CN1986662A - Paint composition for both writing and printing on smooth surface - Google Patents
Paint composition for both writing and printing on smooth surface Download PDFInfo
- Publication number
- CN1986662A CN1986662A CN 200510133798 CN200510133798A CN1986662A CN 1986662 A CN1986662 A CN 1986662A CN 200510133798 CN200510133798 CN 200510133798 CN 200510133798 A CN200510133798 A CN 200510133798A CN 1986662 A CN1986662 A CN 1986662A
- Authority
- CN
- China
- Prior art keywords
- resin
- printing
- colloid
- coating composition
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention is a kind of paint composition, which makes it possible for offset printing ink and writing ink to be printed or written on compact surface of plastic, metal sheet, etc. The present invention makes printing on compact surface inexpensive.
Description
One, technical field
In modern society, needs along with the human being's production life, non-paper printing more and more is widely used, it is a very extensive fields of a purposes, comprising plastic printing, sheet metal printing and special object surfaces printing, this class is printed on and more has a deep effect in recent years in our productive life, therefore, how to handle compact surfaces printing at object, expansion is write, the printing timber range, seek more economical, more convenient, better write, better printing effect will be the press Eternal Theme, also make press become the point of suppon of 21st century economy.
Two, technical background
Mode of printing on the fine and close thing of non-paper class surface is a lot of now, silk screen printing, heat transfer printing, flexographic printing, intaglio printing etc. are arranged, that adopts above mode of printing mainly contains frosting, metal object surface printing, print off plastics, metal products and packages printing fineness, the proper generous main flow that becomes press already of coming, but disadvantageous one side is arranged all the time, mainly contain following some: 1, the single printing cost is too high, and the printing scale can not be too small.2, facility investment is expensive complicated.Though more than which printing technology, if realize extensive printing, all have the facility investment complexity, and existing equipment work failure rate is higher, needing higher professional and technical personnel's operation can be competent at.3, printing cost is higher.The printing ink of seal plastics, mental package is not common ink generally, at first costs an arm and a leg, and secondly be the technical process complexity, it prints to clean all needs high cost, and some synthesis of chemicals easily damages human body.4, print speed is slow.Because plastics, operplate printing packing, printing process complexity, printing ink are difficult for parching, particularly multicolour printing needs large-scale drying plant, so its technical process prolongs the batch process task of influence printing greatly.More than four shortcomings, for lithographic plate and the offset printing of adopting paper, just do not exist.For this reason, a lot of in the world people improve its tinting strength and have carried out unremitting effort improving fine and close thing surface, as United States Patent (USP) 98807165.7: the microporous membrane of ink-jet printable, it has carried out certain innovation to ink jet printing; Belgian patent 97191856.2: printable film, adopt the radiation curable ink printing plastics; United States Patent (USP) 97102115.5: make the printable coating of plastic film, provide a kind of can lithographic plastic film, mainly adopt a kind of ethene---acrylic copolymer and filler particles, certainly, its usage platform is a lithography, does not mention the use range of printing ink.
A fact is, improve in the patent of plastic printing to the sticking power of printing ink in this numerous classes, much all used the olefinic compounds base polymer to change the tinting strength on fine and close thing surface, but, concerning printing itself, adhering to of printing ink is a comprehensive complicated physical and chemical process, is not that single certain compounds can be dealt with problems.
As everyone knows, paper can write that can to print be because wherein contain Mierocrystalline cellulose, and fiber have good absorption moisture and pigmentable ability, and therefore, it becomes us and writes the only choosing of printing with material.
But for fine and close body surface, its surface can not be painted by infiltration, and printing ink can't adhere to combination on its surface, also just can't write and print.Its solution strengthens resin ratio in the printing ink exactly, print with the raising colorant adhesion, but it has a lot of drawbacks, as cost height, complex process, the difficult grasp of color accuracy, the minimum quantity of one-step print is bigger, could satisfy cost requirement, thereby make plastics film or sheet metal printing become a kind of expensive process.What must carry here is the ink typography, promptly by improving the technology that the black quality of seal enlarges print range.The impetus of the development of ink printing now is very fast, on flexo and wheel commentaries on classics gravure, many application have successfully been developed, but it also has very long distance to walk from large-scale promotion, its subject matter is following aspect: 1, be still sixty-four dollar question in the ink application time of drying, unless printing press is furnished with enough drying plants, otherwise print speed therefore and influenced.This also is to influence the greatest factor that ink replaces solvent inkjet ink process speed; 2, because ink is dissolved in basic solution makes ink use in high magnetic environment to be restricted; 3, the application of ink on Frozen Food Packaging still do not have the patience of solvent inkjet ink, although distance is in quick shortening; 4, the high surface free energy owing to water component in the ink makes ink be difficult to well wetting and printing on many base materials.
