CN203853019U - Twin-tower series connection device for removing SO2 and NOx in smoke gas by biological method - Google Patents
Twin-tower series connection device for removing SO2 and NOx in smoke gas by biological method Download PDFInfo
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- CN203853019U CN203853019U CN201420209768.5U CN201420209768U CN203853019U CN 203853019 U CN203853019 U CN 203853019U CN 201420209768 U CN201420209768 U CN 201420209768U CN 203853019 U CN203853019 U CN 203853019U
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- 239000000779 smoke Substances 0.000 title abstract description 6
- 238000010170 biological method Methods 0.000 title abstract 2
- 238000005507 spraying Methods 0.000 claims abstract description 26
- 238000012544 monitoring process Methods 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000012530 fluid Substances 0.000 claims description 94
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 50
- 239000003546 flue gas Substances 0.000 claims description 50
- 238000005276 aerator Methods 0.000 claims description 24
- 238000012856 packing Methods 0.000 claims description 20
- 239000000112 cooling gas Substances 0.000 claims description 16
- 239000003814 drug Substances 0.000 claims description 13
- 238000011953 bioanalysis Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 abstract description 35
- 239000007789 gas Substances 0.000 abstract description 24
- 238000005273 aeration Methods 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 10
- 238000003756 stirring Methods 0.000 abstract description 8
- 239000002912 waste gas Substances 0.000 abstract description 2
- 238000001816 cooling Methods 0.000 abstract 2
- 239000007921 spray Substances 0.000 description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 19
- 239000001301 oxygen Substances 0.000 description 19
- 229910052760 oxygen Inorganic materials 0.000 description 19
- 239000002131 composite material Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 10
- 230000000813 microbial effect Effects 0.000 description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 238000006477 desulfuration reaction Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- 230000001580 bacterial effect Effects 0.000 description 6
- 239000002207 metabolite Substances 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000012445 acidic reagent Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 3
- 238000009395 breeding Methods 0.000 description 3
- 230000001488 breeding effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 230000004060 metabolic process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 2
- 241000726118 Acidovorax facilis Species 0.000 description 2
- 241000131971 Bradyrhizobiaceae Species 0.000 description 2
- 241000223233 Cutaneotrichosporon cutaneum Species 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241001052560 Thallis Species 0.000 description 2
- 241000605118 Thiobacillus Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000003009 desulfurizing effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 206010021143 Hypoxia Diseases 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 239000010796 biological waste Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000003519 ventilatory effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Treating Waste Gases (AREA)
Abstract
The utility model discloses a twin-tower series connection device for removing SO2 and NOx in a smoke gas by a biological method, and belongs to the waste gas treatment field. Smoke gas in a flue enters a cooling dust-collecting tower, a filler tower I and a filler tower II through an induced draft fan in sequence; a demister device is respectively arranged on each of tops of the cooling dust-collecting tower, the filler tower I and the filler tower II; a spraying layer is respectively arranged below each demister device; a circulating liquid storage device is arranged on each of the filler tower I and the filler tower II; an aeration device and a stirring device are arranged in the circulating liquid storage device. The circulating liquid storage device is further equipped with a pH value online monitoring instrument and an automatic dosing device connected with the pH value online monitoring instrument. The device disclosed by the utility model can avoid change of liquid level of the circulating liquid and further can avoid fluctuation of pH vale of the circulating liquid at the same time, so that better removing effect for SO2 and NOx in the smoke gas is further improved.
Description
Technical field
The utility model belongs to exhaust-gas treatment field, is specifically related to a kind of bioanalysis and removes SO in flue gas
2and NO
xdouble-column in series device.
Background technology
At present, the SO of industrial activity discharge
2and NO
xmore and more significant to the harm of environment as environomental pollution source, and this problem is the major subjects that countries in the world research is administered always.Along with the development of industrial technology, people wish the technology and equipment that research makes new advances, can be simultaneously by SO in waste gas
2and NO
xremove.Seek simultaneously desulfurization removing nitric technology and the equipment of Novel flue gas of technical advanced person, reasonable in economy, be one of the new technology of field of Environment Protection and equipment forward position study hotspot always.At present, both at home and abroad generally there is technological process complexity in the simultanously desulfurizing and denitrification technology of test application, equipment investment is large or operating cost is high, to flue gas in low concentration SO
2and NO
xlow, the byproduct of combined removal rate dispose technology or economic problems such as utilizing difficulty, great majority be difficult on a large scale in realization applies widely.Therefore, be necessary in conjunction with Chinese specific national conditions, research and develop novel simultanously desulfurizing and denitrification new technology and equipment.
