CN203883076U - Hydrogen storage device made of silver-cadmium oxide materials - Google Patents
Hydrogen storage device made of silver-cadmium oxide materials Download PDFInfo
- Publication number
- CN203883076U CN203883076U CN201420161243.9U CN201420161243U CN203883076U CN 203883076 U CN203883076 U CN 203883076U CN 201420161243 U CN201420161243 U CN 201420161243U CN 203883076 U CN203883076 U CN 203883076U
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- storage
- hydrogen storage
- bottle
- storing device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000001257 hydrogen Substances 0.000 title claims abstract description 94
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 94
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 239000000463 material Substances 0.000 title claims abstract description 11
- ASMQPJTXPYCZBL-UHFFFAOYSA-N [O-2].[Cd+2].[Ag+] Chemical compound [O-2].[Cd+2].[Ag+] ASMQPJTXPYCZBL-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 24
- 239000011148 porous material Substances 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002041 carbon nanotube Substances 0.000 claims description 6
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002121 nanofiber Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 abstract description 13
- 238000010248 power generation Methods 0.000 abstract 2
- 239000007789 gas Substances 0.000 description 9
- 238000011084 recovery Methods 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 206010020852 Hypertonia Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003949 liquefied natural gas Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
- Y02P90/45—Hydrogen technologies in production processes
Landscapes
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
The utility model relates to a solid hydrogen power generation device which comprises a hydrogen storage device, a hydrogen supply device and a power generation battery device, wherein the hydrogen storage device comprises a hydrogen storage bottle, hydrogen storage particles are contained in the hydrogen storage bottle, the average diameter of the hydrogen storage particles is 20 micrometers to 200 micrometers, and the hydrogen storage particles are provided with inner cavities surrounded by porous walls; an air hole is formed in one end of the hydrogen storage bottle, and a filter is arranged in the air hole; the hydrogen storage bottle is made of silver-cadmium oxide materials.
Description
Technical field
The utility model relates to a kind of novel energy, and especially a kind of solid state hydrogen battery, is specifically related to hydrogen-storing device.
Background technology
The power of automobile generally uses fuel oil at present, and because petroleum resources are limited, people have to seek new alternative energy source, for example electric energy, solar energy etc.As the substitute of vehicle fuel, comprise known liquefied petroleum gas and liquefied natural gas.Use the pernicious gas of motor vehicle emission of these substitutes relatively less, but still fail fundamentally to solve the problem of the energy and pollution.
Hydrogen more and more comes into one's own as the application of fuel, and the hydrogen of gaseous state is very easy to blast.In hydrogen powered vehicle field, hydrogen can be stored in the on-board high-voltage container of the vehicles.Such storage system efficiency in volume level is not high, and for example, due to storage hypertonia, 5,000-10, the about 350-700 Bar of 000psi() air pressure, thereby there is potential safety hazard.
Utility model content
In order to realize above object, the utility model proposes a kind of solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT), using solid state hydrogen as the energy, solid state hydrogen is converted into electric energy, with the acting of electric energy drive motors.This solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT), by supporting relevant servicing unit, as hydrogen-storing device, hydrogen feeding mechanism, generating battery device etc., realizes the object of saving fuel oil and reducing toxic emission.
Described hydrogen-storing device comprises storage hydrogen bottle, and storage hydrogen bottle contains storage hydrogen particle, and this storage hydrogen particle can, by the hydrogen after activation, store with solid-state form, and disengages the hydrogen of storage in the time of heat absorption.Described storage hydrogen particle have by porous wall around internal cavities.One end of storage hydrogen bottle is provided with pore, is provided with filter in pore.Filter is made by metal powder sintered moulding or by the micro-close net of stainless steel, can allow hydrogen circulation and filters and stop other gas and impurity to enter in storage hydrogen bottle.In the time hydrogen being injected to storage hydrogen bottle, hydrogen enters storage hydrogen bottle inside through filter, now store up the storage hydrogen particle that hydrogen bottle contains and absorb rapidly hydrogen, after overactivation, a large amount of hydrogen molecules are changed into solid state hydrogen and are stored in hydrogen bottle inside, hydrogen is no longer stored with the form of high-pressure gaseous, thereby reach safety in transportation and storage object.
