CN204079539U - A kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater - Google Patents
A kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater Download PDFInfo
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- CN204079539U CN204079539U CN201420466220.9U CN201420466220U CN204079539U CN 204079539 U CN204079539 U CN 204079539U CN 201420466220 U CN201420466220 U CN 201420466220U CN 204079539 U CN204079539 U CN 204079539U
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- socket tube
- stainless steel
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- outer sleeve
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 63
- 238000007146 photocatalysis Methods 0.000 title claims abstract description 28
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 19
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 37
- 239000010935 stainless steel Substances 0.000 claims abstract description 37
- 239000010453 quartz Substances 0.000 claims abstract description 36
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910010413 TiO 2 Inorganic materials 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 23
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 239000011941 photocatalyst Substances 0.000 claims abstract description 14
- 230000000630 rising effect Effects 0.000 claims abstract description 11
- 239000004568 cement Substances 0.000 claims description 4
- 230000002070 germicidal effect Effects 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 241000894006 Bacteria Species 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 12
- 239000000126 substance Substances 0.000 abstract description 4
- 230000009849 deactivation Effects 0.000 abstract description 3
- 230000017525 heat dissipation Effects 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 21
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 12
- 239000004408 titanium dioxide Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000010865 sewage Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 239000003651 drinking water Substances 0.000 description 4
- 235000020188 drinking water Nutrition 0.000 description 4
- -1 hydroxyl radical free radical Chemical class 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000002957 persistent organic pollutant Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 229960000935 dehydrated alcohol Drugs 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 230000000249 desinfective effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 230000000721 bacterilogical effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 244000000010 microbial pathogen Species 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 244000045947 parasite Species 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
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- 239000000969 carrier Substances 0.000 description 1
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- 230000002906 microbiologic effect Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
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- 239000010841 municipal wastewater Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 229940126680 traditional chinese medicines Drugs 0.000 description 1
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Abstract
The utility model discloses a kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater.Photocatalysis disinfection reactor comprises sterilizer housing, disinfection reactions district.Described sterilizer housing is provided with water inlet pipe and rising pipe, and sterilizer housing comprises quartz socket tube and stainless steel outer sleeve cylinder; Described disinfection reactions district is by the annular space formed between quartz socket tube and stainless steel outer sleeve cylinder, and disinfection reactions district arranges vertical clapboard every 120mm, and vertical clapboard internal fixtion has activated carbon fiber (ACF) loaded with nano TiO
2photocatalyst material; Described quartz socket tube one end is provided with drawing and heat dissipation fan, is provided with ultraviolet lamp in quartz socket tube.The utility model on the one hand can bacterium effectively in deactivation reuse water and rainwater, on the other hand, reactor convenient operation and management, safe and reliable, certain water yield impact load can be adapted to, in addition, to Organic substance in water, there is certain removal effect, avoid the Biosafety risk that the bacterium in reuse water and rainwater brings.
Description
Technical field
The invention belongs to municipal sewage treatment sterilization field, specifically, relate to a kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater.
Background technology
Urban sewage reutilization and rainwater utilization be alleviate water pollution, the effective way of Urban Water Shortage Problem of Cities of improving the ecological environment, solve, having very large Exploitative potential, is the Strategic solving water scarcity problem.Reuse water and the rainwater utilization health risk possible to human body are one of focal issues of current public attention, the microbiological hazards problem especially in reclaimed wastewater reuse process.Substantially bacterium is divided into the pathogenic micro-organism that HUMAN HEALTH works the mischief, several classes such as bacterial parasite (parasite and protozoon) and virus.Pathogenic micro-organism can cause great harm to population health, therefore, is necessary very much to take effective disinfectant measure to ensure the biological safety of reuse water.Reuse water and rainwater are mainly used in the purposes such as miscellaneous water, water for scenic environment use, all propose Bacteriological Indexes requirement in the standard such as China " urban sewage reutilization urban reclaimed water water quality " (GB/T 18920-2002), " urban sewage reutilization water for scenic environment use water quality " (GB/T 18921-2002).Current mainly through chlorination, but the reuse water of dispersion and rainwater utilization facility are usually less, adopt liquid chlorine disinfection to need liquid chlorine storage tank, there is certain security risk, and due to some reuse waters and the intermittent operation of rainwater treatment facility, water yield fluctuation is large, requires higher to chlorination operational administrative.Therefore, research is a kind of efficient, and easy to operate, safe and reliable reuse water and rainwater disinfection apparatus have important practical for promotion Reclaimed Municipal Wastewater and rainwater utilization and be worth.
