CN201159816Y - Color changing membrane - Google Patents

Color changing membrane Download PDF

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Publication number
CN201159816Y
CN201159816Y CNU2007201965271U CN200720196527U CN201159816Y CN 201159816 Y CN201159816 Y CN 201159816Y CN U2007201965271 U CNU2007201965271 U CN U2007201965271U CN 200720196527 U CN200720196527 U CN 200720196527U CN 201159816 Y CN201159816 Y CN 201159816Y
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CN
China
Prior art keywords
extraction electrode
layer
conducting layer
transparency conducting
variable color
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Expired - Fee Related
Application number
CNU2007201965271U
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Chinese (zh)
Inventor
角磊升
吴伟才
吴波
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BYD Co Ltd
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BYD Co Ltd
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Publication date
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Priority to CNU2007201965271U priority Critical patent/CN201159816Y/en
Application granted granted Critical
Publication of CN201159816Y publication Critical patent/CN201159816Y/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The utility model discloses a electrochromic film which includes a first base layer, a first transparent conducting layer, an electrolyte layer, an electrochromic layer, a second transparent conducting layer, a second base layer, a first extraction electrode and a second extraction electrode. The first extraction electrode is electrically connected with the first transparent conducting layer, the second extraction electrode is electrically connected with the second transparent conducting layer. The electrochromic film also includes a photoelectric conversion layer and a control system which can make the first extraction electrode and the second extraction electrode to be directly connected or make a power supply to be connected between the first extraction electrode and the second extraction electrode. The first base layer, the first transparent conducting layer, the photoelectric conversion layer, the electrolyte layer, the electrochromic layer, the second transparent conducting layer and the second base layer are sequentially arranged. The electrochromic film of the utility model has the electrochromic function and photoelectrochromic function at the same time; thereby has the advantage of fast response time and low energy consumption.