The surface tissue that does not have a kind of mode to change plastics film or sheet metal is arranged, it also can be write, also can on offset press, print, by printer prints? there is dual mode to accomplish, the one, the own surface tissue of change plastics film or sheet metal allows it write or to print; The 2nd, change its surface tissue with coating method.What the present invention adopted is second method.
The present invention will propose is a kind of plastics film, sheet metal and need the compact surfaces of printing object or can write and wash, draw together the wiping nondiscoloration with common pen with the plain paper ink printing of allowing, and can change a kind of coating composition of above object compact surfaces structure behind the applying coating.The present invention also can be described as the coating composition that can write printable sheet, so Ming Siyi promptly writes at the available pen in coated article surface, the pen here is meant the common ink water-color paintbrush.Because general fine and close body surface can not directly be write with pen, having write word also will fall, main purpose of the present invention is the usage space of expanding plastics film, sheet metal and needing the printing object, thereby makes it can equally with paper also can write or print and be widely used.
Three, summary of the invention
1, functional overview of the present invention and each component explanation
The present invention is by a kind of treatment process on stock surface to non-paper class, the result who adopts the present invention to handle be generate at body surface a kind of tough and tensile, permeable to printing ink, the colourability film, but its film is the hydrophobic nature film to water, infiltration that can anti-sealing and not peeling off, the degree of adhering to of its film degree of being kept perfectly greater than 97% situation under the anti-wiping power of drawing together be at least 3kg/m m
2, can intactly substantially present pattern and color.
Macromolecule resin among the present invention should be dissolved in solvent fully, because the kind of macromolecule resin is a lot, the nature difference of each resin is very big, and for same resin, its macromolecule resin choice of Solvent and collocation mode are also varied, so the type decided of selective solvent a kind of dissolving resin degree, have also determined the surface adhesion force of resin, also determining simultaneously and the each component blended ability that mixes, so choice of Solvent is the comparison key.In following examples,, all be the common solvent of using with resin complete as not doing special explanation.In addition, different resins is owing to the different also corresponding differences of sticking power ratio in the present invention, so the difference of its resinous principle is also determining with the portfolio ratio of each component very big-difference is arranged.
Carbohydrate colloid among the present invention comprises monose, oligose and polysaccharide, and they should be the extract of natural goods or natural goods or the colloid of deriving of extract, if it is used to write, its color and luster is water white transparency or white preferably.If adopt the colloid mixture of sugar and starch, generally adopt carbohydrate to mix and boil with starch, the particle diameter of starch is the smaller the better, and the colloid that boils out like this is evenly thorough, does not have big coarse grain.It boils sugar and starch and water formula range and can adopt 3: 1: 6 or 3: 2: 8 or 1: 1: 5 or 4: 6: 9 equal proportions, with sugar and starch wait in proportion measure after, earlier starch is boiled into pasty state separately, and then add water in above ratio and add catalyzer (as all kinds of slightly acidic diluted acids etc.) and boil again, the result who finally boils is the jelly that reaches the moving state of a kind of semi-fluid.The colloid of making like this is more stable, also is easy to mix with the resin colloid.
But its solvent water of the protein-colloid among the present invention or the proteic organic liquor of solubilized, its colloid color and luster is water white transparency, white or faint yellow preferably, can place for a long time and not now the precipitation.Grease among the present invention should mix with resin solvent and form the stabilized mixture that does not react.
It is 5-9 modified starch colloid that the starch-hydrocolloid that adopts among the present invention preferably adopts pH value, and its colloid concentration should reach maximum value.Raising agent among the present invention can adopt and be not less than 10 purpose rigid particles, and the absorption of printing ink is played convergence, osmosis, and how much it decide on the actual needs that the degree of adhering to and the printing of this composition resin are write.
The ratio value difference that should be noted that each component portfolio ratio among the present invention is very big, this is because it is not a chemical formula, to change according to Substance Properties in the component and decide, finally form the tough and tensile film of a kind of hydrophobic nature strong adhesion, that irreversible color reaction can take place with ink or seal China ink on the stock surface, so as long as keep necessary component, and suitably regulate ratio between them, just can generate such film, how much, can only between its possible maximum value and minimum value, choose as for the difference between the each component.
In claims of the present invention in 3 to 6 material should mix in twos and chemical transformation not take place, layering takes place, produce phenomenons such as precipitation, heating, variable color and produce as not having to leave standstill.
Its final color and luster of coating composition of the present invention is in the best state to be colourless, white or yellowish, light gray, grey violet, pale red etc. (as coating composition is that dark color is also passable, but after applying not Ying Yin be coated with the surface composition true qualities and influence it and write printing effect), its physical features is semifluid jelly.
