CN204918477U - Clean processing apparatus of mud - Google Patents

Clean processing apparatus of mud Download PDF

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Publication number
CN204918477U
CN204918477U CN201520503498.3U CN201520503498U CN204918477U CN 204918477 U CN204918477 U CN 204918477U CN 201520503498 U CN201520503498 U CN 201520503498U CN 204918477 U CN204918477 U CN 204918477U
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mud
unit
gas
temperature
sludge
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邹大冰
谢红
柯水洲
唐生誉
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Changsha Nibao Environmental Protection Co Ltd
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Changsha Nibao Environmental Protection Co Ltd
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Abstract

The utility model provides a clean processing apparatus of mud, the device is including the mud feed system, sludge drying - carbomorphism system, mud dry distillation system and the result recovery system that link to each other in proper order. The utility model discloses based on the characteristic of mud, adopt drying - carbomorphism - dry distillation technique, be transformed into combustible gas with the organic composition in the mud, the solid residue carries out recycle, and mud utilization's low -cost cleaning is realized to the make full use of sludge calorific value.

Description

A kind of cleaning device of mud
Technical field
The utility model belongs to field of environment engineering technology, is specifically related to a kind of cleaning device of mud.
Background technology
According to " Chinese sludge disposal Market Report (2013) " prediction, by the end of 2015, national urbanization water treatment plant mud (water ratio 80%) generation that wets will reach 3,359 ten thousand tons, i.e. daily output 9.2 ten thousand tons, mud.China disposes the process of mud and relatively lags behind owing to affecting by the factor of the aspects such as fund, sludge stabilization rate is low, harmless treatment rate is not high, process disposal technology is single, and it is with high costs, cause most of mud unprocessed or after only doing simple process, just direct agricultural, landfill or send refuse tip landfill, burning, sludge landfill characteristics etc., what have even arbitrarily stacks.Random landfill or random stacking of mud take a large amount of land resources, and the perishable fouling of mud, and it produces the surface water bodies such as the easy contaminated soil of percolate, underground water and river, lake, ocean, causes serious secondary pollution to environment.In addition, the heavy metal in mud and toxic organic compound by the food chain Migration And Concentration in ecology, and can burn generation toxic gas, produce harm potential for a long time to ecotope and HUMAN HEALTH.Therefore, reducing sludge treatment cost and improving sludge treatment effect is current China sludge treatment urgent problem.
The residual active sludge of municipal sludge mainly sewage work, mainly containing large quantity of moisture, and other microorganisms and residue thereof, based on organism in residue, and nutritive substance and the organic matter such as nitrogenous, phosphorus.Because mud contains a large amount of organic composition, being the major reason that mud pollutes, is also the important foundation of recycling sludge.
At present, domestic urban wastewater treatment firm specific resistance to filtration technology mainly contains anaerobic sludge digestion technology, sludge aerobic fermentation technique, sludge landfill characteristics technology, sludge incineration technology; Wherein sludge incineration technology comprises: sludge heat drying technology, separately incineration technology and low-temperature carbonization technology etc., up to the present also do not have a kind of technology the resource in mud to be made full use of.
Utility model content
The utility model overcomes the defect of prior art, provides a kind of novel mud cleaning device.Sewage treatment plant residual mud can be carried out low-temperature carbonization and then carry out low-temperature pyrolysis by this device, and obtained inflammable gas, is used for the supply of technique self heat energy, makes full use of sludge calorific value, realize the low cost recycling of mud by inflammable gas.
The utility model provides a kind of cleaning device of mud, and described device comprises mud plenum system, drying sludge-carbonization system, mud distillation system and the product recovery that order is successively connected.
Described mud plenum system comprises the connected storage bin of order and jacketed screw transfer roller.Described jacketed screw transfer roller can also be connected with flare system by exhaust pipeline.
Described drying sludge-carbonization system comprises the connected low-temperature drier of order and carbonizer, and the entrance of described low-temperature drier is connected with the outlet of described jacketed screw transfer roller.Mud, after low-temperature drier dehydration, reacts further in carbonizer, and by reaction, material water ratio reduces further, and material unit calorific value raises, and makes the Organic carbon of generation have superior combustionproperty.
Described drying sludge-carbonization system is airtight negative pressure system, is also provided with closed-type feed device, airtight drawing mechanism, thus ensure mud turnover time equipment stopping property.
