CN1978612A - Disinfecting detergent powder, and its preparing method - Google Patents
Disinfecting detergent powder, and its preparing method Download PDFInfo
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- CN1978612A CN1978612A CN 200510101724 CN200510101724A CN1978612A CN 1978612 A CN1978612 A CN 1978612A CN 200510101724 CN200510101724 CN 200510101724 CN 200510101724 A CN200510101724 A CN 200510101724A CN 1978612 A CN1978612 A CN 1978612A
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- detergent powder
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Abstract
This invention relates to a new type of disinfecting laundry soap powder and its preparation method. The content of weight percentage is: surface active agent: 5%-50%; builder: 5%-80%; additive: 0.01%-10%; disinfector: 5%-25%. The disinfecting laundry soap powder is safe, non-toxic, non-irritating, non-side effect, and has no corrosion to the gallbladder of the washer. It has fineness washing ability, strong decontamination, and convenience using. Otherwise, it can also disinfect Escherichia coil, Staphylococcus aurous and poliovirus, and so on. .
Description
Technical field
The present invention relates to a kind of disinfecting detergent powder and preparation method thereof.
Background technology
In the prior art, washing powder is normally by a kind of or several tensio-active agents, and allocates inorganic assistant agent into and organic additive processes.This class washing powder only has the effect of washing usually, can't effectively kill its function singleness to the harmful germ in the washing articles.Along with the raising of people's living standard, washing machine has stepped into huge numbers of families, and it has been general present situation that one family uses a washing machine, because washing powder does not possess sterilizing function, therefore is easy to produce mutual infection.In recent years, a spot of disinfectant detergent powder occurred, the sterilizing agent that is used for washing powder comprises quaternary ammonium salt, dioxide peroxide and Chinese medicinal materials etc.The sterilization effect that has in these sterilizing agents is undesirable, and what have costs an arm and a leg, have with the composite reaction of washing powder after, directly influence detergency power of laundry powder, also fabric is diminished.Particularly after through SARS in 2003 invasion and attack, people press for a kind of strong detergency, sterilizing power by force, do not stimulate, be free from side effects, the disinfectant detergent powder of safety non-toxic.
Summary of the invention
The present invention is intended to overcome above-mentioned the deficiencies in the prior art, provide a kind of safe, nontoxic, non-stimulated, having no side effect does not have corrosion substantially to the washing machine stainless steel inner bag; Washing is outstanding, strong detergency, easy to use, can also kill disinfecting detergent powder of streptococcus aureus, intestinal bacteria and poliovirus and preparation method thereof.
According to disinfecting detergent powder provided by the invention, its weight percent content is:
A. tensio-active agent: 5%-50%
B. washing assistant: 5%-80%
C. additive: 0.01%-10%
D. sterilizing agent: 5%-25%
The present invention also has following additional technical feature:
Described tensio-active agent comprises anion surfactant and nonionogenic tenside.
Described anion surfactant is Sodium dodecylbenzene sulfonate or sodium alkyl sulfate or fatty alcohol-polyoxyethylene ether or its two above mixing.
Described nonionogenic tenside is fatty alcohol-polyoxyethylene ether (n=9) or nonyl phenol polyethenoxy ether.
Described washing assistant is SPC-D or Sodium peroxoborate or yellow soda ash or water glass or sodium sulfate or tripoly phosphate sodium STPP or its two above mixing.
Described additive is Xylo-Mucine or Sumizyme MP or amylase or essence or its two above mixing.
Described sterilizing agent is trichloroisocyanuric acid or Surchlor GR 60 or its both combination.
A kind of method for preparing disinfecting detergent powder, at first with the riddler screening respectively of solid material in tensio-active agent, washing assistant, the additive, the block raw material that will sift out is then sent into pulverizer and is pulverized; Secondly, take by weighing each raw material for standby successively by formula ratio; Once more standby anion surfactant, washing assistant, additive are mixed and stir; At last, through aging, more standby nonionogenic tenside added stirrer mixing stirring and get final product.
Since adopted washing powder safety that technique scheme, the present invention make, nontoxic, non-stimulated, have no side effect, the washing machine stainless steel inner bag do not had corrosion substantially; Washing is outstanding, strong detergency, easy to use, can also kill streptococcus aureus, intestinal bacteria and poliovirus.Disinfectant detergent powder of the present invention can be widely used in family, hotel, hospital, railway, airport, passenger steamer, school and almost all trades and professions washing, decontamination and sterilization and disinfection, for preventing disease infects, play immeasurable effect.
Embodiment
Embodiment 1
Adopt following weight percent content:
A. anion surfactant: Sodium dodecylbenzene sulfonate 15%
B. nonionogenic tenside: fatty alcohol-polyoxyethylene ether (n=9) 8%
C. washing assistant: SPC-D 8%
Tripoly phosphate sodium STPP 25%
Yellow soda ash 13%
Sodium sulfate 20.9%
D. additive: Xylo-Mucine 0.3%
E. sterilizing agent: trichloroisocyanuric acid 9.8%
Embodiment 2
Adopt following weight percent content:
A. anion surfactant: Sodium dodecylbenzene sulfonate 15%
B. nonionogenic tenside: fatty alcohol-polyoxyethylene ether (n=9) 8%
C. washing assistant: SPC-D 8%
Tripoly phosphate sodium STPP 25%
Yellow soda ash 13%
Sodium sulfate 15.7%
D. additive: Xylo-Mucine 0.3%
E. sterilizing agent: Surchlor GR 60 15%
Embodiment 3
Adopt following weight percent content:
A. anion surfactant: Sodium dodecylbenzene sulfonate 14%
B. nonionogenic tenside: fatty alcohol-polyoxyethylene ether (n=9) 8%
C. washing assistant: SPC-D 8%
Tripoly phosphate sodium STPP 27%
Yellow soda ash 12%
Sodium sulfate 18%
D. additive: Xylo-Mucine 0.5%
E. sterilizing agent: trichloroisocyanuric acid 5%
Surchlor GR 60 7.5%
Embodiment 4
Adopt following weight percent content:
A. anion surfactant: Sodium dodecylbenzene sulfonate 10%
B. nonionogenic tenside: fatty alcohol-polyoxyethylene ether (n=9) 7.5%
C. washing assistant: SPC-D 6%
Tripoly phosphate sodium STPP 25%
Yellow soda ash 12%
Sodium sulfate 24%
D. additive: Xylo-Mucine 0.5%
E. sterilizing agent: Surchlor GR 60 15%
The preparation method of embodiment one to four
At first with the riddler screening respectively of solid material in tensio-active agent, washing assistant, the additive, the block raw material that will sift out is then sent into pulverizer and is pulverized; Press formula ratio and manufacturing technique requirent, with Sodium dodecylbenzene sulfonate, tripoly phosphate sodium STPP, trichloroisocyanuric acid and/or Surchlor GR 60, add successively to mix in the stirrer and stirred 10 minutes, and then add yellow soda ash, SPC-D, sodium sulfate, Xylo-Mucine successively and mix and stirred 20 minutes, add fatty polyoxyethylenated alcohol (n=9) after aging again and add stirrer, mix and stirred 10 minutes.
The washing powder that the present invention makes is through the Guangdong Prov. Disease Prevention-control Center verification test, and its experimental result is as follows:
1, poliovirus inactivating efficacy
Show through 3 revision tests: when 20 ℃～22 ℃ of test temperatures, this sterilizing agent available chlorine content is 294.1mg/L (0.34% diluent), and effect 5min, 10min, 15min are to average deactivation logarithmic value＞4.00 of ridge ash virus.(seeing following table for details).
| Available chlorine content (mg/L) | The logarithmic value of the average virus titer of positive control | The average deactivation logarithmic value and the scope thereof of effect different time (min) | ||
| 5 | 10 | 15 | ||
| 294.1 | 6.00 | ＞4.00 | ＞4.00 | ＞4.00 |
| (＞4.00) | (＞4.00) | (＞4.00) |
Cell contrast: cell well-grown.
2, to staphylococcus aureus and colibacillary killing effect
| Test strain | Available chlorine content (mg/L) | The logarithmic value of the average colony number of positive control | Effect different time (min) on average kill logarithmic value And scope | ||
| 5 | 10 | 15 | |||
| Staphylococcus aureus | 294.1 | 7.17 | ＞5.00 (＞5.00) | ＞5.00 (＞5.00) | ＞5.00 (＞5.00) |
| Intestinal bacteria | 294.1 | 7.19 | 4.37 (4.30～4.44) | ＞5.00 (＞5.00) | ＞5.00 (＞5.00) |
Negative control: diluent, the equal asepsis growth of substratum.
Conclusion: under test conditions, this disinfectant detergent powder available chlorine content is 294.1mg/L (0.34% diluent), and effect 10min is to staphylococcus aureus and colibacillaryly on average kill logarithmic value all＞5.00.
3, to the corrosion of metal degree
| