CN204093284U - For the accident chlorine treatment system in liquid chlorine production - Google Patents

For the accident chlorine treatment system in liquid chlorine production Download PDF

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Publication number
CN204093284U
CN204093284U CN201420311691.2U CN201420311691U CN204093284U CN 204093284 U CN204093284 U CN 204093284U CN 201420311691 U CN201420311691 U CN 201420311691U CN 204093284 U CN204093284 U CN 204093284U
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chlorine
motor
liquid chlorine
driven valve
district
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Withdrawn - After Issue
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CN201420311691.2U
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Chinese (zh)
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许红霞
张金
许红桃
成彦霞
王林
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Abstract

A kind of for the accident chlorine treatment system in liquid chlorine production, comprise the spray equipment be arranged at above liquid chlorine storage tank district and liquid chlorine package district, be arranged at the chlorine detection probe in liquid chlorine storage tank district and liquid chlorine package district, porch is positioned at the ground trench in liquid chlorine storage tank district and liquid chlorine package district, the centralized control system that the recovery pond be connected with ground ditch outlet is electrically connected with chlorine detection probe and motor-driven valve, 32% alkali lye pipeline, production water lines is respectively connected with the water inlet of venturi by a motor-driven valve, the delivery port of venturi is connected with two branch pipeline by total road motor-driven valve that main pipe rail and main pipe rail are arranged, these two branch pipeline are connected with the spray equipment in liquid chlorine storage tank district and liquid chlorine package district by two shunt motor-driven valves, the delivery port of recovery pond passes through reclaim line, recovery pump and recovery motor-driven valve are connected with described main pipe rail.The utility model chlorine treatment better effects if, not easily cause secondary accident, security better, automation remote can be realized control.

