CN201025173Y - Carbinol-hydrogen combined fuel engine - Google Patents

Carbinol-hydrogen combined fuel engine Download PDF

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Publication number
CN201025173Y
CN201025173Y CNU2007200953489U CN200720095348U CN201025173Y CN 201025173 Y CN201025173 Y CN 201025173Y CN U2007200953489 U CNU2007200953489 U CN U2007200953489U CN 200720095348 U CN200720095348 U CN 200720095348U CN 201025173 Y CN201025173 Y CN 201025173Y
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Prior art keywords
engine
carbinol
methanol
hydrogen
pump
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Expired - Fee Related
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CNU2007200953489U
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Chinese (zh)
Inventor
尹承绪
黎苏
何小平
丁文金
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Zhejiang Kaiji Automobile Spare Parts Manufacture Co Ltd
Hebei University of Technology
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Zhejiang Kaiji Automobile Spare Parts Manufacture Co Ltd
Hebei University of Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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Abstract

The utility model discloses an engine which uses the carbinol-hydrogen as the combined fuels. The utility model comprises an engine body, a tail gas purifier, a muffler, a carbinol fuel box and a carbinol pump, etc. a splitting reactor is serially connected between the tail gas purifier and the muffler, and the split hydrogen are connected to a gas inlet system of the engine. The fuels in the carbinol fuel box are directly supplied to the splitting reactor in one path while are reached the gas inlet system of the engine by passing through the carbinol pump, a carbinol fuel pump and a nozzle in a serially connecting method in another way. The space between the engine body and the tail gas purifier is provided with an oxygen sensor as the feedback of the burning signal, the singles of the oxygen sensor and the sensor groups are connected to an electricity controlling unit, and the electricity controlling unit controls the work states of the carbinol nozzle, an adjusting valve, a gas inlet warm-up device, an igniting loop and a carbinol pump. The utility model is characterized in that: the engine exhausting is adopted as the carrier of the circularly heat supplying; the splitting and transferring of the carbinol steam on the special activators are fulfilled with one step; the utility model can effectively protect the environment and makes the tail gas discharged by the engine reach the environment-protection guideline.

