CN201648045U - Bisphenol S wastewater treatment device - Google Patents

Bisphenol S wastewater treatment device Download PDF

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Publication number
CN201648045U
CN201648045U CN2010201425059U CN201020142505U CN201648045U CN 201648045 U CN201648045 U CN 201648045U CN 2010201425059 U CN2010201425059 U CN 2010201425059U CN 201020142505 U CN201020142505 U CN 201020142505U CN 201648045 U CN201648045 U CN 201648045U
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China
Prior art keywords
storage tank
tower
bisphenol
extraction
links
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Expired - Fee Related
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CN2010201425059U
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Chinese (zh)
Inventor
刘云
董元华
孙含元
李志敏
耿治干
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Institute of Soil Science of CAS
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Institute of Soil Science of CAS
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Priority to CN2010201425059U priority Critical patent/CN201648045U/en
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Publication of CN201648045U publication Critical patent/CN201648045U/en
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Abstract

The utility model relates to a bisphenol S wastewater treatment device, which comprises an extraction unit and an extraction additive regenerating unit; the extraction unit comprises an extraction additive storage tank, a bisphenol S wastewater storage tank, a mixed extraction additive storage tank, a multi-level counter-current extraction tower and a metering pump; and the extraction additive regenerating unit comprises a resolvent regenerating tower, a stripping agent storage tank and a lift pump.

