CN204125535U - A kind of device and slightly acidic electrolyzed oxidizing water spray disinfection system preparing slightly acidic electrolyzed oxidizing water - Google Patents

A kind of device and slightly acidic electrolyzed oxidizing water spray disinfection system preparing slightly acidic electrolyzed oxidizing water Download PDF

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Publication number
CN204125535U
CN204125535U CN201420575307.XU CN201420575307U CN204125535U CN 204125535 U CN204125535 U CN 204125535U CN 201420575307 U CN201420575307 U CN 201420575307U CN 204125535 U CN204125535 U CN 204125535U
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electrolytic solution
slightly acidic
water
electric potential
acidic electrolyzed
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CN201420575307.XU
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许劭
丁甜
宣晓婷
刘东红
王蒙蒙
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Zhejiang University ZJU
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Zhejiang University ZJU
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Abstract

The utility model discloses a kind of device and the slightly acidic electrolyzed oxidizing water spray disinfection system of preparing slightly acidic electrolyzed oxidizing water, the device of described preparation slightly acidic electrolyzed oxidizing water comprises electrolytic solution and is equipped with groove, undivided cell and liquid pool, electrolytic solution is equipped with groove and is connected with undivided cell by electrolytic solution injection tube, electrolytic solution is equipped with between groove and undivided cell and is also provided with electric potential water return line, electrolytic solution is equipped with groove and is connected with liquid pool by electric potential water vent pipe, electrolytic solution injection tube, electric potential water return line and electric potential water vent pipe are all provided with the first vacuum primingpump.Acidic oxidized electric potential water in undivided cell is refilled electrolytic solution and is equipped with in groove by the utility model, re-inject after mixing with the electrolytic solution of remnants in undivided cell, carry out cyclic electrolysis, compared with the acidic oxidized electric potential water obtained through once electrolytic, cyclic electrolysis through cyclic electrolysis acquisition concentrates effective chlorine density in electric potential water significantly to be increased, and farthest prevents chlorine to run off.

Description

A kind of device and slightly acidic electrolyzed oxidizing water spray disinfection system preparing slightly acidic electrolyzed oxidizing water
Technical field
The utility model relates to a kind of slightly acidic oxidizing potential water production device, is specifically related to a kind of device and the slightly acidic electrolyzed oxidizing water spray disinfection system of preparing slightly acidic electrolyzed oxidizing water.
Background technology
Along with the raising of people's living standard, people more and more focus on food sanitation and safety problem, and a lot of food sanitation accident outburst in recent years, cause again the extensive concern of society to this problem.And in numerous food safety accident, the existence of " microorganism " plays key player.So, how effectively and efficient sterilizing to become on society and scientific research field a problem urgently to be resolved hurrily.
Acidic oxidized electric potential water is (also known as strong oxidized water, Electrolyzed oxidizing water, strong acidic electrolyzed water, acidic oxidized electric potential water, functional water etc.,) be that one has high redox potential (ORP), low pH, water containing lower concentration available chlorine, this glassware for drinking water has stronger oxidation capacity and quick killing microorganisms effect.
Slightly acidic electrolyzed oxidizing water is called for short SAEW, is obtained by electrolysis dilute sodium chloride or dilute hydrochloric acid solution, has close to the feature such as neutral, corrodibility is little, has efficient sterilizing ability simultaneously.Because its to make using method safe and simple, low residue and the characteristic such as to have no side effect are widely used.
In the conventional production equipment of acidic oxidized electric potential water, the electrolyzer mainly diaphragm electrolytic cell of employing.Diaphragm electrolytic cell utilizes ion-exchange membrane by compartition in electrolyzer into two, and positive and negative electrode is placed in separated electrolyzer.During work, in electrolyzer, inject electrolytic solution, make electrolytic solution generation electrochemical reaction by the electric current of positive and negative electrode, generate acidic oxidized electric potential water in positive pole side, generate alkaline reduction electric potential water in negative pole side.
