CN202116351U - Novel high-efficiency single-stage or multistage tank type gas-liquid contact membrane absorption unit - Google Patents

Novel high-efficiency single-stage or multistage tank type gas-liquid contact membrane absorption unit Download PDF

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Publication number
CN202116351U
CN202116351U CN 201020641558 CN201020641558U CN202116351U CN 202116351 U CN202116351 U CN 202116351U CN 201020641558 CN201020641558 CN 201020641558 CN 201020641558 U CN201020641558 U CN 201020641558U CN 202116351 U CN202116351 U CN 202116351U
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China
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hollow fiber
pot type
fiber membrane
liquid contact
type gas
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CN 201020641558
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陈颖
张召才
郭春刚
关毅鹏
刘国昌
李晓明
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Tianjin Institute of Seawater Desalination and Multipurpose Utilization SOA
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Tianjin Institute of Seawater Desalination and Multipurpose Utilization SOA
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Abstract

The utility model discloses a novel high-efficiency single-stage or multistage tank type gas-liquid contact membrane absorption unit, which comprises a plurality of groups of columnar hydrophobic hollow fiber membrane elements, a tank type casing and a membrane cleaning component horizontally arranged in the tank type casing. Hollow fiber membranes in each group of columnar hydrophobic hollow fiber membrane elements are coiled into a column shape after being braided with yarns, two ends of each hollow fiber membrane are cast hermetically, the groups of columnar hydrophobic hollow fiber membrane elements are relatively independent, and the upper ends and the lower ends of the groups of columnar hydrophobic hollow fiber membrane elements are provided with flow guide supports or support structures for the columnar hydrophobic hollow fiber membrane elements. The membrane cleaning component comprises a plurality of cleaning pipes, a plurality of nozzles are arranged on the wall of each cleaning pipe, and the cleaning pipes are integrally connected onto a water supply pipe. The novel high-efficiency single-stage or multistage tank type gas-liquid contact membrane absorption unit not only reduces high gas phase resistance caused by hollow fiber bundles, but also solves the problem that package cast positions of a hollow fiber membrane component contract or expand and are easy to damage and break after a traditional tubular membrane absorption unit is amplified.

Description

A kind of new and effective single-stage or multistage pot type gas-to-liquid contact film absorptive unit
Technical field
The utility model relates to a kind of gas-to-liquid contact film absorptive unit, is particularly useful for membrane absorption method and removes acidity, alkalescence or gas composition such as poisonous, the application of aspect such as also comprise from the liquid degassing or in liquid, inflate.
Background technology
Common gas absorption equipment (like packing tower, liquid column tower and spray column etc.); In the middle of absorption equipment, liquid through grid distributor from top to bottom in tower filling surface evenly flow down, and gas from bottom to top is blown in the tower; By inner-tower filling material, for gas-to-liquid contact provides surface-area.But because gas-liquid two-phase directly contacts in the absorption process, make this technology be subject to the restriction of hydromeehanics conditions such as liquid flooding, channel and entrainment, cause absorbing the liquids and gases skewness, mass-transfer efficiency is low.Though conventional gas absorption technology and equipment have many improvement, purpose is to make and absorbs the tiny increase specific surface of drop, and airflow field is more evenly optimized, and strengthens gas-liquid mass transfer, promotes assimilated efficiency.It is huge that yet its defective is an equipment volume, and technology controlling and process is complicated, and investment and operation expense are high.
The gas-liquid film absorptive unit (membrane contactor) that occurs in recent years can be through hydrophobic hollow-fibre membrane with the gas-liquid two-phase medium separately; Solved the problem that the conventional gas resorber can not make gas phase and liquid phase independent operation; Avoided the appearance of packed tower leakage and channel under high flow rate underflow stream and the low flow velocity; And contact area is big, and mass-transfer efficiency is high.But existing membrane contactor finds to also have a lot of problems to need to be resolved hurrily in actual through engineering approaches application process.
Publication number CN1642628A; The one Chinese patent application that its open day is on July 20th, 2005 discloses a kind of hollow fiber membrane contactors; Use a large amount of thrust-augmenting nozzles and baffle plate to increase the medium flowing homogeneity; Improve mass-transfer efficiency, the two-phase medium flow velocity can change arbitrarily within the specific limits, but the hollow-fibre membrane tow causes gas-phase pressure drop bigger.