Each component is extremely many because of its kind among the present invention, therefore selected materials is very extensive, make mixture keep good admixture, according to different resins and type of solvent different interpolation order should be arranged: concerning solvent is the water type resin solution (water-miscible paint) of water, because present water-miscible paint is alkalescence mostly, therefore preferably earlier the carbohydrate colloid is mixed with the resin gel phase, generate stable mixture through mixing, then, add protein-colloid or modified starch colloid more successively, add raising agent at last.
Certainly, in actual use, as required, the actual interpolation can be different, also can evenly spray again behind coating composition coated object surface as raising agent, and the coating back is done soon like this, and it is also fine to write printing effect.Another need to prove have than big-difference between the same kind character of present composition material requested, and how much it need reach optimum, and repeatedly debug could success.
Concerning solvent type resin solution, situation will complicated point, be the resin liquid that alcohols or each vegetable oil are tempered at first for solvent composition major part, to being that the protein-colloid of solvent should add or not add less with water, because pure type organic is easy and protein-colloid produces reaction, and all kinds of vegetables oil and water are immiscible.The second, solvent type resin solution with should add honey or other carbohydrate colloids earlier before other components mix, and then add other components, can show intermiscibility preferably like this.The 3rd, solvent type resin is mainly made true solvent with ester class, ketone, ether-ether class etc., and alcohols etc. are solubility promoter, and benzene class etc. is a thinner, much is high volatilised liq.Therefore, generally should add slow curing solvents such as resembling N-BUTYL ACETATE, dimethylbenzene, Virahol, pimelinketone and make certain amount of stabilizer, reduce its volatilization degree.The 4th, solvent type resin is to the coefficient result of several often solvents of dissolving resin power, so its solvent formula is very complicated, along with scientific-technical progress, have a lot of new prescriptions and constantly produce, this specification sheets generally is meant common prescription or brand product as not being specifically noted.
Need to prove especially when the pH value of coating composition is positioned at 7～10 weakly alkaline scope, it writes with printing performance better, but its surperficial produced film is not the water tolerance film, can not stop the infiltration of water, places consequences such as dim pattern, decolouring easily take place when envrionment temperature is lower than 8 ℃.Only during greater than 8 ℃, can consider to produce and use in special requirement, non-aqueous contact and envrionment temperature.
2, embodiment and comparing
Embodiment 1
Its coating composition is selected for use in very common on the market polyamine fat, egg albumen, honey, soybean oil, and brand is not limit, and modified starch should select pH value less than 7 slightly acidic or neutral starch, and the raising agent particle diameter is 300 purpose silicon-dioxide.Its portfolio ratio and result of implementation such as following table:
Last table embodiment 1 lists 10 assembly sides, but its result of implementation is reflected in the acceptance, but acceptance be meant composite dope draw together be coated in the stock surface after, be coated with the writing of surface, the acceptable degree of printing performance drawing together, it should have two indexs: 1. to write dried fully back with burnt black ink or blue-black ink at 6kg/m m
2Its reserving degree of writing pattern is as the criterion under the pressure effect, is the best with 97% in general, down by that analogy; 2. test the firm degree and the water tolerance of coated surface; Estimate its acceptable degree from above two index comprehensives.From 1 to 10 group of embodiment 1, but acceptance is the embodiment that is more than 50%, but acceptance less than 50% be comparative example.We can see from above ten groups of gained data, first three ratio of planting material plays a crucial role, maximum value and mnm. place at polyamine fat, but its acceptance all is lower than 50%, shows that its composition all has very unsatisfied place behind coating of objects, wherein the 9th group since the resin composition few, its anti-wiping scarce capacity of drawing together, its overlay film is insecure easily to be fallen, and its film is not the water tolerance film, is subject to the etch of water; The 10th group since the ratio of other composition very little, its printing and writing ability are affected;
Among the embodiment 1 the 1st group, the 8th group because its polyamine fat composition greater than 60%, causes its protein-colloid and its portfolio ratio of colloid of sugar to be not more than 30%, and the ratio of raising agent is improper, so it writes existing problems, but also is in tolerance interval.
The 7th group still is because polyamine fat ratio is too low among the embodiment 1, and not really firm sign is arranged after its film forming.Among the embodiment 1 other 2,3,4,5 groups but to remove the 3rd group of acceptance low slightly, other several groups should be in acceptable normal range, wherein the 6th group of test result is quite a lot of.