Description

For the accident chlorine treatment system in liquid chlorine production
Technical field
The utility model is specifically related to a kind of for the accident chlorine treatment system in liquid chlorine production.
Background technology
In the production process of liquid chlorine, the steel cylinder in liquid chlorine storage tank and liquid chlorine package district, once reveal, must work the mischief to the personnel of surrounding and environment.Therefore, very strict accident chlorine treatment technique must be taked in liquid chlorine production.
In the prior art, when liquid chlorine storage tank occurs to reveal, while spareslots is vacuumized, leakage grooves is pressurizeed, pressure reduction is utilized to move in spareslots by the liquid chlorine of leakage grooves, spray with production water in the process of transfer liquid chlorine, absorb the chlorine leaked, after liquid chlorine transfer, open leakage grooves vacuum valve, remaining chlorine is evacuated to accident chlorine treatment pond; When liquid chlorine package district steel cylinder generation leakage accident, winch in accident steel cylinder treatment pond with crane by steel cylinder, the chlorine of leakage is by 32% alkali liquor absorption from outer tube, and the waste liquid after saturated is sent to sewage disposal by dredge pump.
But, there is following defect in above accident chlorine treatment technique: (1) is in liquid chlorine storage tank district, the chlorine leaked is absorbed with producing water, assimilation effect is poor, and the hydrochloric acid generated, hypochlorous acid corrosion pipeline and equipment, cause secondary accident, moreover the ability of production water treatment chlorine is not as good as soda bath, when extreme leakage, catastrophic chlorine gas leakage accident cannot be contained; (2) liquid chlorine package district accident steel cylinder treatment pond with 32% alkali liquor absorption chlorine, although assimilation effect is good, concentration of lye is too high can endanger personnel health, can infiltrate subcutaneous cell rapidly after caustic soda and contact human skin, make its stiff necrosis of dewatering, cause degree of depth chemical burn, there is the shouting pain of the bright sample of fire at the place of burning, and when having an intense pain, rotten liquid can be oozed out in the place of burning, severe then also can cause shock, stupor can being there is dead, as being splashed into eyes, very easily occurring blind.
Utility model content
The purpose of this utility model is the deficiency existed to overcome prior art, provide a kind of rational in infrastructure, chlorine treatment better effects if, not easily cause secondary accident, security better, can realize that automation remote controls for the accident chlorine treatment system in liquid chlorine production.
The purpose of this utility model is achieved through the following technical solutions: a kind of for the accident chlorine treatment system in liquid chlorine production, comprise the spray equipment be arranged at above liquid chlorine storage tank district and liquid chlorine package district, be arranged at the chlorine detection probe in liquid chlorine storage tank district and liquid chlorine package district, porch is positioned at the ground trench in liquid chlorine storage tank district and liquid chlorine package district, the recovery pond be connected with ground ditch outlet, 32% alkali lye pipeline, production water lines, venturi, multiple motor-driven valve and the centralized control system be electrically connected with chlorine detection probe and motor-driven valve, described 32% alkali lye pipeline, described production water lines is respectively connected with the water inlet of described venturi by a motor-driven valve, the delivery port of described venturi is connected with two branch pipeline by total road motor-driven valve that main pipe rail and main pipe rail are arranged, these two branch pipeline are connected with the spray equipment in liquid chlorine storage tank district and liquid chlorine package district by two shunt motor-driven valves, the delivery port of recovery pond passes through reclaim line, recovery pump and recovery motor-driven valve are connected with described main pipe rail.
Described reclaim line is connected with clorox reclaim line and blowoff line, clorox reclaim line and blowoff line are provided with motor-driven valve, between the access point and described recovery pump of described clorox reclaim line, described blowoff line one section of described reclaim line is provided with motor-driven valve.
Described production water lines is also directly connected with described main pipe rail by pipeline and motor-driven valve.
The beneficial effects of the utility model are: the mass concentration of alkali lye reduces by the utility model, have both overcome and have produced the deficiency that water absorbs chlorine, turn avoid the excessive harm to personnel health of accident chlorine treatment pond 32% concentration of lye.System of the present utility model have rational in infrastructure, chlorine treatment better effects if, not easily cause secondary accident, security better, the advantage that automation remote controls can be realized.
Accompanying drawing explanation
Fig. 1 is structure principle chart of the present utility model.
In the drawings: 1-liquid chlorine package district; 2-liquid chlorine storage tank district; 3-chlorine detection probe; 4-spray equipment; 5-trench; 6-recovery pond; 7-recovery pump; 8-venturi; 9-first motor-driven valve; 10-second motor-driven valve; 11-the 3rd motor-driven valve; 12-the 4th motor-driven valve; 13-the 5th motor-driven valve; 14-the 6th motor-driven valve; 15-the 7th motor-driven valve; 16-the 8th motor-driven valve; 17-the 9th motor-driven valve; 18-the tenth motor-driven valve; 19-the 11 motor-driven valve; 20-32% alkali lye pipeline; 21-production water lines.
Detailed description of the invention
A kind of for the accident chlorine treatment method in liquid chlorine production, comprise following content: mixed with the alkali lye of mass concentration 32% by production water, the mass concentration of alkali in liquid is made to be down to 15%, when liquid chlorine storage tank district or liquid chlorine package district chlorine leakage, by the mass concentration of above-mentioned alkali be 15% liquid deliver to liquid chlorine storage tank district, liquid chlorine package district, spray from top, absorb the chlorine leaked; When chlorine liquid chlorine storage tank district or liquid chlorine package district leak, the liquid under spray flows into recovery pond through trench; After the liquid level of recovery pond reaches setting liquid level, the liquid in recovery pond is delivered to liquid chlorine storage tank district or liquid chlorine package district and again utilize when there is chlorine leakage accident; After the clorox mass concentration index of liquid in recovery pond reaches setting value, by the Liquid transfer in recovery pond to clorox storage tank; When clorox tank level reaches 80%, the liquid in recovery pond is delivered to Sewage Disposal, process qualified after drain into sewage treatment plant.
The mass concentration of alkali lye is reduced, has both overcome and produced the deficiency that water absorbs chlorine, turn avoid the excessive harm to personnel health of accident chlorine treatment pond 32% concentration of lye.In present chlor-alkali data, major part says that the concentration of caustic soda absorbing chlorine is 20%, but the alkali lye of this concentration is after absorption chlorine, when effective chlorine is qualified in the clorox of production, crosses alkali number higher, causes the waste to caustic soda.Find through test of many times, the mass concentration of the absorption alkali lye of preparation is 15%, and in the clorox of production, effective chlorine is qualified, crosses alkali number also qualified.
As shown in Figure 1, production water lines 21 adds orifice flowmeter, and 32% alkali lye pipeline 20 adds orifice flowmeter, mixes, alkali lye mass concentration is adjusted to 15% in venturi 8.In the course of work, during chlorine gas leakage, liquid chlorine is run out of by leak point under the effect of high pressure, the chlorine gas concentration in external procedure district constantly increases in time, chlorine detection probe 3 detects that chlorine exceeds standard, send sound and light alarm, the signal of telecommunication is passed to centralized control system simultaneously, as chlorine gas leakage occurs in liquid chlorine storage tank district 2, spray motor-driven valve first motor-driven valve 9, second motor-driven valve 10, 3rd motor-driven valve 11, 5th motor-driven valve 13, 7th motor-driven valve 15 is opened, 6th motor-driven valve 14, 8th motor-driven valve 16, 11 motor-driven valve 19 cuts out, spray equipment 4 above liquid chlorine storage tank district 2 sprays, absorb chlorine, as liquid chlorine package district 1 reveals, spray motor-driven valve first motor-driven valve 9, second motor-driven valve 10, the 3rd motor-driven valve 11, the 5th motor-driven valve 13, the 6th motor-driven valve 14 are opened, 7th motor-driven valve 15, the 8th motor-driven valve the 16, the 11 motor-driven valve 19 are closed, spray equipment 4 above liquid chlorine package district 1 sprays, and absorbs chlorine.The alkali lye absorbed after chlorine flows into recovery pond 6 through trench 5, after recovery pond 6 liquid level reaches setting liquid level, when again there is chlorine leakage accident, recovery pump 7 starts, 8th motor-driven valve the 16, the 11 motor-driven valve 19 is opened, first motor-driven valve 9, second motor-driven valve 10, the 3rd motor-driven valve 11 are closed, and alkali lye enters in main pipe rail and sprays to liquid chlorine package district 1 or liquid chlorine storage tank district 2 again.
After the mass concentration index of the clorox in recovery pond 6 reaches setting value, open the 8th motor-driven valve 16, the 9th motor-driven valve 17, close the tenth motor-driven valve the 18, the 11 motor-driven valve 19, clorox is transported to clorox storage tank, for primary brine process refined brine and sell outward.When liquid level as clorox storage tank reaches 80%, open the 8th motor-driven valve 16, the tenth motor-driven valve 18, close the 11 motor-driven valve 19, the liquid in recovery pond 6 is delivered to Sewage Disposal, processes qualified Hou Pai garden sewage treatment plant.
In the utility model, can the concentration of long-range free adjustment preparation alkali lye by motor-driven valve, reach the concentration range needed for accident and flow, the utility model achieves systematization, automation remote controls.Add steam in 32% alkali lye pipeline 20, plant air purges, can effectively reduce corrosion of piping and crystallisation problems.Production water lines 21 is also directly connected with main pipe rail by pipeline and the 4th motor-driven valve 12, can directly pass into production water as required.Reuse pipeline corrosion-resistant trench 5 replaces, and absorbing liquid can be recycled, after concentration lower bound, export outer selling by rear pump.This system can carry out effective process to the chlorine leakage accident in liquid chlorine package district 1 and liquid chlorine storage tank district 2.
Finally should be noted that; above content is only in order to illustrate the technical solution of the utility model; but not the restriction to the utility model protection domain; the simple modification that those of ordinary skill in the art carries out the technical solution of the utility model or equivalently to replace, does not all depart from essence and the scope of technical solutions of the utility model.