Description

The bisphenol S wastewater treatment equipment
One, technical field
The utility model belongs to environmental technology field, particularly a kind of bisphenol S wastewater treatment equipment.
Two, background technology
The chemical name of bisphenol S is 4, and 4 '-dihydroxyl disulfoxide has good heat-resisting, fast light and antioxidant property.Bisphenol S and dihydroxyphenyl propane similar performance, purposes is also similar, particularly can replace dihydroxyphenyl propane aspect polymerization, and the product thermostability after substituting is enhanced better mechanical property.The bisphenol S purposes is very extensive, and its applied research is also quite active.External having had produced tens thousand of tons bisphenol S factory per year, can estimate that domestic and international bisphenol S will develop at faster speed in the several years.Producing bisphenol S is at present both at home and abroad obtained by the phenol Direct Sulfonation.But the organic pollutant of big, the difficult for biological degradation of toxigenicity, biodegradability difference in process of production, comprise the organism (as p-hydroxybenzenyl sulfonate class material) that contains sulfonic acid group, the organic pollutant that contains other groups (as hydroxyl, carboxyl etc.) in addition makes the COD in the waste water be higher than 10000mg/L.Patent 200510019609.4 discloses the bisphenol that utilizes in the cyclodextrin quickening photodegradation processing trade effluent.But complicated component in the bisphenol S industrial wastewater, toxicity is big, difficult degradation, COD height, difficult.
Three, summary of the invention
Goal of the invention: the invention provides a kind of bisphenol S wastewater treatment equipment.This device can effectively reduce the COD of bisphenol S industrial wastewater.
Technical scheme: a kind of bisphenol S wastewater treatment equipment is characterized in that this device is made up of extraction cells and extractant regeneration unit; Extraction cells comprises extraction addition agent storage tank, bisphenol S waste water storage tank, mixed extractant storage tank, multi-stage counter current extraction tower and volume pump; The extractant regeneration unit comprises solvent regeneration tower, strippant storage tank, lift pump and volume pump; The outlet of extraction addition agent storage tank links to each other with the import of bisphenol S waste water storage tank, the extraction auxiliary agent enters into the amount of bisphenol S waste water storage tank and is controlled by first volume pump, the outlet of bisphenol S waste water storage tank links to each other with the upper inlet of multi-stage counter current extraction tower, bisphenol S waste water enters into the amount of extraction tower and is controlled by second volume pump, the outlet of mixed extractant storage tank links to each other with the lower inlet of multi-stage counter current extraction tower, and mixed extractant enters into the amount of multi-stage counter current extraction tower and is controlled by the 3rd volume pump, and the following outlet of multi-stage counter current extraction tower links to each other with the import in wastewater biochemical pond; The upper outlet of multi-stage counter current extraction tower links to each other with first upper inlet of solvent regeneration tower, the outlet of strippant storage tank links to each other with solvent regeneration tower second upper inlet, strippant enters into the amount of regenerator column and is controlled by the 4th volume pump, first time outlet of solvent regeneration tower links to each other with the import of mixed extractant storage tank, and mixed extractant enters into the mixed extractant storage tank from solvent regeneration tower and is finished by lift pump, and second time outlet of solvent regeneration tower links to each other with the import of product retrieving arrangement.
Counter-current extraction Tata inner bottom part is equipped with the support screen, supports on the screen filler is housed.
Beneficial effect: the invention provides a kind of bisphenol S wastewater treatment equipment.This device combines with the co-current regeneration method by counter-current extraction and handles bisphenol S waste water.Wherein extraction cells adopts counter-current extraction tower, and the little solution of proportion enters from the bottom of extraction tower, and heavy solution enters from the top of tower.The tower inner bottom part is equipped with the support screen, supports on the screen filler is housed, and drop is constantly produced break with coalescent again, and to promote the Surface Renewal of drop, thorough mixing effectively reduces COD in the waste water; Regeneration unit adopts chemical method, and the co-current regeneration solvent makes the solvent recycling.This device can effectively reduce COD in the waste water.
Four, description of drawings
Accompanying drawing is a kind of bisphenol S wastewater treatment equipment of the present utility model.Extraction addition agent storage tank 1, bisphenol S waste water storage tank 2 among the figure, mixed extractant storage tank 3, multi-stage counter current extraction tower 4, solvent regeneration tower 5, strippant storage tank 6, lift pump 7, the first volume pump 8a, the second volume pump 8b, the 3rd volume pump 8c, wastewater biochemical pond 9, product retrieving arrangement 10.
Five, embodiment
A kind of bisphenol S wastewater treatment equipment that the utility model is made is made up of extraction cells and extractant regeneration unit.Wherein, extraction cells comprises extraction addition agent storage tank 1, bisphenol S waste water storage tank 2, mixed extractant storage tank 3, multi-stage counter current extraction tower 4, volume pump.Its mode of connection links to each other with the import of bisphenol S waste water storage tank 2 for the outlet of extraction addition agent storage tank 1, the extraction auxiliary agent enters into the amount of bisphenol S waste water storage tank 2 and is controlled by the first volume pump 8a, bisphenol S waste water storage tank 2 links to each other with the upper inlet of multi-stage counter current extraction tower 4, bisphenol S waste water enters into the amount of multi-stage counter current extraction tower 4 and is controlled by the second volume pump 8b, the outlet of mixed extractant storage tank 3 links to each other with the lower inlet of multi-stage counter current extraction tower 4, mixed extractant enters into the amount of multi-stage counter current extraction tower 4 and is controlled by the 3rd volume pump 8c, and the following outlet of multi-stage counter current extraction tower 4 links to each other with the import in wastewater biochemical pond 9.The extractant regeneration unit comprises solvent regeneration tower 5, strippant storage tank 6, lift pump 7, volume pump.Its mode of connection is that the outlet of multi-stage counter current extraction tower 4 links to each other with first upper inlet of solvent regeneration tower 5, the outlet of strippant storage tank 6 links to each other with second upper inlet of solvent regeneration tower 5, strippant enters into the amount of regenerator column 5 and is controlled by the 4th volume pump 8d, 5 first times outlets of solvent regeneration tower link to each other with 3 imports of mixed extractant storage tank, and mixed extractant enters into mixed extractant storage tank 3 from solvent regeneration tower 5 and is finished by lift pump 7, and second time outlet of solvent regeneration tower 5 links to each other with the import of product retrieving arrangement 10.