Be that the novel drinking water disinfection technology of core receives much concern with advanced oxidation, wherein UV/TiO
2photocatalysis disinfection technology is one of focus of water treatment field research.UV/TiO
2photochemical catalytic oxidation sterilization has the features such as nontoxic, broad spectrum sterilization, is a kind of promising alternative chlorine disinfectant technique.UV/TiO
2photocatalysis disinfection mechanism is that first the strong oxidizing property hydroxyl radical free radical (OH) that it produces destroys bacteria cell wall, then causes the Oxidative demage of cytolemma and born of the same parents' intracellular metabolite material and genetic material, finally causes necrocytosis and reach sterilization object.In water treatment applications, in order to avoid powder titanium dioxide be difficult to reclaim problem, mostly by titanium dichloride load on different carriers to realize immobilization.Porous sorptive material is adopted to be an important directions of current research as the carrier of titanium dioxide, as zeolite, gac, activated carbon fiber etc., can be concentrated to around titanium dioxide by target contaminant lower for body phase strength of solution, reaches the object improving light-catalyzed reaction efficiency.
Activated carbon fiber has abundant micropore and high specific surface area, its loading capacity far above other porous adsorbing materials, as zeolite, silica gel etc.; Loading capacity might as well than its like product gac.Because its form is generally felted or cloth-like, in practical application, be more convenient to the design ap-plication of reactor than granular carbon.
Domestic and international UV/TiO
2photocatalysis disinfection technical study is still in the starting stage, has domesticly carried out correlative study with regard to activated carbon fiber (ACF) carried titanium dioxide aspect at present.Such as, Chinese Patent Application No.: 200510035311.2, applying date: on November 30th, 2005, a kind of activated carbon fiber containing nano titanium dioxide particles of this disclosure of the invention and its production and use.This invention relates to a kind of activated carbon fiber containing nano titanium dioxide particles and its production and use.This activated carbon fiber is formed by nano titanium dioxide particles in activated carbon fiber material load, and wherein nano titanium dioxide particles accounts for 5 ﹣ 25% of total mass.This invention adopts sol-gel method, first by TiO
2presoma organic titanic compound through hydrolysis generate TiO
2colloidal sol, and be deposited in activated carbon fiber, drying sol becomes gel, then is converted into nano-TiO through thermal treatment
2particulate is compounded in the surface of activated carbon fiber, the obtained activated carbon fiber containing nano titanium dioxide particles.It had both maintained the porousness of activated carbon fiber, in turn enhanced titanium dioxide fine particles photocatalytic activity, can be used for the removal of low concentration gaseous volatile organic contaminant, was particularly useful for the Adsorption and decomposition of gaseous volatile organic pollutant in little space.It can reach 500mg/g to the loading capacity of gaseous volatile organic pollutant, can reach 36% to the photocatalysis Decomposition rate of light-concentration volatile organic pollutant.But this invention is just for gaseous state light-concentration volatile organic pollutant removal in air, the effect of process reuse water and rainwater is not remarkable.
With regard to current existing achievement in research, mainly concentrate on activated carbon fiber (ACF) carried titanium dioxide technique study and be applied to gas and Organic substance in water removal.In Water Disinfection, appear in the newspapers and be only limitted to other support materials load TiO
2pass through UV/TiO
2method carries out deactivation to the specific bacteria of artificial culture; Such as, Chinese Patent Application No.: 201010017224.5, the applying date: on 01 05th, 2010.A kind of ultraviolet/titanium dioxide (UV/TiO 2) reactor for disinfecting drinking water treated by activated carbon of this Invention Announce.The object of this invention is the Biosafety problem for bacterium in gac water outlet especially charcoal bacterium, proposes the ultraviolet titanium dioxide disinfecting reactor of charcoal bacterium in a kind of effluent water of drinking water activated carbon process.This reactor is at absorption UV sterilization advantage and TiO
2on the basis of catalysis characteristics, by the integrated decontamination reactor assembly of process optimization and integrated formation.UV/TiO
2(ultraviolet/titanium dioxide) disinfecting reactor can charcoal bacterium effectively in the water outlet of inactivation activities charcoal, and its process effluent quality reaches drinking water sanitary standard (GB5749-2006) requirement; And the water supply load change can born to a certain degree.But this invention just rests on theory stage, do not apply in actual applications so far.And the sheet glass support materials in this invention does not have absorption property, surface-area is large not, load TiO
2measure limited, the effect of process microbe species and more reuse water and rainwater is not very desirable.
