CN201866421U - Corrosion-preventing and oxygen-isolating self-cleaning PPR (pentatricopeptide repeats) compound pipe - Google Patents

Corrosion-preventing and oxygen-isolating self-cleaning PPR (pentatricopeptide repeats) compound pipe Download PDF

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Publication number
CN201866421U
CN201866421U CN2010206406798U CN201020640679U CN201866421U CN 201866421 U CN201866421 U CN 201866421U CN 2010206406798 U CN2010206406798 U CN 2010206406798U CN 201020640679 U CN201020640679 U CN 201020640679U CN 201866421 U CN201866421 U CN 201866421U
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pipe
cleaning
layer
ppr
oxygen
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Expired - Fee Related
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CN2010206406798U
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金怀龙
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NANJING JINGMIAO ENERGY-SAVING MATERIALS Co Ltd
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NANJING JINGMIAO ENERGY-SAVING MATERIALS Co Ltd
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Abstract

The utility model discloses a corrosion-preventing and oxygen-isolating self-cleaning PPR compound pipe, which has a three-layer structure and comprises an inner later, an outer layer and an intermediate layer, wherein the inner layer is made of modified polyvinylidene fluoride; the outer layer is made of random copolymerization polypropylene material; and the intermediate layer comprises an oxygen-isolating rubber layer which is a high polymer compound rubber layer. The compound pipe disclosed by the utility model has excellent corrosion-resistant performance so as to effectively prevent ions in water or chemical substances from corroding the inner wall of the pipeline; the compound pipe has an excellent oxygen-isolating function so as to effectively prevent bacteria from growing in the pipe; by taking the polyvinylidene fluoride as the material of the inner pipe, the inner wall is smooth and the system has small pressure loss and high water current speed; and the polyvinylidene fluoride has favorable self-cleaning function, so that the scaling, and the attaching and the growing of the gathered alga and bacteria on the pipe wall can be effectively prevented. Therefore, the compound pipe related in the utility model is an ideal cold and heat water pipe for buildings, also can be applied to the fields of food, chemical industry and the like, and has better application prospect and greater market value.

