CN202011796U - Acetylene sludge washing dechlorination device - Google Patents

Acetylene sludge washing dechlorination device Download PDF

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Publication number
CN202011796U
CN202011796U CN2010206754349U CN201020675434U CN202011796U CN 202011796 U CN202011796 U CN 202011796U CN 2010206754349 U CN2010206754349 U CN 2010206754349U CN 201020675434 U CN201020675434 U CN 201020675434U CN 202011796 U CN202011796 U CN 202011796U
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China
Prior art keywords
washing
water
carbide slag
reuse
pond
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Expired - Fee Related
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CN2010206754349U
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Chinese (zh)
Inventor
陈应强
冯华军
沈东升
宋二喜
张弛
廖�燕
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Zhejiang Gongshang University
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Zhejiang Gongshang University
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Priority to CN2010206754349U priority Critical patent/CN202011796U/en
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Abstract

The utility model discloses an acetylene sludge washing dechlorination device, which comprises a washing system, a solid-liquid separation system, a wastewater recycling system and a circulation pipeline, wherein the washing system comprises a round washing tank, a slurry pump and an agitating instrument; the solid-liquid separation system comprises a radial flow type sedimentation tank and a belt filter press; a recycle water circulating system comprises an electrolysis dechlorination tank and a recycle water collecting tank; and the circulation pipeline comprises a slurry circulation pipeline, a recycle water circulation pipeline, a slurry valve and a filter cake conveyor belt. By the additional arrangement of the wastewater recycling system, the water consumption per unit of acetylene sludge washing is greatly lowered, and wastewater discharge of washing is avoided; and by the additional arrangement of a filter pressing dehydration device, the dechlorination effect is improved.

