Weakly alkaline negative potential brine electrolysis device for making and electrolysis water dispenser
Technical field
The utility model relates to a kind of device that is used to produce electrolytic functional water, belongs to the electrolytic water device technical field.
Background technology
Function water is by suitable means, and under given conditions, with the energy of outside, for example mechanical energy, magnetic energy, electric energy, far infrared heat energy etc. act on ortho-water, and the molecular grouping structure that changes water makes it to have the general designation of a class water of beneficial functions.Obtain at present generally generally acknowledging and uniquely have standard executable to be electrolytic functional water, to be commonly called as brine electrolysis or ionized water.After brine electrolysis is meant and feeds direct current in electrolyzer, at electrolytic oxidation water and the electrolytic reduction water that anode and negative electrode produced; Electrolytic oxidation water contains more acid ion (H
+Ion), has oxidisability, claim sour water, electrolytic reduction water to contain more hydroxide ion (OH again
-), have reductibility, claim alkaline water again.Big quantity research and many decades application practice prove that drinking electrolytic reduction water (weak base or middle alkali) is of value to health both at home and abroad, and the weakly alkaline electrolytic reduction water that especially has negative redox potential is called as " long-lived water " especially.A large amount of reports relevant for brine electrolysis in the existing knowledge provide a reference.
Common on the market existing electrolyzed water machine, the general employing has the diaphragm sell structure, and not only complex structure, and film is contaminated easily.The technology of this respect is existing a lot, and the present invention also need not to be described more.
The applicant in first to file adopt the electrolytic water device of undivided cell structure, have water dispenser, ZL200820184175.2 electrolytic functional water tumbler, ZL200820184176.7 portable electrolytic functional water preparing device of sterilizing function as one kind of disclosed Chinese patent ZL200820183101.7.These openly electrolytic water devices of undivided cell structure started novel method and device that undivided cell is produced brine electrolysis because the little electric current that has adopted direct current pulse power source to produce carries out electrolysis to water.Though these disclosed electrolytic water devices can be realized diaphragm-free electrolysis water,, the one, the restriction that is subjected to little range of current proposes very high request to direct current pulse power source, and pilot circuit is too complicated, the cost height; The 2nd, produce the brine electrolysis overlong time, can't fast and effeciently produce the brine electrolysis of the negative redox potential of weakly alkaline that suitable people drinks.
The utility model content
The technical problems to be solved in the utility model is, proposes a kind of simple in structure and can effectively produce the device of the negative redox potential electrolyzed of weakly alkaline that suitable people drinks fast.
In order to solve the problems of the technologies described above, the technical scheme that the utility model proposes is: a kind of weakly alkaline negative potential brine electrolysis device for making, comprise electrolyzer, place the yin, yang electrode in the electrolyzer, and the direct current pulse power source that is electrically connected with anodic-cathodic, the surface-area of described negative electrode is greater than the surface-area of positive electrode.
Contriver of the present utility model finds through repetition test and further investigation back, when the surface-area that makes negative electrode during greater than the surface-area of positive electrode, can effectively produce out alkalescence fast and be worth and all very good brine electrolysis of redox potential value.Theoretical analysis to this has: 1, the hydrogen root of water electrolysis reaction generation and hydroxide radical are respectively in negative electrode and anode generation reduction reaction and oxidizing reaction.Owing to hydrogen bond forms hydrogen than easier the opening of hydrogen-oxygen key, when cathode area during, just more help the generation of evolving hydrogen reaction like this greater than anode, the relative cathode area of anode is little then can to cause the anodic electrolytic reaction abundant inadequately; Finally cause the whole weakly alkaline that shows of water generation hydroxy in the water makes electrolysis greater than the generation of hydrogen root after.2, when with the pulsed current electrolysis, wavy variation also takes place in electrode voltage thereupon, has improved the unit time transient voltage, can improve chemical energy and produce and the reduction heat energy consumption.High chemical energy then can make electronics gathering in the water, and the hydrogen atom in the water is won electronics easily and formed metastable hydride ion attitude under high-voltage high-energy situation at this moment.Along with constantly gathering of hydride ion in the water, make the redox potential of water continue to reduce, finally become the negative potential water of stable state.
