CN203798781U - Device for treating mixed standard gas testing tail gas of SF6 (sulfur hexafluoride) decomposition products by adopting laboratory wet processing technique - Google Patents

Device for treating mixed standard gas testing tail gas of SF6 (sulfur hexafluoride) decomposition products by adopting laboratory wet processing technique Download PDF

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Publication number
CN203798781U
CN203798781U CN201420137555.6U CN201420137555U CN203798781U CN 203798781 U CN203798781 U CN 203798781U CN 201420137555 U CN201420137555 U CN 201420137555U CN 203798781 U CN203798781 U CN 203798781U
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communicated
gas
air intake
intake opening
gas outlet
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米劲臣
于乃海
胡小男
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State Grid Corp of China SGCC
Electric Power Research Institute of State Grid Shandong Electric Power Co Ltd
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State Grid Corp of China SGCC
Electric Power Research Institute of State Grid Shandong Electric Power Co Ltd
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Abstract

The utility model particularly discloses a device for treating mixed standard gas testing tail gas of SF6 (sulfur hexafluoride) decomposition products by adopting a laboratory wet processing technique. The device comprises a surge flask communicated with the tail gas, a hydrolyzing tank for absorbing gas freely soluble in water and easily hydrolyzing, an absorption tank for containing alkali liquid, a drying cavity, an adsorption cavity and an emptying pipeline, wherein the surge flask is communicated with the hydrolyzing tank by a pipeline, the hydrolyzing tank is communicated with the absorption tank, an exhaust opening of the absorption tank is sequentially communicated with the drying cavity and the adsorption cavity, and the adsorption cavity is communicated with atmosphere by the emptying pipeline. The device can absorb poisonous components in the SF6 decomposition products, is easy to operate and is low in cost, and besides, the device is provided with a special experiment shelf, has the small occupied area and is difficult to turn over.