Publication number is CN1680006A; The one Chinese patent application that its open day is on October 12nd, 2005 discloses a kind of membrane contactor; Adopt the braiding tubular fibre and be equipped with pipe core improving mass transfer process, but the said tubular membrane contactor of above patent is along with the amplification of its diameter, be easy in the position contraction or expansion of tubular fibre encapsulation casting and break; And the vapour lock that fibrous bundle causes can become along with the increase of gas phase flow greatly, is difficult to realize the application of through engineering approaches.
Publication number is CN1689690; The one Chinese patent application that its open day is on November 2nd, 2005 discloses a kind of hollow fiber membrane contactors; Though but the gas-liquid two-phase medium is an independent operation, the gas phase flow velocity can not be adjusted arbitrarily, because gas phase is to flow in the tubular fibre of at one end shutting all the time.
Publication number is CN101121099A; The one Chinese patent application that its open day is on February 13rd, 2008 discloses a kind of preparation method of hollow fiber membrane contactors; Be to adopt rotary centrifugal force to form the moulding of annular wall after fixing down, need not deviating from this step of casting mould, just can to keep tubular fibre member end be open, though saved the step of form removal, assembling; But when the diameter of membrane contactor becomes big; Because cast is once shaped, require not only that rotary forming equipment is big, prolong set time, more be not easy to dismounting, install and transportation.
Also have following notification number or the pairing technical scheme of publication number (be and announce a few days ago or disclose) with the Chinese patent and the patented claim of hollow fiber bundle formula or column-type film components relevant report: CN2869001Y, CN101007675A, CN2835231Y, CN101254978A, CN201473385U etc.But do not see that bundle formula or pillar hydrophobic hollow fiber membrane module are applied to the patent report of gas-liquid film absorption process at present.Particularly use to the embrane method flue gas desulfurization technique, not only flow is big smoke treatment, and pressure is low, and present being seen film absorptive unit form is difficult to meet the demands.
The utility model content
To above-mentioned prior art, the utility model provides a kind of new and effective pot type gas-to-liquid contact film absorptive unit, and not only the gas-liquid two-phase flow velocity can change in the scope of broad independently, and is suitable for handling big flow low resistance gas phase media.Mainly be the assembling form of improving the conventional film absorptive unit, will organize the pillar membrane element more and fill in the great circle tank body.Not only reduce hollow fiber bundle and caused high gas phase drag, also avoided conventional tubular film absorptive unit to amplify position contraction or expansion and the fragile disruptive problem of back hollow fiber film assembly encapsulation casting.
In order to solve the problems of the technologies described above; The technical scheme that a kind of new and effective single-stage pot type gas-to-liquid contact film absorptive unit of the utility model is achieved is: comprise hollow fibre membrane component, a pot type housing and flatly be arranged on the film cleaning part in the said pot type housing; Said hollow fibre membrane component is a pillar hydrophobic hollow fiber membrane element; Evenly be furnished with the described pillar hydrophobic hollow fiber membrane element of many groups in the said pot type housing; Be provided with the support bar parallel in every group of pillar hydrophobic hollow fiber membrane element with a pipe core; The hole of uniform distribution some amount on the tube wall of said pipe core; All occupied region areas in this hole are greater than or equal the cross-sectional area of said pipe core, and the top of said pipe core is provided with plug; Hollow-fibre membrane in every group of pillar hydrophobic hollow fiber membrane element is rolled into column through after the yarns, the sealed at both ends casting; Relatively independent between every group of pillar hydrophobic hollow fiber membrane element; The top and bottom of the said pillar hydrophobic hollow fiber membrane element of a part are provided with the bilateral end socket, and the top and bottom of the said pillar hydrophobic hollow fiber of another part membrane element are provided with the threeway end socket; The pipe end of the bilateral end socket on the said pillar hydrophobic hollow fiber membrane element of many groups and the pipe end of threeway end socket interconnect assembling respectively and form path on same horizontal plane; The pillar hydrophobic hollow fiber membrane element that is provided with the threeway end socket all is positioned at the inwall place of said pot type housing; Wherein, the end socket of the top and bottom of the symmetric threeway end socket pillar of two groups on diagonal lines membrane element all respectively is provided with a free pipe end; Be provided with an aperture in the position that aligns with each free pipe end on the wall of pot type housing, said free pipe end stretches out housing from the aperture that aligns with it; The water conservancy diversion that the top and bottom of the said pillar hydrophobic hollow fiber membrane element of many groups are provided with pillar hydrophobic hollow fiber membrane element supports or supporting structure; Said film cleaning part comprises that flatly being arranged on one in the tank body cleans water service pipe and a plurality of wash tube, and the tube wall of said wash tube is provided with a plurality of nozzles, and said a plurality of wash tubes are integrated and connected to said water service pipe.