Biological waste gas purification technology is as an exhaust-gas treatment new technology, with its economy, effectively, pollutant processes thoroughly, is suitable for processing the features such as low-concentration industrial waste gas, it progressively develops into the hot research field, a forward position of industrial waste gas purifying in the world in recent years.
" simultaneously removing double-column in series formula catalysis-biomembrane filled tower combination unit of sulfur dioxide in flue gas and nitrogen oxide " (utility model patent that early-stage Study of the present invention forms, application number 200920253867.2), be all better than existing routine techniques at aspects such as purifying property, cost of investment, operating cost, operability, byproducts.But because this technical method is the biofilm packing Tower System of front end catalysis-biomembrane filled tower series connection rear end of employing, the pretreatment of former flue gas process is successively through two fillers, but owing to being saturated wet flue gas in processing procedure, can carry a large amount of circulation fluids from front end and enter into rear end, not only affect the liquid level of front end circulation fluid, more can cause catastrophic fluctuation to the pH of rear end circulation fluid, affect microbial growth, and then affect SO
2and NO
xremoval effect, once pH value change and just need to add buffer composition and adjust the pH value of circulation fluid, must be in time and add buffer composition, otherwise microbial growth will be suppressed even death.
Utility model content
The purpose of this utility model is to provide a kind of bioanalysis to remove SO in flue gas for above-mentioned technical problem
2and NO
xdouble-column in series device, this device in use, can keep the liquid level of circulation fluid in circulation fluid storage device, can not cause fluctuation to the liquid level of rear end circulation fluid and pH value, more can not affect microbial growth, thus to the SO in flue gas
2and NO
xthere is good removal effect.
The purpose of this utility model can be achieved through the following technical solutions:
A kind of bioanalysis removes SO in flue gas
2and NO
xdouble-column in series device, flue gas in flue enters cooling gas wash tower, biomembrane filled tower I and biomembrane filled tower II successively by air-introduced machine, the gas outlet at cooling gas wash tower top is connected with the air inlet of biomembrane filled tower I bottom, and the gas outlet at biomembrane filled tower I top is connected with the air inlet of biomembrane filled tower II bottom;
Cooling gas wash tower top is provided with demister device and spraying layer from top to bottom successively, and biomembrane filled tower I and biomembrane filled tower II are all provided with demister device, spraying layer and packing layer from top to bottom successively; Described biomembrane filled tower I and biomembrane filled tower II are equipped with circulation fluid storage device matching used with it, in circulation fluid storage device, be provided with aerator and agitating device, the matching used circulation fluid storage device of biomembrane filled tower I I is connected with the spraying layer I on the outlet of biomembrane filled tower I bottom circulation fluid, top respectively; The matching used circulation fluid storage device of biomembrane filled tower II II is connected with the spraying layer II on the outlet of biomembrane filled tower II bottom circulation fluid, top respectively.
Described circulation fluid storage device I and the automatic medicine adding apparatus that is also provided with pH value on-line monitoring instrument in circulation fluid storage device II and is connected with pH value on-line monitoring instrument.
The packing layer I filler used of biomembrane filled tower I is that diameter is 5～8 centimetres, and surface attachment has biomembranous haydite, this biomembrane by screen and cultivate domestication obtain under pH sour environment condition, have remove flue gas simultaneously in SO
2make with desulfurization bacterium and the denitrifier composite flora biofilm of NOx performance, this composite flora is Thiobacillus thioxidans, moves Sphingol single-cell and Dai Erfute acidovorax facilis less, and the volume fraction of three kinds of bacterial classifications is followed successively by 45%, 30% and 25%.