Described low-temperature drier and carbonizer inside are equipped with thermal cycling crosspoint.Described thermal cycling crosspoint comprises the twin shaft hollow blade and crustless sandwich that can fill thermal oil.In actually operating, mud stirs continuously in device, and with the thermal oil indirect heat exchange in described twin shaft hollow blade and crustless sandwich, thermal chemical reaction occurs, sludge water foam structure destroys, and in mud, water is transformed into water vapour and separates from mud.
Described thermal cycling crosspoint is connected with heat-conducting oil furnace.After thermal oil heats in described thermal oil, be delivered in thermal cycling crosspoint by recycle pump, with mud generation heat exchange, the temperature of thermal oil reduced; Flow in heat-conducting oil furnace by back of pipeline after exchange, then heat, so circulate.Described heat-conducting oil furnace can comprise heat-conducting oil furnace body, fuel combustion system, forced draft induced draft system etc.The combustion gas that the thermal source of described heat-conducting oil furnace can obtain after treatment for mud, also can introduce Sweet natural gas is in addition heat-conducting oil furnace heating.
Described low-temperature drier and carbonizer are also connected with described jacketed screw transfer roller respectively through preheating gas pipeline.Mud is successively after low-temperature drier and carbonizer, and the waste heat gas of discharge carries out preheating to supply mud in Cemented filling to jacketed screw transfer roller; After preheating, enter flare system by exhaust pipeline, then discharge up to standard.
Described mud distillation system comprises the connected storage hopper dredger of order and gas retort; The entrance of described storage hopper dredger is connected with the outlet of described carbonizer.The principal feature of described mud distillation system is: 1. mud is heat under anaerobic state, and its product is water vapour, carbonizing gas and carbon granule mainly; 2. the carbon granule that generates of gas retort lignin-sludge and the structural property of wood charcoal powder similar; 3. the water vapor condensation that pyrolyzing sludge produces is water non-pollution discharge, and carbonizing gas is converted into pure combustible gas recycle, and carbonizing gas calorific value is sufficient, can do fuel gas completely; 4. retort process is reduction reaction, can not produce oxynitride and sulfurous gas (main component of acid rain) as burning method; 5. mud pyrolysis temperature is 550 ~ 700 DEG C, whole process is 10 ~ 80 minutes, part heavy metal ion such as Hg etc. in mud, because fusing point is low, can decompose under high temperature action and vapor away, other heavy metal ion such as Pb, Cd, Cr, Ni etc., will be solidificated in carbide product, becomes highly stable and to environment without harm; Although carbonization system can not remove the heavy metal ion in mud, but the data results of dissolution test shows, carburizing reagent can be solidificated in carbonated product, can by the use of safety in all trades and professions.
Described product recovery comprises the biological carbon recovery unit and gas phase recovery unit that are connected with gas retort respectively; Described gas phase recovery unit comprises the decomposition of unit for treating water, wood vinegar and wood tar oil, purification process unit and organic gas processing unit.
Described organic gas processing unit comprise be linked in sequence successively fly-ash separator, organic substance decomposing purification unit, water cooler, combustion gas storage tank; Combustion gas storage tank in described organic gas processing unit is also connected with mud distillation system with described drying sludge-carbonization system respectively through heating pipe line.
Flare system described in the utility model can comprise order successively and be connected dedusting except acid unit, plasma deodorization unit, alkali cleaning spray unit, agent-feeding treatment unit and gas vent unit, realizes the process up to standard to waste gas.
Device described in the utility model can further include automatic control system.Described automatic control system comprises the temperature control unit controlled the temperature of drying sludge-carbonization system and mud distillation system, to the pressure control unit that the pressure of distillation system controls, and according to the unit etc. that described temperature controls import hot blast rate and import hot blast temperature.
The device that the utility model provides may be used for implementing following methods:
(1) by after pending mud preheating, be no more than the enclosed space inner drying of 250 DEG C in temperature, make the water ratio of mud be down to 30 ~ 40%, then carbonize in the enclosed space that temperature is no more than 300 DEG C, make the water ratio of mud be down to less than 30%;
(2) get the mud after step (1) process, under the oxygen free condition of 550 ~ 700 DEG C, destructive distillation 10 ~ 80min, obtains solid phase residue and gas-phase product respectively; Described solid phase residue is reclaimed as biological carbon;
(3) step (2) gained gas-phase product is carried out cooling, being separated, obtain gas and mixing liquid respectively; Described gas is carried out aftertreatment, is described drying, charing, destructive distillation energy supply as combustion gas; Described mixing liquid is carried out water separating of oil; Gained aqueous phase qualified discharge after treatment; Gained oil phase decomposes further, is separated; Decomposed becomes combustible gas, and partial purification obtains wood vinegar and wood tar oil.
