CN202949681U - Stacking structure of flexible graphite paper material and flexible graphite paper obtained through heat treatment - Google Patents

Stacking structure of flexible graphite paper material and flexible graphite paper obtained through heat treatment Download PDF

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Publication number
CN202949681U
CN202949681U CN 201220570460 CN201220570460U CN202949681U CN 202949681 U CN202949681 U CN 202949681U CN 201220570460 CN201220570460 CN 201220570460 CN 201220570460 U CN201220570460 U CN 201220570460U CN 202949681 U CN202949681 U CN 202949681U
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China
Prior art keywords
layer
graphite paper
flexible graphite
stacked structure
polyimide film
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Expired - Fee Related
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CN 201220570460
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Chinese (zh)
Inventor
翁明生
萧龙达
曾哲律
李宏元
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Green Crystal Energy Ltd
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Green Crystal Energy Ltd
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Abstract

The utility model discloses a stacking structure of flexible graphite paper material and flexible graphite paper obtained by heat treatment, the stacking structure of flexible graphite paper material comprises a first spacing material layer, a second spacing material layer and a polyimide film, the polyimide film is arranged between the first spacing material layer and the second spacing material layer; the first spacing material layer and the second spacing material layer are carbon material layers, metal material layers or ceramic material layers. The flexible graphite paper obtained by heat treatment of the flexible graphite paper material comprises a carbon material layer, a metal material layer or a ceramic material layer.