Though diaphragm electrolytic cell can make acidic oxidized electric potential water, the alkaline reduction electric potential water that negative pole produces does not possess sterilizing ability, generally goes out of use, and makes tap water utilization ratio lose 50%; And the chlorine-containing gas generated in electrolytic process very easily spreads, be not only difficult to again be utilized, also environment produced and pollute.
Publication number is the device that the Chinese patent literature of CN 102217649B discloses that a kind of diaphragm-free electrolysis legal system gets slightly acidic electrolyzed oxidizing water, comprise the electrolytic solution connected successively by pipe connecting and be equipped with groove, undivided cell and liquid pool (i.e. two-stage dilution case), electrolytic solution is equipped with groove and injects electrolytic solution by pipe connecting to undivided cell, undivided cell carries out electrolysis to electrolytic solution and obtains strongly-acid electrolyzed oxidizing water, strongly-acid EO water is injected liquid pool by pipe connecting and dilutes by undivided cell, obtains slightly acidic electrolyzed oxidizing water.
But in its slightly acidic electrolyzed oxidizing water obtained, effective chlorine density is lower, is easily subject to the impact of some impurity, thus causes the rapid decay of available chlorine and affect sterilization effect in use procedure.
Utility model content
The utility model provides a kind of device preparing slightly acidic electrolyzed oxidizing water, and utilize this device to produce slightly acidic electrolyzed oxidizing water, its effective chlorine density significantly improves.
A kind of device preparing slightly acidic electrolyzed oxidizing water, comprise electrolytic solution and be equipped with groove, undivided cell and liquid pool, electrolytic solution is equipped with groove and is connected with undivided cell by electrolytic solution injection tube, electrolytic solution is equipped with between groove and undivided cell and is also provided with electric potential water return line, and electrolytic solution outfit groove is connected with liquid pool by electric potential water vent pipe, and electrolytic solution injection tube, electric potential water return line and electric potential water vent pipe are all provided with the first vacuum primingpump.
Electrolytic solution is equipped with groove and injects electrolytic solution by electrolytic solution injection tube to undivided cell, electrolytic solution generates acidic oxidized electric potential water after undivided cell electrolysis, acidic oxidized electric potential water returns electrolytic solution through electric potential water return line again and is equipped with groove, to be equipped with in groove after residual electrolytic solution mixes with electrolytic solution, to be again injected in undivided cell and to carry out electrolysis.Cyclic electrolysis like this, is as far as possible all converted into available chlorine by the chlorine that chlorion and electrolysis produce, and obtains cyclic electrolysis and concentrates electric potential water; Cyclic electrolysis is concentrated electric potential water and inject liquid pool through electric potential water vent pipe, be diluted to the concentration of required slightly acidic electrolyzed oxidizing water according to specific needs, used.
Each first vacuum primingpump effectively realizes liquid fast transfer between each groove.
Device of the present utility model also comprises the first intelligent liquid mixing system, and the first intelligent liquid mixing system is for adjusting the concentration of available chlorine in slightly acidic electrolyzed oxidizing water in liquid pool.
As preferably, described intelligent liquid mixing system comprises:
Effective chlorine density detector, is arranged on electric potential water vent pipe;
First water tank, is connected by the first pipeline with liquid pool, this first pipeline is provided with valve and first-class gauge;
First controller, for receiving the information that effective chlorine density detector and first-class gauge send, and according to the keying of the information Control valve received.
Before dosing, first to the first controller input preset concentration, then the first controller receives the information of effective chlorine density detector, if cyclic electrolysis to concentrate in electric potential water effective chlorine density higher than preset concentration, then Open valve, and calculate institute's water requirement, otherwise not Open valve; Water after valve opening in the first water tank enters liquid pool, and first-class gauge detects flow rate, according to the detection data of first-class gauge, the first controller judges that whether the water yield is enough, the enough rear valve-off of the water yield.