Pending mud described in the utility model is sewage work's remaining mud after sewage disposal.The water ratio of described pending mud is not less than 50%.In described pending mud, organic content is not less than 40%, is preferably 40 ~ 60%.
The concrete grammar of the utility model step (1) described drying and charing is: carry out indirect heat exchange with the thermal oil of 220 ~ 240 DEG C.Described thermal oil is for recycling.
Described dry time, the temperature of enclosed space preferably no more than 280 DEG C, more preferably less than 240 DEG C.
During described charing, the temperature of enclosed space preferably no more than 350 DEG C, more preferably less than 270 DEG C.
As a kind of preferred version, described step (1) is specially: after pending mud preheating, carries out indirect heat exchange, make the water ratio of mud be down to 30 ~ 40% in the enclosed space of 200 ~ 250 DEG C with the thermal oil of 220 ~ 240 DEG C; In the enclosed space of 250 ~ 270 DEG C, carry out indirect heat exchange with the thermal oil of 220 ~ 240 DEG C again, make the water ratio of mud be down to less than 30%.
In described step (2), available rare gas element, as nitrogen replacement oxygen, thus oxygen-free environment when realizing destructive distillation.
When after step (1) process, the water ratio of mud is 10 ~ 30%, the destructive distillation described in step (2) is preferably: destructive distillation 12 ~ 75min under the oxygen free condition of 600 ~ 700 DEG C, obtains solid phase, gas-phase product respectively.
When after step (1) process, the water ratio of mud is less than 10%, destructive distillation described in step (2) is preferably: suppress balling-up after mud water ratio being less than 10% mixes with the wood chip accounting for mud weight 15%, under the oxygen free condition of 550 ~ 600 DEG C, destructive distillation 12 ~ 75min, obtains solid phase, gas-phase product respectively.The effect that the utility model adds wood chip mainly improves the carbon content in mud, with the quality of the quality and biomass charcoal that improve combustible gas.
Described method can also comprise the process of waste gas, is specially: waste gas step (1) described drying and charing produced is described pending mud preheating as thermal source, then qualified discharge after treatment.Described process is specially: send in exhaust gas centralized into alkali wash spray tower, removing dust and acidic substance, and then send into low temperature high energy plasma equipment, destroy organic molecule, oxidation small organic molecule, then send into alkali wash spray tower by induced draft fan, after oxidation, in and acidic oxide, last qualified discharge.
After gained solid phase residue reclaims as biological carbon, carbon-point or agriculture fertilizer can be processed into.
The utility model, based on the characteristic of municipal sludge, adopts drying-charing-retorting technique, the organic composition in mud is transformed into inflammable gas, and solid residue is used as carbon-point or agriculture is fertile, really accomplishes to make the best use of everything.Compared with prior art, the utility model at least has following advantages and beneficial effect:
(1) sludge at low temperature charing destructive distillation clean of the present utility model can make full use of the rear heat formed of carbonizing gas burning that dewatered sludge produces in retort process, be back in sludge drying, charing, retort process, heat energy is reclaimed in recycle, reaches energy-conservation object;
(2) after sludge at low temperature charing destructive distillation clean of the present utility model carries out low-temperature carbonization destructive distillation to dewatered sludge, not only substantially reduce the number volume and the weight of mud, and farthest save the calorific value of mud, further, product after dewatered sludge charing destructive distillation has the characteristic similar with charcoal, can be used as soil improvement agent and afforestation etc.;
(3) after sludge at low temperature charing destructive distillation clean of the present utility model carries out low-temperature carbonization destructive distillation to dewatered sludge, heavy metal ion is cured in carbide product, heavy metal relative is stablized, and sludge heavy-metal Leaching can reach the requirement that sludge from wastewater treatment plant disposes emission limit completely;
(4) after sludge at low temperature charing destructive distillation clean of the present utility model carries out low-temperature carbonization destructive distillation to dewatered sludge, not only circulation and stress heat energy, reduce the energy consumption in sludge treatment, reduce sludge treatment to the pollution of environment, and the byproducts such as the wood vinegar of output high added value, wood tar oil and gac, both had an economic benefit, had social benefit again;
(5) sludge at low temperature charing destructive distillation clean of the present utility model investment in fixed assets is far below code requirement;
(6) sludge at low temperature charing destructive distillation clean technique of the present utility model is suitable for the process of more than 100 tons municipal sludges.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of device described in the utility model embodiment 1; Wherein 1, storage bin; 2, jacketed screw transfer roller; 3, low-temperature drier; 4, heat-conducting oil furnace; 5, carbonizer; 6, lifting gear; 7, feeding warehouse; 8, gas retort; 9, fly-ash separator; 10, organic substance decomposing purification unit; 11, water cooler; 12, combustion gas storage tank; 13, biological carbon recovery unit; 14, dedusting is except acid unit; 15, plasma deodorization unit; 16, induced draft fan; 17, alkali cleaning spray unit.