Description

The self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier
Technical field
The utility model relates to composite pipe, the self-cleaning PPR composite pipe of specifically a kind of anticorrosion oxygen barrier.
Background technique
The PPR pipe is because of advantages such as its good wholesomeness, toughness, resistance to pressures, is widely used at the building field of China.The nontoxic salubrity requirement of PPR plastic tube itself, but the PPR plastic tube does not have self-cleaning function and kills the bacterium function, under this specific environment of domestic water, the backward technology of contaminated water source, waterworks and pipe network thereof outmoded unreasonable, after the PPR plastic water pipe uses a period of time, the inner tube wall secondary pollution is serious, is the ground of growing of bacterium, Legionella, the serious threat health.Simultaneously also exist weather resistance poor, can not blocking oxygen, easily cause microorganism/algae to grow in the pipe, cause that water pollutes in the pipe.Therefore this defective that existing P PR tubing exists is necessary to improve.
The model utility content
(1) technical problem that will solve
The purpose of this utility model is the defective that exists at prior art, provides a kind of anticorrosion oxygen barrier self-cleaning PPR composite pipe, has solved the problem of the seriously polluted breed bacteria that the composite pipe of prior art exists.
(2) technological scheme
The technological scheme that its technical problem that solves the utility model adopts is: the self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier, its structure comprise one-time formed interior China and foreign countries three-decker.
China and foreign countries' three-decker is respectively the internal layer of modified polyvinilidene fluoride formation, macromolecule compound adhesive middle level, the atactic copolymerized polypropene skin with oxygen barrier function in described.
Internal layer, atactic copolymerized polypropene skin that described modified polyvinilidene fluoride constitutes bond together mutually by the macromolecule compound adhesive middle level with oxygen barrier function and become one.
Serve as with having oxygen barrier function glue material in macromolecule compound adhesive middle level with oxygen barrier function, employing generally contains EVA (ethylene-vinyl acetate copolymer), EVOH (ethylene-vinyl alcohol copolymer) or acrylate and derivative thereof etc. serve as, and is characterized in that the macromolecule composite layer can starvation.
(3) beneficial effect
The self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier of the present utility model is compared with prior art, has following beneficial effect:
Polyvinylidene fluoride described in the PPR composite pipe that the utility model relates to is a polyvinylidene fluoride resin after the modification, and described polyvinylidene fluoride resin also can adopt the commercially available prod, as: A Kema produces
Figure BSA00000372114600021
The ADX resin.Described polyvinylidene fluoride modified fluororesin has outstanding self-cleaning function and remarkable corrosion-resistant and ageing-resistant function, can prevent effectively that tube wall incrustation from really accomplishing not have dirt and never fouling, can prevent effectively that also bacterium and algae from adhering at tube wall, bacterium of thoroughly stopping and algae are caused water pollution once again owing to adhering to and growing.Described atactic copolymerized polypropene material layer claims the PPR layer usually, can adopt the commercially available prod, the PPR that produces as Korea S LG chemistry or Finland Borealis etc.Described oxygen barrier glue-line promptly has the macromolecule composite layer of oxygen barrier function, available commercially available oxygen barrier glue material serves as, usually adopt down and contain EVA (ethylene-vinyl acetate copolymer), EVOH (ethylene-vinyl alcohol copolymer) or acrylate and derivative thereof etc. serve as, be characterized in that the macromolecule composite layer can starvation, avoided interior bacterium of pipeline and algae to grow, guarantee that water quality is not contaminated, and the polyvinylidene fluoride layer of composite layer and modification has good cementability, interlaminar strength is very high, thereby has prolonged the working life of composite pipe, guarantee the quality of product.
Preparation method of the present utility model adopts prior art, adopt the three-layer co-extruded technology that goes out, once-through prepares described PPR composite pipe, compare with existing like product, PPR composite pipe of the present utility model, not only technology is simple, and composite pipe has corrosion resistance and good, the oxygen barrier performance is good and have outstanding self-cleaning function, be a kind of desirable hot and cold water tubing for building, product price ratio height has the very big market value of better application prospect.
Description of drawings
Accompanying drawing is the structural representation of the self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier of the present utility model.
Among the figure: 1, atactic copolymerized polypropene skin; 2, the macromolecule compound adhesive middle level that has the oxygen barrier function; 3, the internal layer of modified polyvinilidene fluoride formation.
Embodiment
Next explain below with reference to Figure of description the self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier of the present utility model being done.
The self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier, its structure comprise one-time formed interior China and foreign countries three-decker.China and foreign countries' three-decker is respectively the internal layer 3 of modified polyvinilidene fluoride formation, macromolecule compound adhesive middle level 2, the atactic copolymerized polypropene skin 1 with oxygen barrier function in described.Internal layer, atactic copolymerized polypropene skin that described modified polyvinilidene fluoride constitutes bond together mutually by the macromolecule compound adhesive middle level with oxygen barrier function and become one.
Serve as with having oxygen barrier function glue material in macromolecule compound adhesive middle level with oxygen barrier function, employing generally contains EVA (ethylene-vinyl acetate copolymer), EVOH (ethylene-vinyl alcohol copolymer) or acrylate and derivative thereof etc. serve as, and is characterized in that the macromolecule composite layer can starvation.
Polyvinylidene fluoride described in the PPR composite pipe that the utility model relates to is a polyvinylidene fluoride resin after the modification, and described polyvinylidene fluoride resin also can adopt the commercially available prod, as: A Kema produces
Figure BSA00000372114600031
The ADX resin.Described polyvinylidene fluoride modified fluororesin has outstanding self-cleaning function and remarkable corrosion-resistant and ageing-resistant function, can prevent effectively that tube wall incrustation from really accomplishing not have dirt and never fouling, can prevent effectively that also bacterium and algae from adhering at tube wall, bacterium of thoroughly stopping and algae are caused water pollution once again owing to adhering to and growing.Described atactic copolymerized polypropene material layer claims the PPR layer usually, can adopt the commercially available prod, the PPR that produces as Korea S LG chemistry or Finland Borealis etc.Described oxygen barrier glue-line promptly has the macromolecule composite layer of oxygen barrier function, available commercially available oxygen barrier glue material serves as, usually adopt down and contain EVA (ethylene-vinyl acetate copolymer), EVOH (ethylene-vinyl alcohol copolymer) or acrylate and derivative thereof etc. serve as, be characterized in that the macromolecule composite layer can starvation, avoided interior bacterium of pipeline and algae to grow, guarantee that water quality is not contaminated, and the polyvinylidene fluoride layer of composite layer and modification has good cementability, interlaminar strength is very high, thereby has prolonged the working life of composite pipe, guarantee the quality of product.
The above embodiment is a kind of of the more preferably concrete mode of execution of the utility model, and common variation that those skilled in the art carries out in the technical solutions of the utility model scope and replacement all should be included in the protection domain of the present utility model.