Device of the present utility model also comprises the second intelligent liquid mixing system, and the second intelligent liquid mixing system is for being equipped with the electrolytic solution in electrolytic solution outfit groove.As preferably, described second intelligent liquid mixing system comprises:
Liquid level detector, for detecting the liquid level in electrolytic solution outfit groove;
Second water tank, is equipped with groove by the second pipeline with solution liquid and is connected, the second pipeline is provided with the second vacuum primingpump and second gauge;
Electrolytic solution storage tank, is equipped with groove by the 3rd pipeline with solution liquid and is connected, the 3rd pipeline is provided with the 3rd vacuum primingpump and the 3rd under meter;
Second controller, for the information that receiving liquid bit detector, second gauge and the 3rd under meter send, and controls the start and stop of the second vacuum primingpump and the 3rd vacuum primingpump respectively according to the information received.
When liquid level detector detects that electrolytic solution is equipped with liquid level in groove lower than preset height, signal is sent to second controller, second controller starts the second vacuum primingpump and the 3rd vacuum primingpump, and the electrolytic solution mother liquor in the water in the second water tank, electrolytic solution storage tank is injected into electrolytic solution and is equipped with groove; In injection process, second gauge and the 3rd under meter detect the liquid flow rate of the second pipeline and the 3rd pipeline respectively and send to second controller, second controller is according to the concentration of electrolyte preset, control the second vacuum primingpump in due course and the 3rd vacuum primingpump cuts out, realize the automatic outfit that electrolytic solution is equipped with groove electrolyte inside.
The utility model additionally provides a kind of slightly acidic electrolyzed oxidizing water spray disinfection system, comprise slightly acidic oxidizing potential water preparation apparatus and slightly acidic electrolyzed oxidizing water flusher, described slightly acidic oxidizing potential water preparation apparatus is the device of above-mentioned preparation slightly acidic electrolyzed oxidizing water.
As preferably, described slightly acidic electrolyzed oxidizing water flusher comprises the shower nozzle be connected with liquid pool by spray line, described spray line is provided with the 4th vacuum primingpump.Sprayed by slightly acidic electrolyzed oxidizing water in liquid pool by the 4th vacuum primingpump and shower nozzle, carry out disinfection sterilization.
Working process of the present utility model is:
Second intelligent liquid mixing system makes to be full of electrolytic solution in electrolytic solution outfit groove, and the first vacuum primingpump on electrolytic solution injection tube injects the electrolyte into undivided cell, and electrolytic solution generates acidic oxidized electric potential water after undivided cell electrolysis; After electrolysis completes, the first vacuum primingpump on electric potential water return line acidic oxidized electric potential water is returned inject electrolytic solution be equipped with groove, with electrolytic solution is equipped with in groove remain electrolytic solution mix after, be again injected in undivided cell through electrolytic solution injection tube and carry out electrolysis.Cyclic electrolysis like this, is as far as possible all converted into available chlorine by chlorion and chlorine, obtains cyclic electrolysis and concentrates electric potential water; After electrolysis completes, cyclic electrolysis is concentrated electric potential water and injects liquid pool by the first vacuum primingpump on electric potential water vent pipe, and cyclic electrolysis is concentrated electric potential water and is diluted to desired concn by the second intelligent liquid mixing system according to specific needs, obtains slightly acidic electrolyzed oxidizing water; Slightly acidic electrolyzed oxidizing water sprays from shower nozzle by the 4th vacuum primingpump on spray line, and carry out disinfection sterilization.
Compared with prior art, the beneficial effects of the utility model are:
(1) acidic oxidized electric potential water in undivided cell refills in electrolytic solution outfit groove by the utility model, re-inject after mixing with the electrolytic solution of remnants in undivided cell, carry out repeatedly cyclic electrolysis, compared with the acidic oxidized electric potential water obtained through once electrolytic, cyclic electrolysis through cyclic electrolysis acquisition concentrates effective chlorine density in electric potential water significantly to be increased, and farthest prevents chlorine to run off;
(2) device of the present utility model, structure is simple, and the process safety of preparation slightly acidic electrolyzed oxidizing water is efficient, with low cost, easy to utilize;
(3) the utility model utilizes the second intelligent liquid mixing system automatic preparation electrolytic solution, the first intelligent liquid mixing system is utilized automatically to adjust the concentration of slightly acidic electrolyzed oxidizing water, intelligence degree is higher, makes the preparation process simple and effective more of slightly acidic electrolyzed oxidizing water.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of slightly acidic electrolyzed oxidizing water of the utility model spray disinfection system.