Embodiment 2
Its coating composition is selected polymeric amide fat, honey, egg albumen, carrageenin (brand is not limit) for use.It should be noted that water content should reach minimum in the carrageenin colloid.Modified starch should select pH value less than 7 slightly acidic or neutral starch, and the raising agent particle diameter is 300 purpose kaolin.Its portfolio ratio and result of implementation are as follows:
The the 9th, the 10th liang of group is comparative example among the embodiment 2, and obviously, when polymeric amide fat was in high or extremely low ratio, applying its quilt of back through composition, to be coated with surface properties the poorest, its write and print result very unstable.Because it is 8 weakly alkaline that polymeric amide fat is partial to pH value, therefore slightly acidic modified starch add-on and preceding two examples are relatively more some more, other external cause has added carrageenin, but film that its coating composition forms increases the wettability of printing ink, but simultaneously its film hydrophobic nature is also than the difference that becomes of embodiment 1, but generally write and printing effect on improve a lot.Wherein best between writing of providing of its combination in 30%～45% o'clock, printing capability at polymeric amide fat, as the 3rd, 4,5,6 group among the embodiment 2.The the 1st, the 2nd, the 8th these three groups of effects are general among the embodiment 2, and main influence should be that the egg albumen add-on is less, cause its coated surface tinting strength to reduce, certainly also with the rare pass of the add-on of carrageenin, this is that composite factor causes.Among the embodiment 2 the 7th group mainly still film degree of adhering to is not enough, this is less and raising agent is more relevant with resin.
Embodiment 3
Its coating composition is selected polyamine fat, honey, whole milk (boil, contain the fat of 3%-5%, following examples are not as being specifically noted, and its contained fat ratio is identical), carrageenin (brand is not limit) for use, but water content should reach minimum in the carrageenin colloid.Modified starch should select pH value less than 7 slightly acidic or neutral starch, and the raising agent particle is 350 purpose medical talc powders.Its portfolio ratio and result of implementation are as follows:
Embodiment 3 compares with embodiment 2, considerable change does not take place in its allocation ratio, but but the acceptance that test draws improves greatly, the main variation is that polyamine fat has replaced polymeric amide fat, whole milk has replaced egg albumen, because polyamine fat compares with polymeric amide fat, the mutual solubility and the stability of its and other material are eager to excel in whatever one does, not outer effect owing to casein in the milk and raising agent is strengthened the color reaction on coated surface significantly, thereby improves its tinting strength.The the 9th, the 10th liang of group is comparative example among the embodiment 3, finds out that obviously resin ratio is too high or too low in these two groups, all influences the tinting strength or the anti-wiping ability of drawing together of its coated surface.In the first eight group, the 5th, the 6th liang of group shows that tinting strength and stability are best, has good practicality.Other several groups differences owing to the each component allocation ratio, but its acceptance of writing, printing is in better level, but compare with the 5th, the 6th liang of group, the allocation ratio of milk is less relatively, and its adaptability of writing, printing is less better.Therefore,, be stressed that by embodiment 3, the allocation ratio of milk protein-colloid to composition be coated with the writing of surface, printing capability has material impact.
Embodiment 4
Its coating composition selects for use water soluble acrylic resin, pH value to be neutral or weakly alkaline modified starch, egg albumen, carrageenin (brand is not limit), honey.It should be noted that water content should reach minimum in the carrageenin colloid.The raising agent particle is 300 purpose medical talc powders.Its portfolio ratio and result of implementation are as follows:
Among the embodiment 4 these ten groups, containing carbohydrate gum body ratio increases greatly, improve composition and be coated with the degree of adhering on surface and the stability of composition, but composition will differ from respect to embodiment 3 the permeable degree and the color reaction of ink, the 10th group is comparative example, keeps or is lower than at 1/3 o'clock in resin ratio but its acceptance is lower than the 50%, the 5, the 6th, the 7th group, it is write, printing and the anti-wiping degree of drawing together all reach effect preferably, should be reasonable allocation ratio.In embodiment 4, the 9th group more special, and the writing of this group, printing effect are better, but show that after tested its anti-wiping degree of drawing together is at 4 kg/m m
2Effect under less than 85%, its print surface is more easily damaged, so but acceptance is lower.
We are in front among the four class embodiment, the appearance degree that can find honey is the highest, in fact just like this, in the many experimentations of the present invention, reality has adopted rice meal, wheat-flour, Semen Maydis powder, sugar shallow lake mixture, pea flour, mealy potato, honey, and carrageenin, pectin, polyose polymer colloids such as konjak gum, in non-extraction class plant colloid, honey and sugared shallow lake mixture are tested through reality, their stability and can writing, printable contribution will be waited until direct plant carbohydrate colloid significantly better than rice meal, in extracting class plant carbohydrate colloid, carrageenin, pectin, polyose polymer colloids such as konjak gum performance in composition is equally stable, so in above four examples, we have selected honey, carrageenin illustrates as representative component.Modified starch also belongs to and extracts family macromolecule carbohydrate colloid, but it compares with other extract, is that polar is arranged, and therefore, we are mainly used in the Balancing degree in above embodiment.Change and a large amount of the use but also be not precluded within the actual use, boil etc. as mixing with monose, oligose according to composition components.
