CN205542917U - Polymer lithium ion battery uses two aluminium lamination type plastic -aluminum membranes - Google Patents

Polymer lithium ion battery uses two aluminium lamination type plastic -aluminum membranes Download PDF

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Publication number
CN205542917U
CN205542917U CN201620131259.4U CN201620131259U CN205542917U CN 205542917 U CN205542917 U CN 205542917U CN 201620131259 U CN201620131259 U CN 201620131259U CN 205542917 U CN205542917 U CN 205542917U
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China
Prior art keywords
layer
tack coat
aluminium foil
ion battery
tie coat
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Expired - Fee Related
Application number
CN201620131259.4U
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Chinese (zh)
Inventor
章结兵
谢凤秀
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Suzhou Lidun Energy Storage Material Technology Co Ltd
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Suzhou Lidun Energy Storage Material Technology Co Ltd
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Priority to CN201620131259.4U priority Critical patent/CN205542917U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The utility model relates to a polymer lithium ion battery uses two aluminium lamination type plastic -aluminum membranes. This plastic -aluminum membrane includes polypropylene layer, first tie coat, aluminium foil layer, second tie coat, resin rete, third tie coat, aluminium foil layer, fourth tie coat, resin rete, and it is by interior polypropylene layer, first tie coat, aluminium foil layer, second tie coat, resin rete, third tie coat, aluminium foil layer, fourth tie coat, the resin rete of being in proper order outside to. The utility model discloses a composite membrane layer who increases aluminium foil and resin at inlayer aluminium foil layer outer can effectively improve the separation and the wear resistance of inlayer aluminium foil, is that a high resistant separates type plastic -aluminum membrane, can be applied to polymer lithium ion battery.

Description

A kind of double aluminium lamination type aluminum plastic film of polymer Li-ion battery application
Technical field
This utility model relates to battery packaging material field, particularly to a kind of double aluminium lamination of polymer Li-ion battery application Type aluminum plastic film.
Background technology
Lithium ion battery owing to it is lightweight, capacity is big, have extended cycle life (more than 1000 times) and memory-less effect Advantage is quickly at the battery applications such as mobile phone, notebook computer field Quick Extended, simultaneously because the unique advantage of lithium ion battery, Apply at electrokinetic cell and energy-storage battery field.
Polymer battery have than liquid lithium ionic cell more weight amount, voltage is high, capacity is big, the life-span is long, self discharge is low, More advantage such as memory-less effect and safety, in recent years along with its wide at 3C Products such as iPhone, iPad, Ultrabook General application, the in addition exploitation of lithium ion battery electric automobile, the application of polymer Li-ion battery the most quickly increases, due to plastic-aluminum Film is the housing material that lithium ion battery flexible package is important, has the most also driven the quick growth of aluminum plastic film demand.
Have the fluorinated materials such as hexafluorophosphoric acid aluminum due to the electrolyte in lithium ion battery, water is had by these fluorochemicals Having the strongest sensitivity, electrolyte is met water and is readily generated severe corrosive Fluohydric acid. and other gases, and it will be to aluminum plastic film Heat-sealing and material cause corrosion, have a strong impact on cycle-index and the service life of battery, cause battery rapid failure, therefore aluminum Plastic film need to have the barrier property of excellence, intercepts the factor destructions to electrolyte such as the steam of external environment, oxygen.Meanwhile, battery Aluminum plastic film outer layer need to resist in cell processing course and fall the destruction caused, need aluminum plastic film outer layer to have the wearability of excellence Energy.How to improve the anti-wear performance of aluminum plastic film, barrier property and other correlated performances to promoting polymer Li-ion battery quality It it is the most crucial matter of science and technology.
Utility model content
For solving above-mentioned technical problem, this utility model provides a kind of double aluminium lamination type plastic-aluminum of polymer Li-ion battery application Film, this aluminum plastic film has barrier property and the anti-wear performance of excellence, can improve the service life of battery.
The technical solution of the utility model is: a kind of double aluminium lamination type aluminum plastic film of polymer Li-ion battery application.This plastic-aluminum Film include polypropylene layer, the first tack coat, aluminium foil layer, the second tack coat, resin film layer, the 3rd tack coat, aluminium foil layer, the 4th glue Knot layer, resin film layer, its be followed successively by from inside to outside polypropylene layer, the first tack coat, aluminium foil layer, the second tack coat, resin film layer, 3rd tack coat, aluminium foil layer, the 4th tack coat, resin film layer.
As a kind of preferred version of the present utility model, described polypropylene layer material is polypropylene, polypropylene and polyethylene Co-extrusion thing, polypropylene and the one in cyclenes hydro carbons co-extrusion thing, described polypropylene layer thickness is 10~80 μm.
As a kind of preferred version of the present utility model, described first tack coat, the second tack coat, the 3rd tack coat, the The material of four tack coats is one or more in hot melt adhesive film, adhesive, the hydrosol, described first tack coat, the second bonding Layer, the 3rd tack coat, the thickness of the 4th tack coat are respectively 0.01~30 μm.
As a kind of preferred version of the present utility model, the curing mode of described tack coat be heat cure, ultra-violet curing and One or more combination in electronic beam curing.
As a kind of preferred version of the present utility model, described resin film layer material is polyethylene, polypropylene, polyamide fibre In dimension film, polyethylene terephthalate, polybutylene terephthalate, cycloolefin analog copolymer, fluoro-containing copolymer film One or more combination, described resin film layer thickness is 3~30 μm.
As a kind of preferred version of the present utility model, the thickness of described aluminium foil layer is 10~60 μm, aluminum foil material surface One or more in available chemical treatment, Cement Composite Treated by Plasma, physical treatment.
After using technique scheme, the beneficial effects of the utility model: first, this aluminum plastic film uses the structure of Double-layer aluminum Design can be effectively improved the barrier property of aluminum plastic film;Secondly, this aluminum plastic film outer layer aluminium film surface is combined one layer of resin molding can be effective Improve the anti-wear performance of aluminum plastic film, so that this aluminum plastic film has barrier property and the anti-wear performance of excellence.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
1. polypropylene layer;2. the first tack coat;3. aluminium foil layer;4. the second tack coat;5. resin film layer;6. the 3rd bonding Layer;7. aluminium foil layer;8. the 4th tack coat;9. resin film layer.
Detailed description of the invention
Below in conjunction with detailed description of the invention, it is further elucidated with this utility model.
Embodiment
As it is shown in figure 1, this utility model provides a kind of double aluminium lamination type aluminum plastic film of polymer Li-ion battery application, including 1. polypropylene layer, 2. the first tack coat, 3. aluminium foil layer, 4. the second tack coat, 5. resin film layer, 6. the 3rd tack coat, 7. aluminium foil Layer, 8. the 4th tack coat, 9. resin film layer.
The material of described polypropylene layer 1 is polypropylene, polypropylene and polyethylene co-extrusion thing, polypropylene and cyclenes hydro carbons co-extrusion One in thing, described polypropylene layer thickness is 10~80 μm.
The material of described first tack coat the 2, second tack coat the 4, the 3rd tack coat 6 and the 4th tack coat 8 is PUR One or more in film, adhesive, the hydrosol, described first tack coat, the second tack coat, the 3rd tack coat, the 4th bonding The thickness of layer is respectively 0.01~30 μm, described first tack coat, the second tack coat, the 3rd tack coat, the consolidating of the 4th tack coat Change mode is the one or more combination in heat cure, ultra-violet curing and electronic beam curing.
Described aluminium foil layer 3, the thickness of aluminium foil layer 7 are 10-60 μm, and chemical treatment, plasma can be used in aluminum foil material surface One or more in process, physical treatment.
The material of described resin film layer 5 and resin film layer 9 is polyethylene, polypropylene, Fypro film, poly-terephthaldehyde One or more combination in acid glycol ester, polybutylene terephthalate, cycloolefin analog copolymer, fluoro-containing copolymer film, Described resin film layer thickness is 3~30 μm.
Product of the present utility model reaches following index through mensuration:
1. peel strength test: electrolyte soaks 85 DEG C, 1 day, film interlaminar strength is more than or equal to 8N/15mm.
2. permeability resistance test: soak 3 days in the water of 60 DEG C, without layering, weight change is less than 0.05 gram.
3. deep drawability test, the deep-draw degree of depth reaches more than 6mm.
The above is only preferred implementation of the present utility model, it is noted that for the common skill of the art For art personnel, on the premise of without departing from this utility model principle, it is also possible to make some improvements and modifications, these improve and Retouching also should be regarded as protection domain of the present utility model.