Description

Laboratory wet processing SF 6the device of decomposition product mixing gas test tail gas
Technical field
The utility model relates to a kind of test exhaust gas processing device and using method, especially for SF 6the treating apparatus of poisonous component in decomposition product.
Background technology
Along with sulfur hexafluoride (SF 6) gas is widely used in mesohigh power equipment, by each component concentration analysis of sulfur hexafluoride decomposition product is judged to the ruuning situation of sulfur hexafluoride electrical equipment becomes more and more important, the research of this respect is also more and more.The decomposition product of general common sulfur hexafluoride is divided into following several: 1. fluoro-hydrogen compound, hydrogen fluoride (HF); 2. fluoro-sulphur compound, sulfur tetrafluoride (SF 4), bifluoride sulphur (SF 2), ten fluoridize two sulphur (S 2f 10); 3. fluoro-oxygen-sulphur compound, fluoridizes thionyl (SOF 2), fluoridize sulfonyl (SO 2f 2), tetrafluoro sulfur oxide (SOF 4o); Oxygen-sulphur compound, sulphuric dioxide (SO 2); Sulphur-hydrogen compound, sulfuretted hydrogen (H 2s) etc.To sulfur hexafluoride decomposition product, research is mainly carried out from two aspects, and the firstth, laboratory red, orange, green, blue, yellow (ROGBY) etc., the secondth, on-the-spot sulfur hexafluoride decomposition product analyzer determination method.The utility model is mainly for the test vent gas treatment of laboratory red, orange, green, blue, yellow (ROGBY).
Table 1 is SF 6the harm of each component of decomposition gas to human body
Compound To human body main harm
Hydrogen fluoride (HF) Stimulate respiratory tract, injury skin, acute pneumonia
Sulphuric dioxide (SO 2 Harm lung and respiratory tract
Bifluoride sulphur (SF 2 Stimulate respiratory tract, injury skin
Ten fluorine are oxidized two sulphur (S 2F 10O) Toxicity is extremely strong, causes pulmonary edema
Fluoridize thionyl (SOF 2 Cause pulmonary edema
Tetrafluoro sulfur oxide (SOF 4 Injury respiratory tract, infringement lung
Fluoridize sulfonyl (SO 2F 2 Cause empsyxis
Sulfuretted hydrogen (H 2S) Stimulate respiratory tract, very big to eye irritation
Sulfur hexafluoride decomposition product substantially all has toxicity concerning human body as known from Table 1, and the toxicity having is quite large.OSHA(U.S. Occupational Safety and Health Administration) regulation, it is 3ppm(volume fraction that 8 hours weighted means of hydrogen fluoride (take F) allow contact ultimate values (TWA-PEL)), the concentration that sulphuric dioxide can Long Term Contact is 5ppm(13mg/m 3).And ACGIH(ACGIH) recommend the Long Term Contact value of sulfuretted hydrogen must not be greater than 10ppm(14mg/m 3) and ACGIH(ACGIH) recommend the Long Term Contact value of sulphuric dioxide must not be greater than 2ppm(5.2mg/m 3), in the short time, contact value must not be greater than 5ppm(13mg/m 3).Adopt chromatography to analyze and need to carry out before gas analysis sulfur hexafluoride decomposition product, calibrating gas divides single gas and mixes gas, no matter single gas or mix gas, general high-purity helium (He) gas as a setting that adopts, the concentration range of each component is 10ppm~500ppm, much larger than the acceptable scope of human body, while therefore testing in laboratory, the poisonous component in these test tail gas is processed to become being even more important.
Because sulfur hexafluoride decomposition product gaseous species is more, process more complicatedly, not yet find that there is at present Patents the calibrating gas test tail gas of sulfur hexafluoride decomposition product is processed.
Utility model content
In order to address the above problem, the utility model discloses a kind of laboratory wet processing SF 6the device of decomposition product mixing gas test tail gas.
The technical solution adopted in the utility model is as follows:
A kind of laboratory wet processing SF 6the device of decomposition product mixing gas test tail gas, comprise the surge flask that is communicated with tail gas, for absorbing the hydrolytic tank of soluble in water and facile hydrolysis gas, absorption cell, drying chamber and adsorbent chamber for splendid attire alkali lye, described surge flask is communicated with hydrolytic tank by pipeline, described hydrolytic tank is communicated with absorption cell, the escape hole of described absorption cell is communicated with drying chamber, adsorbent chamber successively, and described adsorbent chamber communicates with atmosphere by evacuated tube.
In described drying chamber, be contained with for adsorbing the discolour silica gel of the moisture carrying from hydrolytic tank and alkali lye pond.
Discolour silica gel adsorbent is blue spherical, and specification is 3-5mm average pore size 2.0-2.5nm, specific surface 700-800m 2/ g, pore volume 0.35-0.4mL/g.
In described adsorbent chamber, be contained with activated alumina adsorbents.
Described activated alumina is that white is spherical, specification 3-5mm, specific surface 300-360m 2/ g, pore volume is 0.38-0.40mL/g.