Embodiment
As shown in Figure 1, a kind of slightly acidic electrolyzed oxidizing water of the utility model spray disinfection system, comprises slightly acidic oxidizing potential water preparation apparatus 1 and slightly acidic electrolyzed oxidizing water flusher 2.
Slightly acidic oxidizing potential water preparation apparatus 1 comprises electrolytic solution and is equipped with groove 101, and electrolytic solution is equipped with groove 101 built with electrolytic solution.The present embodiment utilizes the second intelligent liquid mixing system to be equipped with the electrolytic solution that electrolytic solution is equipped with groove 101.
In the present embodiment, the second intelligent liquid mixing system comprises:
Liquid level detector (omitting in figure), for detecting the liquid level in electrolytic solution outfit groove 101;
Second water tank 102, is equipped with groove 101 by the second pipeline 103 and electrolytic solution and is connected, and the second pipeline 103 is provided with the second vacuum primingpump 104 and second gauge (omitting in figure);
Electrolytic solution storage tank 105 (electrolytic solution mother liquor is housed), is equipped with groove 101 by the 3rd pipeline 106 and electrolytic solution and is connected, and the 3rd pipeline 106 is provided with the 3rd vacuum primingpump 107 and the 3rd under meter (omitting in figure);
Second controller (omitting in figure), for the information that receiving liquid bit detector, second gauge and the 3rd under meter send, and controls the start and stop of the second vacuum primingpump 104 and the 3rd vacuum primingpump 107 respectively according to the information received.
When liquid level detector detects that electrolytic solution is equipped with liquid level in groove 101 lower than preset height, signal is sent to second controller, second controller starts the water in the second vacuum primingpump 104 and/or the 3rd vacuum primingpump 107, second water tank 102, the electrolytic solution mother liquor in electrolytic solution storage tank 105 is injected into electrolytic solution and is equipped with groove 101; In injection process, second gauge and the 3rd under meter detect the liquid flow rate of the second pipeline 103 and the 3rd pipeline 106 respectively and send to second controller, second controller is according to the concentration of electrolyte preset, control the second vacuum primingpump 104 in due course and/or the 3rd vacuum primingpump 107 cuts out, realize the automatic outfit that electrolytic solution is equipped with groove 101 electrolyte inside.
Electrolytic solution is equipped with groove 101 and is connected with undivided cell 108 by electrolytic solution injection tube 109, after electrolytic solution has been equipped with, electrolytic solution enters in undivided cell 108 through electrolytic solution injection tube 109, and undivided cell 108 pairs of electrolytic solution carry out electrolysis and generate acidic oxidized electric potential water.Electrolytic solution is equipped with between groove 101 and undivided cell 108 and is also provided with electric potential water return line 110, acidic oxidized electric potential water in undivided cell 108 returns electrolytic solution through electric potential water return line 110 again and is equipped with groove 101, to be equipped with in groove 101 after residual electrolytic solution mixes with electrolytic solution, to be again injected in undivided cell 108 and to carry out electrolysis.Cyclic electrolysis like this, is as far as possible all converted into available chlorine by the chlorine that chlorion and electrolysis produce, and obtains cyclic electrolysis and concentrates electric potential water.
Electrolytic solution injection tube 109 and electric potential water return line 110 are all provided with the first vacuum primingpump 111.
Electrolytic solution is equipped with groove 101 and is connected with liquid pool 113 by electric potential water vent pipe 112, electric potential water vent pipe 112 is also provided with the first vacuum primingpump 111.After cyclic electrolysis completes, cyclic electrolysis is concentrated electric potential water and inject liquid pool 113 through electric potential water vent pipe 112, be diluted to the concentration of required slightly acidic electrolyzed oxidizing water according to specific needs, used.
In working process, open when the first vacuum primingpump 111 on electrolytic solution injection tube 109, electric potential water return line 110 and electric potential water vent pipe 112 is all different.
