification source, such as municipal tap water pipeline;Hydrophilic Triafol T CTA hollow is fine The high intensity of dimension film be enough to ensure its safe operation under water purification end condition, and thinner thickness is more conducive to the mixed of hydrogen and water Close so that this utility model becomes low-pressure, big flow, a mistake formula high concentration hydrogen rich water preparation facilities.
Accompanying drawing explanation
Below in conjunction with the accompanying drawings this utility model is further described:
Fig. 1 is schematic diagram of the present utility model.
Detailed description of the invention:
Explanation of nouns: ECMO
The abbreviation of Extracorporeal Membrane Oxygenation, i.e. extracorporeal membrane oxygenation technology.This technology is passed through Oxygen is efficiently dissolved in blood by polymeric membrane technical substitution alveolar.This technology starts from 1971, and at present, ECMO divides doughnut With two kinds of forms of silica gel.The most all using.It is by extracorporeal circulation, blood to be drawn, and hollow-fibre membrane in vitro Film intracavity swap with oxygen, replace lung work, for cardiopulmonary, major operation patient provides oxygen supply guarantee.
As shown in Figure 1: this utility model a kind of molten hydrogen assembly removable on-line continuous high concentration hydrogen rich water preparation dress Put, the hollow-fibre membrane group 7 that this hydrogen rich water preparation facilities sets in including shell body 11 and shell body, be additionally provided with in described shell body With the SPE electrolysis bath 3 of special pure water tank 1, described doughnut module is the miniature Triafol T CTA high score of class ECMO Sub-hollow-fibre membrane, it is located in an independent inner housing 9, and shell body is provided with water inlet 10 and hydrogen rich water outlet 12, it Utilize the snap joint 6 and the gateway pair of hydrophilic Triafol T CTA hollow-fibre membrane that water pipe passes through on inner housing Should connect, the hydrogen outlet of described SPE electrolysis bath also utilizes pipeline to be passed through hydrophilic three vinegar by the snap joint on inner housing Acid cellulose CTA hollow-fibre membrane, the thickness of described hydrophilic Triafol T CTA hollow-fibre membrane is 15 μm.Due to interior Housing is connected with outer by snap joint, and therefore it can be changed rapidly, and CTA three cellulose acetate membrane of the present utility model is allusion quotation The hydrophilic film of type, have hydrophilic, toughness is high, the feature of not swelling, allow gas-liquid be easier to combine;And thinner structure (15 μm) Ensure that this film more preferable gas-liquid mixed efficiency.This is also that it is used as a reason crossing formula gas-liquid mixed;Simultaneously because it is good Good toughness, it is sufficient to meet the hydraulic demand of water purification end.
Described molten hydrogen assembly removable on-line continuous high concentration hydrogen rich water preparation facilities, described special pure water tank Inside it is provided with liquid level sensor 2.
Described molten hydrogen assembly removable on-line continuous high concentration hydrogen rich water preparation facilities, described SPE electrolysis bath is also Connect and have the waste discharge mouth 31 outside shell body.
Described molten hydrogen assembly removable on-line continuous high concentration hydrogen rich water preparation facilities, the hydrogen of described SPE electrolysis bath The pipeline of gas outlet is provided with relief valve 5 and pressure transducer 4.
Described molten hydrogen assembly removable on-line continuous high concentration hydrogen rich water preparation facilities, described SPE electrolysis bath divides The hydrogen gas pressure solved is 0.025-0.045Mpa, and the hydrogen rich water rate of outflow is 2100-3000ml/min each doughnut mould Group, its concentration is 2-3.5ppm.
Product described in the utility model is as water purification end prod, and according to national quality relevant criterion, the limit is pressure is 1.08MP.This utility model i.e. can reach the result of high concentration without high pressure hydrogen, and is that a formula excessively completes.
Hydrogen rich water concentration is together decided on by Water discharge flow speed and pressure, it is known that when Water discharge flow speed is 2300ml/min and hydrogen When atmospheric pressure is 0.03MP, this utility model one is crossed the hydrogen water concentration formed and be can reach 3.0ppm;Single doughnut film structural component It is suitable for the highest 3000ml/min flow velocity water yield requirement.If flow velocity need to be strengthened further, hollow membrane component can be carried out Used in parallel.