The technical scheme that is achieved of a kind of new and effective multistage pot type gas-to-liquid contact film absorptive unit of the utility model is, by multistage above-mentioned efficient single-stage pot type gas-to-liquid contact film absorptive unit parallel connection and/or connect integrated; Wherein, the pipe core of mutual placed in-line pot type gas-to-liquid contact film absorptive unit is communicated with, and is provided with the water conservancy diversion supporting structure between the placed in-line in twos pot type gas-to-liquid contact film absorptive unit.
The utility model is compared with existing form membrane contactor, and the beneficial effect that is had is:
Because the pipe core tube wall in a kind of new and effective pot type gas-to-liquid contact film absorptive unit of the utility model is a porous, be convenient to gas phase and flow from the pipe tap free shuttling of pipe core, vapour lock is low, and it is big to handle gas flow, and efficient is high; The pillar membrane element with certain tamped density, be uniformly distributed in the pot type housing; The gas-liquid two-phase uniform distribution, effectively contact area is big, rate of mass transfer is fast; The gas-liquid two-phase flow velocity is independently controlled, and can in relative broad range, operate; Can realize on-line cleaning, decelerating membrane pollution to the inside and outside surface of hollow-fibre membrane; The film absorptive unit can form modularization, is easy to multistage integrated amplification, is convenient to through engineering approaches and uses.
Description of drawings
Fig. 1 a is a pillar hydrophobic hollow fiber membrane element synoptic diagram in the utility model pot type gas-to-liquid contact film absorptive unit;
Fig. 1 b is the pillar hydrophobic hollow fiber membrane element synoptic diagram that has the threeway end socket;
Fig. 1 c is the pillar hydrophobic hollow fiber membrane element synoptic diagram that has the bilateral end socket;
Fig. 1 d is the end socket mode of connection synoptic diagram of 9 groups of pillar membrane elements in the single-stage pot type film absorptive unit;
Fig. 2 a is the structural representation of water conservancy diversion back up pad in the utility model;
Fig. 2 b is the structural representation of film cleaning part in the utility model;
Fig. 2 c is the structural representation of base plate in the utility model;
Fig. 3 a is a single-stage pot type film absorptive unit operational mode synoptic diagram in the utility model;
Fig. 3 b is the back-flushing operation pattern diagram of the utility model single-stage pot type film absorptive unit;
The synoptic diagram of Fig. 3 c after to be the multistage pot type film of the utility model absorptive unit by two-stage series connection integrated.
Among the figure:
1---hollow-fibre membrane 2---yarn
3---pipe core 4---cast material
5--- support bar 6,7 logical end sockets
8---pipe tap 9,10---threeway end socket
11---water conservancy diversion back up pad 12---draw-in groove hole
13---aperture 14---film cleaning part
15---wash tube 16---nozzle
17---water service pipe 18---base plate
19---clean-out system outlet 20---pot type housing
21---clean-out system import 22,23,25,26---liquid phase is imported and exported
24---plug
I---first step pot type film absorptive unit II---second stage pot type film absorptive unit
A---liquid phase B---clean-out system
C---gas phase
Embodiment
Below in conjunction with accompanying drawing and embodiment the utility model is done to describe in further detail.