Fig. 2 is the process flow sheet of sludge at low temperature charing destructive distillation clean technique in embodiment 2 and embodiment 3.
Embodiment
Following examples for illustration of the utility model, but are not used for limiting scope of the present utility model.
Embodiment 1
A kind of cleaning device (shown in figure 1) of mud; Described device comprises mud plenum system, drying sludge-carbonization system, mud distillation system and the product recovery that order is successively connected;
Described mud plenum system comprises the connected storage bin 1 of order and jacketed screw transfer roller 2;
Described drying sludge-carbonization system comprises the connected low-temperature drier 3 of order and carbonizer 5, and the entrance of described low-temperature drier is connected with the outlet of described jacketed screw transfer roller 2; Described low-temperature drier and carbonizer are also connected with described jacketed screw transfer roller 2 respectively through preheating gas pipeline;
Described low-temperature drier and carbonizer inside are equipped with thermal cycling crosspoint; Described thermal cycling crosspoint comprises the twin shaft hollow blade and crustless sandwich that can fill thermal oil; Described thermal cycling crosspoint is connected with heat-conducting oil furnace 4;
Described mud distillation system comprises the connected storage hopper dredger of order and gas retort 8; The entrance of described storage hopper dredger is connected with the outlet of described carbonizer, and described storage hopper dredger is made up of the lifting gear 6 be sequentially connected and feeding warehouse 7;
Described product recovery comprises the biological carbon recovery unit 13 and gas phase recovery unit that are connected with gas retort respectively; Described gas phase recovery unit comprises the decomposition of unit for treating water, wood vinegar and wood tar oil, purification process unit and organic gas processing unit;
Described organic gas processing unit comprise be linked in sequence successively fly-ash separator 9, organic substance decomposing purification unit 10, water cooler 11, combustion gas storage tank 12; Combustion gas storage tank 12 in described organic gas processing unit is also connected with mud distillation system with described drying sludge-carbonization system respectively through heating pipe line;
Described jacketed screw transfer roller 2 is also connected with flare system by exhaust pipeline; Described flare system comprises order successively and is connected dedusting except acid unit 14, plasma deodorization unit 15, induced draft fan 16, alkali cleaning spray unit 17, agent-feeding treatment unit and gas vent unit.
Embodiment 2
100 tons, remaining mud after obtaining sewage disposal from certain municipal sewage plant A, its water content is 80%, and organic content is 40%.
The device utilizing embodiment 1 to provide, processes according to following steps, treatment scheme as shown in Figure 2:
(1) by after pending mud preheating, in the enclosed space of 240 DEG C, carry out indirect heat exchange with the thermal oil of 220 DEG C, make the water ratio of mud be down to 40%; In the enclosed space of 270 DEG C, carry out indirect heat exchange with the thermal oil of 220 DEG C again, make the water ratio of mud be down to 28%;
(2) get the mud after step (1) process, under the oxygen free condition of 600 DEG C, destructive distillation 15min, obtains solid phase, gas-phase product respectively; Described solid phase residue is reclaimed as biological carbon;
(3) step (2) gained gas-phase product is carried out cooling, being separated, obtain gas and mixing liquid respectively;
Described gas is carried out aftertreatment, is described drying, charing, destructive distillation energy supply as combustion gas;
Described mixing liquid is carried out water separating of oil; Gained aqueous phase qualified discharge after treatment; Gained oil phase is separated further, purifying obtains wood vinegar and wood tar oil, and wood vinegar and wood tar oil decompose through organic substance decomposing purification unit, become inflammable gas to greatest extent.
Embodiment 3
100 tons, remaining mud after obtaining sewage disposal from certain municipal sewage plant B, its water content is 50%, and organic content is 60%.
