CN202814766U - Escape ammonia sampling analyzing device of smoke pretreatment type power plant denitrating system - Google Patents

Escape ammonia sampling analyzing device of smoke pretreatment type power plant denitrating system Download PDF

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Publication number
CN202814766U
CN202814766U CN 201220526204 CN201220526204U CN202814766U CN 202814766 U CN202814766 U CN 202814766U CN 201220526204 CN201220526204 CN 201220526204 CN 201220526204 U CN201220526204 U CN 201220526204U CN 202814766 U CN202814766 U CN 202814766U
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China
Prior art keywords
power plant
denitrating system
sampling
escape ammonia
flue gas
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Expired - Lifetime
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CN 201220526204
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Chinese (zh)
Inventor
崔福兴
胡志宏
杨兴森
侯凡军
王海超
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State Grid Corp of China SGCC
Electric Power Research Institute of State Grid Shandong Electric Power Co Ltd
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State Grid Corp of China SGCC
Electric Power Research Institute of State Grid Shandong Electric Power Co Ltd
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Priority to CN 201220526204 priority Critical patent/CN202814766U/en
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Abstract

The utility model relates to an escape ammonia sampling analyzing device of a smoke pretreatment type power plant denitrating system. The escape ammonia sampling analyzing device comprises a sampling gun connected with a sulfur oxide absorbing device connected with a filtering device, the filtering device is connected with a drying device outside a smoke channel through a connection pipe, and the drying device is communicated with an absorbing bottle through a volume flow meter and an air pump. Excess adsorbent in a SO2 and SO3 absorbing device is utilized to absorb SO2 and SO3 in a smoke sample, loss of NH3 is reduced, and sampling accuracy is improved.

Description

Flue gas pre-service formula power plant denitrating system escape ammonia sampling analysis device
Technical field
The utility model relates to a kind of sampling system of generating plant, mainly for power plant's denitrating system escape ammonia sampling analysis device, for power plant's day-to-day operation is offered help.
Background technology
Along with the pay attention to day by day of country to environmental protection, country begins to pay attention to promoting the use of of denitration technology, power plant is as the blowdown rich and influential family, carrying out progressively carrying out the denitration transformation after desulfurization is transformed, wherein adopt SCR or SNCR all to use the principle of ammonia reducing NOx, exist the part ammonia to have neither part nor lot in the phenomenon of reaction, be referred to as the escaping of ammonia.Escape ammonia causes more greatly ammoniacal liquor or urea waste on the one hand, and can cause secondary pollution, escape ammonia easily forms ammonium salt and is attached on the back-end ductwork metallic walls when being lower than 300 ℃ on the other hand, and metal is caused larger corrosion and then reduces its serviceable life, affects the unit operation security.If escape ammonia size in the time of therefore can measuring actual motion smoothly will improve security and the economy of unit overall operation, reach the purpose of energy-saving and emission-reduction.
Germany generally leaks the ammonium salt concentration in the flying dust of back-end ductwork as afterbody ammonia index, U.S. kentucky university adopts ammonium concentration in the ion selective electrode method test flying dust, but because the unevenness of Fly ash sampling, error is larger.No matter external or domestic, for ammonium concentration in the flying dust measure lack can operation for reference relevant criterion.
Directly to smoke sampling and since ammonia when being lower than 300 ℃ easily and the SO in the flue gas 2, SO 3Stick on the sampling system tube wall in conjunction with forming ammonium salt, sampling result is caused larger error, sampling system is answered special design.
Summary of the invention
The purpose of this utility model is to overcome above-mentioned deficiency, and a kind of flue gas pre-service formula power plant denitrating system escape ammonia sampling analysis device is provided, the method quick and precisely, it can guarantee the integrality of ammonia in flue gas gas sampling, and unit operation is estimated.
The technical scheme that the utility model is taked is:
Flue gas pre-service formula power plant denitrating system escape ammonia sampling analysis device, comprise sampling gun, sampling gun connects the oxysulfide absorption plant, the oxysulfide absorption plant links to each other with filtration unit, filtration unit is connected by the outer drying device of connecting pipe and flue, and drying device communicates with absorption bottle through volumetric displacement meter, aspiration pump.
Described oxysulfide absorption plant is built-in with SO 2, SO 3Absorbing agent.
In the described absorption bottle NH is housed 3Absorption liquid.
Described oxysulfide absorption plant is in flue.
Described connecting pipe is emulsion tube.
The beneficial effects of the utility model are:
Under the hot conditions of flue inside, utilize SO 2, SO 3Adsorbent excessive in the absorption plant is with the SO in the flue gas sample 2, SO 3Absorb, reduce NH 3The loss of sampling improves the sampling degree of accuracy.
Description of drawings
Fig. 1 is structural representation of the present utility model;
Wherein, 1. sampling gun, 2. oxysulfide absorption plant, 3. filtration unit, 4. connecting pipe, 5. drying device, 6. volumetric displacement meter, 7. aspiration pump, 8. absorption bottle, 9. furnace wall.
Embodiment
Below in conjunction with accompanying drawing utility model is described further.
As shown in the figure, flue gas pre-service formula power plant denitrating system escape ammonia sampling analysis device, comprise sampling gun 1, sampling gun 1 connects oxysulfide absorption plant 2, oxysulfide absorption plant 2 links to each other with filtration unit 3, filtration unit 3 is connected by the outer drying device 5 of connecting pipe 4 and flue, and drying device 5 communicates with absorption bottle 8 through volumetric displacement meter 6, aspiration pump 7.
Oxysulfide absorption plant 2 is built-in with SO 2, SO 3Absorbing agent is such as alkali.In the absorption bottle 8 NH is housed 3Absorption liquid is such as water.Oxysulfide absorption plant 2 is in flue.Connecting pipe 4 is emulsion tube.
Sampling gun 1 is put into flue, open aspiration pump 7, flue gas slowly enters in the sampling gun 1, flows through the SO of excessive absorbing agent is housed 2, SO 3Oxysulfide absorption plant 2 because the oxysulfide absorption plant is positioned at flue, its internal temperature about 350 ℃, this moment absorbing agent very easily with flue gas in SO 2, SO 3Reaction, the SO of unit volume during reaction 2Or SO 3Generate the water vapour of unit volume, flue gas volume is constant.Filtration unit 3 filters out the ash in the flue gas and a small amount of absorbing agent of escaping.Flue gas flows into the emulsion tube 4 from sampling gun 1 outlet, enters drying device 5, and excessive drying agent all absorbs the water in the flue gas, according to the volume V that calculates water vapor of poor quality of drying device before and after the sampling 1, in the volumetric displacement meter 6 of flowing through, volumetric displacement meter 6 is surveyed out the flue gas cumulative volume V that flows through when sampling begins to the sampling end 2, the flue gas of processing is through absorption bottle 8, and absorbing agent keeps ammonia in flue gas gas.Owing to have certain volume V in emulsion tube and the sampling gun before the sampling 3Air, the flue gas population of samples is long-pending to be V 1+ V 2-V 3, the ammonium ion in the absorbing agent is carried out quantitative test, the volume V of ammonia calculates ammonia concentration=V/ (V in the flue gas sample when drawing the sampling beginning to the sampling end 1+ V 2-V 3) * 10 6Ppm.