A kind of new and effective single-stage pot type gas-to-liquid contact film absorptive unit of the utility model comprises pillar hydrophobic hollow fiber membrane element, a pot type housing and flatly be arranged on the film cleaning part in the said pot type housing; Shown in Fig. 3 a; Described pillar hydrophobic hollow fiber membrane elements are organized in evenly loose being furnished with more in the said pot type housing 20; Shown in Fig. 1 a; Be provided with the support bar 5 parallel in every group of pillar hydrophobic hollow fiber membrane element with a pipe core 3, the pipe tap 8 of uniform distribution some amount on the tube wall of said pipe core 3, and these pipe tap 8 occupied region areas are greater than or equal the cross-sectional area of said pipe core 3; Hollow-fibre membrane 1 in every group of pillar hydrophobic hollow fiber membrane element is rolled into column after through yarn 2 braidings; Two ends are with cast material 4 sealing casting; The hollow-fibre membrane 1 that said pillar hydrophobic hollow fiber membrane element is woven by yarn 2, pipe core 3, support bar 5 adopt a cast molding of technology of these known, and be relatively independent between every group of pillar hydrophobic hollow fiber membrane element; For guaranteeing that hollow-fibre membrane 1 is evenly distributed in the surrounding space of pipe core 3; Hollow-fibre membrane all is through the evenly accurate braiding of yarn 2; This structure helps gas uniform distribution between hollow-fibre membrane; Help the effective contact area maximization of gas-liquid, can prevent effectively that hollow-fibre membrane is combined into pencil.But want control center's pipe 3 suitable with the diameter ratio of hollow-fibre membrane 1 cast; If both diameters than with inner diameter of centerpipe than hour; Hollow-fibre membrane tow around the pipe core 3 can thicken so; Not only increase gas phase unrestricted flow resistance, also reduced the assimilated efficiency of unit tubular fibre membrane area.Therefore, the utility model is controlled at pipe core 3 and pillar membrane element diameter ratio between 1: 5 to 1: 2, and the pipe core diameter is that DN25 is between the DN80.
Every group of pillar hydrophobic hollow fiber membrane element, its porous-film maximum diameter of hole scope are 0.01 μ m~2.0 μ m, and wall thickness range is 20 μ m~200 μ m, and porosity ranges is 30%~80%; Hollow-fibre membrane mean diameter scope is 100 μ m~3000 μ m.
The structure of said film cleaning part is shown in Fig. 2 b; Comprise a plurality of wash tubes 15; The tube wall of said wash tube 15 is provided with a plurality of nozzles 16; Said a plurality of wash tube 15 is uniformly distributed with and integrated being connected on the said water service pipe 17 according to a determining deviation, can evenly spray clean-out system to hollow-fibre membrane, realizes the cleaning to the tubular fibre film outer surface.
Shown in Fig. 1 b; The top and bottom of the said pillar hydrophobic hollow fiber membrane element of a part are provided with bilateral end socket 6,7; Shown in Fig. 1 c; The top and bottom of the said pillar hydrophobic hollow fiber of another part membrane element are provided with threeway end socket 9,10; Be the angle of 90 °, 135 ° and 135 ° or 90 °, 90 ° and 180 ° between each pipe end of threeway end socket respectively, the angle between said bilateral end socket and the threeway end socket pipe end can be adjusted according to mode of connection between each pillar membrane element, is not unalterable.Fig. 1 d shows the end socket mode of connection synoptic diagram (circle that has sequence number 01-09 shown in the figure is not for representing the end socket of 9 groups of pillar membrane elements) of 9 groups of pillar membrane elements in the single-stage pot type film absorptive unit:
01 and 07 is the threeway end socket: angle is 90 °, 135 °, 135 ° between the pipe end;
04 and 06 is the threeway end socket: angle is 90 °, 90 °, 180 ° between the pipe end;
02,05,08 is the bilateral end socket, and angle is 180 ° between the pipe end;
03 and 09 is the bilateral end socket, and angle is 90 ° between the pipe end;
01 and 07 respectively is provided with a free pipe end.