Improvement of the technical scheme is: described positive electrode with the perpendicular plane of the geometric centre line of described yin, yang electrode in orthographicprojection be positioned at described negative electrode within the scope of the orthographicprojection on described plane.
Contriver of the present utility model is finding above-mentioned yin, yang two electrode areas to differ in size after this gordian technique, in further experiment, find, when positive electrode and negative electrode with the perpendicular plane of its geometric centre line in orthographicprojection surround (being that the orthographicprojection of positive electrode in this plane is positioned at negative electrode under the situation within the scope of the orthographicprojection on this plane) under the situation about overlapping each other, weakly alkaline and the negative redox potential index of producing brine electrolysis are even more ideal.
Further improvement in the technical proposal is: described positive electrode is 1: 1.5~1: 8 with the ratio of the surface-area of negative electrode; The scope of the spacing of described positive electrode and negative electrode is 4mm-1000mm.Contriver of the present utility model sums up from countless experiments again: when the ratio of positive electrode and the surface-area of negative electrode and the spacing of positive electrode and negative electrode satisfy above-mentioned condition and range simultaneously, can produce the brine electrolysis that satisfies weakly alkaline and negative redox potential index.
The further improvement of technique scheme is: described direct current pulse power source is all adjustable scanning frequency pulse producer of waveform, amplitude, dutycycle, power of output dc pulse voltage.Draw through a large amount of experiments of the present inventor, adopt this direct current pulse power source more effectively to finish and produce the negative redox potential electrolyzed of weakly alkaline that suitable people drinks.
The one of perfect of technique scheme is: described yin, yang electrode all is parallel flat boards that are placed in the electrolyzer with cell sidewall.
Perfect two of technique scheme is: described yin, yang electrode with the perpendicular plane of its geometric centre line in shadow area basic identical, be shaped on the through hole that evenly gathers on the described positive electrode.
Perfect three of technique scheme is: described yin, yang electrode incline is placed in the electrolyzer and with the electrolyzer inner side-wall and forms an angle.
Perfect four of technique scheme is: described positive electrode is a spheroid, and described negative electrode is dull and stereotyped.
Perfect five of technique scheme is: described positive electrode is irregular approximate spheroid, and described negative electrode is irregular curved slab.
Perfect six of technique scheme is: described positive electrode is the irregular flat board that has through hole, and described negative electrode is the flat board greater than four sideband chamferings of positive electrode.
Perfect seven of technique scheme is: described positive electrode is the right cylinder that is positioned at the electrolyzer centre, and the inwall of described electrolyzer is as negative electrode.
Further improving of technique scheme is: described positive electrode is the noble electrode of being made by titanium-based surface plating inert material, and described inert material is one of platinum, iridium and ruthenium.
The another kind of technical scheme of the utility model institute's deutero-on the basis of technique scheme is: a kind of electrolysis water dispenser, comprise weakly alkaline negative potential brine electrolysis device for making, and also comprise water-in, water outlet and be serially connected with the heating unit of water outlet; Described electrolyzer is a metal drum, and its inwall is as negative electrode; Described positive electrode is placed in the inner centre of described metal drum.
The perfect of above-mentioned another kind of technical scheme is: described positive electrode is 1: 6 with the ratio of the surface-area of negative electrode, and the scope of the spacing of described positive electrode and negative electrode is 30mm-1000mm.
Further improving of above-mentioned another kind of technical scheme is: described metal drum is the stainless steel metal bucket, and described positive electrode is the cylindrical toroidal noble electrode of being made by titanium-based surface plating inert material, and described inert material is one of platinum, iridium and ruthenium.
Description of drawings
Below in conjunction with accompanying drawing weakly alkaline negative potential brine electrolysis device for making of the present utility model and electrolysis water dispenser are described further.
Fig. 1 is the structural representation that explanation is different from first kind of anodic-cathodic placement situation of the utility model weakly alkaline negative potential brine electrolysis device for making.