Described drying chamber, adsorbent chamber are set in turn in same adsorber.
The opening part of described adsorber, surge flask, hydrolytic tank and absorption cell all seals.
The bottle cap of described surge flask is provided with air intake opening I, gas outlet I, on the bottle cap of hydrolytic tank, be provided with air intake opening II and gas outlet II, on the bottle cap of absorption cell, be provided with air intake opening III and gas outlet III, described air intake opening I is communicated with chromatograph gas outlet, described gas outlet I is communicated with by glass tube with air intake opening II, described gas outlet II is communicated with by glass tube with air intake opening III, and the mouth of pipe of the glass tube of air intake opening II, air intake opening III is incorporated into respectively in hydrolytic tank and absorption cell, the mouth of pipe of the glass tube of air intake opening I, gas outlet I, II, III is all higher than liquid level.
Described gas outlet III is connected with the entrance of adsorber by pipeline.
Described device is arranged on a support, described support is a rectangular support frame, on the base plate of support, be provided with the hole of three splendid attire surge flasks, hydrolytic tank, absorption cell, on two side plates of described support, be provided with the hole of supporting adsorber, and one of them side plate is provided with the hole that the connecting line for absorption cell and adsorber passes.
In the utility model, the effect of each stage arrangement is as follows:
1, surge flask.Experiment stops rear current meeting suck-back to chromatograph, and infringement chromatograph pipe system and column system, even cause security incident, and surge flask can prevent this point, and the alkali lye of surge flask bottom is in order slowly to absorb the acid toxic gas of staying surge flask inside.
2, hydrolytic tank.Absorb part gas soluble in water, absorb the gas of a part of facile hydrolysis.
3, alkali liquor absorption pond.Absorb all sour gas that are easy to sodium hydroxide solution reaction, the sluggish toxic gas (SO of absorption portion and NaOH 2f 2).After this one-level absorbs, testing the gas containing in tail gas is: whole helium (He), most ten fluoridize two sulphur (S 2f 10o), a part is fluoridized stream acyl (SO 2f 2), and large quantity of moisture.Other component is all hydrolyzed pond and alkali liquor absorption pond absorbs.
4, drying chamber.Hold discolour silica gel, the moisture that main absorption is carried from hydrolytic tank and alkali lye pond.Because activated alumina can absorb moisture, if not moisture drying, can reduce the service time of activated alumina.The Main Function of drying chamber is to allow the gas that enters activated alumina adsorber there is no moisture.
5, activated alumina adsorbent chamber.Hold activated alumina adsorbents, Main Function is that selectivity absorbs fluorochemicals, absorbs polar gas, adsorption moisture, and do not absorb as non-polar gases such as helium (He).
6, emptying pipe.Other gases after poisonous component is absorbed are discharged outside laboratory.
The beneficial effects of the utility model are:
The utility model can effectively absorb processing to the poisonous component in sulfur hexafluoride decomposition product, simple to operate, with low cost, and this device has special-purpose experimental frame, takies testing table area little, is difficult for overturning.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of three reaction units of the present utility model;
Fig. 2 is the schematic diagram of adsorber of the present utility model
Fig. 3 is the structural representation of emptying pipe;
Fig. 4 is the schematic diagram of sheet rubber;
Fig. 5 is device laying rack schematic diagram.
In figure: 1. rubber plug, 2. rubber tube, 3. glass tube, 4. surge flask, 5. sodium hydroxide solution, 6. demineralized water, 7 hydrolytic tanks, 8. cork, 9. drying chamber, 10. adsorbent chamber, 11. narrow meshed sheet rubbers, 12. glass infusers, 13. emptying pipes, 14. apertures, 15. device laying racks, 16. pipeline holes, 17. fixed heads, 18. air intake opening I, 19. air intake opening I, 20. air intake opening II, 21 gas outlet II, 22. air intake opening III, 23. gas outlet III, 24 adsorber entrances, 25. absorption cells.
Embodiment
In sulfur hexafluoride decomposition product, majority of compounds is sour gas, and what have is soluble in water (as bifluoride sulphur SF 2), some facile hydrolysis are (as tetrafluoro sulfur oxide SOF 4), what have is easily absorbed (most of SF by sodium hydroxide solution 6what decomposition product), have can only be adsorbed (S by activated alumina 2f 10), or preferentially by activated alumina absorption (SO 2f 2), in order to realize calibrating gas test tail gas, to process, the concrete device adopting is as Figure 1-3;