Description

A kind of carbide slag washing dechlorination device
Technical field
The utility model relates to carbide slag washing process field, especially a kind of carbide slag washing dechlorination device.
Technical background
Solid waste carbide slag for the generation of PVC enterprise, because entering of a large amount of chlorine-contained wastewaters that discharge in the chlor-alkali Workshop Production process, wherein containing very high salinity (mainly is villaumite, reach as high as 0.2%), make the treatment and disposal and the recycling of carbide slag run into various difficulties, such as utilizing carbide slag to produce the cement field as calcareous raw material, national standard has just been done clearly regulation to the content of chlorine in the calcareous raw material, requires it to surpass 0.03%.Therefore necessary carbide slag is washed pre-treatment, reduce the content of objectionable constituent such as villaumite.
Mentioning in the Chinese invention patent 03825874.9 sprays water flying ash when mobile on pressure filter simultaneously washes desalination, wash desalination immediately, have advantages such as equipment is simple, easy and simple to handle, occupation of land is little, but there are associated problem such as washing institute water requirement is big, dechlorination effect is not good in this patented technology.
Adopt secondary water washing technology in China's utility model patent 200820130430.5, equipment adopts an agitated pool+primary sedimentation basin+secondary stirring pond+secondary sedimentation basins to be provided with, there are a plurality of problems in this equipment: 1, do not have washing cycling utilization of wastewater scheme, produce a large amount of waste water, increased the washing cost and the pressure of waste water control; 2, patent adopts natural gravity to be deposited in the mud-water separation effect and is much worse than press filtration, dewatering such as centrifugal greatly, thereby will cause the decline of washing dechlorination effect or the rising of water consumption.
Summary of the invention
The purpose of this utility model is a kind of water-saving of design and dechlorination effect is good, simple in equipment, floor space are little, stable carbide slag washing dechlorination device, and because the waste water salt concentration after the washing is higher, to cause secondary pollution after draining into water body, so the utility model carries out recycle to washing waste water under the situation that does not influence the washing effect.
A kind of carbide slag water washing device comprises water wash system, solid-liquid separation system, waste water reuse system and circulation line, wherein has circulation line to connect between water wash system, the solid-liquid separation system, and carbide slag slurry is reciprocation cycle between each device.Have pipeline to interconnect between solid-liquid separation system and the waste water reuse system, the waste water that solid-liquid separation system produces by waste water reuse system purify store after again as the washing water circulation use of water wash system.
Described water wash system comprises circular washing pool, slush pump and stirring instrument.
Described solid-liquid separation system comprises radical sedimentation basin and belt filter press.
Described waste water reuse system comprises electrolysis dechlorination pond and reuse water collecting tank.Wherein electrolysis dechlorination pond comprises rectangular parallelepiped pond body, negative plate, positive plate and gas sweetening collection device, and it is parallel that the limit is grown in negative plate, positive electricity pole plate and pond, according to actual requirement of engineering configured electrodes plate quantity.The reuse water collecting tank is used to collect the waste water after electrolysis dechlorination pond purifies, and water wash system washing water is provided.
Described circulation line comprises slurries circulation line, reuse water circulation line.
During the operation of the utility model device, the carbide slag slurries that factory discharges is sent into circular washing pool, use from the reuse water mixing fresh supplemented water of reuse water collecting tank and wash, starting the stirring instrument simultaneously stirs, make solid-liquid fully contact mutually, the slurries after stirring pump into radical sedimentation basin by slush pump.Slurries obtain supernatant liquor and carbide slag slurries in the radical sedimentation basin natural sedimentation, and supernatant liquor goes to electrolysis dechlorination pond to flow through between cathode-anode plate, and villaumite is generated chlorine and enters into the gas sweetening collection device with other electrolytic waste gas by electrolysis, obtains pure gas.Waste water flows into the reuse water collecting tank after removing chlorine, the carbide slag that precipitates detects whether reach the washing requirement, the carbide slag slurries that does not reach the washing requirement flows back to circular washing pool, the slurries that reach the washing requirement enter the belt filter press dehydration, obtain filtrate and carbide slag filter cake, filtrate still flows to electrolysis dechlorination pond, and the carbide slag filter cake is delivered to the warehouse by belt conveyor.
The utlity model has following beneficial effect:
1. increased waste water reuse system, the unit's of greatly reducing carbide slag washing water loss, and do not wash effluxing of waste water;
2. increase the filter-press dehydration device, improved dechlorination effect.
Description of drawings
Fig. 1 is the utility model schematic representation of apparatus.
Fig. 2 is the electrolysis dechlorination pond side-view of the utility model device.
Fig. 3 is the electrolysis dechlorination pond A-A sectional view of the utility model device.
Embodiment
Embodiment 1
A kind of carbide slag water washing device comprises water wash system, solid-liquid separation system, waste water reuse system and circulation line, and water wash system comprises a circular washing pool 1, slush pump 12 and stirs instrument 2; Solid-liquid separation system comprises a radical sedimentation basin 3 and a belt filter press 4; The reuse water recycle system comprises electrolysis dechlorination pond 6 and a reuse water collecting tank 5, and wherein electrolysis dechlorination pond comprises rectangular parallelepiped pond body 16, negative plate 19, two positive plates 17 and gas sweetening collection devices 18; Circulation line comprises slurries circulation line, reuse water circulation line, Parallel Slide Valves 15 and filter cake conveying belt 8, the slurries circulation line comprises first pipeline 7, second pipeline 11, the 3rd pipeline 14 and Parallel Slide Valves 15, and the reuse water circulation line comprises the 4th pipeline 9, the 5th pipeline 10, the 6th pipeline 13.Wherein connected by the slurries circulation line between water wash system, the solid-liquid separation system, carbide slag slurry is reciprocation cycle between each device, when the washing effect reaches requirement, opens Parallel Slide Valves 15, and slurries enter solid-liquid separation system.Interconnect by the reuse water circulation line between solid-liquid separation system and the waste water reuse system, the waste water that solid-liquid separation system produces by waste water reuse system purify store after again as the washing water circulation use of water wash system.
As shown in Figure 1, when suite of equipment of the present invention moves, carbide slag slurry at first enters circular washing pool 1, use from the reuse water mixing fresh supplemented water of reuse pool 5 and once wash, carbide slag and rinse water thorough mixing, make soluble components strippings such as villaumite, after finishing, washing stops to stir, by slush pump 12 suspension liquid is pumped into radical sedimentation basin 3, make the carbide slag natural sedimentation, obtain supernatant liquor and carbide slag slurries, supernatant liquor dechlorinates through electrolysis and flows into reuse pools 5 after handle in pond 6, and the carbide slag slurries that does not reach the washing requirement flows back to circular washing pool through second pipeline 11.The slurries that reach the washing requirement obtain filtrate and carbide slag filter cake after the 3rd pipeline 14 enters belt filter press 4 dehydrations, filtrate still flows to electrolysis dechlorination pond 6 through the 4th pipeline 9, and the carbide slag filter cake is delivered to the warehouse by belt conveyor 8.
Embodiment 2
Device arranges that with embodiment 1 the washing object is the carbide slag that Shaoxing PVC enterprise produces, and this carbide slag chloride ion content reaches 0.22%.Reuse water and fresh water ratio are that the selected electrolytic solution in electrolysis in 4: 1 dechlorination pond is that concentration is 4% ca nitrate soln in the circular washing pool, once washing dechlorination back carbide slag is chloride is 0.13%, secondary water washing dechlorination back carbide slag is chloride to be 0.08%, reaches into the kiln requirement after calculating by the cement slurry volume.Carbide slag washing water consumption rate per ton is 0.4t.
Comparative Examples
The device layout is compared with embodiment 2 and is lacked the reuse water recycle system, promptly lack electrolysis dechlorination pond 6 and reuse water collecting tank 5 and respective line 9,10,13, then when washing same electrical rock ballast, because of the carbide slag chloride ion content too high, have to carry out secondary water washing, the washing water can only replenish with fresh water, and carbide slag washing water consumption rate then per ton is 2t.