The bilateral end socket 6 of the bilateral end socket 7 of 9 groups of said pillar hydrophobic hollow fiber membrane element upper ends and the pipe end of threeway end socket 10, lower end and the pipe end of threeway end socket 9 interconnect assembling respectively and form path; As connecting among Fig. 1 d shown in the line between the relevant end socket (circle); The benefit that connects like this is the idle space that has reduced feedwater line, increases the tamped density of film; Wherein, the pillar hydrophobic hollow fiber membrane element that is provided with the threeway end socket all is positioned at the inwall place of said pot type housing 20; The threeway end socket is equipped with a free pipe end; Shown in 100 among Fig. 1 d; The end socket of the top and bottom of two groups of symmetric threeway end socket pillar membrane elements on the diagonal lines all respectively is provided with a free pipe end, and all the other membrane element end socket pipe ends all form closed circuit, up and down totally 4 free pipe ends; Be provided with an aperture in the position that aligns with the free pipe end of each said threeway end socket on the wall of pot type housing 20; Promptly corresponding respectively 4 free pipe end places open 4 apertures; Said free pipe end stretches out housing from the aperture that aligns with it, these apertures are respectively as the liquid phase import and export; No matter be bilateral or threeway end socket with said pillar hydrophobic hollow fiber membrane element between can be to be threaded or the interlocking draw-in groove form such as is connected and all can.Shown in Fig. 1 b; Liquid phase A flow path is in the band bilateral end socket membrane element: the left side opening of bilateral end socket 7 flows into liquid phase A; A part is from top to bottom flowed through in the hollow-fibre membrane 1, and another part liquid phase A will be that the next one membrane element that is connected provides liquid phase A through the right opening of this bilateral end socket 7; At this moment, the bilateral end socket 6 of lower end will be received last one from left side opening and coupledly meet effusive liquid phase A in the effusive liquid phase A of membrane element and this membrane element hollow-fibre membrane 1 and discharge through the right opening of this bilateral end socket 6 in the lump.Gas phase C is diffused into hollow-fibre membrane 1 outside surface after flowing out through the pipe tap on the pipe core 38.
The water conservancy diversion that the top and bottom of the said pillar hydrophobic hollow fiber membrane element of many groups are provided with pillar hydrophobic hollow fiber membrane element supports or supporting structure; Shown in Fig. 2 a; Said water conservancy diversion supporting structure is one to be positioned at the water conservancy diversion back up pad 11 at said pipe core top; Said water conservancy diversion back up pad 11 is provided with pipe core locator card slotted eye 12 and gas phase pod apertures 13; Wherein, draw-in groove hole 12 can guarantee that not only gas phase C can flow into next stage pot type gas-to-liquid contact film absorptive unit in the pipe core 3, also plays the effect of sharing next stage pot type gas-to-liquid contact film absorptive unit weight.The aperture that is uniformly distributed with on the water conservancy diversion back up pad 11 is the passage that flows to next stage pot type gas-to-liquid contact film absorptive unit for effusive gas phase C from the pipe tap 8 of pipe core; Therefore this aperture is a gas phase pod apertures 13; The aperture of gas phase pod apertures 13 and quantity are wanted suitably; Whole gas phase pod apertures 13 occupied region areas are greater than on the said pipe core the occupied region area of whole pipe tap 8 on the said water conservancy diversion back up pad, can circulate smoothly to realize big flow low pressure gas phase.Shown in Fig. 2 c, said supporting structure is one to be positioned at the support base plate 18 of said pipe core bottom, is provided with pipe core locator card slotted eye 12 on the said support base plate 18 equally.Certainly, support on the base plate 18 with water conservancy diversion back up pad 11 on pipe core locator card slotted eye 12 be that quantity equates, placement position is one to one, thereby plays effect fixing and support pillar hydrophobic hollow fiber membrane element.
The running status of the utility model pot type gas-to-liquid contact film absorptive unit comprises forward operation, back-flushing operation and three kinds of patterns of cleaning operation, through the optimization design of automatic control, can realize the timing automatic switchover operation.