Claims (2)

1. bisphenol S wastewater treatment equipment is characterized in that this device is made up of extraction cells and extractant regeneration unit; Extraction cells comprises extraction addition agent storage tank (1), bisphenol S waste water storage tank (2), mixed extractant storage tank (3), multi-stage counter current extraction tower (4) and volume pump; The extractant regeneration unit comprises solvent regeneration tower (5), strippant storage tank (6), lift pump (7) and volume pump; The outlet of extraction addition agent storage tank (1) links to each other with the import of bisphenol S waste water storage tank (2), the extraction auxiliary agent enters into the amount of bisphenol S waste water storage tank (2) and is controlled by first volume pump (8a), the outlet of bisphenol S waste water storage tank (2) links to each other with the upper inlet of multi-stage counter current extraction tower (4), bisphenol S waste water enters into the amount of extraction tower and is controlled by second volume pump (8b), the outlet of mixed extractant storage tank (3) links to each other with the lower inlet of multi-stage counter current extraction tower (4), and mixed extractant enters into the amount of multi-stage counter current extraction tower (4) by the 3rd volume pump (8c) control, and the following outlet of multi-stage counter current extraction tower (4) links to each other with the import of wastewater biochemical pond (9); The upper outlet of multi-stage counter current extraction tower (4) links to each other with first upper inlet of solvent regeneration tower (5), strippant storage tank (6) outlet links to each other with solvent regeneration tower (5) second upper inlets, strippant enters into the amount of regenerator column (5) and is controlled by the 4th volume pump (8d), (5) first times outlets of solvent regeneration tower link to each other with mixed extractant storage tank (3) import, and mixed extractant enters into mixed extractant storage tank (3) from solvent regeneration tower (5) and is finished by lift pump (7), and second time outlet of solvent regeneration tower (5) links to each other with the import of product retrieving arrangement (10).
2. a bisphenol S wastewater treatment equipment is characterized in that counter-current extraction tower (4) tower inner bottom part is equipped with the support screen, supports on the screen filler is housed.
CN2010201425059U 2010-03-26 2010-03-26 Bisphenol S wastewater treatment device Expired - Fee Related CN201648045U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010201425059U CN201648045U (en) 2010-03-26 2010-03-26 Bisphenol S wastewater treatment device

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Application Number Priority Date Filing Date Title
CN2010201425059U CN201648045U (en) 2010-03-26 2010-03-26 Bisphenol S wastewater treatment device

Publications (1)

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CN201648045U true CN201648045U (en) 2010-11-24

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102942235A (en) * 2012-11-28 2013-02-27 中国科学院南京土壤研究所 Stirring extraction tower-back extraction tower combined device for processing high chemical oxygen demand (COD) waste water and technology of combined device
CN103466894A (en) * 2013-09-24 2013-12-25 天津长芦汉沽盐场有限责任公司 Method for treating and recycling TBBP (tetrabromobisphenol)-A production wastewater
CN105923833A (en) * 2016-06-13 2016-09-07 郑州天萃取科技有限公司 Phenolic wastewater treatment system and phenolic wastewater treatment technology

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102942235A (en) * 2012-11-28 2013-02-27 中国科学院南京土壤研究所 Stirring extraction tower-back extraction tower combined device for processing high chemical oxygen demand (COD) waste water and technology of combined device
CN102942235B (en) * 2012-11-28 2014-01-08 中国科学院南京土壤研究所 Stirring extraction tower-back extraction tower combined device for processing high chemical oxygen demand (COD) waste water and technology of combined device
CN103466894A (en) * 2013-09-24 2013-12-25 天津长芦汉沽盐场有限责任公司 Method for treating and recycling TBBP (tetrabromobisphenol)-A production wastewater
CN105923833A (en) * 2016-06-13 2016-09-07 郑州天萃取科技有限公司 Phenolic wastewater treatment system and phenolic wastewater treatment technology

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C17 Cessation of patent right
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Granted publication date: 20101124

Termination date: 20110326