CN203545851U - Integrated device of water purification, disinfection and activation for aquaculture - Google Patents

Integrated device of water purification, disinfection and activation for aquaculture Download PDF

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Publication number
CN203545851U
CN203545851U CN201320757394.6U CN201320757394U CN203545851U CN 203545851 U CN203545851 U CN 203545851U CN 201320757394 U CN201320757394 U CN 201320757394U CN 203545851 U CN203545851 U CN 203545851U
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activation
water
electrolysis machine
aquaculture
electrolysis
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张世文
许雅玲
郑宣庆
庞志强
李丹
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Boying Xiamen Science and Technology Co Ltd
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Abstract

The utility model discloses an integrated device of water purification, disinfection and activation for aquaculture. The integrated device comprises a box, an electrolysis system, an aeration system, and an activation system, wherein the electrolysis system, the aeration system, and the activation system are located in the box. The electrolysis system and the aeration system are located at the upper portion of the box, and the activation system is located at the lower portion of the box. The integrated device integrates the techniques of filtering, electrolysis, aeration, activation and the like, the unit size of the integrated device is small, equipment combination and expansion are convenient, energy consumption is very low, and operation expense is far lower than that of other traditional disinfection methods. The integrated device can effectively carry out water purification, disinfection and activation on waste water of aquaculture without any additional agents, secondary pollution caused when additional agents are added is avoided, and zero release of waste water of aquaculture can be achieved. In addition, the growth of farmed fishes, shrimps and shellfishes will not be influenced at all through short-time aerobic treatment, no cancerogenic substances are generated, and therefore the integrated device is safe and harmful.

Description

Aquaculture water purifying sterilizing and activation integral gasifying device
Technical field
The utility model relates to a kind of aquaculture water treatment device, particularly relates to a kind of aquaculture water purifying sterilizing and activation integral gasifying device that integrates the technology such as filtration, electrolysis, aeration and activation.
Background technology
In the past, sea farming was to realize by the extensive traditional aquaculture model of extensive style to a great extent.Along with the innovation of scientific and technical development and cultivation idea, industrialized aquiculture (comprise and growing seedlings) unblemished fish, shrimp, shellfish, realize seawater recycle and whole process and carry out closed management, become low-carbon (LC) breeding production modes high-quality and efficient, energy-saving and emission-reduction.No matter be industrialized culture or traditional aquaculture model, in order to prevent the disease of fish, shrimps and crab class etc., all must in culturing pool, add sterilizing agent and microbiotic, aquatic product quality is declined, cause pollution of dining table.It is healthy that pollution of dining table directly affects people, thereby cause Aquatic product price significantly to drop.In order to solve pollution of dining table problem, must control from source, the crucial culture water quality of tank system that will guarantee exactly fish, shrimps and crab class etc., must not make aquaculture water poisonous with heterochromatic, foreign odor, peculiar smell, intestinal bacteria, heavy metal, organic pesticide, petroleum-type etc., harmful.Water quality will meet the requirement of < < water quality standard for fishery > > and < < pollution-free food aquiculture fresh water water quality > >, thereby ensures the quality of fishery products.
Utility model content
That the purpose of this utility model is is not up to standard for existing aquaculture water water quality, add sterilizing agent and microbiotic causes the serious deficiencies such as pollution of dining table, and a kind of aquaculture water purifying sterilizing and activation integral gasifying device are provided.
The utility model adopts following technical scheme:
Aquaculture water purifying sterilizing and activation integral gasifying device, comprise casing, electrolytic system, aerating system and activation system, described electrolytic system, aerating system and activation system are positioned at described casing, described electrolytic system and aerating system are positioned at the top of casing, and activation system is positioned at the bottom of casing; Described electrolytic system is for filtering aquaculture water waste water and sterilize, it is provided with electrolysis machine, electrolysis machine water-in and electrolysis machine washpipe, electrolysis machine water-in connects with electrolysis machine, and electrolysis machine washpipe is positioned at electrolysis machine top, and anode and negative electrode are installed in electrolysis machine; Described aerating system is for carrying out aeration except the chlorine residue of anhydrating by aquaculture water after filtration and sterilization, and it is provided with aeration inlet pipe and aerating apparatus; Described activation system is for carrying out bioactivation by the aquaculture water after sterilization and aeration purification, it is provided with filter material layer, backwash overflow port, water collector and water outlet, and the aeration inlet pipe in described aerating system and aerating apparatus are arranged in the bottom of activation system filter material layer.