The packing layer II filler used of packed tower II is that diameter is 5～8 centimetres, surface attachment has biomembranous haydite, this biomembrane by screen and cultivate domestication obtain under pH neutral environment condition, have remove flue gas in NOx performance denitrifier composite flora biofilm make, this composite flora is Nitrobacteraceae bacterium and the trichosporon cutaneum of growing thickly, and the volume fraction of two kinds of bacterial classifications is followed successively by 60% and 40%.
One is utilized said apparatus to carry out bioanalysis and is removed SO in flue gas
2and NO
xmethod, the method comprises the following steps:
1) flue gas in flue enters bottom up spraying layer and the demister device through lowering the temperature in gas wash tower successively of cooling gas wash tower by air-introduced machine, and flue gas is discharged from the top of cooling gas wash tower afterwards;
2) flue gas of discharging from the top of cooling gas wash tower, through the bottom of biomembrane filled tower I, goes upward to packing layer I, spraying layer I and demister device I successively, and flue gas is discharged from the top of biomembrane filled tower I afterwards;
3) flue gas of discharging from the top of biomembrane filled tower I, through the bottom of biomembrane filled tower II, goes upward to packing layer II, spraying layer II and demister device II successively, and flue gas is discharged from the top of packed tower II afterwards.
Step 2) in the spray liquid of spraying layer I be, with pump, the circulation fluid in circulation fluid storage device I is delivered to spraying layer I, and get back to circulation fluid storage device I from the outlet of biomembrane filled tower I (4) bottom circulation fluid, described spray liquid is in every premium on currency, to contain 0.5g/L MgSO
4, 0.5g/L NaCl and 0.3g/L KH
2pO
4solution, the pH value of this spray liquid is 0.8～1.5.When the pH of this spray liquid is higher than 1.5 time, in this spray liquid, add acid reagent, described acid reagent includes but not limited to sulfuric acid solution or salpeter solution; When the pH of spray liquid value is during lower than this numerical value, in circulation fluid storage device I, add sodium bicarbonate solution by automatic medicine adding apparatus, regulate pH value to 0.8～1.5.
In circulation fluid storage device I, the mixing speed of agitating device I is 150～250rpm, and the speed preferably stirring is 168rpm; The aeration rate of aerator I is 1.0～1.8Nm
3/ min, is preferably 1.42Nm
3/ min.
Step 3) in the spray liquid of spraying layer II be, with pump, the circulation fluid in circulation fluid storage device II is delivered to spraying layer II, and get back to circulation fluid storage device II from the outlet of biomembrane filled tower II bottom circulation fluid, described spray liquid is in every premium on currency, to contain 0.5g/L MgSO
4, 0.5g/L NaCl and 0.3g/L KH
2pO
4solution, the pH value of this spray liquid is 7.When the pH of spray liquid value is during lower than this numerical value, in circulation fluid storage device I, add sodium bicarbonate solution by automatic medicine adding apparatus, regulating pH value is 7.
In circulation fluid storage device II, the mixing speed of agitating device II is 150～250rpm, and the speed preferably stirring is 168rpm; The aeration rate of aerator II is 1.0～1.8Nm
3/ min, is preferably 1.42Nm
3/ min.
In technical solution of the present invention, in circulation fluid storage device, increase and have agitating device and aerator, because oxygen is to be difficult to water-soluble gas, therefore, aspect oxygen supply, liquid-film resistance is more remarkable, governing factor, in the situation that having stirring, on the one hand, thalline clustering phenomena is reduced, relative motion between liquid and thalline increases, and has reduced film thickness, thereby has improved oxygen-supplying amount; On the other hand, stirring can make new fresh oxygen mix with circulation fluid better, ensures the dissolving to greatest extent of oxygen, and stirs and be conducive to heat exchange, makes the temperature of nutrient solution consistent, also helps the dispersion of nutriment and metabolin.
In device of the present invention, mixing speed is 150～250rpm, within the scope of this mixing speed, can improve preferably ventilatory effect, if mixing speed is too fast, not only cause on the one hand energy waste, can cause on the other hand nutrient solution to gush in a large number bubble, easily increase the chance of living contaminants, thereby make the easy oxidative deformation of enzyme on liquid film top layer, in addition, volume biomembrane disintegrates or microbiologic population disintegrates, and also can cause water outlet muddiness.If mixing speed is excessively slow, will cause Metabolite Accumulation, can not make oxygen be uniformly distributed, easily cause local anoxic, be unfavorable for the conveying of nutriment and the dispersion of metabolite.