Claims (3)

1. one kind for the accident chlorine treatment system in liquid chlorine production, it is characterized in that: describedly comprise the spray equipment be arranged at above liquid chlorine storage tank district and liquid chlorine package district for the accident chlorine treatment system in liquid chlorine production, be arranged at the chlorine detection probe in liquid chlorine storage tank district and liquid chlorine package district, porch is positioned at the ground trench in liquid chlorine storage tank district and liquid chlorine package district, the recovery pond be connected with ground ditch outlet, 32% alkali lye pipeline, production water lines, venturi, multiple motor-driven valve and the centralized control system be electrically connected with chlorine detection probe and motor-driven valve, described 32% alkali lye pipeline, described production water lines is respectively connected with the water inlet of described venturi by a motor-driven valve, the delivery port of described venturi is connected with two branch pipeline by total road motor-driven valve that main pipe rail and main pipe rail are arranged, these two branch pipeline are connected with the spray equipment in liquid chlorine storage tank district and liquid chlorine package district by two shunt motor-driven valves, the delivery port of recovery pond passes through reclaim line, recovery pump and recovery motor-driven valve are connected with described main pipe rail.
2. according to claim 1 for the accident chlorine treatment system in liquid chlorine production, it is characterized in that: described reclaim line is connected with clorox reclaim line and blowoff line, clorox reclaim line and blowoff line are provided with motor-driven valve, between the access point and described recovery pump of described clorox reclaim line, described blowoff line one section of described reclaim line is provided with motor-driven valve.
3. according to claim 1 and 2 for the accident chlorine treatment system in liquid chlorine production, it is characterized in that: described production water lines is also directly connected with described main pipe rail by pipeline and motor-driven valve.
CN201420311691.2U 2014-06-12 2014-06-12 For the accident chlorine treatment system in liquid chlorine production Withdrawn - After Issue CN204093284U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201420311691.2U CN204093284U (en) 2014-06-12 2014-06-12 For the accident chlorine treatment system in liquid chlorine production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201420311691.2U CN204093284U (en) 2014-06-12 2014-06-12 For the accident chlorine treatment system in liquid chlorine production

Publications (1)

Publication Number Publication Date
CN204093284U true CN204093284U (en) 2015-01-14

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CN201420311691.2U Withdrawn - After Issue CN204093284U (en) 2014-06-12 2014-06-12 For the accident chlorine treatment system in liquid chlorine production

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104028092A (en) * 2014-06-12 2014-09-10 许红霞 Treatment method and system for chlorine leaking in accident of liquid chlorine production process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104028092A (en) * 2014-06-12 2014-09-10 许红霞 Treatment method and system for chlorine leaking in accident of liquid chlorine production process
CN104028092B (en) * 2014-06-12 2016-01-13 许红霞 For the accident chlorine treatment method and system in liquid chlorine production

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AV01 Patent right actively abandoned

Granted publication date: 20150114

Effective date of abandoning: 20160113

C25 Abandonment of patent right or utility model to avoid double patenting