The device utilizing embodiment 1 to provide, processes according to following steps, treatment scheme as shown in Figure 2:
(1) by after pending mud preheating, in the enclosed space of 240 DEG C, carry out indirect heat exchange with the thermal oil of 240 DEG C, make the water ratio of mud be down to 40%; In the enclosed space of 270 DEG C, carry out indirect heat exchange with the thermal oil of 240 DEG C again, make the water ratio of mud be down to 10%;
(2) get step (1) process after mud, with 15% wood chip mix after suppress balling-up, under the oxygen free condition of 600 DEG C, destructive distillation 15min, obtains solid phase, gas-phase product respectively; Described solid phase residue is reclaimed as biological carbon;
(3) step (2) gained gas-phase product is carried out cooling, being separated, obtain gas and mixing liquid respectively;
Described gas is carried out aftertreatment, is described drying, charing, destructive distillation energy supply as combustion gas;
Described mixing liquid is carried out water separating of oil; Gained aqueous phase qualified discharge after treatment; Gained oil phase is separated further, purifying obtains wood vinegar and wood tar oil, and wood vinegar and wood tar oil decompose through organic substance decomposing purification unit, become inflammable gas to greatest extent.
Although above done detailed description to the utility model with a general description of the specific embodiments, on the utility model basis, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements on the basis of not departing from the utility model spirit, all belong to the scope that the utility model is claimed.

Claims (10)

1. a cleaning device for mud, is characterized in that, described device comprises mud plenum system, drying sludge-carbonization system, mud distillation system and the product recovery that order is successively connected;
Described mud plenum system comprises the connected storage bin of order and jacketed screw transfer roller;
Described drying sludge-carbonization system comprises the connected low-temperature drier of order and carbonizer, and the entrance of described low-temperature drier is connected with the outlet of described jacketed screw transfer roller; Described low-temperature drier and carbonizer inside are equipped with thermal cycling crosspoint; Described low-temperature drier and carbonizer are also connected with described jacketed screw transfer roller respectively through preheating gas pipeline;
Described mud distillation system comprises the connected storage hopper dredger of order and gas retort; The entrance of described storage hopper dredger is connected with the outlet of described carbonizer;
Described product recovery comprises the biological carbon recovery unit and gas phase recovery unit that are connected with gas retort respectively; Described gas phase recovery unit comprises the decomposition of unit for treating water, wood vinegar and wood tar oil, purification process unit and organic gas processing unit.
2. device according to claim 1, is characterized in that, described drying sludge-carbonization system is airtight negative pressure system, and this system comprises closed-type feed device and airtight drawing mechanism.
3. device according to claim 1 and 2, is characterized in that, described thermal cycling crosspoint is connected with heat-conducting oil furnace by recycle pump;
The twin shaft hollow blade for filling thermal oil and crustless sandwich is comprised in described thermal cycling crosspoint.
4. device according to claim 3, is characterized in that, described heat-conducting oil furnace comprises heat-conducting oil furnace body, fuel combustion system, forced draft induced draft system.
5. device according to claim 1 and 2, is characterized in that, described gas phase recovery unit comprises unit for treating water, wood vinegar and wood tar oil processing unit and organic gas processing unit.
6. device according to claim 5, is characterized in that, comprise in described organic gas processing unit be linked in sequence successively fly-ash separator, organic substance decomposing purification unit, water cooler, combustion gas storage tank.
7. device according to claim 5, is characterized in that, described organic gas processing unit is also connected with mud distillation system with described drying sludge-carbonization system respectively through heating pipe line.
8. device according to claim 1, is characterized in that, described jacketed screw transfer roller is also connected with flare system by exhaust pipeline.
9. device according to claim 8, is characterized in that, described flare system comprises order successively and is connected dedusting except acid unit, plasma deodorization unit, alkali cleaning spray unit, agent-feeding treatment unit and gas vent unit.
10. device according to claim 1, is characterized in that, described device also comprises automatic control system;
Described automatic control system comprises the temperature control unit controlled the temperature of drying sludge-carbonization system and mud distillation system, to the pressure control unit that the pressure of distillation system controls, and according to the control unit that described temperature controls import hot blast rate and import hot blast temperature.
CN201520503498.3U 2015-07-13 2015-07-13 Clean processing apparatus of mud Active CN204918477U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105038822A (en) * 2015-07-13 2015-11-11 长沙泥宝环保有限公司 Sludge clean treatment method and device
CN107311416A (en) * 2017-08-17 2017-11-03 安徽益佳园环境工程有限公司 A kind of integrated ecological sludge treatment device
CN110451767A (en) * 2019-08-23 2019-11-15 安阳艾尔旺新能源环境有限公司 Sludge drying system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105038822A (en) * 2015-07-13 2015-11-11 长沙泥宝环保有限公司 Sludge clean treatment method and device
CN107311416A (en) * 2017-08-17 2017-11-03 安徽益佳园环境工程有限公司 A kind of integrated ecological sludge treatment device
CN110451767A (en) * 2019-08-23 2019-11-15 安阳艾尔旺新能源环境有限公司 Sludge drying system

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