Description

Methanol-hydrogen compounded fuel engine
Technical field
The utility model belongs to substitute Fuel of Internal Combustion Engine, and being specifically related to a kind of is the motor of composite fuel with the methanol-hydrogen.
Background technique
Along with the anxiety of the energy and the people reinforcement to atmospheric environment protection consciousness, the motor fuel of seeking high-efficiency cleaning becomes one of major issue in the internal-combustion engine technology.Alcohol is as clean alternative fuel, and is in liberal supply at present, and price is suitable.Thereby single from economic analysis, what motor use methyl alcohol will be good than use gasoline Economy is many.From technical development, the methanol decomposition hydrogen producing technology is used widely in industries such as chemical industry, metallurgy, oil.At current outstanding environmental problem, necessary the methanol decomposition hydrogen producing technology is applied in motor energy-conservation.Obtain by retrieval Chinese patent abstract database, at digest " the automotive residual heat schizolysis hydrogen production plants of environmental protection and energy saving " (searching number: propose a kind of technology CN2485438), the auxiliary electro-heat bolt is distributed in the cracking room, owing to adopted the auxiliary electro-heat bolt, motor is when the low temperature low cruise, and the logical heating of electric heating bolt raises cracking temperature rapidly, with crossing employing center short circuit pipe shunting mode, and can control automatically and make the cracking temperature can be not too high.In patent " the engine producing hydrogen with remainder heat " (patent No.: also propose a kind of technology ZLO1221486.8), promptly utilize the waste heat of engine exhaust, the alcohol catalysis cracking of liquid state is become the hydrogen of gaseous state, again with its with enter the cylinder internal combustion after gasoline mixes, realize alcohol---hydrogen is for combustion, lean combustion, improve the energy source power, reduce the pollution of engine emission atmosphere environment.These measures are a kind of new methods for improvement combustion in IC engine effect.But have following shortcoming: because delivery temperature is low, and directly cracking alcohol is produced hydrogen, this moment, motor must use gasoline during (1) engine cold-start; (2) the hydrogen mixed gas of cracking can not satisfy the requirement of motor high load working condition, promptly burns when motor still need adopt gasoline and hydrogen fellowship when middle high load working condition moves, and this will make engine control system complicated; (3) vehicle need be provided with methyl alcohol, two fuel tanks of gasoline, and is very inconvenient.
Given this, in the key technology of alcohol (hydrogen) Dai Ran, the utility model proposes a kind of new technology, it does not need the original structure of motor is done big change, as long as a cover lytic response apparatus is set on vent systems, and on motor, install a cover centralized control system additional, and just can utilize engine exhaust heat, the alcohols catalytic pyrolysis is produced hydrogen, the generation combustion is energy-conservation, reduces pollution emissions.
Summary of the invention
The purpose of this utility model is that proposing a kind of is the motor of composite fuel with the methanol-hydrogen, utilize the exhaust heat of motor that methyl alcohol catalytic pyrolysis in cracking reactor is produced hydrogen, then hydrogen is introduced motor and burn, to reach the purpose that reduces pollution emissions as fuel.
Below in conjunction with accompanying drawing know-why of the present utility model is described.The utility model is to utilize the exhaust heat of motor with methyl alcohol catalytic pyrolysis in cracking reactor, produces hydrogen, then hydrogen is introduced engine combustion.When motor is in the state of cold machine startup, directly burning methanol operation of motor, treat exhaust with cracking reactor be heated to temperature required after, the control system of motor automatically switches to the fuel of hydrogen cracking gas as motor, thereby realizes the methanol-hydrogen combination of engine combustion.Methanol-hydrogen compounded fuel engine mainly comprises engine body 1, exhaust purifier 2, silencing apparatus 3, methanol fuel case 4, methanol pump 5, pressure regulator valve 6, methanol fuel rail 7, methyl alcohol nozzle 8, flow control valve 9, lambda sensor 10, cracking reactor 11, gas handling system 12, engine condition sensor group 13, control system 14, air-intake heating mechanism 15 and spark coil 16 etc.Constitute the methanol fuel supply system of motor by methanol pump 5, pressure regulator valve 6, methanol fuel rail 7, methyl alcohol nozzle 8.Constitute the vent systems (frame of broken lines among the figure) of engine exhaust by exhaust purifier 2, cracking reactor 11, silencing apparatus 3, cracking reactor 11 is serially connected between exhaust purifier 2 and the silencing apparatus 3, and its exhaust airstream inlet exports close-coupled with the exhaust airstream of exhaust purifier 2.Exhaust heat by exhaust purifier 2 flow outlets produces hydrogen with methyl alcohol catalytic pyrolysis in cracking reactor 11, the hydrogen that cracking goes out is connected to the gas handling system 12 supply engines burning of engine body 1 by the road, constitutes methanol fuel cracking gas (hydrogen) supply system of motor thus.Methanol fuel in the methanol fuel case 4 divides the two-way supply: the one tunnel through flow control valve 9 supply cracking reactors 11, are cracked into the gas handling system 12 that hydrogen arrives at engine body 1 in reactor; The methanol fuel on another road arrives at the gas handling system 12 of engine body 1 through methyl alcohol nozzle 8 by methanol pump 5, pressure regulator valve 6, methanol fuel rail 7 in the serial connection mode.On the gas-entered passageway of gas handling system 12, be provided with air-intake heating mechanism 15.The sensor groups of being made up of the sensor of various perception engine behaviors 13 (sensor groups comprises: crankshaft position sensor, speed probe, air inlet pressure sensor, throttle position sensor, cooling-water temperature transmitter, fuel gas temperature sensor, gaseous-pressure sensor) is housed on engine body 1.Be provided with lambda sensor 10 as feedback signal between engine body 1 and the exhaust purifier 2, the output signal of lambda sensor 10 and sensor groups 13 is connected to the signal input part of ECU (Electrical Control Unit) 14.The output terminal of ECU (Electrical Control Unit) 14 is by the working state of signaling line control methanol pump 5, methyl alcohol nozzle 8, flow control valve 9, air-intake heating mechanism 15 and spark coil 16.System adopts air inlet heating device 15 to its objective is the fogging degree that improves methanol fuel, makes burning more abundant.Adopt the delivery volume of flow control valve 9 control methyl alcohol, make dissociated methanol gas satisfy the requirement of Under Different Work Condition of Engine to cracking reactor 11.
Methanol decomposition hydrogen manufacturing principle:
(1) methyl alcohol by catalyzer, is cracked into carbon monoxide and hydrogen under 280~350 ℃ of temperature.Reaction equation is as follows: CH 3OH → CO+3H 2
(2) carbon monoxide and hydrogen are discharged carbon dioxide and water in the acting of engine air in-cylinder combustion.Reaction equation is as follows:
2CO+O 2→2CO 2;2H 2+O 2→2H 2O。
Description of drawings
Accompanying drawing is methanol-hydrogen compounded fuel engine critical piece and control wiring connection diagram thereof.
Among the figure: the signaling line and the control wiring of → expression control system;---→ expression methyl alcohol is supplied with route;--→ expression cracking gas air inlet route; The mixed gas of → expression air and fuel;
Figure Y20072009534800051
Expression exhausting waste gas route.
Embodiment
Below by specific embodiment know-why of the present utility model is further described.By shown in the accompanying drawing each parts being assembled.Cracking reactor 11 is installed in the pipeline between exhaust purifier 2 and the silencing apparatus 3, the exhaust airstream outlet close-coupled of its exhaust airstream inlet and exhaust purifier 2.By the lambda sensor 10 that is provided with on vent systems, the inflammable mixture concentration of monitoring combustion process is regulated control as feedback signal by the delivery volume of 14 pairs of pure fuel of ECU (Electrical Control Unit).The working procedure of methanol-hydrogen compounded fuel engine is to supply with the inflammable mixture of variable concentrations (is measurement index with the air excess factor), to realize the requirement of Under Different Work Condition of Engine.At first, during engine cold-start, because there is not exhaust heat, thus can not cracking hydrogen production, ECU (Electrical Control Unit) 14 control methyl alcohol nozzles 8 sprayed methanol fuels and entered engine chamber and burn this moment.Along with the rising of engine temperature, when delivery temperature reached 280 ℃, the part methyl alcohol of the high temperature of exhaust in can cracking reactor 11 produced hydrogen, and this moment, supply engine carried out the mixture that burnt fuel is methyl alcohol and hydrogen---and alcohol and hydrogen mixed.Along with the carrying out of burning when engine exhaust temperature surpasses 350 ℃, promptly be able to cracking when going out a large amount of hydrogen, ECU (Electrical Control Unit) 14 will be cut off pure fuel injection branch road automatically, realize pure hydrogen burning.
Whole process methanol decomposition thermomechanics is as follows:
Methyl alcohol is having under the condition of catalyzer 350 ℃ by following reaction equation cracking: CH 3OH → CO+2H 2
Every mol methyl alcohol has absorbed the waste heat of vehicle exhaust, is vaporized into 350 ℃ steam from the liquid heating of normal temperature, and the heat content increment is: 156 (64.51-25)+35000+106 (350-64.51)=71.4kJ/mol
Behind the 1mol methanol decomposition, produce the carbon monoxide of 1mol and the hydrogen of 2mol.Its calorific value increases to:
CO+1/2O 2→CO 2,ΔH=284.7kJ/mol;H 2+1/2O 2→H 2O,ΔH=242.6kJ/mol。
Every mol methyl alcohol is by after the catalytic pyrolysis, and the increment of its heat content is:
(248.7+2×242.6+71.4)-726.55=78.8kJ/mol
Embodiment utilizes the cracking gas of engine tail gas waste-heat dissociated methanol generation as can be known thus, and its calorific value has improved 10.8% than the methyl alcohol of original homogenous quantities.
The beneficial effects of the utility model are: adopt engine exhaust as the circulation heating carrier, except satisfying technological requirement Outer and energy consumption is low, methanol steam cracking and transform a step and finishes on special-purpose catalyst. That special-purpose catalyst has is active high, Selectively good, serviceability temperature is low, the characteristics that the life-span is long. The utility model is protection of the environment effectively, makes engines tail The gas discharging reaches environmental protection index.