Description

The stacked structure of flexible graphite paper material and the flexible graphite paper that obtains through heat treatment
Technical field
The utility model is relevant for a kind of graphite paper, and particularly relates to a kind of stacked structure of flexible graphite paper material and the flexible graphite paper that obtains through heat treatment.
Background technology
Along with the development of science and technology, (for example: function 3C Product) also is raised electronic installation always.This electronic component that also means electronic installation inside need to have better heat radiation medium when work done, can be in good time the electronics unit running of electronic installation inside the time loose the removing of heat energy, to keep the function quality that electronic installation was provided.
In addition, due to some electronic installation (such as mobile phone or notebook computer etc.) towards lightening development.Therefore, how to provide the heat radiation medium to help electronic element radiating in the confined space of electronic installation and become an important subject under discussion.Flexible graphite paper has the characteristics such as frivolous, flexible, gradually becomes the strength member of heat radiation module in 3C Product.
During but existing flexible graphite paper is produced, be stacking with multilayer polyimide film (Polyimide, PI) and exert pressure, nitrogen-atoms is slowly disengaged, to produce foamed phenomenon from polyimide film; When but multilayer polyimide film is stacking, if certain strata acid imide film out-of-flatness, to affect the yield of all polyimide films, and utilize the number of polyimide film and exert pressure to control foaming degree, can cause the limited and not good problem of yield of volume production condition.
The utility model content
In order to address the above problem, this is novel provides a kind of stacked structure that comprises the flexible graphite paper material of layer of spacer material.
A kind of stacked structure of flexible graphite paper material comprises the first layer of spacer material, the second layer of spacer material and polyimide film.Polyimide film is configured between the first layer of spacer material and the second layer of spacer material; Wherein, the first layer of spacer material and the second layer of spacer material are material with carbon element layer, metal material layer or ceramic material layer.
Preferably, above-mentioned material with carbon element is graphite flake layer, graphite flaggy or carbon dust layer.
Preferably, above-mentioned metal material is that fusing point is at the sheet-metal layers more than 2000 ℃ or metal bisque.
Preferably, above-mentioned ceramic material is that fusing point is at the oxide skin(coating) more than 2000 ℃, nitride layer, boride layer or carbide lamella.
Preferably, above-mentioned polyimide film is the carbonization polyimide film.
The flexible graphite paper that the utility model also provides a kind of stacked structure of above-mentioned flexible graphite paper material to obtain through Overheating Treatment, this flexible graphite paper comprises material with carbon element layer, metal material layer or ceramic material layer.
Preferably, this material with carbon element layer, this metal material layer or this ceramic material layer are formed on the surface of this flexible graphite paper.
The beneficial effects of the utility model: the stacked structure of flexible graphite paper material can be in heat treatment process, by layer of spacer material (for example, the first layer of spacer material and the second layer of spacer material) control the foaming degree of polyimide film, so not only can promote the thermal conduction characteristic of the graphite paper after moulding, and can make simultaneously various polyimide films; Because can optionally exert pressure by changing layer of spacer material, so yield also can improve.
Description of drawings
Fig. 1 is the schematic diagram of the stacked structure of this novel embodiment flexible graphite paper material.
Fig. 2 is the schematic diagram of the stacked structure of this novel another embodiment flexible graphite paper material.
The main element symbol description:
The stacked structure of 10 flexible graphite paper material;
10a the first layer of spacer material;
10b the second layer of spacer material;
The 10c polyimide film.
Embodiment
For making this novel structure, feature, effect and purpose that more detailed understanding can be arranged, now coordinate graphic this novel related embodiment to be described in detail as follows.
See also Fig. 1, Fig. 1 is the schematic diagram of the stacked structure of this novel embodiment flexible graphite paper material.
As shown in Figure 1, the stacked structure 10 of flexible graphite paper material comprises the first layer of spacer material 10a, the second layer of spacer material 10b and polyimide film 10c.
Polyimide film 10c is configured between the first layer of spacer material 10a and the second layer of spacer material 10b.For example, polyimide film 10c is configured between the upper surface of the lower surface of the first layer of spacer material 10a and the second layer of spacer material 10b, but is not limited to this.Polyimide film 10c can be the carbonization polyimide film.Polyimide film 10c has the characteristics such as excellent pyroconductivity, frivolous and flexible.
According to the stacked structure 10 of above-mentioned flexible graphite paper material, the producer can be used to make graphite paper.Specifically, when making graphite paper, the producer can prepare the first layer of spacer material 10a and the second layer of spacer material 10b in advance.The first layer of spacer material 10a and the second layer of spacer material 10b are material with carbon element layer, metal material layer or ceramic material layer.Wherein, the material with carbon element layer is graphite flake layer, graphite flaggy or carbon dust layer; Metal material is sheet-metal layers or metal bisque.For example, metal material layer is that fusing point is at the sheet-metal layers more than 2000 ℃ or metal bisque; Ceramic material layer is oxide skin(coating), nitride layer, boride layer or carbide lamella.For example, ceramic material is that fusing point is at the oxide skin(coating) more than 2000 ℃, nitride layer, boride layer or carbide lamella.
Then, polyimide film 10c is configured between the first layer of spacer material 10a and the second layer of spacer material 10b to form the stacked structure 10 of flexible graphite paper material.
Particularly, the producer can be in advance (utilizing artificial or machine) with the raw material of the first layer of spacer material 10a, polyimide film 10c and the second layer of spacer material 10b stacked arrangement sequentially, and the stacked structure 10 of this flexible graphite paper material is sent into a high temperature graphitization stove heat-treat to make flexible graphite paper.
By using the high temperature graphitization stove to utilize above-mentioned the first layer of spacer material 10a and the second layer of spacer material 10b to press.Be heated to 3000 ℃ by room temperature.In this embodiment, but be not limited to, heated by the stepwise heating mode, also can be directly be heated between 2400 ℃ to 3000 ℃ of temperature by room temperature.The stepwise heating mode, particularly, in the time of can being heated to (comprise 1000 ℃) below 1000 ℃ by room temperature, heating per minute be no more than 2 ℃, and when being heated to more than 1000 ℃ (comprise 3000 ℃) below 3000 ℃, heating per minute is no more than 10 ℃.When the stepwise heating mode is adopted in heat treatment, utilize the first layer of spacer material 10a and the second layer of spacer material 10b also can control the foaming degree of polyimide film 10c in heat treatment process.
For example, in heat treatment process, can have the denitrogenation effect when being heated due to the raw material of polyimide film 10c, thereby produce foamed phenomenon.Therefore, utilize the first layer of spacer material 10a and the second layer of spacer material 10b can help the foaming degree of polyimide film 10c in heat treatment process, make foamed phenomenon can be subject to suitable control.And after completing heat treatment, obtain the flexible graphite paper with uniform in foaming.That is to say, the stacked structure 10 of flexible graphite paper material carries out can becoming flexible graphite paper after above-mentioned heat treatment process.
Wherein, made flexible graphite paper comprises material with carbon element layer, metal material layer or ceramic material layer.Described material with carbon element layer, metal material layer or ceramic material layer are formed on the surface (for example: upper surface or lower surface, but be not limited to this) of flexible graphite paper.
In addition, by changing the first layer of spacer material 10a and the second layer of spacer material 10b, can make simultaneously different polyimide film (carbonization polyimide film).Or change weight and the material of the first layer of spacer material 10a and the second layer of spacer material 10b, and come optionally polyimide film 10c to be exerted pressure, also can improve so make yield.
That is to say, utilize the first layer of spacer material 10a and the second layer of spacer material 10b can help the foaming degree homogenizing of polyimide film 10c when heat-treating program.
See also Fig. 2, Fig. 2 is the schematic diagram of the stacked structure of this novel another embodiment flexible graphite paper material.
As shown in Figure 2, the difference of Fig. 2 and Fig. 1 is: the stacked structure of sequentially arranging to form the flexible graphite paper material with more the first layer of spacer material 10a, the second layer of spacer material 10b and polyimide film 10c.
Hence one can see that, dispose the stacked structure of polyimide film 10c between the first layer of spacer material 10a (or second layer of spacer material 10b) and the second layer of spacer material 10b (or first layer of spacer material 10a), its stacking number of plies can be decided according to actual demand, is not limited to the number of plies of Fig. 1 and Fig. 2.
The stacked structure of the described flexible graphite paper material of this new embodiment has following characteristics: but utilize the first layer of spacer material and the foaming degree of the second layer of spacer material homogenizing polyimide film in heat treatment process, to promote the thermal conductivity of making rear flexible graphite paper.
In sum, above embodiment for this novel preferred embodiment of enumerating, is not only the scope that limits this novel enforcement.Be that the equalization that the novel claim of Fan Yiben is done changes and modifies, be all this new patent protection range and contain.Protection range of the present utility model is as the criterion with claims.