Description

A kind of variable color film
Technical field
The utility model relates to a kind of variable color film.
Background technology
Existing variable color film or employing electrochromism or employing Photoelectrochromic, the electrochromic film response time is fast but want consumed power, and need manual light modulation, the Photoelectrochromic film need not consumed power, but the response time is slow and can not arbitrarily change the transmittance of variable color film.At present, do not see the variable color film that has electrochromism and Photoelectrochromic function simultaneously as yet.
Summary of the invention
The utility model is exactly in order to overcome above deficiency, to have proposed a kind of variable color film that has electrochromism and Photoelectrochromic function simultaneously.
Technical matters of the present utility model is solved by following technical scheme: a kind of variable color film, comprise first basic unit, first transparency conducting layer, dielectric substrate, electrochromic layer, second transparency conducting layer, second basic unit, first extraction electrode and second extraction electrode, described first extraction electrode is electrically connected with first transparency conducting layer, described second extraction electrode is electrically connected with second transparency conducting layer, also comprises photoelectric conversion layer and is used to make first extraction electrode and second extraction electrode directly is communicated with or makes the control system of connecting with the mains between first extraction electrode and second extraction electrode; Described first basic unit, first transparency conducting layer, photoelectric conversion layer, dielectric substrate, electrochromic layer, second transparency conducting layer and second basic unit arrange in turn.
Preferably, the number of described first extraction electrode has the number of at least two and/or second extraction electrode to have at least two.
The selector switch that described control system comprises straight-through branch road, second branch road, be used to make straight-through branch road or second branch road and first extraction electrode to link to each other with second extraction electrode; Described second branch road comprises power supply.
Described second branch road also comprises variable resistor, described power supply and variable resistor series connection.
Also comprise pressure-sensitive adhesive layer and release rete, described pressure-sensitive adhesive layer is between the release rete and first basic unit.
Also comprise wearing layer, described second basic unit is between the wearing layer and second transparency conducting layer.
The beneficial effect that the utility model is compared with the prior art is: the control system that variable color film of the present utility model comprises photoelectric conversion layer, electrochromic layer and is used for switching between Photoelectrochromic and electrochromism, this makes variable color film of the present utility model have electrochromism and Photoelectrochromic function simultaneously, thereby possesses fast, advantage of low energy consumption of response time.
Description of drawings
Fig. 1 is the structural representation of the utility model embodiment;
Fig. 2 is the structural representation of the control system of the utility model embodiment.
Embodiment
Also in conjunction with the accompanying drawings the utility model is described in further details below by concrete embodiment.
As shown in Figure 1, a kind of variable color film comprises first extraction electrode 14, second extraction electrode 11, control system 12 and first basic unit 3, first transparency conducting layer 4, photoelectric conversion layer 5, dielectric substrate 6, electrochromic layer 7, second transparency conducting layer 8, second basic unit 9 of arranging in turn.Described first extraction electrode 14 is electrically connected with first transparency conducting layer 4, and described second extraction electrode 11 is electrically connected with second transparency conducting layer 8.Described control system 12 is used to make first extraction electrode 14 and second extraction electrode 11 directly to be communicated with or makes between first extraction electrode 14 and second extraction electrode 11 connects with the mains.
Described first basic unit 3 and second basic unit 9 can be by polyethylene plastic film or polypropylene screen or polyester plastics film or polyethylene terephthalate (PET) film formations.This embodiment selects for use the PET film as first basic unit 3 and second basic unit 9, and through evidence, its toughness, shock resistance are all fine, have good explosion-proof effect.Described first transparency conducting layer 4 and second transparency conducting layer 8 can be the SnO of indium tin metal oxide (ITO) or doped with fluorine 2(FTO) film.Described photoelectric conversion layer can be made of zinc ferrite-titania.Described dielectric substrate is by polymeric matrix polymethylmethacrylate (PMMA), lithium salts (LiClO 4) and plastifier polycarbonate (PC) composition, dielectric substrate of the present utility model can be finished ion transfer and ion storage simultaneously.Therefore the utility model need not to be provided with ion storage layer again, has simplified the structure of variable color film.Described electrochromic layer can be by tungstic acid (WO 3) constitute.
The number of described first extraction electrode 14 and/or second extraction electrode 11 has at least two respectively.Because can there be internal resistance in first transparency conducting layer 4 and second transparency conducting layer 8, by being set, at least two extraction electrodes can make the voltage that is added on the electrochromic layer 7 more even, the variable color of electrochromic film is also more even, has overcome the uneven shortcoming of existing variable color film variable color.
As shown in Figure 2, described control system 12 comprises straight-through branch road, second branch road and selector switch 18.Described selector switch 18 is used to make straight-through branch road to link to each other with second extraction electrode 11 with first extraction electrode 14 or second branch road is linked to each other with second extraction electrode 11 with first extraction electrode 14.Described second branch road comprises power supply 16, the variable resistor 17 of mutual series connection.Described selector switch 18 is a single-pole double-throw switch (SPDT), can control switching to single-pole double-throw switch (SPDT) by remote control mode, so that the user operates.
Above-mentioned variable color film also comprises pressure-sensitive adhesive layer 2, release rete 1 and wearing layer 10, described pressure-sensitive adhesive layer 2 is between the release rete 1 and first basic unit 3, the pressure sensitive adhesive of described pressure-sensitive adhesive layer has very strong adhesive aggregation effect to glass, when glass is broken, can cling glass fragment, the people in order to avoid glass fragment splashes around the injury.Described release rete 1 can be made of the PET film that scribbles mould release.Described wearing layer 10 is positioned at second basic unit, 9 outsides, and promptly second basic unit 9 is between the wearing layer 10 and second transparency conducting layer 8.Described wearing layer can adopt that a kind of ultraviolet (UV) is coating material solidified to solidify to form through UV.
The principle of work of above-mentioned variable color film is as follows:
When selecting switch 18 that straight-through branch road is directly linked to each other with second extraction electrode 11 with first extraction electrode 14, photoelectric conversion layer 5 converts luminous energy (being generally sunshine) to electric energy, photoelectric conversion layer 5 makes photoelectric conversion layer 5, dielectric substrate 6, electrochromic layer 7, second transparency conducting layer 8 and first transparency conducting layer 4 form the loop as power supply.Along with the change of intensity of illumination, the electric energy after photoelectric conversion layer 5 conversion also can change, and has changed simultaneously electrochromic layer 7 is injected and the electronics and the amount of ions of extracting out, therefore cause electrochromic layer painted/colour killing, thereby change the transmittance of variable color film.At this moment, the variable color film need not consumed power, can also be heat insulation.When selecting switch 18 that second branch road is linked to each other with second extraction electrode 11 with first extraction electrode 14, connect with the mains 18 and variable resistor 17 between first extraction electrode 14 and second extraction electrode 11.Power supply 18, first transparency conducting layer 4, photoelectric conversion layer 5, dielectric substrate 6, electrochromic layer 7, second transparency conducting layer 8 and variable resistor 17 form the loop, the voltage that is added on the electrochromic layer 7 will be provided by power supply 18, the resistance of regulating variable resistor 17 can change the transmittance of variable color film, the user can arbitrarily change the transmittance of film at any time rapidly, and the response time is short.
When using variable color film of the present utility model, need take release film earlier off, the pressure sensitive adhesive face is attached to glass inner side, flatten the back firmly compacting get final product, the whole erection process is convenient and swift.The production technology of variable color film of the present utility model is simple, cost is low, the convenient installation.
Above content be in conjunction with concrete preferred implementation to further describing that the utility model is done, can not assert that concrete enforcement of the present utility model is confined to these explanations.For the utility model person of an ordinary skill in the technical field, under the prerequisite that does not break away from the utility model design, can also make some simple deduction or replace, all should be considered as belonging to protection domain of the present utility model.