Claims (1)

1. methanol-hydrogen compounded fuel engine, comprise engine body (1), exhaust purifier (2), silencing apparatus (3), methanol fuel case (4), methanol pump (5), pressure regulator valve (6), methanol fuel rail (7), methyl alcohol nozzle (8), modulating valve (9), lambda sensor (10), it is characterized in that: between described exhaust purifier (2) and described silencing apparatus (3), be connected in series a cracking reactor (11), the hydrogen that cracking reactor (11) cracking goes out is connected to the gas handling system (12) of engine body (1) by the road, and the methanol fuel one tunnel in the methanol fuel case (4) is directly supplied with cracking reactor (11) through flow control valve (9); The methanol fuel on another road reaches the gas handling system (12) of engine body (1) in the methanol fuel case (4) through methyl alcohol nozzle (8) by methanol pump (5), pressure regulator valve (6), methanol fuel rail (7) in the serial connection mode; Sensor groups (13) is housed on engine body (1), be provided with lambda sensor (10) between engine body (1) and the exhaust purifier (2), the signal output part of lambda sensor (10) and sensor groups (13) is connected to the signal input part of ECU (Electrical Control Unit) (14), by the working state of ECU (Electrical Control Unit) (14) control methyl alcohol nozzle (8), modulating valve (9), air inlet heating device (15), spark coil (16) and methanol pump (5).
CNU2007200953489U 2007-02-27 2007-02-27 Carbinol-hydrogen combined fuel engine Expired - Fee Related CN201025173Y (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111197532A (en) * 2020-01-09 2020-05-26 杰锋汽车动力***股份有限公司 Hydrogen/methanol composite fuel engine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111197532A (en) * 2020-01-09 2020-05-26 杰锋汽车动力***股份有限公司 Hydrogen/methanol composite fuel engine

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Granted publication date: 20080220

Termination date: 20130227