Fig. 3 a is the utility model single-stage pot type film absorptive unit (forward) operational mode synoptic diagram, and wherein: A is a liquid phase, and B is a clean-out system, and C is a gas phase, and 19 is the clean-out system outlet, and 21 is the clean-out system import, and 22,23,25,26 are the liquid phase import and export, and 24 is plug.Said single-stage pot type film absorptive unit mainly comprises parts such as pillar hydrophobic hollow fiber membrane element, water conservancy diversion back up pad 11, base plate 18, film cleaning part 14, pot type housing 20; Pillar hydrophobic hollow fiber membrane element forms more than one group pillar membrane elements through bilateral and the assembling of threeway end socket; Certainly; The structure of end socket can have various ways, includes but not limited to bilateral end socket described in the present invention and threeway end socket.Wherein pillar hydrophobic hollow fiber membrane element fills in the pot type housing 20 with certain tamped density.The hollow-fibre membrane TV that the pillar of group more than its tamped density is meant hydrophobic hollow fiber membrane elements comprise accounts for the per-cent of enclosure interior spatial volume, and hollow-fibre membrane TV that many groups of described pillar hydrophobic hollow fiber membrane elements in the said pot type housing are comprised and the per-cent between the said pot type vome of shell are 3%~50%.When the utility model pot type gas-to-liquid contact film absorptive unit got into forward mode of operation, it was closing conditions that liquid phase imports and exports 25 and 26.A kind of liquid phase A gets into pot type film absorptive units from import 22, imports and exports 23 from liquid phase behind the hollow-fibre membrane of the pillar hydrophobic hollow fiber membrane element that is connected through a plurality of bilaterals or threeway end socket of flowing through and flows out.Liquid phase A is from top to down through flowing through in the hollow-fibre membrane; After gas phase C then is pipe tap 8 outflows through pipe core 3; Along hollow-fibre membrane outside towards on be diffused into the gas phase pod apertures 13 of water conservancy diversion back up pad 11 the aperture discharge; That is to say that the flow direction of gas-liquid phase is opposite in the tank body, well-known, to flow to when opposite both mass-transfer efficiency the highest when two-phase medium.Cleaning process is after clean-out system B can regularly flow into film cleaning part 14 from clean-out system import 21, to be sprayed at hollow-fibre membrane 2 surfaces and to wash, to prevent that impurity causes irreversible pollution to hollow-fibre membrane in the gas phase.Last clean-out system B discharges from tank shell clean-out system outlet 19.
Fig. 3 b shows the utility model single-stage pot type gas-to-liquid contact film absorptive unit back-flushing operation pattern.The visible pillar hydrophobic hollow fiber membrane element of part of analysing and observe at Fig. 3 b fills in the pot type housing with certain tamped density through many groups pillar membrane element that bilateral and threeway end socket assemble.When pot type gas-to-liquid contact film absorptive unit got into the recoil operational mode, it was closing conditions that liquid phase imports and exports 22 and 23.A kind of liquid phase A imports and exports 25 from liquid phase and gets into pot type gas-to-liquid contact film absorptive units, imports and exports 26 from liquid phase behind the hollow-fibre membrane of the pillar hydrophobic hollow fiber membrane element that is connected through a plurality of bilaterals or threeway end socket of flowing through and flows out.The flow direction and the forward mode of operation of liquid phase in hollow-fibre membrane is opposite, and such operation can rinse out the impurity that sticks to the hollow-fibre membrane internal surface, prevents that long-play from causing irreversible pollution to hollow-fibre membrane.Clean-out system B also is that periodic the inflow from clean-out system import 21 is sprayed at hollow-fibre membrane 2 surfaces and washes, and discharges from tank shell outlet 19 at last.
A kind of new and effective multistage pot type gas-to-liquid contact film absorptive unit of the utility model is promptly by the parallel connection of multistage above-mentioned single-stage pot type gas-to-liquid contact film absorptive unit and/or connect integrated; Wherein, the pipe core of mutual placed in-line pot type gas-to-liquid contact film absorptive unit is communicated with, and is provided with the water conservancy diversion supporting structure between the placed in-line in twos pot type gas-to-liquid contact film absorptive unit.In addition, the series connection of film absorptive unit and/or parallel way have multiple, comprise the series-parallel mutual combination of water route SP and gas circuit, i.e. gas circuit when series connection, the series connection in water route is during with parallelly connected and gas circuit parallel connection, the series connection in water route and and the four kinds of basic modes of allying the communists.Said water route and gas circuit are respectively the paths of liquid phase and gas phase circulation.Can select the mode of connection between the multistage pot type gas-to-liquid contact film absorptive unit according to concrete working condition in a word.Fig. 3 c is one of numerous mode of connection.