The solid state hydrogen that described hydrogen feeding mechanism can store storage hydrogen particle by the wireway at storage hydrogen bottle pore place divides submode to disengage with Gaseous Hydrogen, sends into generating battery device.
Described generating battery device and general battery structure are similar, are adopted material difference.This device overlaps to form generating battery device with the Porous hydrogen fuel utmost point (anode) and air pole (negative electrode) and polymer dielectric film.At anode, hydrogen is decomposed into hydrogen ion (proton) and electronics, and polymer dielectric film only allows proton to pass and the negative electrode that arrives, and electronics moves on to negative electrode along external circuit, carries out chemical reaction become water (H2O) at negative electrode and oxygen.In electronics moving process, obtain electric energy.
The hydrogen storage technology that the utility model provides and Blast Furnace Top Gas Recovery Turbine Unit (TRT) have solved the existing series of problems of gaseous state storing mode effectively, have replenished the blank of this technical field, have novelty.This hydrogen storage technology and Blast Furnace Top Gas Recovery Turbine Unit (TRT) can be used for the various vehicles, and the features such as, transitory efficient safe and reliable with it, economic convenient, environmental protection and energy saving, have vast potential for future development.Use solid state hydrogen can solve as the energy environmental pollution that oil discharging waste gas causes, and use solid state hydrogen can reduce costs as the energy.
The said storage hydrogen of above-mentioned hydrogen-storing device bottle contains storage hydrogen particle, and the average diameter of this storage hydrogen particle is 20 microns to 200 microns, have by porous wall around internal cavities.One end at storage hydrogen bottle is provided with pore, is provided with filter in pore.Described storage hydrogen bottle is made up of silver cadmium oxide material.
Further, the average diameter of described storage hydrogen particle is 50 microns to 80 microns.
Further, described storage hydrogen particle is CNT (carbon nano-tube), nano-glass ball, nano ceramics.The mixture of nano zeolite, nanofiber or these materials.
Further, described storage hydrogen particle has the wall thickness of 1 to 30 micron, preferably the wall thickness of 1 to 10 micron.
Further, the wall of described storage hydrogen particle is porous wall, and the aperture in described porous wall is 50 dust-1000 dusts, and preferably the aperture in porous wall is 200 dust-500 dusts.
Further, described filter is made up of metal powder sintered moulding, or is made up of the micro-close net of stainless steel, and contains Metal Palladium.
Further, the wall thickness of described storage hydrogen bottle is 2-6 millimeter.
Brief description of the drawings
Fig. 1 is the utility model solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT) schematic diagram.
1 storage hydrogen bottle in figure, 2 oxygen-storage devices, 3 generating battery devices, 12 storage hydrogen bottle pores, 13 filters, 22 oxygen-storage device pores, the electric energy delivery outlet of 31 generating battery devices.
Embodiment
Below in conjunction with accompanying drawing, the utility model is further described.
Figure 1 shows that the utility model solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT) schematic diagram.This device comprises storage hydrogen bottle 1, oxygen-storage device 2 and generating battery device 3.Storage hydrogen bottle 1 is connected with generating battery device 3 with oxygen-storage device pore 22 by storage hydrogen bottle pore 12 respectively with oxygen-storage device 2, the storage hydrogen bottle pore 12 interior filters 13 that arrange, and the electric energy delivery outlet 31 of generating battery device is connected with motor.
Described storage hydrogen bottle 1 contains storage hydrogen particle, and storage hydrogen bottle 1 pore 12 is connected with generating battery device 3.
Described oxygen-storage device 2 internal reservoir oxygen, oxygen-storage device 2 pores 22 are connected with generating battery device 3.