Claims (3)

1. self-cleaning PPR composite pipe of anticorrosion oxygen barrier is characterized in that: its structure comprise one-time formed in China and foreign countries' three-decker.
2. the self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier according to claim 1 is characterized in that: China and foreign countries' three-decker is respectively the internal layer of modified polyvinilidene fluoride formation, macromolecule compound adhesive middle level, the atactic copolymerized polypropene skin with oxygen barrier function in described.
3. the self-cleaning PPR composite pipe of a kind of anticorrosion oxygen barrier according to claim 2 is characterized in that: internal layer, atactic copolymerized polypropene skin that described modified polyvinilidene fluoride constitutes bond together mutually by the macromolecule compound adhesive middle level with oxygen barrier function and become one.
CN2010206406798U 2010-12-03 2010-12-03 Corrosion-preventing and oxygen-isolating self-cleaning PPR (pentatricopeptide repeats) compound pipe Expired - Fee Related CN201866421U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106947193A (en) * 2017-03-24 2017-07-14 南京晶淼节能材料股份有限公司 A kind of self-cleaning materials in the tube and preparation method thereof and its multiple tube being made
CN107166112A (en) * 2017-04-21 2017-09-15 山东冠通管业有限公司 Flexible composite pipe and preparation method thereof
CN109253320A (en) * 2018-08-23 2019-01-22 浙江巨化新材料研究院有限公司 A kind of MULTILAYER COMPOSITE tubing and preparation method thereof
CN112049991A (en) * 2020-08-27 2020-12-08 湖南创瑾科技有限公司 High-pressure plastic pipeline and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106947193A (en) * 2017-03-24 2017-07-14 南京晶淼节能材料股份有限公司 A kind of self-cleaning materials in the tube and preparation method thereof and its multiple tube being made
CN107166112A (en) * 2017-04-21 2017-09-15 山东冠通管业有限公司 Flexible composite pipe and preparation method thereof
CN107166112B (en) * 2017-04-21 2019-07-26 山东冠通管业有限公司 Flexible composite pipe and preparation method thereof
CN109253320A (en) * 2018-08-23 2019-01-22 浙江巨化新材料研究院有限公司 A kind of MULTILAYER COMPOSITE tubing and preparation method thereof
CN109253320B (en) * 2018-08-23 2021-01-05 浙江巨化新材料研究院有限公司 Multilayer composite pipe and preparation method thereof
CN112049991A (en) * 2020-08-27 2020-12-08 湖南创瑾科技有限公司 High-pressure plastic pipeline and preparation method thereof

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Granted publication date: 20110615

Termination date: 20151203

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