Fig. 2 is the structural representation that explanation is different from second kind of anodic-cathodic placement situation of the utility model weakly alkaline negative potential brine electrolysis device for making.
Fig. 3 is the structural representation of the utility model embodiment one weakly alkaline negative potential brine electrolysis device for making.
Fig. 4 is that the A-A of Fig. 3 is to sectional view.
Fig. 5 is the structural representation of the utility model embodiment two weakly alkaline negative potential brine electrolysis device for making.
Fig. 6 is that the B-B of Fig. 5 is to sectional view.
Fig. 7 is the cross section structure synoptic diagram of the utility model embodiment three weakly alkaline negative potential brine electrolysis device for making.
Fig. 8 is the structural representation of the embodiment of the invention four weakly alkaline negative potential brine electrolysis device for making.
Fig. 9 is the structural representation of the utility model embodiment five weakly alkaline negative potential brine electrolysis device for making.
Figure 10 is the structural representation of the utility model embodiment six weakly alkaline negative potential brine electrolysis device for making.
Figure 11 is the cross section structure synoptic diagram of the utility model embodiment seven weakly alkaline negative potential brine electrolysis device for making.
Figure 12 is the structural representation of the utility model embodiment eight weakly alkaline negative potential brine electrolysis device for making.
Figure 13 is the structural representation of the utility model embodiment nine electrolysis water dispensers.
Embodiment
Embodiment one
The weakly alkaline negative potential brine electrolysis device for making of present embodiment as shown in Figure 3 and Figure 4, comprises electrolyzer 1, places yin, yang electrode 2,3 and the direct current pulse power source 4 that is connected yin, yang electrode 2,3 in the electrolyzer 1.Electrolyzer 1 adopts non-conductive material to make, and yin, yang electrode 2,3 all is tabular and all is noble electrodes of being made by inert materials such as titanium-based surface platinum plating, iridium or rutheniums, and the parallel sidewalls of yin, yang electrode 2,3 and electrolyzer 1 is placed in the electrolyzer 1.The surface-area of negative electrode 2 is greater than the surface-area of positive electrode 3, wherein, positive electrode 3 is 1: 1.5 with the ratio of the surface-area of negative electrode 2, positive electrode 3 with the perpendicular plane of the geometric centre line of yin, yang electrode 2,3 in orthographicprojection be positioned at negative electrode 2 within the scope of the orthographicprojection on this plane.This moment, positive electrode 3 was 80mm-300mm with the ideal range of the spacing of negative electrode 2 according to the experiment measuring and calculating.Direct current pulse power source 4 is all adjustable scanning frequency pulse producers of waveform, amplitude, dutycycle, power of output dc pulse voltage.
Embodiment two
The weakly alkaline negative potential brine electrolysis device for making of present embodiment is the improvement on embodiment one basis, as shown in Figure 5 and Figure 6, different is except that identical with embodiment one: yin, yang electrode 2,3 with the perpendicular plane of its geometric centre line in shadow area basic identical, but be shaped on the through hole 5 that evenly gathers on the positive electrode 3, the ratio of positive electrode 3 and the surface-area of negative electrode 2 be 1: 5 (present embodiment positive electrode surface-area be meant remove through hole 5 backs surplus surface-area).Experiment measuring and calculating this moment, positive electrode 3 is 10mm-450mm with the ideal range of the spacing of negative electrode 2.
Embodiment three
Present embodiment is the improvement on embodiment two bases, as shown in Figure 7, different is except that identical with embodiment two: the through hole 5 on the positive electrode 3 is bigger more intensive, is 1: 8 (surface-area of present embodiment positive electrode is meant and removes the surplus surface-area in through hole 5 backs) thereby make the ratio of the positive electrode and the surface-area of negative electrode.This moment, positive electrode 3 was 4mm-600mm with the ideal range of the spacing of negative electrode 2 according to the experiment measuring and calculating.