Aerator is in order to supply with oxygen aerobic or that facultative aerobe is appropriate, to meet thalli growth breeding and the needed oxygen amount of accumulation metabolite, there is agitating device bubble can be smashed and increase in circulation fluid storage device, the turbulent extent of strengthening fluid, air is fully mixed with circulation fluid, and gas, liquid, solid three-phase contacts better, increases on the one hand dissolved oxygen speed, make on the other hand microbial suspension mix consistent, promote the mass transfer rate of metabolite.Stir and can also improve dissolved oxygen coefficient simultaneously.By increasing agitating device and aerator and by the synergy of the two, can effectively improve thalli growth breeding and the needed oxygen amount of accumulation metabolite, thereby further improve and remove SO in flue gas in circulation fluid storage device
2and NO
x.
The aeration rate of aerator is 1.0～1.8Nm
3the more suitable microbial growth of/min, in the time that aeration rate is excessive, the corresponding increase of air line speed, thus increase dissolved oxygen; Meanwhile, when air line speed is excessive, " overload " phenomenon can occur, now the blade of agitating device can not be broken up air, and air-flow forms air pocket effusion around axle, and stirring efficiency and dissolved oxygen speed are all reduced greatly.Thereby, increase merely aeration rate and improve the effect that dissolved oxygen coefficient might not obtain.Simple increase aeration rate might not improve dissolved oxygen effect (will prevent air overload) to be had the impact of microorganism:
1. excess aeration can cause microorganism excessive multiplication and death, if dead microorganism is too much, affects circulation fluid water quality.
2. miscellaneous bacteria undue growth, such as der Pilz meeting undue growth, affects the metabolism breeding of dominant bacteria
3. make a lot of microorganisms in the endogenous respiration stage, cause rapidly dissolved oxygen content to reduce, be unfavorable for the metabolism of function bacterial classification
Because dissolved oxygen is the key factor of can not ignore on the impact of microbial enzyme, therefore, if aeration rate is too small, dissolved oxygen deficiency can cause the bad result of metabolic process metabolite.In aeration tank, oxygen is not enough and excessive all can bring adverse effect to microorganism living environment, in the time that oxygen is not enough, on the one hand due to der Pilz meeting amount reproduction in aeration tank, functional bacterial activity deficiency, the organic biochemical reaction speed of microbial degradation and growth rate slow down, can reduce on the other hand the effect that bacterium is decomposed, extend the processing time, even cause biological treatment to be lost efficacy.
The beneficial effects of the utility model:
The utility model provides one to remove SO in flue gas
2and NO
xdouble-column in series device, in this device, be provided with demister device, this device can be avoided flue gas to carry too much circulation fluid and enter into next reaction tower, thereby has avoided the variation of circulation fluid liquid level.In addition, the automatic medicine adding apparatus that is also provided with pH value on-line monitoring instrument in the circulation fluid storage device of packed tower and is connected with pH value on-line monitoring instrument, when the pH of circulation fluid value exceeds the scope of setting, chemicals dosing plant can start, aerator and agitating device mix the circulation fluid of circulation fluid storage device in time, thereby adjust in time the pH value of circulation fluid, be also that in circulation fluid, microorganism increases oxygen simultaneously.Be conducive to like this microbial growth, thereby further improved the SO in flue gas
2and NO
xthere is good removal effect.
Brief description of the drawings
Fig. 1 is the SO in flue gas that removes of the present utility model
2and NO
xdouble-column in series device technique flow chart.
1-flue, 2-air-introduced machine, the 3-gas wash tower of lowering the temperature, 301-spraying layer, 302-demister device, 4-biomembrane filled tower I, 401-packing layer I, 402-spraying layer I, 403-demister device I, 5-biomembrane filled tower II, 501-packing layer II, 502-spraying layer II, 503-demister device II, 6-circulation fluid storage device I, 601-agitating device I, 602-pH value on-line monitoring instrument I, 603-automatic medicine adding apparatus I, 604-aerator I, 7-circulation fluid storage device II, 701-agitating device II, 702-pH value on-line monitoring instrument II, 703-automatic medicine adding apparatus II, 704-aerator II.