Embodiment 5
Its coating composition is selected Synolac (brand is not limit, and its solvent has contained boiled wood oil), honey, egg albumen, carrageenin (brand is not limit) for use.It should be noted that water content should reach minimum in the carrageenin colloid.The raising agent particle is 300 purpose quartz.Its portfolio ratio and result of implementation are as follows:
Above embodiment 5, we have adopted different resins, and therefore, respective change will take place in the actual sticking power of its composition, and also some is different with above 4 examples in its configuration.Among the embodiment 5 the 8th, the 9th, the 10 3 kind of combination be comparative example, smears the film of looking unfamiliar with the 10th group of its composition for the 8th group because resin ratio is higher, its film forming is to the perviousness of printing ink, but the color reaction acceptance of ink is lower than 50%.The 9th group problem then remains can not waterproof, anti-ly draw together wiping, and it is write and printablity should be in than higher acceptable level, but but its comprehensive acceptance shortly past 50%.
And the 6th, 7 liang of group should be to dispose relatively preferably among the embodiment 5, and from the result, resin, albumen two class colloids respectively account for a little less than in the of 1/3 in two groups, and the carbohydrate colloid accounts for the last 1/3, and the each component configuration is balanced, does not have the king-sized phenomenon of certain class colloid proportion.Other several groups integral body can be write to print to be in and be surpassed 50% moderate acceptable level.
Embodiment 6
Its coating composition is selected terephthalic acid polyester, sucrose and tapioca (flour) colloid mixture (ratio in 3: 2 boils), honey, carrageenin (brand is not limit) for use, egg albumen, and it is 300 purpose Calucium Silicate powder that raising agent adopts particle.It should be noted that water content should reach minimum in the carrageenin colloid.Its portfolio ratio and result of implementation are as follows:
Among the embodiment 6, the large percentage of alcohols thing in the solvating agent of terephthalic acid polyester, therefore, it and carbohydrate colloid and protein-colloid have good intermiscibility, the composition that is constituted is also more stable, also can find out from last table, though the composition of polyester what, but its coated article surface is write the acceptance of printing and is all maintained on the higher scope, implements in the combination the 8th, the 10th comparative example of other combination of embodiment for this reason.The same 5 routine embodiment are the same, but composition configuration relatively its coated article surface book of isostatic the the 5th, the 6th, the 7th combination acceptance of printing surely maintain one preferably on the level.
Embodiment 7
Its coating composition is selected polyvinyl resin, honey, gelatinum (brand is not limit), extra large bath glue (brand is not limit) for use, whole milk (boiling), and it is 300 purpose Calucium Silicate powder that raising agent adopts particle.It should be noted that water content should reach minimum in the extra large bath micelle colloid.Its portfolio ratio and result of implementation are as follows:
Polyvinyl resin among the embodiment 7 belongs to thermoplastic resin, and its solvating agent is a p-Xylol, trichlorobenzene, but in dissolution process if any grumeleuse, should slowly heat, allow it fully dissolve.Add honey more successively, extra large bath glue, gelatinum and milk add raising agent at last, are noted that not produce in adition process to condense, if the generation of condensing is arranged, also will continue to add solvating agent.From ten combined result of last example, but acceptance is not too high, and wherein the 1st group is comparative example with the 9th, the 10th group, but the 4th, the 5th, the 6 three group of acceptance after implementing is higher, this illustrates that once more extremalization can not appear in resin and other composition ratio, otherwise effect is bad.
Embodiment 8
Its coating composition is selected unsaturated polyester (commercially available), sucrose and tapioca (flour) colloid mixture (ratio in 3: 2 boils), gelatinum (brand is not limit), carrageenin (brand is not limit) for use, honey, and it is 300 purpose Calucium Silicate powder that raising agent adopts particle.It should be noted that water content should reach minimum in the carrageenin colloid.Its portfolio ratio and result of implementation are as follows:
Unsaturated polyester can not use solvent in this example when using as lacquer, but when mixing, had better use certain polyester thinner with other components of composition, can mix with honey earlier then, after the stirring again with carrageenin, gelatinum, sugared shallow lake mixture thorough mixing, then coating is applied to can print the thing surface after, evenly spray calcium silicate powder again, the surface is done soon like this, also help writing and printing, 7 examples also can adopt the example method to the use of raising agent before this, just more one operational procedures.
The particle diameter of starch helps thorough mixing so preferably less than 250 orders in this example, improves coating property.But the acceptance in this example between each group is relatively balanced, not have very big fluctuations, and raising agent is because of also having adopted the method that sprays in this group, so its proportion is low slightly.
Embodiment 9
Its coating composition is selected nitro-resin (lacquer, brand is not limit), honey, plam oil (brand is not limit), carrageenin (brand is not limit) for use, egg albumen, and it is 300 purpose Mierocrystalline celluloses that raising agent adopts particle.It should be noted that water content should reach minimum in the carrageenin colloid.Its portfolio ratio and result of implementation are as follows:
The nitro-resin that uses in this example, be based on nitrocotton, add a kind of varnish that synthetic resins, toughner, solvent and thinner are converted, it mix with above material the coating composition formed draw together be coated onto seal thing surface after, should spray with cellulose powder in the present embodiment again, but shown in the acceptance of the write printing that records as above shows.