Embodiment four
Present embodiment is a kind of variation on embodiment one basis, and as shown in Figure 8, its structure and embodiment one are basic identical, changes part and is: yin, yang electrode 2,3 is to tilt to place in electrolyzer 1, and two battery lead plates and electrolyzer 1 inner side-wall form an angle.
Embodiment five
Present embodiment is that the another kind on embodiment one basis changes, and as shown in Figure 9, its structure and embodiment one are basic identical, and change part and be: positive electrode 3 is spheroids, and negative electrode 2 is tabulars.
Embodiment six
Present embodiment is another variation on embodiment one basis, and as shown in figure 10, its structure and embodiment one are basic identical, and change part and be: positive electrode 3 is irregular approximate sphere-likes, and negative electrode 2 is that irregular curved surface is tabular.
Embodiment seven
Present embodiment is a kind of variation on embodiment three bases, as shown in figure 11, its structure and embodiment three are basic identical, and change part and be: positive electrode 3 is the irregular tabulars that have through hole 5, and negative electrode 2 is the tabulars that are slightly larger than four sideband chamferings of positive electrode 3.
Embodiment eight
Present embodiment is a kind of variation on the various embodiments described above basis, as shown in figure 12, its structure is except that with the various embodiments described above are identical, changing part is: positive electrode 3 is the right cylinders that are positioned at electrolyzer 1 centre, electrolyzer 1 adopts electro-conductive material to make, and the inwall of electrolyzer 1 is as negative electrode 2.
Embodiment nine
Present embodiment is to improve and next a kind of electrolysis water dispenser on the foregoing description eight bases, as shown in figure 13, this electrolysis water dispenser except that the weakly alkaline negative potential brine electrolysis device for making that comprises the foregoing description, 1) also comprise water-in 6, water outlet 7 and be serially connected with heating unit 8 on the water outlet 7; 2) electrolyzer 1 is the stainless steel metal bucket, and its inwall is as negative electrode; 3) positive electrode 3 is cylindrical toroidal noble electrodes of being made by inert materials such as titanium-based surface platinum plating, iridium or rutheniums, and positive electrode 3 is installed in the inner centre of stainless steel metal staving; 4) positive electrode 3 and the ratio of the surface-area of negative electrode 2 are that (surface-area of present embodiment positive electrode comprised that the exposed all surfaces that contact with water outside amassed in 1: 6, the surface-area of negative electrode 2 is areas of stainless steel metal bucket inwall), this moment, positive electrode 3 was 30mm-1000mm with the ideal range of the spacing of negative electrode 2 according to the experiment measuring and calculating.
Because the stainless steel metal staving has good physical strength and outside surface is ornamental, can save the water dispenser shell to reduce product cost; Stainless steel metal bucket itself is again a jumbo water butt, can save the outside water tank of water dispenser; Especially, for producing weakly alkaline negative potential small micelle drinking water, stainless steel metal bucket inwall double as is a cathode electrode, can avoid the insoluble heavy metal of conventional water dispenser (hot courage) to separate out the problem of exceeding standard.
The electrolysis water dispenser of present embodiment, electrolyzer 1 are in activation work, and the calcium ions and magnesium ions in the water of source etc. is constantly shifted to negative electrode, on the stainless steel metal bucket inwall as electrolyzer 1, makes water hardness be minimized.When finishing all after dates of some system water, can switch the polarity of anode and cathode, make and be applied to as the voltage on the stainless steel metal bucket inwall of negative electrode 2 to just, and the voltage on the positive electrode 3 is for negative, so just can make attached to the scum on the stainless steel metal bucket inwall to strip down, discharge through sewage draining exit 9.
The various embodiments described above that are not limited to of the present utility model, such as: the noble electrode that yin, yang electrode 2,3 is not necessarily made by inert materials such as titanium-based surface platinum plating, iridium or rutheniums, it also can be the non-noble electrode of making by other metallic substance of ordinary metallic material (as copper, aluminium, stainless steel etc.) surface plating, but consider that from the safe drinking water angle positive electrode 3 preferably adopts above-mentioned noble electrode; Or the like.All employings are equal to replaces the technical scheme that forms, and all drops on the protection domain of the utility model requirement.