In described activation system, the top of filter material layer is positioned at 3/5ths places of box height.
In described activation system, backwash overflow port is positioned at the top of filter material layer, and is positioned at apart from casing top one of four parts.
In described electrolytic system, filter bag is equipped with in electrolysis machine water inlet.
In described electrolytic system, electrolysis machine is fixed on casing top by anchor ear and support.
It is the titanium-base anode with precious metal oxide coating of 17-42nm that described anode adopts surface coverage to have crystal grain, and described anode is tabular anode, circular-arc anode, cylindric anode or meshed anode; Described negative electrode is titanium negative electrode, iron cathode, aluminium negative electrode, stainless steel cathode, zinc negative electrode, cathode, nickel cathode, lead electrode or graphite cathode, and described negative electrode is circular-arc negative electrode, cylindric negative electrode or mesh cathode.
In described activation system, filter material layer comprises upper and lower layer, and wherein, upper strata is than the filler great, particle diameter is little, and the lower floor of filter material layer is the filler that proportion is little, particle diameter is large, and upper and lower layer packed height ratio is 11:4.
In described activation system, in filter material layer, throw in and have microorganism and the algae that is applicable to cultivation kind growth needs.
Aquaculture water purifying sterilizing and activation method comprise the following steps:
(1) filter
Aquaculture water enters electrolysis machine by electrolysis machine water-in after filter bag filters, and by filter bag, removes remaining feed, cultivation ight soil, microorganism corpse and other foreign material in breeding wastewater;
(2) electrolysis
Aquaculture water enters after electrolysis machine, the strong oxidizing property material producing through electrolysis machine electrolysis, organism in rapid oxygenolysis water, kill and suppress hydroplankton, bacterium, virus and algae, realize aquaculture water purification sterilization, operating voltage during electrolysis between anode and negative electrode is 2~8V, and current density is 10~300mA/cm 2;
(3) aeration
Water outlet overflow after electrolysis enters aerating system, by being installed on the aerating apparatus aeration of filter material layer bottom, removes chlorine residue and other strong oxidizing property materials in water;
(4) activation
Pass through Air Exposure and remove the filter material layer in the current overactivation system of chlorine residue, the microorganism and the algae that are of value to cultivation kind growth needs in filter material layer, cultivated, make the water after sterilization recover biological activity, realizes the activation of aquaculture water; Water outlet after aeration and activation enters in culturing pool through water collector and water outlet successively, realizes the recycling utilization of aquaculture water;
(5) rinse
Device, after operation for some time, need carry out back flushing and electrolysis machine is rinsed the filter material layer in device, and backwashing water, by water outlet access to plant, is removed after the pollutent adhering in filter material layer, and after rinsing, water outlet is discharged through backwash overflow port; Wash-down water enters in electrolysis machine through electrolysis machine washpipe, removes the pollutent adhering on electrolysis machine anode and negative electrode and discharges by electrolysis machine water-in.
Described step (5) is 5 ~ 10 minutes to the backwashing time of filter material layer in rinsing, and to the flush time of electrolysis machine, is 5 ~ 10 minutes.
From the above-mentioned description to the utility model structure, compared to the prior art, the utlity model has following advantage:
(1) plant energy consumption is extremely low, and working cost is far below other traditional disinfection way.
(2) unit volume is little, and combination dilatation is convenient.
(3) in the fresh water of the rapid oxygenolysis cultivation of the strong oxidizing property substances such as [Cl] producing by electrolysis, [O], [OH] use or seawater, fish, shrimps and crab class etc. are endangered to the organism such as larger nitrite, hydrogen sulfide, making its oxygenolysis is nontoxic organism, thereby reduces BOD and COD in water.
(4) electrolysis has powerful killing and restraining effect to bacterium, virus, microorganism and algae etc. in water, is a kind of quick, easy, sterilization mode that efficiency is high.First, during electrolysis, large electric current punctures bacterium, microbial cell wall, makes its death; Secondly, under the effect of electric field, capture bacterium, the self-contained electronics of microorganism, make it lose biological activity and death; The 3rd, the radical in a large number with strong oxidizing property producing in electrolytic process, can kill bacterium, virus and microorganism in water fast; The 4th, the radical in a large number with strong oxidizing property producing in electrolytic process, can not only penetrate in the cell of algae, and blocking-up algae carries out DNA replication dna, and energy fast decoupled cell walls, destroys the cellularstructure of algae, suppresses algal grown in water.