Claims (6)

1. variable color film, comprise first basic unit (3), first transparency conducting layer (4), dielectric substrate (6), electrochromic layer (7), second transparency conducting layer (8), second basic unit (9), first extraction electrode (14) and second extraction electrode (11), described first extraction electrode (14) is electrically connected with first transparency conducting layer (4), described second extraction electrode (11) is electrically connected with second transparency conducting layer (8), it is characterized in that: also comprise photoelectric conversion layer (5) and be used to make first extraction electrode (14) and second extraction electrode (11) directly to be communicated with or make the control system (12) of connecting with the mains between first extraction electrode (14) and second extraction electrode (11); Described first basic unit (3), first transparency conducting layer (4), photoelectric conversion layer (5), dielectric substrate (6), electrochromic layer (7), second transparency conducting layer (8) and second basic unit (9) arrange in turn.
2. variable color film according to claim 1 is characterized in that: the number of described first extraction electrode (14) has the number of at least two and/or second extraction electrode (11) to have at least two.
3. variable color film according to claim 1 is characterized in that: the selector switch (18) that described control system (12) comprises straight-through branch road, second branch road, be used to make straight-through branch road or second branch road and first extraction electrode (14) to link to each other with second extraction electrode (11); Described second branch road comprises power supply (16).
4. variable color film according to claim 3 is characterized in that: described second branch road also comprises variable resistor (17), described power supply (16) and variable resistor (17) series connection.
5. according to the arbitrary described variable color film of claim 1-4, it is characterized in that: also comprise pressure-sensitive adhesive layer (2) and release rete (1), described pressure-sensitive adhesive layer (2) is positioned between release rete (1) and first basic unit (3).
6. according to the arbitrary described variable color film of claim 1-4, it is characterized in that: also comprise wearing layer (10), described second basic unit (9) is positioned between wearing layer (10) and second transparency conducting layer (8).
CNU2007201965271U 2007-12-27 2007-12-27 Color changing membrane Expired - Fee Related CN201159816Y (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101852960A (en) * 2010-05-14 2010-10-06 马鞍山市盛宁高分子材料科技有限公司 Full-solid state macromolecule controllable electrochromism flexible film device and manufacturing method thereof
CN102841473A (en) * 2011-06-23 2012-12-26 比亚迪股份有限公司 Electrochromism device and preparation method thereof
CN103676391A (en) * 2012-09-24 2014-03-26 纬创资通股份有限公司 Electrochromic panel and control device
CN105022199A (en) * 2015-08-13 2015-11-04 武汉大学 Energy-saving display device and display method
CN105185296A (en) * 2015-10-27 2015-12-23 武汉大学 Display device
CN106384565A (en) * 2016-09-12 2017-02-08 昆山国显光电有限公司 Display device and manufacturing method thereof
CN108445661A (en) * 2012-04-18 2018-08-24 开关材料公司 System and method for controlling filter assembly
CN109557739A (en) * 2019-01-18 2019-04-02 南京工业大学 A kind of optical drive electrochromic device and preparation method thereof
CN109634018A (en) * 2019-01-29 2019-04-16 信利光电股份有限公司 A kind of discoloration cover board
CN113156731A (en) * 2020-01-23 2021-07-23 北京开阳亮微科技有限公司 Method for controlling electrochromic device

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101852960A (en) * 2010-05-14 2010-10-06 马鞍山市盛宁高分子材料科技有限公司 Full-solid state macromolecule controllable electrochromism flexible film device and manufacturing method thereof
CN102841473A (en) * 2011-06-23 2012-12-26 比亚迪股份有限公司 Electrochromism device and preparation method thereof
CN102841473B (en) * 2011-06-23 2016-03-30 比亚迪股份有限公司 A kind of electrochromic device and preparation method thereof
CN108445661A (en) * 2012-04-18 2018-08-24 开关材料公司 System and method for controlling filter assembly
CN108445661B (en) * 2012-04-18 2021-09-07 首诺加拿大公司 System and method for controlling an optical filter assembly
CN103676391A (en) * 2012-09-24 2014-03-26 纬创资通股份有限公司 Electrochromic panel and control device
CN103676391B (en) * 2012-09-24 2016-08-24 纬创资通股份有限公司 Electrochromic panel and control device
CN105022199A (en) * 2015-08-13 2015-11-04 武汉大学 Energy-saving display device and display method
CN105185296A (en) * 2015-10-27 2015-12-23 武汉大学 Display device
CN106384565A (en) * 2016-09-12 2017-02-08 昆山国显光电有限公司 Display device and manufacturing method thereof
CN109557739A (en) * 2019-01-18 2019-04-02 南京工业大学 A kind of optical drive electrochromic device and preparation method thereof
CN109634018A (en) * 2019-01-29 2019-04-16 信利光电股份有限公司 A kind of discoloration cover board
CN113156731A (en) * 2020-01-23 2021-07-23 北京开阳亮微科技有限公司 Method for controlling electrochromic device
CN113156731B (en) * 2020-01-23 2022-06-07 青岛凯欧斯光电科技有限公司 Method for controlling electrochromic device

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C14 Grant of patent or utility model
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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20081203

Termination date: 20151227

EXPY Termination of patent right or utility model