Claims (5)

1. flue gas pre-service formula power plant denitrating system escape ammonia sampling analysis device, it is characterized in that, comprise sampling gun, sampling gun connects the oxysulfide absorption plant, the oxysulfide absorption plant links to each other with filtration unit, filtration unit is connected by the outer drying device of connecting pipe and flue, and drying device communicates with absorption bottle through volumetric displacement meter, aspiration pump.
2. flue gas pre-service formula according to claim 1 power plant denitrating system escape ammonia sampling analysis device is characterized in that described oxysulfide absorption plant is built-in with SO 2, SO 3Absorbing agent.
3. flue gas pre-service formula according to claim 1 power plant denitrating system escape ammonia sampling analysis device is characterized in that, in the described absorption bottle NH is housed 3Absorption liquid.
4. flue gas pre-service formula according to claim 1 power plant denitrating system escape ammonia sampling analysis device is characterized in that described oxysulfide absorption plant is in flue.
5. flue gas pre-service formula according to claim 1 power plant denitrating system escape ammonia sampling analysis device is characterized in that described connecting pipe is emulsion tube.
CN 201220526204 2012-10-15 2012-10-15 Escape ammonia sampling analyzing device of smoke pretreatment type power plant denitrating system Expired - Lifetime CN202814766U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201220526204 CN202814766U (en) 2012-10-15 2012-10-15 Escape ammonia sampling analyzing device of smoke pretreatment type power plant denitrating system

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CN 201220526204 CN202814766U (en) 2012-10-15 2012-10-15 Escape ammonia sampling analyzing device of smoke pretreatment type power plant denitrating system

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102879239A (en) * 2012-10-15 2013-01-16 山东电力集团公司电力科学研究院 Flue gas pre-treatment type sampling and analysis device and method for escaping ammonia of denitration system of power plant
CN104857832A (en) * 2015-06-05 2015-08-26 山东钢铁股份有限公司 Absorption device of hydrogen sulfide gas
CN105467086A (en) * 2015-12-28 2016-04-06 国网山东省电力公司电力科学研究院 Method for measuring flue gas amount of boiler of power station
CN107515136A (en) * 2017-09-21 2017-12-26 安徽环境科技研究院股份有限公司 A kind of flue laying dust gathers rifle

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102879239A (en) * 2012-10-15 2013-01-16 山东电力集团公司电力科学研究院 Flue gas pre-treatment type sampling and analysis device and method for escaping ammonia of denitration system of power plant
CN104857832A (en) * 2015-06-05 2015-08-26 山东钢铁股份有限公司 Absorption device of hydrogen sulfide gas
CN105467086A (en) * 2015-12-28 2016-04-06 国网山东省电力公司电力科学研究院 Method for measuring flue gas amount of boiler of power station
CN105467086B (en) * 2015-12-28 2017-03-22 国网山东省电力公司电力科学研究院 Method for measuring flue gas amount of boiler of power station
CN107515136A (en) * 2017-09-21 2017-12-26 安徽环境科技研究院股份有限公司 A kind of flue laying dust gathers rifle

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Granted publication date: 20130320

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