Wherein the 8th, the 9th, the 10th these three groups be comparative example, several embodiment are different with the front, but the 10th group acceptance is lower in this example, this character with nitrocellulose resin itself is relevant, the film that nitro-resin forms at body surface has big fragility, less as proportion in composition, degree of adhering to relative mistake after its composition is smeared is a little, it is anti-draws together the wiping degree and water-repellancy can be a greater impact, in the 6th group, it is the highest that but its nitro-resin ratio accounts for 30% o'clock its acceptance, but but have the phenomenon that acceptance fluctuates up and down because of other factors in actually operating.
Embodiment 10
Its coating composition is selected Resins, epoxy, honey, egg albumen, pectin (brand is not limit) for use, whole milk (boiling), and it is 300 purpose Calucium Silicate powder that raising agent adopts particle.It should be noted that water content should reach minimum in the pectin colloid.Its portfolio ratio and result of implementation are as follows:
In this example the 8th, the 10th liang of group is comparative example, Resins, epoxy can adopt epoxy resin-based paint on the market, preface adds honey successively, egg albumen, pectin and whole milk, after stirring the stable mixture of composition, be applied to the stock surface again, be coated with the surface to quilt then and evenly spray the Calucium Silicate powder powder, treat to record above result after the surface drying, co-solvent is arranged, if amount is bigger if Resins, epoxy adds, then should strengthen the amount of egg albumen, reduce the milk ratio, prevent to produce muddy or precipitation, as can be known from above result, the 5th, the 6th, but the 7th group of acceptance wants high, the 9th group can to write state passable, but the anti-wiping degree difference of drawing together is a little, and writing is unintelligible.
More than ten examples only just basic skills of the present invention made description, but included timber range and extensively can not list one by one, can determine its moiety according to cost requirement in suitability for industrialized production.
Claims (8)
1. one kind is used for smooth object surface spraying, make be coated with the surface can have can common pen write, the coating composition of offset-printable.It is composed as follows:
(a) account for resin and the solvent of coating total mass 2%-97%;
(b) account for the monose of coating total mass 0-90% or oligose or polysaccharide colloid (or colloid mixture of all kinds of sugar, sugar and starch);
(c) account for the grease of coating total mass 0-5.7%;
(d) account for the protein-colloid of coating total mass 0-85%;
(e) account for the raising agent of coating total mass 0-20%;
Wherein: (a) and (b), (c), (d), (e) sum are not more than 100%.
2. as 1 described coating composition of claims, it applies back coated article Surface Physical feature should be to write printing back pattern fonts waterproof, anti-ly draw together wiping, in general, its anti-wiping power index of drawing together is, the degree of adhering to of its film draw together under the wiping degree of being kept perfectly greater than 97% o'clock its draw together wiping power and be at least 3kg/mm
2Have tinting strength, can be used for writing and printing of various inks commonly used, all kinds of printing ink.
3. as the described coating composition of claims 1-2 item, one of its feature is the formed lysate of macromolecule resin and solvent thereof, comprise synthetic resins and natural resin, the resin dissolves liquid that can mix with other composition of coating composition as Resins, epoxy, polyester, polyamine fat, Synolac, resol, ethenoid resin, nitro-resin, acrylic resin, polyamide resin, furane resin, celluosic resin, silicone resin, natural resin (as raw lacquer, shellac, amber) etc.
4. as the described coating composition of claims 1-2 item, one of its feature is the colloid mixture of monose (or oligose or polysaccharide) colloid or various carbohydrates or the colloid mixture that sugar is followed the starch heating and pressurizing, administration's class extract, monose or oligose and starch process mixture, honey, Mierocrystalline cellulose are arranged, all kinds of vegetable jelly and the colloid of deriving thereof are as guar gum, konjak gum, Viscogum BE, xanthan gum, carrageenin, seaweed gel, pectin, gum arabic, tragacanth gum, agar etc.
5. as the described coating composition of claims 1-2 item, one of its feature is this group compound oil-soluble grease, comprises vegetative grease and animal raw fat.As rape oil, soybean oil, peanut oil, sesame oil, Viscotrol C, tung oil, Oleum Gossypii semen, plam oil, sweet oil, Oleum Cocois, lard, butter, sheep oil, whale oil, sea dog wet goods.
6. as the described coating composition of claims 1-2 item, one of its feature is a protein-colloid, and promptly all kinds of vegetable-protein colloids are as soybean, Semen arachidis hypogaeae protein etc.; The animal proteinum colloid, as animal skin glue, gelatine, gelatinum, Air Bladder pseudosciaenae seu Acipenser, animal ovum egg white; Various animals milks, for example milk, goat milk, mare's milk etc.