(5) generation group, auxochrome group and the osmophore of the radical of the strong oxidation that electrolysis produces in can fast degradation water, removes colourity and foreign odor, peculiar smell.
(6) electric field that electrolysis produces can make rapidly de-steady, the flocculating settling of the colloidalmaterial in water, simultaneously, [H] that negative electrode produces can form a large amount of bubbles, floating along with bubble, can take a large amount of suspended solids out of, reach the effect of solid-liquid separation, effectively remove colloidalmaterial and suspended matter in water.
(7) without additional any medicament, avoid the secondary pollution that causes because of outer adding medicine, realize breeding wastewater zero release; And, through short-term oxygenation, process cultivation fish, shrimp, shellfish are grown and had no effect, do not produce carcinogenic substance, safe and harmless.
Accompanying drawing explanation
Fig. 1 is the structural representation of the utility model aquaculture water purifying sterilizing and activation integral gasifying device;
Fig. 2 is the left view of the utility model aquaculture water purifying sterilizing and activation integral gasifying device;
Fig. 3 is the front view of the utility model aquaculture water purifying sterilizing and activation integral gasifying device;
Fig. 4 is the vertical view of the utility model aquaculture water purifying sterilizing and activation integral gasifying device;
Fig. 5 is the rear view of the utility model aquaculture water purifying sterilizing and activation integral gasifying device.
Embodiment
Embodiment of the present utility model is described with reference to the accompanying drawings.
Aquaculture water purifying sterilizing and activation integral gasifying device, with reference to Fig. 1, comprise casing 1 and the electrolytic system, aerating system and the activation system that are positioned at casing 1, and wherein, electrolytic system and aerating system are positioned at the top of casing, and activation system is positioned at the bottom of casing.In conjunction with Fig. 2 and Fig. 3, electrolytic system is provided with electrolysis machine 2, electrolysis machine water-in 6 and electrolysis machine washpipe 4, electrolysis machine 2 is fixed on casing top by anchor ear 13 and support 14, electrolysis machine water-in 6 connects with electrolysis machine 2, filter bag is equipped with at electrolysis machine water-in 6 places, electrolysis machine washpipe 4 is positioned at electrolysis machine 2 tops, anode 11 and negative electrode 12 battery lead plates are installed in electrolysis machine 2, it is the titanium-base anode of the coating of metal oxides of 17-42nm that anode 11 adopts surface coverage to have crystal grain, anode 11 can be tabular anode, circular-arc anode, cylindric anode or meshed anode, negative electrode 12 can be titanium negative electrode, iron cathode, aluminium negative electrode, stainless steel cathode, zinc negative electrode, cathode, nickel cathode, lead electrode or graphite cathode etc., negative electrode 12 can be circular-arc negative electrode, cylindric negative electrode or mesh cathode, aerating system is provided with aeration inlet pipe 3 and aerating apparatus 9, and aeration inlet pipe 3 and aerating apparatus 9 connect.With reference to Fig. 2, Fig. 4 and Fig. 5, activation system is provided with filter material layer 8, backwash overflow port 5, water collector 10 and water outlet 7, aeration inlet pipe 3 in aerating system and aerating apparatus 9 are arranged in the bottom of activation system filter material layer 8, the top of filter material layer 8 is positioned at 3/5ths places of casing 1 height, backwash overflow port 5 is positioned at the top of filter material layer 8, and is positioned at apart from one of four parts, casing 1 top.
With reference to Fig. 2, in activation system, filter material layer 8 comprises upper strata 81He lower floor 82, upper strata 81 is than the filler great, particle diameter is little, lower floor 82 is the filler that proportion is little, particle diameter is large, upper strata 81He lower floor 82 packed height ratios are 11:4, in activation system, also throw in and have microorganism and the algae that is applicable to cultivation kind growth needs in filter material layer 8.