Claims (3)

1. a carbide slag water washing device comprises water wash system, solid-liquid separation system, waste water reuse system and circulation line, it is characterized in that:
Described water wash system comprises circular washing pool (1), slush pump (12) and stirs instrument (2);
Described solid-liquid separation system comprises radical sedimentation basin (3) and belt filter press (4);
Described waste water reuse system comprises electrolysis dechlorination pond (6) and reuse water collecting tank (5);
Described circulation line comprises slurries circulation line, reuse water circulation line, Parallel Slide Valves (15) and filter cake conveying belt (8);
Described circular washing pool (1), slush pump (2), radical sedimentation basin (3), Parallel Slide Valves (15), belt filter press (4) connect successively, and described stirring instrument (2) is located in the circular washing pool (1).
2. carbide slag water washing device according to claim 1 is characterized in that: described electrolysis dechlorination pond comprises pond body (16), is provided with negative plate (19) and positive plate (17) in the body of pond.
3. carbide slag water washing device according to claim 2 is characterized in that: be connected with gas sweetening collection device (18) on the pond body (16).
CN2010206754349U 2010-12-22 2010-12-22 Acetylene sludge washing dechlorination device Expired - Fee Related CN202011796U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010206754349U CN202011796U (en) 2010-12-22 2010-12-22 Acetylene sludge washing dechlorination device

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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104561610A (en) * 2014-12-26 2015-04-29 河南豫光锌业有限公司 Method and device for treating washing water in refined indium production
CN104947376A (en) * 2014-03-27 2015-09-30 海尔集团公司 Washing machine flocculation cleaning stirring device and control method
CN106311719A (en) * 2016-08-22 2017-01-11 四川龙蟒钛业股份有限公司 Recycling method for carbide slag
CN108439553A (en) * 2018-04-20 2018-08-24 武汉大学 A kind of Electrochemical oxidation device for removing chlorion in water removal
CN109701991A (en) * 2018-12-26 2019-05-03 河南省福可思环保科技有限公司 From the method for water treatment agent polyaluminium chloride waste residue recycling bauxite resource
CN111205007A (en) * 2020-02-26 2020-05-29 广东新龙海洋装备科技有限公司 Sea sand dechlorination equipment and sea sand dechlorination method
CN112777906A (en) * 2020-12-22 2021-05-11 江山市虎鼎环保科技有限公司 Efficient filter pressing process for household garbage incineration fly ash washing slurry

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104947376A (en) * 2014-03-27 2015-09-30 海尔集团公司 Washing machine flocculation cleaning stirring device and control method
CN104947376B (en) * 2014-03-27 2018-08-07 青岛海尔洗衣机有限公司 A kind of washing machine flocculation cleaning agitating device and control method
CN104561610A (en) * 2014-12-26 2015-04-29 河南豫光锌业有限公司 Method and device for treating washing water in refined indium production
CN106311719A (en) * 2016-08-22 2017-01-11 四川龙蟒钛业股份有限公司 Recycling method for carbide slag
CN108439553A (en) * 2018-04-20 2018-08-24 武汉大学 A kind of Electrochemical oxidation device for removing chlorion in water removal
CN109701991A (en) * 2018-12-26 2019-05-03 河南省福可思环保科技有限公司 From the method for water treatment agent polyaluminium chloride waste residue recycling bauxite resource
CN111205007A (en) * 2020-02-26 2020-05-29 广东新龙海洋装备科技有限公司 Sea sand dechlorination equipment and sea sand dechlorination method
CN111205007B (en) * 2020-02-26 2023-09-22 广东新龙海洋装备科技有限公司 Sea sand chlorine removal equipment and sea sand chlorine removal method
CN112777906A (en) * 2020-12-22 2021-05-11 江山市虎鼎环保科技有限公司 Efficient filter pressing process for household garbage incineration fly ash washing slurry
CN112777906B (en) * 2020-12-22 2022-04-22 江山市虎鼎环保科技有限公司 Efficient filter pressing process for household garbage incineration fly ash washing slurry

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Granted publication date: 20111019

Termination date: 20131222