CN205484194U - Dbd ionization detector - Google Patents

Dbd ionization detector Download PDF

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Publication number
CN205484194U
CN205484194U CN201620245452.0U CN201620245452U CN205484194U CN 205484194 U CN205484194 U CN 205484194U CN 201620245452 U CN201620245452 U CN 201620245452U CN 205484194 U CN205484194 U CN 205484194U
Authority
CN
China
Prior art keywords
electrode
polarizing
test chamber
polarization
dbd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn - After Issue
Application number
CN201620245452.0U
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Chinese (zh)
Inventor
卜晓庆
高心岗
孙清峰
张岩
宋玉
隋宗斌
朱晓丹
郭文霞
张丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QINGDAO JIAMING MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
Original Assignee
QINGDAO JIAMING MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
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Publication date
Application filed by QINGDAO JIAMING MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd filed Critical QINGDAO JIAMING MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
Priority to CN201620245452.0U priority Critical patent/CN205484194U/en
Application granted granted Critical
Publication of CN205484194U publication Critical patent/CN205484194U/en
Withdrawn - After Issue legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The utility model provides a DBD ionization detector, includes the body, the chamber is detected to this internal being provided with. It is provided with carrier gas inlet and sample gas export respectively to detect chamber top and bottom. Detect the intracavity and install the tubular column, the tubular column bottom is linked together with the sample gas entry of body setting. This internal dielectric barrier discharge mechanism and polarization voltage ion collection mechanism of installing. Dielectric barrier discharge mechanism is located the outside of detecting chamber top inner wall including relative two discharge electrode that set up. Polarization voltage ion collection mechanism is including polarization electrode and collector electrode, polarization electrode and collector electrode all stretch into and detect in the chamber, polarization electrode and collector electrode all link to each other with the record appearance. DBD ionization detector falls into DBD region of discharge and polarization voltage ion collection district from top to bottom, through all compound ionizationouns of plasma messenger, realizes that equipment structure is simple to effective detection of all components, need not not ally oneself with with the continuous monitor that can realize the semi -volatile organic matter by the multi -detector, can not make the compound take place to react, guarantees compound ionic integrality, guarantees to detect the precision.