Photocatalysis disinfection for the reuse water in practical application and rainwater is applied, and is not reported both at home and abroad.And adopt absorption property better, the UV/TiO of the ACF carried titanium dioxide that surface-area is larger
2photocatalysis disinfection reactor does not have report.So can UV/TiO be solved in the urgent need to one now
2photocatalysis disinfection reactor processes the scheme of reuse water and rainwater more ideally.
Summary of the invention
The problem that 1, will solve
Lack efficiently for prior art, the problem of easy to operate, safe and reliable reuse water and rainwater disinfection apparatus, the invention provides a kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater, its UV/TiO sterilized for reuse water and rainwater
2photocatalysis disinfection reactor is at sterilize in conjunction with UV advantage and TiO
2on the basis of photocatalysis characteristic, be that carrier prepares loading nano-titania material with ACF, by the integrated decontamination reactor assembly of process optimization and integrated formation, it not only can bacterium effectively in deactivation reuse water and rainwater, and the water yield impact load effectively born to a certain degree, convenient operation and management, safe and reliable.
2, technical scheme
For solving the problem, technical scheme provided by the invention is as follows.
A kind of UV/TiO sterilized for reuse water and rainwater
2photocatalysis disinfection reactor, comprises sterilizer housing, disinfection reactions district, and described sterilizer housing is provided with water inlet pipe and rising pipe; Described sterilizer housing comprises quartz socket tube and stainless steel outer sleeve cylinder; Described quartz socket tube is arranged in stainless steel outer sleeve cylinder; Described disinfection reactions district is by the annular space formed between quartz socket tube and stainless steel outer sleeve cylinder; The spacing of described quartz socket tube and stainless steel outer sleeve cylinder is 60-120mm; Described disinfection reactions district arranges vertical clapboard every 120mm, and vertical clapboard internal fixtion has activated carbon fiber (ACF) loaded with nano TiO
2photocatalyst material; Described quartz socket tube two ends are provided with opening, and one end is provided with suction fan; Ultraviolet lamp is provided with in described quartz socket tube.
Preferably, described ultraviolet lamp adopts predominant wavelength 253.7nm germicidal lamp, and power is between 18-40w, and in sterilizating area, average UV light intensity is set to 0.25-0.53mw/cm
2; Sterilizer shell length is greater than ultraviolet lamp length, and length is 1200mm, and 50mm interface is stayed in both sides.
Preferably, described stainless steel outer sleeve cylinder is stainless steel, diameter 200 ~ 300mm.
Preferably, described stainless steel outer sleeve cylinder is bonding at rising pipe side glass cement with between quartz socket tube, and is fixed by outside collar and seal; Flange joint is passed through after water inlet pipe side adds sealing-ring.
3, beneficial effect
Compared to prior art, beneficial effect of the present invention is:
(1) reactor of the present invention comprises sterilizer housing, disinfection reactions district, and sterilizer housing is provided with water inlet pipe and rising pipe; Sterilizer housing comprises quartz socket tube and stainless steel outer sleeve cylinder; Quartz socket tube is arranged in stainless steel outer sleeve cylinder; Disinfection reactions district is by the annular space formed between quartz socket tube and stainless steel outer sleeve cylinder; The spacing of quartz socket tube and stainless steel outer sleeve cylinder is 60-120mm; Disinfection reactions district arranges vertical clapboard at interval of 120mm, and vertical clapboard internal fixtion has the nano-TiO of ACF load
2photocatalyst material, forms UV/TiO under UV effect
2photocatalysis disinfection, activated carbon fiber is to Adsorption of Organic effect and UV/TiO simultaneously
2to the coupling of organic matter degradation effect, Organic substance in water can be removed; Quartz socket tube two ends are provided with opening, and one end is provided with suction fan, are provided with ultraviolet lamp in quartz socket tube; Because the migration circle of the OH that photocatalyst surface produces is limited, the photocatalysis of disinfection reactions district mainly concentrates on UV/TiO