The present embodiment utilizes the first intelligent liquid mixing system to adjust the concentration of available chlorine in slightly acidic electrolyzed oxidizing water in liquid pool 113, and described intelligent liquid mixing system comprises:
Effective chlorine density detector (omitting in figure), is arranged on electric potential water vent pipe 112;
First water tank 114, is positioned at the top of liquid pool 113, is connected, this first pipeline 115 is provided with valve 116 and first-class gauge (omitting in figure) with liquid pool 113 by the first pipeline 115;
First controller (omitting in figure), for receiving the information that effective chlorine density detector and first-class gauge send, and according to the keying of the information Control valve 116 received.
Before dosing, first to the first controller input preset concentration, then the first controller receives the information of effective chlorine density detector, if cyclic electrolysis to concentrate in electric potential water effective chlorine density higher than preset concentration, then Open valve 116, and calculate institute's water requirement, otherwise not Open valve 116; The water that valve 116 is opened in rear first water tank 116 enters liquid pool 113, and first-class gauge detects flow rate, according to the detection data of first-class gauge, the first controller judges that whether the water yield is enough, the enough rear valve-off 116 of the water yield.
Slightly acidic electrolyzed oxidizing water flusher 2 comprises the shower nozzle 202 be connected with liquid pool 115 by spray line 201, spray line 201 is provided with the 4th vacuum primingpump 203.Utilize the 4th vacuum primingpump 203 to be sprayed from shower nozzle 202 by the slightly acidic electrolyzed oxidizing water adjusting concentration, carry out disinfection sterilization.
Embodiment 2
To contain 0.05%NaCl, electrolytic solution made by 4 liters of mineral waters of 0.03%HCl, utilize the slightly acidic oxidizing potential water preparation apparatus cyclic electrolysis of embodiment 1, get cyclic electrolysis when cyclic electrolysis 1min, 3min, 5min and concentrate electric potential water (CEW), measure its ACC value (effective chlorine density), ORP value (redox potential), pH value; To contain 1.8%NaCl, electrolytic solution made by 4 liters of mineral waters of 0.03%HCl, utilize publication number device disclosed in the Chinese patent literature of CN 102217649B to prepare once electrolytic electric potential water (SAEW) (without dilution), measure its ACC value (effective chlorine density), ORP value (redox potential), pH value; And compare with each performance perameter that cyclic electrolysis concentrates electric potential water, result is as shown in table 1.
Table 1
From table 1, containing 1.8% NaCl in the electrolytic solution adopted when preparing once electrolytic electric potential water, and prepare only containing 0.05% NaCl in the electrolytic solution adopted when cyclic electrolysis concentrates electric potential water, in electrolytic solution, chlorine ion concentration reduces 97%; But during slightly acidic oxidizing potential water preparation apparatus cyclic electrolysis 1min of the present utility model, it is suitable, even slightly high with traditional once electrolytic electric potential water that cyclic electrolysis concentrates effective chlorine density in electric potential water; And with cyclic electrolysis time lengthening, the effective chlorine density that cyclic electrolysis concentrates in electric potential water constantly increases, and during cyclic electrolysis 5min, ACC value reaches 234.33, be 11.6 times of traditional once electrolytic electric potential water ACC value.As can be seen here, slightly acidic oxidizing potential water preparation apparatus of the present utility model carries out cyclic electrolysis to electrolytic solution effectively can be increased cyclic electrolysis and concentrate effective chlorine density in electric potential water, farthest prevents chlorine to run off.

Claims (7)

1. prepare the device of slightly acidic electrolyzed oxidizing water for one kind, comprise electrolytic solution and be equipped with groove, undivided cell and liquid pool, electrolytic solution is equipped with groove and is connected with undivided cell by electrolytic solution injection tube, it is characterized in that, electrolytic solution is equipped with between groove and undivided cell and is also provided with electric potential water return line, and electrolytic solution outfit groove is connected with liquid pool by electric potential water vent pipe, and electrolytic solution injection tube, electric potential water return line and electric potential water vent pipe are all provided with the first vacuum primingpump.