Claims (7)

1. the removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly, this hydrogen rich water preparation facilities includes shell body With the hollow-fibre membrane group set in shell body, it is characterised in that be additionally provided with the SPE electricity with special pure water tank in described shell body Solving groove, described hollow-fibre membrane group is located in an independent inner housing, and shell body is provided with connection pipeline or pipeline tap water Water inlet and hydrogen rich water outlet, they utilize the snap joint and the gateway pair of hollow-fibre membrane that water pipe passes through on inner housing Should connect, the hydrogen outlet of described SPE electrolysis bath also utilizes pipeline to be passed through hollow-fibre membrane by the snap joint on inner housing.
The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly the most according to claim 1, it is characterised in that Described hollow-fibre membrane group uses the miniature Triafol T CTA hollow fiber polymer membrane of hydrophilic class ECMO, it Thickness is 15 μm.
The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly the most according to claim 1, it is characterised in that It is provided with liquid level sensor in described special pure water tank.
The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly the most according to claim 1, it is characterised in that Described SPE electrolysis bath is also associated with the waste discharge mouth outside shell body.
5., according to the removable online low pressure hydrogen rich water preparation facilities of hydrogen assembly molten described in claim 1 or 4, its feature exists In, the pipeline of the hydrogen outlet of described SPE electrolysis bath is provided with relief valve and pressure transducer.
The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly the most according to claim 1, it is characterised in that The hydrogen gas pressure that described SPE electrolysis bath decomposes is 0.025-0.045MPa, and the hydrogen rich water rate of outflow is 2100-3000ml/min Each hollow-fibre membrane group, its concentration is 2-3.5ppm.
The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly the most according to claim 1, it is characterised in that The pressure of supply water of tolerance is up to the limiting pressure i.e. 1.08MPa of country's domestic pipe-line drinker testing standard.
CN201620638183.4U 2016-06-23 2016-06-23 The removable online low pressure hydrogen rich water preparation facilities of molten hydrogen assembly Withdrawn - After Issue CN205740468U (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107540075A (en) * 2016-06-23 2018-01-05 上海紫盒生物科技有限公司 The replaceable online low pressure hydrogen-rich water preparation apparatus of molten hydrogen component
CN112079426A (en) * 2020-09-10 2020-12-15 夏建华 Preparation device and preparation method of hydrogen water solution by utilizing air suction circulation of hollow fibers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107540075A (en) * 2016-06-23 2018-01-05 上海紫盒生物科技有限公司 The replaceable online low pressure hydrogen-rich water preparation apparatus of molten hydrogen component
CN112079426A (en) * 2020-09-10 2020-12-15 夏建华 Preparation device and preparation method of hydrogen water solution by utilizing air suction circulation of hollow fibers

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Effective date of registration: 20210430

Address after: 100124 room 950, 9th floor, building 10, huashanyuan Cultural Media Industrial Park, 1376 folk culture street, Gaobeidian village, Gaobeidian Township, Chaoyang District, Beijing

Patentee after: BEIJING ZHONGQINGYUAN ENGINEERING TECHNOLOGY Co.,Ltd.

Address before: 200442 room 216, area L, 2 / F, building 2, 249 xicen street, Qingpu District, Shanghai

Patentee before: SHANGHAI PURPLE-BOX BIOLOGICAL TECHNOLOGY Co.,Ltd.

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AV01 Patent right actively abandoned

Granted publication date: 20161130

Effective date of abandoning: 20210601

AV01 Patent right actively abandoned

Granted publication date: 20161130

Effective date of abandoning: 20210601

AV01 Patent right actively abandoned
AV01 Patent right actively abandoned