7. as the described coating composition of claims 1-2 item, one of its feature be fineness at 10 order to 1000 orders or above raising agent, for example talcum, calcite, chalkstone, quartz, Mierocrystalline cellulose, kaolin, silicon bath soil, silicon-dioxide, lime carbonate, calcium sulfate, Calucium Silicate powder, barium sulfate, aluminum oxide, zinc oxide etc.
8. as the described coating composition of claims 1-2 item, the scope of its coated article is to print the smooth-flat-surface of object, and after covering this coating composition coating, its smooth-flat-surface has can be write, can use flexographic ink printing or printer prints, its surface through more than write or the pattern of undertaking the printing of and font in washing or draw together the wiping degree and be not less than 3kg/mm
2The effect of pressure keeps down that it is write, the tolerance interval of print characteristics about 97%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510133798 CN1986662A (en) | 2005-11-21 | 2005-12-23 | Paint composition for both writing and printing on smooth surface |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200510125574.2 | 2005-11-21 | ||
| CN200510125574 | 2005-11-21 | ||
| CN 200510133798 CN1986662A (en) | 2005-11-21 | 2005-12-23 | Paint composition for both writing and printing on smooth surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1986662A true CN1986662A (en) | 2007-06-27 |
Family
ID=38183606
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510133798 Pending CN1986662A (en) | 2005-11-21 | 2005-12-23 | Paint composition for both writing and printing on smooth surface |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1986662A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597442B (en) * | 2009-04-17 | 2011-06-01 | 张一鲜 | Ink water-tight additive and preparation method and application thereof |
| CN102492332A (en) * | 2011-12-05 | 2012-06-13 | 天津市鸵鸟墨水有限公司 | Novel ink and production method thereof |
| CN101812255B (en) * | 2009-02-24 | 2013-06-05 | 东莞市英科水墨有限公司 | Preprinted ink for high-temperature resistant carton |
| CN103275546A (en) * | 2013-05-24 | 2013-09-04 | 苏州凹凸彩印厂 | Soybean oil type peacock blue offset ink and preparation method thereof |
| CN103642052A (en) * | 2013-11-22 | 2014-03-19 | 北京迪百斯特科技发展有限公司 | Waterborne epoxy colorful floor paint and colored waterborne epoxy resin gel particle |
| CN104151915A (en) * | 2014-07-25 | 2014-11-19 | 浙江绿能塑粉有限公司 | Processing method of powder paint bulking agent |
| CN103436135B (en) * | 2013-09-22 | 2015-11-18 | 梁平县银丝竹帘有限责任公司 | High tint permanence paint and application thereof |
| CN105907296A (en) * | 2016-06-14 | 2016-08-31 | 安徽华业建工集团有限公司 | Building paint and preparation method thereof |
| CN105968951A (en) * | 2016-06-12 | 2016-09-28 | 夏泽民 | Environmentally friendly gel pen ink and preparation method thereof |
| CN106097880A (en) * | 2016-04-14 | 2016-11-09 | 浙江诚信包装材料有限公司 | A kind of plastic label of intention of scribbling and preparation method thereof |
| CN106281002A (en) * | 2016-07-19 | 2017-01-04 | 金寨县凯歌塑业有限公司 | A kind of water-repellent paint of the lettering on woven bag |
| CN107216784A (en) * | 2017-07-21 | 2017-09-29 | 太仓市双凤镇薄彩工艺品厂 | A kind of culinary glass paint film |
| CN108395840A (en) * | 2018-03-27 | 2018-08-14 | 陕西杨凌陕特农业发展有限公司 | A kind of paint and preparation method thereof containing honey |
| CN108611921A (en) * | 2016-12-08 | 2018-10-02 | 金东纸业（江苏）股份有限公司 | A kind of preparation method of coating for paper, coating paper and coating for paper |
| CN110965391A (en) * | 2019-12-17 | 2020-04-07 | 浙江金龙纸业有限公司 | Method for manufacturing high-strength white craft paper |
| CN113480915A (en) * | 2021-07-08 | 2021-10-08 | 张兴 | Pigment for filling color of stone cultural relics and preparation method thereof |
-
2005
- 2005-12-23 CN CN 200510133798 patent/CN1986662A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812255B (en) * | 2009-02-24 | 2013-06-05 | 东莞市英科水墨有限公司 | Preprinted ink for high-temperature resistant carton |
| CN101597442B (en) * | 2009-04-17 | 2011-06-01 | 张一鲜 | Ink water-tight additive and preparation method and application thereof |