2on the surface, generation and the main sterilization process of OH concentrate on TiO to photocatalyst material
2in the distance range of 0 ~ 50mm of material surface, porous activated carbon fiber has very large superiority as carrier, and current flow through in the process of activated carbon fiber space and more easily contact with the OH that photochemical catalysis produces and produce desirable photocatalysis disinfection effect; UV/TiO in photocatalysis disinfection reactor
2photocatalyst material is arranged perpendicular to water (flow) direction, and current are evenly passed through by the space of activated carbon fiber, adds bacterium and TiO in water outlet
2the collision of catalytic material and and TiO
2the contact probability of the hydroxyl radical free radical (OH) that surface is formed, thus strengthen the sterilising effect of OH; In addition, current adopt the mode of plug-flow by sterilizating area, avoid back-mixing and cause disinfection efficiency to decline;
(2) the present invention well meets distributing reuse water and rainwater utilization project sterilization demand, in reuse water and rainwater sterilization, the present invention has some superiority than traditional chlorine disinfectant, the cylindrical structural of reactor and contact disinfection way allow it to be arranged on easily in outlet conduit, and can flexibly serial or parallel connection reactor to tackle change and the water quality requirement of the different treatment water yield, embody comparatively strong adaptability and practicality, to Organic substance in water, there is removal effect obtaining desired sanitisation effect simultaneously, to a certain degree improve reuse water and Rainwater Quality;
(3) ultraviolet lamp of the present invention adopts predominant wavelength 253.7nm germicidal lamp, and power is between 18-40w, and in sterilizating area, average UV light intensity is set to 0.25-0.53mw/cm
2; Sterilizer shell length is greater than ultraviolet lamp length, and length is about 1200mm, and 50mm interface is stayed in both sides; In sterilizating area, on average UV light intensity is too little can reduce disinfection effect, and light intensity too conference causes energy dissipation and contributes little to improving disinfection efficiency further;
(4) stainless steel outer sleeve cylinder of the present invention is stainless steel, diameter 200 ~ 300mm; When ensureing that the mechanical mechanics property of material requires, selecting stainless steel, can effectively reduce costs, and UV-light can be avoided to leak cause actual bodily harm to the staff on side;
(5) stainless steel outer sleeve cylinder of the present invention is bonding by glass cement by rising pipe side with between quartz socket tube, and is fixed by outside collar and seal, and Flange joint is passed through after adding sealing-ring in water inlet pipe side; The cylindrical structural of reactor and contact disinfection way allow it to be arranged on easily in outlet conduit; And can flexibly serial or parallel connection reactor to tackle change and the water quality requirement of the different treatment water yield, embody comparatively strong adaptability and practicality, the design of the concentric locking collar cylindrical shell of stainless steel outer sleeve cylinder and quartz socket tube not only farthest improves the space availability ratio of photo catalysis reactor, and convenient being connected with front and back segment process; In addition, cylindrical-concentric sleeve body structure made pool streamflow regime steady, and avoid producing slough and air-teturning mixed phenomenon thus affect disinfection efficiency, hydraulics is superior.
Accompanying drawing explanation
Fig. 1 is activated carbon fiber-loaded UV/TiO of the present invention
2photo catalysis reactor structure iron;
Fig. 2 is UV/TiO of the present invention
2catalytic material hardens composition;
Fig. 3 is UV/TiO of the present invention
2the inside and outside sleeve structure iron of reactor.
In figure: 1, water inlet pipe; 2, water distributing area; 3, activated carbon fiber (ACF) loaded with nano TiO
2photocatalyst material; 4, ultraviolet lamp; 5, rising pipe; 6, quartz socket tube; 7, suction fan; 8, stainless steel outer sleeve cylinder.
Embodiment
Describe the present invention below in conjunction with accompanying drawing.