Fig. 2 increases aeration and/or the impact of agitating device on system desulfuration efficiency.
Fig. 3 increases aeration and/or the impact of agitating device on system denitration efficiency.
Fig. 4 is the impact of automatic medicine adding apparatus on circulation fluid pH value in circulation fluid storage device I.
Detailed description of the invention
Below in conjunction with embodiment, the utility model is described in further detail, but protection domain of the present utility model is not limited to this:
Embodiment 1
A kind of bioanalysis removes SO in flue gas
2and NO
xdouble-column in series device, flue gas in flue enters cooling gas wash tower, biomembrane filled tower I and biomembrane filled tower II successively by air-introduced machine, the gas outlet at cooling gas wash tower top is connected with the air inlet of biomembrane filled tower I bottom, and the gas outlet at biomembrane filled tower I top is connected with the air inlet of biomembrane filled tower II bottom;
Described cooling gas wash tower top is provided with demister device and spraying layer from top to bottom successively; Described biomembrane filled tower I is all provided with demister device I, spraying layer I and packing layer I from top to bottom successively; Described biomembrane filled tower II is all provided with demister device II, spraying layer II and packing layer II from top to bottom successively.
Described biomembrane filled tower I is provided with circulation fluid storage device I matching used with it, in circulation fluid storage device I, be provided with aerator I and agitating device I, the automatic medicine adding apparatus I that described circulation fluid storage device I is also provided with pH value on-line monitoring instrument I and is connected with pH value on-line monitoring instrument I.
Described biomembrane filled tower II is provided with circulation fluid storage device II matching used with it, in circulation fluid storage device II, be provided with aerator II and agitating device II, the automatic medicine adding apparatus II that described circulation fluid storage device II is also provided with pH value on-line monitoring instrument II and is connected with pH value on-line monitoring instrument II.
The packing layer I filler used of biomembrane filled tower I is that diameter is 5～8 centimetres, and surface attachment has biomembranous haydite, this biomembrane by screen and cultivate domestication obtain under pH sour environment condition, have remove flue gas simultaneously in SO
2make with desulfurization bacterium and the denitrifier composite flora biofilm of NOx performance, this composite flora is Thiobacillus thioxidans, moves Sphingol single-cell and Dai Erfute acidovorax facilis less, and the volume fraction of three kinds of bacterial classifications is followed successively by 45%, 30% and 25%.
The packing layer II filler used of packed tower II is that diameter is 5～8 centimetres, surface attachment has biomembranous haydite, this biomembrane by screen and cultivate domestication obtain under pH neutral environment condition, have remove flue gas in NOx performance denitrifier composite flora biofilm make, this composite flora is Nitrobacteraceae bacterium and the trichosporon cutaneum of growing thickly, and the volume fraction of two kinds of bacterial classifications is followed successively by 60% and 40%.
One removes SO in flue gas
2and NO
xmethod, flue gas in flue enters cooling gas wash tower by air-introduced machine, and (what enter cooling gas wash tower is raw flue gas, the effect of this tower is mainly that raw flue gas is lowered the temperature, and flue gas is carried out to secondary washing, remove wherein residual a small amount of flue dust) bottom, the spray liquid counter current contacting of this flue gas and cooling gas wash tower, this spray liquid is fresh water (FW); Flue gas after contact enters demister device, and discharges from the top of cooling gas wash tower;
The gas of discharging from cooling gas wash tower enters the bottom of biomembrane filled tower I, and going upward to the packing layer I in biomembrane filled tower I, the flue gas in road is by the moistening biomembrane absorption on surface in packing layer I sulfur dioxide and the NO that is caught by composite flora and degrade in purifying smoke
x, the gas after being cleaned afterwards and the spray liquid counter current contacting of spraying layer I, the gas that contains certain water yield of contact enters demister device I, removes the moisture in flue gas, and the flue gas of removing after moisture is discharged from the top of biomembrane filled tower I.