In multistage pot type gas-to-liquid contact film absorptive unit, said water conservancy diversion supporting structure is the water conservancy diversion back up pad that is positioned at said pipe core top, and said water conservancy diversion back up pad is provided with the gentle phase pod apertures of pipe core locator card slotted eye; Said supporting structure is the support base plate that is set in place in each pot type gas-to-liquid contact film absorptive unit bottom of lowermost layer, and said support base plate is provided with pipe core locator card slotted eye.A kind of intergration model of two-stage series connection has been shown among Fig. 3 c, mainly is to have first step pot type gas-to-liquid contact film absorptive unit I and second stage pot type gas-to-liquid contact film absorptive unit II assembled in series to form.Compare with single-stage pot type gas-to-liquid contact film absorptive unit pattern, the main difference part is that the pipe core top of first step pot type gas-to-liquid contact film absorptive unit I does not have plug 24, just communicates between the pipe core of two pot type gas-to-liquid contact film absorptive units.The flow path of gas phase C is in the middle of to be a part of gas phase from the pipe tap 8 of the pipe core of first step pot type gas-to-liquid contact film absorptive unit I be diffused into the pot type housing of first step pot type gas-to-liquid contact film absorptive unit I, and another part gas phase is diffused in the pot type housing of second stage pot type gas-to-liquid contact film absorptive unit II from its pipe tap 8 after flowing to the pipe core of second stage pot type gas-to-liquid contact film absorptive unit II again; The intravital gas phase C of pot type shell that is diffused into first step pot type gas-to-liquid contact film absorptive unit I can discharge through the back of flowing through in the pot type housing of second stage pot type gas-to-liquid contact film absorptive unit II of the gas phase pod apertures 13 on the water conservancy diversion back up pad 11.In addition, the clean-out system that cleans operation is discharged through clean-out system outlet 19.
Although top combination figure is described the utility model; But the utility model is not limited to above-mentioned embodiment, and above-mentioned embodiment only is schematically, rather than restrictive; Those of ordinary skill in the art is under the enlightenment of the utility model; Under the situation that does not break away from the utility model aim, can also make a lot of distortion, these all belong within the protection of the utility model.

Claims (8)

1. a new and effective single-stage pot type gas-to-liquid contact film absorptive unit comprises hollow fibre membrane component, it is characterized in that:
Said hollow fibre membrane component is a pillar hydrophobic hollow fiber membrane element;
Also comprise a pot type housing and flatly be arranged on the film cleaning part in the said pot type housing;
Evenly be furnished with the described pillar hydrophobic hollow fiber membrane element of many groups in the said pot type housing; Be provided with the support bar parallel in every group of pillar hydrophobic hollow fiber membrane element with a pipe core; The hole of uniform distribution some amount on the tube wall of said pipe core; All occupied region areas in this hole are greater than or equal the cross-sectional area of said pipe core, and the top of said pipe core is provided with plug;
Hollow-fibre membrane in every group of pillar hydrophobic hollow fiber membrane element is rolled into column through after the yarns, the sealed at both ends casting; Relatively independent between every group of pillar hydrophobic hollow fiber membrane element;
The top and bottom of the said pillar hydrophobic hollow fiber membrane element of a part are provided with the bilateral end socket, and the top and bottom of the said pillar hydrophobic hollow fiber of another part membrane element are provided with the threeway end socket; The pipe end of the bilateral end socket on the said pillar hydrophobic hollow fiber membrane element of many groups and the pipe end of threeway end socket interconnect assembling respectively and form path on same horizontal plane; The pillar hydrophobic hollow fiber membrane element that is provided with the threeway end socket all is positioned at the inwall place of said pot type housing; Wherein, the end socket of the top and bottom of the symmetric threeway end socket pillar of two groups on diagonal lines membrane element all respectively is provided with a free pipe end; Be provided with an aperture in the position that aligns with each free pipe end on the wall of pot type housing, said free pipe end stretches out housing from the aperture that aligns with it;
The water conservancy diversion that the top and bottom of the said pillar hydrophobic hollow fiber membrane element of many groups are provided with pillar hydrophobic hollow fiber membrane element supports or supporting structure;
Said film cleaning part comprises that flatly being arranged on one in the tank body cleans water service pipe and a plurality of wash tube, and the tube wall of said wash tube is provided with a plurality of nozzles, and said a plurality of wash tubes are integrated and connected to said water service pipe.