| CN102492332A (en) * | 2011-12-05 | 2012-06-13 | 天津市鸵鸟墨水有限公司 | Novel ink and production method thereof |
| CN103275546A (en) * | 2013-05-24 | 2013-09-04 | 苏州凹凸彩印厂 | Soybean oil type peacock blue offset ink and preparation method thereof |
| CN103436135B (en) * | 2013-09-22 | 2015-11-18 | 梁平县银丝竹帘有限责任公司 | High tint permanence paint and application thereof |
| CN103642052A (en) * | 2013-11-22 | 2014-03-19 | 北京迪百斯特科技发展有限公司 | Waterborne epoxy colorful floor paint and colored waterborne epoxy resin gel particle |
| CN103642052B (en) * | 2013-11-22 | 2015-09-23 | 北京迪百斯特科技发展有限公司 | The colorful floor paint of water-base epoxy and color aqueous epoxy resin gel particle |
| CN104151915A (en) * | 2014-07-25 | 2014-11-19 | 浙江绿能塑粉有限公司 | Processing method of powder paint bulking agent |
| CN104151915B (en) * | 2014-07-25 | 2016-06-22 | 浙江绿能塑粉有限公司 | The processing method of powdery paints raising agent |
| CN106097880A (en) * | 2016-04-14 | 2016-11-09 | 浙江诚信包装材料有限公司 | A kind of plastic label of intention of scribbling and preparation method thereof |
| CN105968951A (en) * | 2016-06-12 | 2016-09-28 | 夏泽民 | Environmentally friendly gel pen ink and preparation method thereof |
| CN105907296A (en) * | 2016-06-14 | 2016-08-31 | 安徽华业建工集团有限公司 | Building paint and preparation method thereof |
| CN106281002A (en) * | 2016-07-19 | 2017-01-04 | 金寨县凯歌塑业有限公司 | A kind of water-repellent paint of the lettering on woven bag |
| CN108611921A (en) * | 2016-12-08 | 2018-10-02 | 金东纸业（江苏）股份有限公司 | A kind of preparation method of coating for paper, coating paper and coating for paper |
| CN108611921B (en) * | 2016-12-08 | 2020-09-18 | 金东纸业（江苏）股份有限公司 | Paper coating, coated paper and preparation method of paper coating |
| CN107216784A (en) * | 2017-07-21 | 2017-09-29 | 太仓市双凤镇薄彩工艺品厂 | A kind of culinary glass paint film |
| CN108395840A (en) * | 2018-03-27 | 2018-08-14 | 陕西杨凌陕特农业发展有限公司 | A kind of paint and preparation method thereof containing honey |
| CN110965391A (en) * | 2019-12-17 | 2020-04-07 | 浙江金龙纸业有限公司 | Method for manufacturing high-strength white craft paper |
| WO2021120176A1 (en) * | 2019-12-17 | 2021-06-24 | 浙江金龙纸业有限公司 | Manufacturing method for high-strength white kraft paper |
| CN113480915A (en) * | 2021-07-08 | 2021-10-08 | 张兴 | Pigment for filling color of stone cultural relics and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1986662A (en) | Paint composition for both writing and printing on smooth surface | |
| EP0034881B1 (en) | Non-opaque jet ink composition and method | |
| CN104937051B (en) | Paint with micro-structure | |
| GB2325670A (en) | Ink for application of variable colour marks | |
| CN104708933A (en) | Novel new-formula fragrance microcapsule printing ink | |
| NO781044L (en) | PRINTING COLOR WITH HIGH SOLID CONTENT | |
| CN101787234A (en) | Antique tusche and new preparation method thereof | |
| US20200199388A1 (en) | Ink Composition for Inkjet Printing | |
| CN106752338B (en) | A kind of water-soluble ink for screen printing and preparation method thereof | |
| CN104031463A (en) | Water-based plastic composite printing ink | |
| CN105440778A (en) | Novel environment-friendly printing ink | |
| CN104031469A (en) | Formula of lithographic offset printing ink | |
| CN110194906A (en) | A kind of food grade shellac mixed liquor and preparation method thereof | |
| WO2013192307A1 (en) | Laser reactive solvent based inks manufactured from masterbatch concentrates | |
| US4231906A (en) | Ink composition for non woven fabrics of synthetic fibers | |
| CN102702860B (en) | Ink-jet pigment ink composition and application thereof | |
| US3086873A (en) | Silk screen printing ink | |
| CN105440777A (en) | Preparation method of novel environment-friendly printing ink | |
| JP4581465B2 (en) | ink | |
| JP2573637B2 (en) | Ink composition and its preparation method | |
| CN100491481C (en) | Pearlescent UV water-based screen-printing ink | |
| CN1158346A (en) | High grade edible paint mimeograph | |
| JPH01503071A (en) | ink composition | |
| JP2007031495A (en) | Protein-containing ink composition and method for manufacturing the same | |
| CN107964278A (en) | One kind printing ink and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20070627 |