Claims (5)

1. the double aluminium lamination type aluminum plastic film of polymer Li-ion battery application, it is characterised in that include polypropylene layer, the first bonding Layer, aluminium foil layer, the second tack coat, resin film layer, the 3rd tack coat, aluminium foil layer, the 4th tack coat, resin film layer, its by interior to It is followed successively by outward polypropylene layer, the first tack coat tack coat, aluminium foil layer, the second tack coat, resin film layer, the 3rd tack coat, aluminium foil Layer, the 4th tack coat, resin film layer.
2. apply double aluminium lamination type aluminum plastic film according to the polymer Li-ion battery described in claim 1, it is characterised in that described Polypropylene layer thickness is 10~80 μm.
3. apply double aluminium lamination type aluminum plastic film according to the polymer Li-ion battery described in claim 1, it is characterised in that described First tack coat, the second tack coat, the 3rd tack coat, the thickness of the 4th tack coat are respectively 0.01~30 μm.
4. apply double aluminium lamination type aluminum plastic film according to the polymer Li-ion battery described in claim 1, it is characterised in that described Resin film layer thickness is 3~30 μm.
5. apply double aluminium lamination type aluminum plastic film according to the polymer Li-ion battery described in claim 1, it is characterised in that described The thickness of aluminium foil layer is 10~60 μm.
CN201620131259.4U 2016-02-22 2016-02-22 Polymer lithium ion battery uses two aluminium lamination type plastic -aluminum membranes Expired - Fee Related CN205542917U (en)

Priority Applications (1)

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CN201620131259.4U CN205542917U (en) 2016-02-22 2016-02-22 Polymer lithium ion battery uses two aluminium lamination type plastic -aluminum membranes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201620131259.4U CN205542917U (en) 2016-02-22 2016-02-22 Polymer lithium ion battery uses two aluminium lamination type plastic -aluminum membranes

Publications (1)

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CN205542917U true CN205542917U (en) 2016-08-31

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105529413A (en) * 2016-02-22 2016-04-27 苏州锂盾储能材料技术有限公司 Double aluminum layer type aluminum plastic film applied to polymer lithium ion battery
CN112054162A (en) * 2020-09-16 2020-12-08 北京理工大学 Packaging method of metal lithium reference electrode for lithium battery

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105529413A (en) * 2016-02-22 2016-04-27 苏州锂盾储能材料技术有限公司 Double aluminum layer type aluminum plastic film applied to polymer lithium ion battery
CN112054162A (en) * 2020-09-16 2020-12-08 北京理工大学 Packaging method of metal lithium reference electrode for lithium battery
CN112054162B (en) * 2020-09-16 2022-02-25 北京理工大学 Packaging method of metal lithium reference electrode for lithium battery

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160831

Termination date: 20170222