Described generating battery device 3 is built up generating battery device with the Porous hydrogen fuel utmost point (anode) and air pole (negative electrode) and polymer dielectric film, and electric energy is connected with motor by electric energy delivery outlet 31.
The average diameter of described storage hydrogen particle is 20 microns to 200 microns, preferably 50 microns to 80 microns.
Described storage hydrogen particle can be CNT (carbon nano-tube), nano-glass ball, nano ceramics.The mixture of nano zeolite, nanofiber or these materials.This storage hydrogen particle has 1 to 30 micron, preferably the wall thickness of 1 to 10 micron.
The wall of described storage hydrogen particle is porous wall, and the aperture in described porous wall is 50 dust-1000 dusts, preferably 200 dust-500 dusts.
Described filter 13 is made up of metal powder sintered moulding or is made up of the micro-close net of stainless steel, and described filter contains Metal Palladium.
Described storage hydrogen bottle is made up of silver cadmium oxide material, wall thickness 2-6 millimeter.
The utility model solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT) can reduce costs hydrogen as the energy, solves the environmental pollution that oil discharging waste gas causes.Described hydrogen-storing device can reach safety in transportation and storage object, for using hydrogen energy source that technical guarantee is provided.
Claims (8)
1. the hydrogen-storing device that prepared by silver cadmium oxide material, comprises storage hydrogen bottle, and storage hydrogen bottle contains storage hydrogen particle, and the average diameter of this storage hydrogen particle is 20 microns to 200 microns, have by porous wall around internal cavities; One end at storage hydrogen bottle is provided with pore, is provided with filter in pore; Described storage hydrogen bottle is made up of silver cadmium oxide material.
2. hydrogen-storing device according to claim 1, is characterized in that, the average diameter of described storage hydrogen particle is 50 microns to 80 microns.
3. hydrogen-storing device according to claim 1 and 2, is characterized in that, described storage hydrogen particle is the mixture of CNT (carbon nano-tube), nano-glass ball, nano ceramics, nano zeolite, nanofiber or these materials.
4. hydrogen-storing device according to claim 1 and 2, is characterized in that, described storage hydrogen particle has the wall thickness of 1 to 30 micron.
5. hydrogen-storing device according to claim 1 and 2, is characterized in that, the aperture in described porous wall is 50 dust-1000 dusts.
6. hydrogen-storing device according to claim 1 and 2, is characterized in that, described filter is made up of metal powder sintered moulding.
7. hydrogen-storing device according to claim 1 and 2, is characterized in that, described filter is made up of the micro-close net of stainless steel.
8. hydrogen-storing device according to claim 1 and 2, is characterized in that, the thickness of described storage hydrogen bottle is 2-6 millimeter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420161243.9U CN203883076U (en) | 2014-04-03 | 2014-04-03 | Hydrogen storage device made of silver-cadmium oxide materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420161243.9U CN203883076U (en) | 2014-04-03 | 2014-04-03 | Hydrogen storage device made of silver-cadmium oxide materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN203883076U true CN203883076U (en) | 2014-10-15 |
Family
ID=51683548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420161243.9U Expired - Lifetime CN203883076U (en) | 2014-04-03 | 2014-04-03 | Hydrogen storage device made of silver-cadmium oxide materials |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN203883076U (en) |
-
2014
- 2014-04-03 CN CN201420161243.9U patent/CN203883076U/en not_active Expired - Lifetime
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160427 Address after: 313000, 1207-26, 12, 3, 1366 Hongfeng Road, Zhejiang, Huzhou Patentee after: ZHEJIANG XUNDING SEMICONDUCTOR MATERIAL TECHNOLOGY Co.,Ltd. Address before: 200031 Shanghai city Xuhui District old humin Road No. 1130 No. 8 floor Patentee before: Shanghai Huapeng Explosion-proof Technology Co.,Ltd. |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20141015 |