Embodiment 1
As shown in Figure 1, Figure 2 and Figure 3, a kind of UV/TiO sterilized for reuse water and rainwater
2photocatalysis disinfection reactor, comprises sterilizer housing, disinfection reactions district, and sterilizer housing is provided with water inlet pipe 1 and rising pipe 5; Sterilizer housing comprises quartz socket tube 6 and stainless steel outer sleeve cylinder 8; Quartz socket tube 6 is arranged in stainless steel outer sleeve cylinder 8; Disinfection reactions district is by the annular space formed between quartz socket tube 6 and stainless steel outer sleeve cylinder 8; The spacing of quartz socket tube 6 and stainless steel outer sleeve cylinder 8 is 90mm; Two row vertical clapboards are arranged every 120mm in disinfection reactions interval, and two row vertical clapboard internal fixtion have activated carbon fiber (ACF) loaded with nano TiO
2photocatalyst material 3; Quartz socket tube 6 two ends are provided with opening, and one end is provided with suction fan 7; Ultraviolet lamp 4 is provided with in quartz socket tube 6.Ultraviolet lamp 4 adopts predominant wavelength 253.7nm germicidal lamp, and power is 30w, and in sterilizating area, average UV light intensity is 0.39mw/cm
2; Sterilizer shell length is 1200mm, and 50mm interface is stayed in both sides.Stainless steel outer sleeve cylinder 8 is stainless steel, diameter 250mm.Bonding by rising pipe 5 side glass cement between stainless steel outer sleeve cylinder 8 with quartz socket tube 6, and fixed by outside collar and seal, water inlet pipe 1 side adds rubber ring rear flange and connects.
The loaded with nano TiO used in aforesaid device
2the preparation method of photocatalyst material ACF, the steps include:
A prepares viscose-based active carbon fiber (Nantong Sen You Carbon fibe company limited, its specific surface area 1500m
2g
-1, pore volume 0.752mLg
-1, tetrabutyl titanate), tetrabutyl titanate (C
l6h
36o
4ti AR, Shanghai Ling Feng chemical reagent factory), trolamine (C
6h
l5nO
3aR, traditional Chinese medicines group chemical reagent), dehydrated alcohol (C
2h
5oH AR, Nanjing chemical reagent factory), H
2o, the mol ratio of raw material is C
l6h
36o
4ti:C
6h
l5nO
3: C
2h
5oH:H
2o=1:0.86:26.6:1.5, mix and blend is made into colloidal sol; The concrete grammar that wherein prepared by colloidal sol is: get 678mL dehydrated alcohol and be placed in 1000mL beaker, adds 170mL tetrabutyl titanate, then adds 30mL hydrolysis inhibitor trolamine, make presoma under slowly stirring;
Get 100mL dehydrated alcohol, add 10mL water, stir, then add the concentrated hydrochloric acid of 6mL.This solution is moved into drop-burette slowly join under vigorous stirring in the middle of above-mentioned presoma; Add and continue to stir 30min, obtain faint yellow colloidal sol, for subsequent use after colloidal sol ageing 24h, obtain TiO
2colloidal sol;
The annular activated carbon fiber of sizing is carried out water, EtOH Sonicate cleaning by B, removing ash and organism; Felt is immersed in colloidal sol and soaks 10min; After slowly being lifted out from colloidal sol by annular active carbon fiber felt, then put it into the dry 2h of thermostatic drying chamber that temperature is 105 DEG C;
C by the annular active carbon fiber felt repeating step B that obtains in step B once;
The annular active carbon fiber felt obtained in step C is placed in retort furnace by D, after being warming up to 550 DEG C of maintenance 2h under nitrogen protection, takes out after naturally cooling; Obtain UV/TiO
2photocatalyst material; Wherein temperature rise rate is 50 DEG C/min, and nitrogen flow is 25mL/min.
In the present embodiment, undressed reuse water and rainwater evenly enter disinfection reactions district from water inlet pipe 1, in plug-flow mode sequentially through activated carbon fiber (ACF) the loaded with nano TiO in water distributing area 2
2photocatalyst material 3.With loaded with nano TiO in disinfection reactions district under the ultraviolet lamp 4 of current in ultraviolet region irradiates
2sterilize under the catalytic association effect of the ACF of photocatalyst material 3, the reuse water after sterilization and rainwater are discharged through rising pipe 5, and suction fan 7 operates the heat reducing ultra violet lamp generation all the time.
Use loaded with nano TiO
2the ACF of photocatalyst material 3 carries out five batches of tests altogether to reuse water and rainwater, and experimental result is:
Note: "--" expression does not detect
UV/TiO
2free total plate count in the water outlet of photocatalysis disinfection reactor actual motion proposes Bacteriological Indexes requirement far below in existing " urban sewage reutilization urban reclaimed water water quality " (GB/T 18920-2002), " urban sewage reutilization water for scenic environment use water quality " (GB/T 18921-2002), bacterium disinfection efficiency reaches more than 99%, intestinal bacteria disinfection efficiency nearly 100%, guarantees the biological safety of water outlet.