Below in conjunction with Fig. 1-Fig. 5, provide the specific embodiment of aquaculture water purifying sterilizing and activation method:
Embodiment 1
Certain seawater is supported the method for shrimp aquaculture water purifying sterilizing and activation.
It is as shown in table 1 after measured that described seawater is supported shrimp aquaculture waste water quality index.
Table 1 seawater is supported the water-quality guideline of shrimp aquaculture waste water
Sequence number Project Unit Measured value Sequence number Project Unit Measured value
1 Odor smell - Have 5 Total coli group (individual/L) 3×10 5
2 COD mg/L 55 6 DO mg/L 3.0
3 SS mg/L 89 7 Ammonia nitrogen mg/L 6.7
4 Total phosphorus mg/L 1.5 ? ? ? ?
(1) filter
Seawater is supported shrimp aquaculture water and after filter bag filters, is entered electrolysis machine 2 by electrolysis machine water-in 6, by filter bag, removes remaining feed, cultivation ight soil, microorganism corpse and other foreign material in breeding wastewater;
(2) electrolysis
Seawater is supported shrimp aquaculture water and is entered after electrolysis machine 2, the strong oxidizing property material that 2 electrolysis produce through electrolysis machine, and the organism in oxygenolysis water, kills and suppresses hydroplankton, bacterium, virus and algae rapidly, realizes the purifying sterilizing of aquaculture water; Operating voltage during described electrolysis between anode and negative electrode is 3 ~ 5V, and current density is 10 ~ 200mA/cm 2;
(3) aeration
Water outlet overflow after electrolysis enters aerating system, by being installed on aerating apparatus 9 aerations of filter material layer 8 bottoms, removes chlorine and other strong oxidizing property materials in water;
(4) activation
Through Air Exposure, remove the filter material layer 8 in the current overactivation system of chlorine residue, the genus bacillus and the EM bacterium that are of value to cultivation kind growth needs in filter material layer 8, cultivated, make the water after sterilization recover biological activity, realizes the activation of aquaculture water; Water outlet after aeration and activation enters in culturing pool through water collector 10 and water outlet 7 successively, realizes the recycling utilization of aquaculture water;
(5) rinse
Device, after operation for some time, need carry out back flushing and electrolysis machine 2 is rinsed the filter material layer 8 in device.Backwashing water, by water outlet 7 accesss to plant, is removed after the pollutent adhering in filter material layer 8, and after rinsing, water outlet is through 5 discharges of backwash overflow port, and backwashing time is 5 minutes; Wash-down water enters in electrolysis machine 2 through electrolysis machine washpipe 4, removes the pollutent adhering on electrolysis machine 2 anodes 11 and negative electrode 12 and discharges by electrolysis machine water-in 6, and flush time is 10 minutes.
Effect after each step process is as shown in table 2.
Water-quality guideline after table 2 breeding wastewater is processed
Figure 229576DEST_PATH_IMAGE002
Embodiment 2
The breed fish method of aquaculture water purifying sterilizing and activation of certain seawater.
The described seawater breeding wastewater water-quality guideline of breeding fish is as shown in table 3 after measured.
The breed fish water-quality guideline of breeding wastewater of table 3 seawater
Sequence number Project Unit Measured value Sequence number Project Unit Measured value