Description

DBD ionization detector
Technical field
This utility model relates to a kind of detection equipment, specifically, is a kind of for detecting half volatile in surface water, drinking water Organic detector.
Background technology
Semi-volatile organic matter SVOC is the big important pollutant of class in surface water, drinking water.For overall monitor Water quality, have Effect supervision all kinds of emission sources, timely response environment contamination accident, need to include environment monitoring system online, on-the-spot in by water body SVOC, Realize at least 24 kinds of semi-volatile organic matter Monitoring factors in " water environment quality standard " GB3838 2002 continuously from Dynamic monitoring.
At present, conventional detector mainly has thermal conductivity detector TCD, flame ionization ditector FID, electron capture detection Device ECD, flame photometric detector FPD etc..In these detectors, TCD is capable of the detection of all components, but sensitivity The highest;The detector selectivitys such as FID, ECD, FPD are relatively strong, it is generally required to be applied in combination, equipment is relative complex.
Utility model content
The deficiency that this utility model exists for above-mentioned prior art, it is proposed that a kind of be capable of the detection of all components, sensitive Spend high DBD ionization detector.
DBD ionization detector of the present utility model, including body, described internal is provided with test chamber.
Described test chamber top and bottom are respectively arranged with carrier gas inlet and sample gas outlet.
Being provided with tubing string in described test chamber, the sample gas inlet that described tubing string bottom is arranged with body is connected.
Described internal is provided with dielectric barrier discharge mechanism and polarizing voltage ioncollection mechanism.
Described dielectric barrier discharge mechanism includes two sparking electrodes being oppositely arranged, and is positioned at the outside of test chamber top inner wall.
Described polarizing voltage ioncollection mechanism includes that polarizing electrode and passive electrode, described polarizing electrode and passive electrode all stretch into In test chamber, described polarizing electrode is all connected with monitor with passive electrode.
Described tubing string top is between dielectric barrier discharge mechanism and polarizing voltage ioncollection mechanism.
Preferably, described polarizing electrode connects DC source, and described DC source is connected with monitor by polarization wire, Described polarization wired earth;Described passive electrode is connected with monitor by collecting wire;Described polarization wire with collect wire it Between connect have high resistance.
Preferably, two setting up and down of described polarizing electrode, described passive electrode is between polarizing electrode.
The beneficial effects of the utility model are: DBD ionization detector is divided into DBD region of discharge and polarizing voltage ioncollection up and down District, makes all compound ions by plasma, it is achieved the effective detection to all components, device structure is simple, need not Multi-detector combination can realize the continuous monitoring of semi-volatile organic matter, and compound will not be made to react, it is ensured that compound from The integrity of son, it is ensured that accuracy of detection.
Use two polarizing electrodes and passive electrode to carry out the collection of electronics, detected by the micro-electric current formed, sensitive Degree height, stability is strong.Polarizing electrode and passive electrode are directly connected to the high resistance that resistance value is higher, make electric potential signal amplify, just Detect in monitor.Use the electrode arranging structure of polarizing electrode passive electrode polarizing electrode, make micro-electric current of formation Sensitivity is higher, more stable, and capacity of resisting disturbance is strong.
Accompanying drawing explanation
Accompanying drawing 1 is the structural representation of DBD ionization detector;
Accompanying drawing 2 is the structure composition schematic diagram of polarizing voltage ioncollection mechanism.
Detailed description of the invention
In order to be able to further appreciate that structure of the present utility model, feature and other purpose, in conjunction with appended preferred embodiment specifically Bright as follows, illustrated preferred embodiment is merely to illustrate the technical solution of the utility model, and non-limiting this utility model.
Detailed description of the invention of the present utility model is as follows:
As it is shown in figure 1, DBD ionization detector includes the body 1 made with insulant such as quartz or corundum, in body 1 It is provided with test chamber 2.
Test chamber 2 top and bottom are respectively arranged with carrier gas inlet 1-1 and sample gas outlet 1-2.
Tubing string 3, tubing string 3 top end opening, the sample gas inlet 1-3 that tubing string 3 bottom is arranged with body 1 are installed in test chamber 2 It is connected.
Dielectric barrier discharge mechanism and polarizing voltage ioncollection mechanism are installed in body 1, are divided into DBD to discharge test chamber 2 District and polarizing voltage ioncollection district.
Dielectric barrier discharge mechanism includes two the sparking electrode 4-1 being oppositely arranged, two sparking electrode 4-1 respectively with discharge power supply It is connected.In order to avoid sparking electrode 4-1 contacts with gas in test chamber 2, sparking electrode 4-1 is positioned at test chamber 2 top inner wall Outside, separate with gas.
Polarizing voltage ioncollection mechanism includes polarizing electrode 5-1 and passive electrode 5-2.Polarizing electrode 5-1 and passive electrode 5-2 All extending in test chamber 2, polarizing electrode 5-1 is connected with monitor with passive electrode 5-2.
As in figure 2 it is shown, polarizing electrode 5-1 connects DC source 5-3, provide polarizing voltage for polarizing voltage ioncollection district. DC source 5-3 positive pole connects polarizing electrode, and negative pole is connected with monitor 5-4 by polarization wire, and polarize wired earth.
Passive electrode 5-2 is connected with monitor 5-4 by collecting wire.Polarization wire has high resistance with collecting to be connected between wire 5-5, also makes passive electrode 5-2 by high resistance 5-5 ground connection.
Two setting up and down of polarizing electrode 5-1, passive electrode 5-2, between polarizing electrode 5-1, form polarizing electrode and collect The electrode arranging structure of electrode polarization electrode, the micro-current sensitivity making formation is higher, more stable.
Tubing string 3 top is between dielectric barrier discharge mechanism and polarizing voltage ioncollection mechanism, it is to avoid enter to detection from tubing string The sample gas in chamber 2 enters DBD region of discharge, and can mix with Plasma contact rapidly, carries out ionizing.
During detection, inert gas helium is passed in test chamber by carrier gas inlet, connects the power supply being connected with sparking electrode, Power supply is discharged by sparking electrode, owing to discharge energy is higher, punctures the wall of test chamber 2, enters in test chamber, swashs Send out helium gas plasma.
Sample gas the most to be detected is entered in tubing string by sample gas inlet, and along tubing string upwards, flows out from tubing string top end opening, Enter in test chamber.
Helium gas plasma flows downward, and recoil enters the sample gas in test chamber, mixes with sample gas and blows sample gas and flows downward.
Owing to helium gas plasma energy is higher, make the compound ions in sample gas, produce cation and anion.
The gas flowed downward enters polarizing voltage ioncollection district, and under the electric field action that polarizing voltage is formed, sample gas ionization is produced Raw electronics is collected electrode and collects, and makes to form micro-electric current between passive electrode and polarizing electrode.
The micro-electric current between passive electrode and polarizing electrode measured by monitor, and appearance time and peak area according to micro-current waveform are surveyed Go out the content of the composition in sample gas and composition.
And residual gas enters into sample gas outlet 1-2 by the annular space between test chamber 2 and tubing string 3, and discharge.