The gas that above-mentioned cooling gas wash tower is discharged enters packing layer I and from the top discharge process of packed tower I, spray liquid used is to adopt pump that the circulation fluid in circulation fluid storage device I is delivered to spraying layer I, and get back to circulation fluid storage device I from the outlet of biomembrane filled tower I bottom circulation fluid, described spray liquid is the MgSO that contains 0.5g/L in every premium on currency
4, the NaCl of 0.5g/L and the KH of 0.3g/L
2pO
4solution, the pH value of this spray liquid is 0.8～1.5; When the pH of this spray liquid is higher than 1.5 time, in this spray liquid, add acid reagent, described acid reagent includes but not limited to sulfuric acid solution or salpeter solution; As the sulfur dioxide in flue gas and NO
xcaught by composite flora and degrade after purification, the pH of circulation fluid is to reducing, when pH is to being reduced to 0.8～1.5, in circulation fluid, add sodium bicarbonate solution, and in time the circulation fluid of circulation fluid storage device I is mixed by agitating device and aerator.Wherein, the mixing speed of agitating device is 168rpm, and the aeration rate of aerator is 1.42Nm
3/ min.
Enter the bottom of biomembrane filled tower II from the top Exhaust Gas of biomembrane filled tower I, and going upward to the packing layer II in biomembrane filled tower II, the flue gas in road is by the moistening biomembrane absorption on surface in packing layer the NO that is caught and degrade in purifying smoke by composite flora
x, the gas after being cleaned afterwards and the spray liquid counter current contacting of spraying layer II, the gas that contains certain water yield of contact enters demister device II, removes the moisture in flue gas, and the flue gas of removing after moisture is discharged from the top of biomembrane filled tower II.
The above-mentioned gas entering from the bottom of biomembrane filled tower II is from the top discharge process of biomembrane filled tower II, spray liquid used is, with pump, the circulation fluid in circulation fluid storage device II is delivered to spraying layer II, and get back to circulation fluid storage device II from the outlet of biomembrane filled tower II bottom circulation fluid, described spray liquid is in every premium on currency, to contain 0.5g/L MgSO
4, 0.5g/L NaCl and 0.3g/L KH
2pO
4solution, the pH value of this spray liquid is 7; As the NO in flue gas
xcaught by composite flora and degrade after purification, the pH of circulation fluid is to reducing, when pH is to being reduced to 7, in circulation fluid, adding sodium bicarbonate solution to the pH value of circulation fluid is 7, and in time the circulation fluid of circulation fluid storage device I is mixed by agitating device and aerator.Wherein, the mixing speed of agitating device is 168rpm, and the aeration rate of aerator is 1.42Nm
3/ min.
Comparative example 1
Test device used with embodiment 1, but remove SO in flue gas
2and NO
xthe circulation fluid storage device I of double-column in series device in do not adopt agitating device.
Comparative example 2
Test device used with embodiment 1, but remove SO in flue gas
2and NO
xthe circulation fluid storage device I of double-column in series device in do not adopt aerator.
Comparative example 3
Test device used with embodiment 1, but remove SO in flue gas
2and NO
xthe circulation fluid storage device I of double-column in series device in do not adopt automatic medicine adding apparatus.
As shown in Figure 1, in circulation fluid storage device I, do not adopt agitating device and aerator, system desulfuration efficiency is unstable, is 65～80% left and right; When adopting agitating device or aerator in circulation fluid storage device I, system desulfuration efficiency is 80～86%; But when increase agitating device and aerator in circulation fluid storage device I simultaneously, system desulfuration efficiency significantly increases, and desulfuration efficiency can reach 90～95%.
As shown in Figure 2, in circulation fluid storage device I, do not adopt agitating device and aerator, system nitric efficiency is unstable, and the nitric efficiency of system is only 20～30% left and right; When adopting agitating device or aerator in circulation fluid storage device I, system nitric efficiency is 35～50%; But when increase agitating device and aerator in circulation fluid storage device I simultaneously, system nitric efficiency significantly increases, and nitric efficiency can reach 60～70%, and nitric efficiency is more stable.