1 Odor smell - Have 5 Total coli group (individual/L) 6.3×10 5
2 COD mg/L 76 6 DO mg/L 2.8
3 SS mg/L 78 7 Ammonia nitrogen mg/L 8.5
4 Total phosphorus mg/L 1.9 ? ? ? ?
(1) filter
The seawater aquaculture water of breeding fish enters electrolysis machine 2 by electrolysis machine water-in 6 after filter bag filters, and by filter bag, is removed remaining feed in breeding wastewater, is cultivated ight soil, microorganism corpse and other foreign material;
(2) electrolysis
The seawater aquaculture water of breeding fish enters after electrolysis machine 2, the strong oxidizing property material that 2 electrolysis produce through electrolysis machine, and the organism in oxygenolysis water, kills and suppresses hydroplankton, bacterium, virus and algae rapidly, realizes the purifying sterilizing of aquaculture water; Operating voltage during described electrolysis between anode and negative electrode is 4 ~ 6V, and current density is 50 ~ 250mA/cm 2;
(3) aeration
Water outlet overflow after electrolysis enters aerating system, by being installed on aerating apparatus 9 aerations of filter material layer 8 bottoms, removes chlorine and other strong oxidizing property materials in water;
(4) activation
Through Air Exposure, remove the filter material layer 8 in the current overactivation system of chlorine residue, the photosynthetic bacteria, nitrifier and the diatom that are of value to cultivation kind growth needs in filter material layer 8, cultivated, make the water after sterilization recover biological activity, realizes the activation of aquaculture water; Water outlet after aeration and activation enters in culturing pool through water collector 10 and water outlet 7 successively, realizes the recycling utilization of aquaculture water;
(5) rinse
Device, after operation for some time, need carry out back flushing and electrolysis machine 2 is rinsed the filter material layer 8 in device.Backwashing water, by water outlet 7 accesss to plant, is removed after the pollutent adhering in filter material layer 8, and after rinsing, water outlet is through 5 discharges of backwash overflow port, and backwashing time is 10 minutes; Wash-down water enters in electrolysis machine 2 through electrolysis machine washpipe 4, removes the pollutent adhering on electrolysis machine 2 anodes 11 and negative electrode 12 and discharges by electrolysis machine water-in 6, and flush time is 7 minutes.
Effect after each step process is as shown in table 4.
Water-quality guideline after table 4 breeding wastewater is processed
Embodiment 3
The method of certain freshwater aquiculture water purifying sterilizing and activation.
Described fresh-water fish-culture culture water quality of tank system index is as shown in table 5 after measured.
The water-quality guideline of table 5 fresh-water fish-culture breeding wastewater
Sequence number Project Unit Measured value Sequence number Project Unit Measured value
1 Odor smell - Have 5 Total coli group (individual/L) 9×10 4
2 COD mg/L 60 6 DO mg/L 3.1
3 SS mg/L 80 7 Ammonia nitrogen mg/L 5.0
4 Total phosphorus mg/L 1.2 ? ? ? ?
(1) filter
Fresh-water fish-culture aquaculture water enters electrolysis machine 2 by electrolysis machine water-in 6 after filter bag filters, and by filter bag, removes remaining feed, cultivation ight soil, microorganism corpse and other foreign material in breeding wastewater;
(2) electrolysis
Fresh-water fish-culture aquaculture water enters after electrolysis machine 2, the strong oxidizing property material that 2 electrolysis produce through electrolysis machine, and the organism in oxygenolysis water, kills and suppresses hydroplankton, bacterium, virus and algae rapidly, realizes the purifying sterilizing of aquaculture water; Operating voltage during described electrolysis between anode and negative electrode is 5 ~ 8V, and current density is 100 ~ 300mA/cm 2;
(3) aeration
Water outlet overflow after electrolysis enters aerating system, by being installed on aerating apparatus 9 aerations of filter material layer 8 bottoms, removes chlorine and other strong oxidizing property materials in water;
(4) activation
Through Air Exposure, remove the filter material layer 8 in the current overactivation system of chlorine residue, that in filter material layer 8, cultivates is of value to the cultivation hidden algae of kind growth needs and chrysophyceae, makes the water after sterilization recover biological activity, realizes the activation of aquaculture water; Water outlet after aeration and activation enters in culturing pool through water collector 10 and water outlet 7 successively, realizes the recycling utilization of aquaculture water;
(5) rinse
Device, after operation for some time, need carry out back flushing and electrolysis machine 2 is rinsed the filter material layer 8 in device.Backwashing water, by water outlet 7 accesss to plant, is removed after the pollutent adhering in filter material layer 8, and after rinsing, water outlet is through 5 discharges of backwash overflow port, and backwashing time is 7 minutes; Wash-down water enters in electrolysis machine 2 through electrolysis machine washpipe 4, removes the pollutent adhering on electrolysis machine 2 anodes 11 and negative electrode 12 and discharges by electrolysis machine water-in 6, and flush time is 5 minutes.
Effect after each step process is as shown in table 6.
Water-quality guideline after table 6 breeding wastewater is processed
Figure 194438DEST_PATH_IMAGE006
Above are only embodiment of the present utility model, but design concept of the present utility model is not limited to this, allly utilizes this design to carry out the change of unsubstantiality to the utility model, all should belong to the behavior of invading the utility model protection domain.