Embodiment 2
With embodiment 1, difference is the spacing of quartz socket tube 6 and stainless steel outer sleeve cylinder 8 is 65mm; Ultraviolet lamp 4 power is 18w, and in sterilizating area, average UV light intensity is 0.35mw/cm
2; Stainless steel outer sleeve cylinder 8 diameter 200mm.
Embodiment 3
With embodiment 1, difference is the spacing of quartz socket tube 6 and stainless steel outer sleeve cylinder 8 is 115mm; Ultraviolet lamp 4 power is 40w, and in sterilizating area, average UV light intensity is set to 0.53mw/cm
2; Stainless steel outer sleeve cylinder 8 diameter 300mm.
Claims (4)
1., for the photocatalysis disinfection reactor that reuse water and rainwater are sterilized, comprise sterilizer housing, disinfection reactions district, is characterized in that: described sterilizer housing is provided with water inlet pipe (1) and rising pipe (5); Described sterilizer housing comprises quartz socket tube (6) and stainless steel outer sleeve cylinder (8); Described quartz socket tube (6) is arranged in stainless steel outer sleeve cylinder (8); Described disinfection reactions district is by the annular space formed between quartz socket tube (6) and stainless steel outer sleeve cylinder (8); Described quartz socket tube (6) and the spacing of stainless steel outer sleeve cylinder (8) are 60-120mm; Described disinfection reactions district arranges vertical clapboard every 120mm, and vertical clapboard internal fixtion has activated carbon fiber-loaded nano-TiO
2photocatalyst material (3); Described quartz socket tube (6) two ends are provided with opening, and one end is provided with suction fan (7); Ultraviolet lamp (4) is provided with in described quartz socket tube (6).
2. a kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater according to claim 1, it is characterized in that: described ultraviolet lamp (4) adopts predominant wavelength 253.7nm germicidal lamp, power is between 18-40w, and in sterilizating area, average UV light intensity is 0.25-0.53mw/cm
2; Sterilizer shell length is greater than ultraviolet lamp (4) length, and length is 1200mm, and 50mm interface is stayed in both sides.
3. a kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater according to claim 1, is characterized in that: described stainless steel outer sleeve cylinder (8) is stainless steel, diameter 200 ~ 300mm.
4. a kind of photocatalysis disinfection reactor of sterilizing for reuse water and rainwater according to claim 1, it is characterized in that: described stainless steel outer sleeve cylinder (8) is bonding at rising pipe (5) side glass cement with between quartz socket tube (6), and is fixed by outside collar and seal; Flange joint is passed through after water inlet pipe (1) side adds sealing-ring.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104150561A (en) * | 2014-08-18 | 2014-11-19 | 南京工业大学 | Photocatalytic disinfection reactor used for disinfecting reclaimed water and rainwater, photocatalysis material and preparation method thereof, application and application method thereof |
| CN108147494A (en) * | 2018-02-09 | 2018-06-12 | 北方工业大学 | Adsorption type floating island |
| WO2019075615A1 (en) * | 2017-10-16 | 2019-04-25 | 深圳前海小有技术有限公司 | Fluid sterilization device |
| CN111320233A (en) * | 2020-03-18 | 2020-06-23 | 东南大学 | Coupling light and particle response water treatment equipment, photoreactor and treatment method |
| CN113087258A (en) * | 2021-03-16 | 2021-07-09 | 南京中微纳米功能材料研究院有限公司 | Device for treating organic nitrogen sewage through automatic catalytic oxidation and working method |
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2014
- 2014-08-18 CN CN201420466220.9U patent/CN204079539U/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104150561A (en) * | 2014-08-18 | 2014-11-19 | 南京工业大学 | Photocatalytic disinfection reactor used for disinfecting reclaimed water and rainwater, photocatalysis material and preparation method thereof, application and application method thereof |
| WO2019075615A1 (en) * | 2017-10-16 | 2019-04-25 | 深圳前海小有技术有限公司 | Fluid sterilization device |
| CN108147494A (en) * | 2018-02-09 | 2018-06-12 | 北方工业大学 | Adsorption type floating island |
| CN111320233A (en) * | 2020-03-18 | 2020-06-23 | 东南大学 | Coupling light and particle response water treatment equipment, photoreactor and treatment method |
| CN113087258A (en) * | 2021-03-16 | 2021-07-09 | 南京中微纳米功能材料研究院有限公司 | Device for treating organic nitrogen sewage through automatic catalytic oxidation and working method |
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