As shown in Figure 3, in circulation fluid storage device I, do not adopt automatic medicine adding apparatus, days running was at 1～30 day, and in circulation fluid storage device I, the pH value of circulation fluid is 0.4～0.6 left and right, and the circulation fluid of this pH value is unfavorable for microbial growth in packed tower; But in circulation fluid storage device I, adopt automatic medicine adding apparatus, days running was at 31～51 days, and in circulation fluid storage device I, the pH value of circulation fluid is 0.8～0.9 left and right, and the circulation fluid of this pH value is conducive to microbial growth in packed tower.
Claims (3)
1. a bioanalysis removes SO in flue gas
2and NO
xdouble-column in series device, it is characterized in that: cooling gas wash tower (3) top is provided with demister device and spraying layer from top to bottom successively, and biomembrane filled tower I (4) and biomembrane filled tower II (5) are all provided with demister device, spraying layer and packing layer from top to bottom successively; Described biomembrane filled tower I (4) and biomembrane filled tower II (5) are equipped with circulation fluid storage device matching used with it, in circulation fluid storage device, be provided with aerator and agitating device, biomembrane filled tower I (4) matching used circulation fluid storage device I (6) is connected with the spraying layer I (402) on the outlet of biomembrane filled tower I (4) bottom circulation fluid, top respectively; Biomembrane filled tower II (5) matching used circulation fluid storage device II (7) is connected with the spraying layer II (502) on the outlet of biomembrane filled tower II (5) bottom circulation fluid, top respectively.
2. bioanalysis according to claim 1 removes SO in flue gas
2and NO
xdouble-column in series device, it is characterized in that: described circulation fluid storage device I (6) and the automatic medicine adding apparatus that is also provided with pH value on-line monitoring instrument in circulation fluid storage device II (7) and is connected with pH value on-line monitoring instrument.
3. bioanalysis according to claim 1 removes SO in flue gas
2and NO
xdouble-column in series device, it is characterized in that: the packing layer I filler used of biomembrane filled tower I (4) is that diameter is 5～8 centimetres, and surface attachment has biomembranous haydite; The packing layer II filler used of packed tower II (5) is that diameter is 5～8 centimetres, and surface attachment has biomembranous haydite.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420209768.5U CN203853019U (en) | 2014-04-26 | 2014-04-26 | Twin-tower series connection device for removing SO2 and NOx in smoke gas by biological method |
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| CN201420209768.5U CN203853019U (en) | 2014-04-26 | 2014-04-26 | Twin-tower series connection device for removing SO2 and NOx in smoke gas by biological method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103933855A (en) * | 2014-04-26 | 2014-07-23 | 南京宇行环保科技有限公司 | Double-tower serially-connected device and method for removing SO2 and NOx from smoke by using biological method |
| CN105498523A (en) * | 2015-12-11 | 2016-04-20 | 天紫工程管理（天津）有限公司 | Waste gas treatment system |
| CN108889105A (en) * | 2018-07-31 | 2018-11-27 | 王保行 | Sulphur purification system and its purification process are consolidated in the strength denitration of cement furnace coal-fired flue-gas |
| CN111545031A (en) * | 2019-02-12 | 2020-08-18 | 源洁科技股份有限公司 | Fossil fuel pollutant control system |
-
2014
- 2014-04-26 CN CN201420209768.5U patent/CN203853019U/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103933855A (en) * | 2014-04-26 | 2014-07-23 | 南京宇行环保科技有限公司 | Double-tower serially-connected device and method for removing SO2 and NOx from smoke by using biological method |
| CN103933855B (en) * | 2014-04-26 | 2016-09-14 | 南京宇行环保科技有限公司 | SO in bioanalysis removing flue gas2and NOxdouble-column in series device and method |
| CN105498523A (en) * | 2015-12-11 | 2016-04-20 | 天紫工程管理（天津）有限公司 | Waste gas treatment system |
| CN108889105A (en) * | 2018-07-31 | 2018-11-27 | 王保行 | Sulphur purification system and its purification process are consolidated in the strength denitration of cement furnace coal-fired flue-gas |
| CN111545031A (en) * | 2019-02-12 | 2020-08-18 | 源洁科技股份有限公司 | Fossil fuel pollutant control system |
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