In Fig. 1, laboratory wet processing SF 6the device of decomposition product mixing gas test tail gas comprises the surge flask 4 that is communicated with tail gas, for absorbing the hydrolytic tank 7 of soluble in water and facile hydrolysis gas, absorption cell 25, drying chamber 9, adsorbent chamber 10 and emptying pipe 13 for splendid attire alkali lye, described surge flask is communicated with hydrolytic tank by pipeline, described hydrolytic tank is communicated with absorption cell, the escape hole of described absorption cell is communicated with drying chamber 9, adsorbent chamber 10 successively, and described adsorbent chamber 10 communicates with atmosphere by emptying pipe 13.
All vials are all with cork 8 or rubber plug 1 sealing, each connector is as shown in the figure connected with rubber tube 2 with glass tube 3, test tail gas containing sulfur hexafluoride decomposition product out enters surge flask 4 by the air intake opening I18 at surge flask middle part (not contacting liquid level) from chromatographic exhausr port, after going out, air intake opening I19 by top enters hydrolytic tank, air intake opening II20 is in the bottom of hydrolytic tank, after going out by gas outlet II21 after being hydrolyzed, enter alkali liquor absorption pond, air intake opening III22 is in the bottom in alkali liquor absorption pond, occur after absorption reaction from gas outlet III23 goes out, gas outlet III23 is connected to adsorber entrance 24, tail gas enters activated alumina adsorber after entering exsiccator, unabsorbed toxic gas is adsorbed, after being disposed, gas is discharged from exhausr port, be connected in emptying pipe 13 evacuated tube and lead to outside laboratory.Test tail gas is after treatment only remaining nontoxic helium (He) in theory.
In Fig. 1, it is 15% sodium hydroxide solution 5 that liquid in surge flask bottom and alkali liquor absorption pond is massfraction, in hydrolytic tank, be loaded with demineralized water 6, what in drying chamber 9, hold is discolour silica gel adsorbent, and what in activated alumina adsorbent chamber 10, hold is activated alumina.
Discolour silica gel adsorbent is blue spherical, specification is 3-5mm average pore size 2.0-2.5nm, specific surface 700-800m2/g, pore volume 0.35-0.4mL/g, Main Function is adsorption moisture, before inefficacy, be blue, after losing efficacy, pulverize was red, after table look silica gel loses efficacy, should change or carry out re-using after processed.
Activated alumina is that white is spherical, specification 3-5mm, and specific surface 300-360m2/g, pore volume is 0.38-0.40mL/g, Main Function is that selectivity absorbs fluorochemicals, absorbs polar gas, adsorption moisture, and do not absorb as non-polar gases such as helium (He).
The internal diameter of glass infuser 12 is 5.0cm, and wall thickness is 3mm, and length is 30cm.Wherein the length of drying chamber 9 is 10cm, and activated alumina cavity length is 10cm.
In sheet rubber 11, have aperture, aperture size is slightly less than the particle diameter of adsorbent, is 2.8mm, and aperture number is greater than 8, The more the better in theory, indeformable with sheet rubber, and it is principle that two kinds of adsorbents can not see through aperture.The Main Function of sheet rubber is that two kinds of adsorbents are divided into two chambers, and a chamber holds discolour silica gel, and another chamber holds activated alumina, and these three sheet rubbers all can allow test tail gas pass through.The diameter 4.9cm of sheet rubber, and require the shape distortion that differs.As shown in Figure 2.
The length of emptying pipe 13 is as the criterion with actual conditions, and object is that the tail gas after processing is discharged to laboratory, in the situation that meeting object, more short better in principle.
Fig. 3 is this device laying rack, and material is wooden or plastics.
In Fig. 3, the fixed head 17 of laying rack 15 is provided with three holes, respectively: C place circular port is surge flask fixedly, D place circular port is hydrolytic tank fixedly, F place circular port is alkali lye absorption cell fixedly, on the side plate of both sides, A, two circular arcs of B block adsorber, and B end blocks the inlet end of adsorber, the outlet side that A end blocks adsorber.Pipeline connects by pipeline hole 16 and is communicated with upper and lower two parts.
Whole shelf becomes cuboid, and length is 27cm, is highly 18cm, and width is 12cm, and the internal diameter of C, D, tri-round mouths of F is 8cm, and the diameter of A, B two and half arcs is 6.0cm, and pipe hole 16 internal diameters are 1.0cm.
The utility model is because be classification absorption test tail gas, various piece is disperseed, therefore take testing table larger, and easily overturn, smash, the device laying rack 14 in Fig. 3 can be saved very large space, also each device is fixed in shelf, effectively prevent from overturning, in order to avoid infringement experimental apparatus causes personal injury and economic loss.
The utility model connects after chromatograph exhausr port, can effectively absorb the poisonous component in sulfur hexafluoride decomposition product listed above, both applicable to the absorption of sulfur hexafluoride decomposition product hybrid standard gas test tail gas, also applicable to the absorption of single standard gas test tail gas.