2. according to the said new and effective single-stage pot type gas-to-liquid contact film absorptive unit of claim 1; It is characterized in that; Said water conservancy diversion supporting structure is one to be positioned at the water conservancy diversion back up pad at said pipe core top, and said water conservancy diversion back up pad is provided with the gentle phase pod apertures of pipe core locator card slotted eye; Said supporting structure is one to be positioned at the support base plate of said pipe core bottom, and said support base plate is provided with pipe core locator card slotted eye.
3. according to the said new and effective single-stage pot type gas-to-liquid contact film absorptive unit of claim 1; It is characterized in that; Every group of pillar hydrophobic hollow fiber membrane element; Its porous-film maximum diameter of hole scope is 0.01 μ m~2.0 μ m, and wall thickness range is 20 μ m~200 μ m, and porosity ranges is 30%~80%; Hollow-fibre membrane mean diameter scope is 100 μ m~3000 μ m.
4. according to the said new and effective single-stage pot type gas-to-liquid contact film absorptive unit of claim 1; It is characterized in that hollow-fibre membrane TV that many groups of described pillar hydrophobic hollow fiber membrane elements in the said pot type housing are comprised and the per-cent between the said pot type vome of shell are 3%~50%.
5. according to the said new and effective single-stage pot type gas-to-liquid contact film absorptive unit of claim 2, it is characterized in that the occupied region area of gas phase pod apertures is greater than total hole area of said central tube cinclides on the said water conservancy diversion back up pad.
6. according to the said new and effective single-stage pot type gas-to-liquid contact film absorptive unit of claim 1, it is characterized in that the occupied region area of said nozzle is less than or equal to the cross-sectional area of wash tube.
7. a new and effective multistage pot type gas-to-liquid contact film absorptive unit is characterized in that, by multistage pot type gas-to-liquid contact film absorptive unit as claimed in claim 1 parallel connection and/or connect integrated; Wherein, the pipe core of mutual placed in-line pot type gas-to-liquid contact film absorptive unit is communicated with, and is provided with the water conservancy diversion supporting structure between the placed in-line in twos pot type gas-to-liquid contact film absorptive unit.
8. according to the said new and effective multistage pot type gas-to-liquid contact film absorptive unit of claim 7; It is characterized in that; Said water conservancy diversion supporting structure is the water conservancy diversion back up pad that is positioned at said pipe core top, and said water conservancy diversion back up pad is provided with the gentle phase pod apertures of pipe core locator card slotted eye; Said supporting structure is the support base plate that is set in place in each pot type gas-to-liquid contact film absorptive unit bottom of lowermost layer, and said support base plate is provided with pipe core locator card slotted eye.
CN 201020641558 2010-12-05 2010-12-05 Novel high-efficiency single-stage or multistage tank type gas-liquid contact membrane absorption unit Expired - Fee Related CN202116351U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103349914A (en) * 2013-07-16 2013-10-16 杭州艾吉克膜科技有限公司 Hollow-fiber membrane contactor
CN105561630A (en) * 2016-03-10 2016-05-11 浙江大学 Hollow fibrous membrane extractor
CN108793392A (en) * 2018-06-16 2018-11-13 江苏吉隆环保科技有限公司 A kind of MBR films special multi-purpose way inner liner support pipe
CN112362613A (en) * 2020-10-22 2021-02-12 中国科学院南海海洋研究所 Low-power-consumption small-volume long-term-duty deep-sea trace gas in-situ measuring instrument
CN112752600A (en) * 2018-09-27 2021-05-04 Dic株式会社 Degassing system, method for degassing liquid, degassing module, method for manufacturing degassing system, and method for producing natural resource

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103349914A (en) * 2013-07-16 2013-10-16 杭州艾吉克膜科技有限公司 Hollow-fiber membrane contactor
CN105561630A (en) * 2016-03-10 2016-05-11 浙江大学 Hollow fibrous membrane extractor
CN108793392A (en) * 2018-06-16 2018-11-13 江苏吉隆环保科技有限公司 A kind of MBR films special multi-purpose way inner liner support pipe
CN112752600A (en) * 2018-09-27 2021-05-04 Dic株式会社 Degassing system, method for degassing liquid, degassing module, method for manufacturing degassing system, and method for producing natural resource
CN112362613A (en) * 2020-10-22 2021-02-12 中国科学院南海海洋研究所 Low-power-consumption small-volume long-term-duty deep-sea trace gas in-situ measuring instrument

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