2. the device of preparation slightly acidic electrolyzed oxidizing water as claimed in claim 1, it is characterized in that, comprise the first intelligent liquid mixing system, the first intelligent liquid mixing system is for adjusting the concentration of available chlorine in slightly acidic electrolyzed oxidizing water in liquid pool.
3. prepare the device of slightly acidic electrolyzed oxidizing water as claimed in claim 2, it is characterized in that, described intelligent liquid mixing system comprises:
Effective chlorine density detector, is arranged on electric potential water vent pipe;
First water tank, is connected by the first pipeline with liquid pool, this first pipeline is provided with valve and first-class gauge;
First controller, for receiving the information that effective chlorine density detector and first-class gauge send, and according to the keying of the information Control valve received.
4. as described in as arbitrary in claims 1 to 3, the device of preparation slightly acidic electrolyzed oxidizing water, is characterized in that, comprise the second intelligent liquid mixing system, and the second intelligent liquid mixing system is equipped with electrolytic solution in groove for being equipped with electrolytic solution.
5. prepare the device of slightly acidic electrolyzed oxidizing water as claimed in claim 4, it is characterized in that, described second intelligent liquid mixing system comprises:
Liquid level detector, for detecting the liquid level in electrolytic solution outfit groove;
Second water tank, is equipped with groove by the second pipeline with solution liquid and is connected, the second pipeline is provided with the second vacuum primingpump and second gauge;
Electrolytic solution storage tank, is equipped with groove by the 3rd pipeline with solution liquid and is connected, the 3rd pipeline is provided with the 3rd vacuum primingpump and the 3rd under meter;
Second controller, for the information that receiving liquid bit detector, second gauge and the 3rd under meter send, and controls the start and stop of the second vacuum primingpump and the 3rd vacuum primingpump respectively according to the information received.
6. a slightly acidic electrolyzed oxidizing water spray disinfection system, comprise slightly acidic oxidizing potential water preparation apparatus and slightly acidic electrolyzed oxidizing water flusher, it is characterized in that, described slightly acidic oxidizing potential water preparation apparatus is the device of the arbitrary described preparation slightly acidic electrolyzed oxidizing water of Claims 1 to 5.
7. slightly acidic electrolyzed oxidizing water spray disinfection system as claimed in claim 6, it is characterized in that, described slightly acidic electrolyzed oxidizing water flusher comprises the shower nozzle be connected with liquid pool by spray line, described spray line is provided with the 4th vacuum primingpump.
CN201420575307.XU 2014-09-30 2014-09-30 A kind of device and slightly acidic electrolyzed oxidizing water spray disinfection system preparing slightly acidic electrolyzed oxidizing water Expired - Fee Related CN204125535U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104856867A (en) * 2015-05-05 2015-08-26 韩永俊 Subacidity oxidation electric potential water treatment apparatus
CN105239088A (en) * 2015-09-16 2016-01-13 浙江大学 Application of citric acid in preparation of weak-acid electrolyzed water and preparation method of weak-acid electrolyzed water
CN110042416A (en) * 2019-05-15 2019-07-23 朝阳市现代化学技术研究院 A kind of high oxidation water generation equipment and preparation method thereof
CN110604171A (en) * 2019-09-17 2019-12-24 山东省农业科学院农产品研究所 Commercialized treatment method for picked cherries

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104856867A (en) * 2015-05-05 2015-08-26 韩永俊 Subacidity oxidation electric potential water treatment apparatus
CN105239088A (en) * 2015-09-16 2016-01-13 浙江大学 Application of citric acid in preparation of weak-acid electrolyzed water and preparation method of weak-acid electrolyzed water
CN105239088B (en) * 2015-09-16 2017-07-07 浙江大学 A kind of preparation method of application and faintly acid electric potential water of the citric acid in faintly acid electric potential water is prepared
CN110042416A (en) * 2019-05-15 2019-07-23 朝阳市现代化学技术研究院 A kind of high oxidation water generation equipment and preparation method thereof
CN110604171A (en) * 2019-09-17 2019-12-24 山东省农业科学院农产品研究所 Commercialized treatment method for picked cherries

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