Claims (8)

1. aquaculture water purifying sterilizing and activation integral gasifying device, it is characterized in that: comprise casing, electrolytic system, aerating system and activation system, described electrolytic system, aerating system and activation system are positioned at described casing, described electrolytic system and aerating system are positioned at the top of casing, and activation system is positioned at the bottom of casing;
Described electrolytic system is for filtering aquaculture water waste water and sterilize, it is provided with electrolysis machine, electrolysis machine water-in and electrolysis machine washpipe, electrolysis machine water-in connects with electrolysis machine, and electrolysis machine washpipe is positioned at electrolysis machine top, and anode and negative electrode are installed in electrolysis machine;
Described aerating system is for carrying out aeration except the chlorine residue of anhydrating by aquaculture water after filtration and sterilization, and it is provided with aeration inlet pipe and aerating apparatus;
Described activation system is for carrying out bioactivation by the aquaculture water after sterilization and aeration purification, it is provided with filter material layer, backwash overflow port, water collector and water outlet, and the aeration inlet pipe in described aerating system and aerating apparatus are arranged in the bottom of activation system filter material layer.
2. aquaculture water purifying sterilizing as claimed in claim 1 and activation integral gasifying device, is characterized in that: in described activation system, the top of filter material layer is positioned at 3/5ths places of box height.
3. aquaculture water purifying sterilizing as claimed in claim 1 and activation integral gasifying device, is characterized in that: in described activation system, backwash overflow port is positioned at the top of filter material layer, and be positioned at apart from casing top one of four parts.
4. aquaculture water purifying sterilizing as claimed in claim 1 and activation integral gasifying device, is characterized in that: in described electrolytic system, filter bag is equipped with in electrolysis machine water inlet.
5. aquaculture water purifying sterilizing as claimed in claim 1 and activation integral gasifying device, is characterized in that: in described electrolytic system, electrolysis machine is fixed on casing top by anchor ear and support.
6. aquaculture water purifying sterilizing as claimed in claim 1 and activation integral gasifying device, it is characterized in that: it is the titanium-base anode with precious metal oxide coating of 17-42nm that described anode adopts surface coverage to have crystal grain, and described anode is tabular anode, circular-arc anode, cylindric anode or meshed anode; Described negative electrode is titanium negative electrode, iron cathode, aluminium negative electrode, stainless steel cathode, zinc negative electrode, cathode, nickel cathode, lead electrode or graphite cathode, and described negative electrode is circular-arc negative electrode, cylindric negative electrode or mesh cathode.
7. aquaculture water purifying sterilizing as claimed in claim 1 and activation integral gasifying device, it is characterized in that: in described activation system, filter material layer comprises upper and lower layer, wherein, upper strata is than the filler great, particle diameter is little, the lower floor of filter material layer is the filler that proportion is little, particle diameter is large, and upper and lower layer packed height ratio is 11:4.
8. aquaculture water purifying sterilizing as claimed in claim 1 and activation integral gasifying device, is characterized in that: in described activation system, in filter material layer, throw in and have microorganism and the algae that is applicable to cultivation kind growth needs.
CN201320757394.6U 2013-11-27 2013-11-27 Integrated device of water purification, disinfection and activation for aquaculture Withdrawn - After Issue CN203545851U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103613243A (en) * 2013-11-27 2014-03-05 波鹰(厦门)科技有限公司 Purification, disinfection and activation integrated device and purification, disinfection and activation method for aquaculture water
CN105165665A (en) * 2015-04-30 2015-12-23 佛山市顺德区德心和水产养殖有限公司 Aquaculture method and aquaculture system
CN108002605A (en) * 2017-11-17 2018-05-08 浙江海洋大学 The processing method of antibiotic in a kind of marine culture wastewater

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103613243A (en) * 2013-11-27 2014-03-05 波鹰(厦门)科技有限公司 Purification, disinfection and activation integrated device and purification, disinfection and activation method for aquaculture water
CN105165665A (en) * 2015-04-30 2015-12-23 佛山市顺德区德心和水产养殖有限公司 Aquaculture method and aquaculture system
CN108002605A (en) * 2017-11-17 2018-05-08 浙江海洋大学 The processing method of antibiotic in a kind of marine culture wastewater
CN108002605B (en) * 2017-11-17 2021-05-14 浙江海洋大学 Method for treating antibiotics in mariculture wastewater

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