Claims (7)

1. the stacked structure of a flexible graphite paper material, is characterized in that, comprising:
One first layer of spacer material;
One second layer of spacer material; And
One polyimide film is configured between this first layer of spacer material and this second layer of spacer material;
Wherein, this first layer of spacer material and this second layer of spacer material are material with carbon element layer, metal material layer or ceramic material layer.
2. the stacked structure of flexible graphite paper material as claimed in claim 1, is characterized in that, this material with carbon element layer is graphite flake layer, graphite flaggy or carbon dust layer.
3. the stacked structure of flexible graphite paper material as claimed in claim 1, is characterized in that, this metal material layer is that fusing point is at the sheet-metal layers more than 2000 ℃ or metal bisque.
4. the stacked structure of flexible graphite paper material as claimed in claim 1, is characterized in that, this ceramic material layer is that fusing point is at the oxide skin(coating) more than 2000 ℃, nitride layer, boride layer or carbide lamella.
5. the stacked structure of flexible graphite paper material as claimed in claim 1, is characterized in that, this polyimide film is the carbonization polyimide film.
One kind by the stacked structure of flexible graphite paper material claimed in claim 1 through the flexible graphite paper that Overheating Treatment obtains, it is characterized in that, this flexible graphite paper comprises material with carbon element layer, metal material layer or ceramic material layer.
7. the stacked structure of flexible graphite paper material as claimed in claim 6 through the flexible graphite paper that Overheating Treatment obtains, is characterized in that, this material with carbon element layer, this metal material layer or this ceramic material layer are formed on the surface of this flexible graphite paper.
CN 201220570460 2012-08-09 2012-11-01 Stacking structure of flexible graphite paper material and flexible graphite paper obtained through heat treatment Expired - Fee Related CN202949681U (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW101215344U TWM446318U (en) 2012-08-09 2012-08-09 Material stacked structure of flexible graphite paper
TW101215344 2012-08-09

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103568418A (en) * 2012-08-09 2014-02-12 绿晶能源股份有限公司 Stacking structure of flexible graphite paper material and manufacturing method of flexible graphite paper
CN107043108A (en) * 2014-01-26 2017-08-15 斯迪克新型材料(江苏)有限公司 Fin manufacturing process for smart mobile phone
CN111326591A (en) * 2018-11-29 2020-06-23 东泰高科装备科技有限公司 Flexible solar cell and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103568418A (en) * 2012-08-09 2014-02-12 绿晶能源股份有限公司 Stacking structure of flexible graphite paper material and manufacturing method of flexible graphite paper
CN107043108A (en) * 2014-01-26 2017-08-15 斯迪克新型材料(江苏)有限公司 Fin manufacturing process for smart mobile phone
CN111326591A (en) * 2018-11-29 2020-06-23 东泰高科装备科技有限公司 Flexible solar cell and preparation method thereof

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20130522

Termination date: 20161101