Claims (10)

1. a laboratory wet processing SF 6the device of decomposition product mixing gas test tail gas, it is characterized in that: comprise the surge flask that is communicated with tail gas, for absorbing the hydrolytic tank of soluble in water and facile hydrolysis gas, absorption cell, drying chamber and adsorbent chamber for splendid attire alkali lye, described surge flask is communicated with hydrolytic tank, described hydrolytic tank is communicated with absorption cell, and the escape hole of absorption cell is communicated with drying chamber, adsorbent chamber successively, described adsorbent chamber communicates with atmosphere by evacuated tube.
2. device as claimed in claim 1, is characterized in that: in described drying chamber, be contained with for adsorbing the discolour silica gel of the moisture carrying from hydrolytic tank and alkali lye pond.
3. device as claimed in claim 2, is characterized in that: discolour silica gel adsorbent is for blue spherical, and specification is 3-5mm average pore size 2.0-2.5 nm, specific surface 700-800m 2/ g, pore volume 0.35-0.4mL/g.
4. device as claimed in claim 1, is characterized in that: in described adsorbent chamber, be contained with activated alumina adsorbents.
5. device as claimed in claim 4, is characterized in that: described activated alumina is that white is spherical, specification 3-5mm, specific surface 300-360m 2/ g, pore volume is 0.38-0.40mL/g.
6. the device as described in claim 1 or 2 or 3, is characterized in that: described drying chamber, adsorbent chamber are set in turn in same adsorber.
7. device as claimed in claim 6, is characterized in that: the opening part of described adsorber, surge flask, hydrolytic tank and absorption cell all seals.
8. device as claimed in claim 1, it is characterized in that: the bottle cap of described surge flask is provided with air intake opening I, gas outlet I, on the bottle cap of hydrolytic tank, be provided with air intake opening II and gas outlet II, on the bottle cap of absorption cell, be provided with air intake opening III and gas outlet III, described air intake opening I is communicated with chromatograph gas outlet, described gas outlet I is communicated with by glass tube with air intake opening II, described gas outlet II is communicated with by glass tube with air intake opening III, and air intake opening II, the mouth of pipe of the glass tube of air intake opening III is incorporated into respectively in hydrolytic tank and absorption cell, air intake opening I, gas outlet I, II, the mouth of pipe of the glass tube of III is all higher than liquid level.
9. device as claimed in claim 8, is characterized in that: described gas outlet III is connected with the entrance of adsorber by pipeline.
10. device as claimed in claim 1, it is characterized in that: described device is arranged on a support, described support is a rectangular support frame, on the base plate of support, be provided with the hole of three splendid attire surge flasks, hydrolytic tank, absorption cell, on two side plates of described support, be provided with the hole of supporting adsorber, and one of them side plate is provided with the hole that the connecting line for absorption cell and adsorber passes.
CN201420137555.6U 2014-03-25 2014-03-25 Device for treating mixed standard gas testing tail gas of SF6 (sulfur hexafluoride) decomposition products by adopting laboratory wet processing technique Expired - Lifetime CN203798781U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107413187A (en) * 2017-09-08 2017-12-01 国家电网公司 A kind of environment-friendly type sulfur hexafluoride/nitrogen mixed gas separating and reclaiming device and method
CN115624849A (en) * 2022-10-21 2023-01-20 国家电网有限公司 Optimizing device based on dielectric barrier discharge degradation sulfur hexafluoride

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107413187A (en) * 2017-09-08 2017-12-01 国家电网公司 A kind of environment-friendly type sulfur hexafluoride/nitrogen mixed gas separating and reclaiming device and method
CN107413187B (en) * 2017-09-08 2020-09-29 国家电网公司 Environment-friendly sulfur hexafluoride/nitrogen mixed gas separation and recovery device and method
CN115624849A (en) * 2022-10-21 2023-01-20 国家电网有限公司 Optimizing device based on dielectric barrier discharge degradation sulfur hexafluoride

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Address after: 100031 No. 86 West Chang'an Avenue, Beijing, Xicheng District

Patentee after: STATE GRID CORPORATION OF CHINA

Patentee after: Shandong Electric Power Research Institute

Address before: 250002 Wang Yue Road, Ji'nan City, Shandong Province, No. 2000

Patentee before: State Grid Corporation of China

Patentee before: Shandong Electric Power Research Institute

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Effective date of registration: 20220125

Address after: 100031 No. 86 West Chang'an Avenue, Beijing, Xicheng District

Patentee after: STATE GRID CORPORATION OF CHINA

Patentee after: ELECTRIC POWER RESEARCH INSTITUTE OF STATE GRID SHANDONG ELECTRIC POWER Co.

Address before: 100031 No. 86 West Chang'an Avenue, Beijing, Xicheng District

Patentee before: STATE GRID CORPORATION OF CHINA

Patentee before: Shandong Electric Power Research Institute

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CX01 Expiry of patent term

Granted publication date: 20140827