Claims (3)

1. a DBD ionization detector, it is characterised in that include body (1), be provided with test chamber (2) in described body (1),
Described test chamber (2) top and bottom are respectively arranged with carrier gas inlet (1-1) and sample gas outlet (1-2),
Tubing string (3), the sample gas inlet (1-3) that described tubing string (3) bottom and body (1) are arranged are installed in described test chamber (2) It is connected,
Dielectric barrier discharge mechanism and polarizing voltage ioncollection mechanism are installed in described body (1),
Described dielectric barrier discharge mechanism includes two sparking electrodes (4-1) being oppositely arranged, and is positioned at test chamber (2) top inner wall Outside,
Described polarizing voltage ioncollection mechanism includes polarizing electrode (5-1) and passive electrode (5-2), described polarizing electrode (5-1) All extend in test chamber (2) with passive electrode (5-2), described polarizing electrode (5-1) and passive electrode (5-2) all with note Record instrument is connected,
Described tubing string (3) top is between dielectric barrier discharge mechanism and polarizing voltage ioncollection mechanism.
DBD ionization detector the most according to claim 1, it is characterised in that described polarizing electrode (5-1) connects to be had directly Stream power supply (5-3), described DC source (5-3) is connected with monitor (5-4) by polarization wire, described polarization wire Ground connection;Described passive electrode (5-2) is connected with monitor (5-4) by collecting wire;Described polarization wire is led with collection Connect between line and have high resistance (5-5).
DBD ionization detector the most according to claim 1 and 2, it is characterised in that described polarizing electrode (5-1) is upper and lower Arranging two, described passive electrode (5-2) is positioned between polarizing electrode (5-1).
CN201620245452.0U 2016-03-28 2016-03-28 Dbd ionization detector Withdrawn - After Issue CN205484194U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201620245452.0U CN205484194U (en) 2016-03-28 2016-03-28 Dbd ionization detector

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201620245452.0U CN205484194U (en) 2016-03-28 2016-03-28 Dbd ionization detector

Publications (1)

Publication Number Publication Date
CN205484194U true CN205484194U (en) 2016-08-17

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CN201620245452.0U Withdrawn - After Issue CN205484194U (en) 2016-03-28 2016-03-28 Dbd ionization detector

Country Status (1)

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CN (1) CN205484194U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105606695A (en) * 2016-03-28 2016-05-25 青岛佳明测控科技股份有限公司 DBD (Dielectric Barrier Discharge) ionization detector and detection method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105606695A (en) * 2016-03-28 2016-05-25 青岛佳明测控科技股份有限公司 DBD (Dielectric Barrier Discharge) ionization detector and detection method thereof
CN105606695B (en) * 2016-03-28 2019-01-22 青岛佳明测控科技股份有限公司 DBD ionization detector and its detection method

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C14 Grant of patent or utility model
GR01 Patent grant
AV01 Patent right actively abandoned

Granted publication date: 20160817

Effective date of abandoning: 20190122

AV01 Patent right actively abandoned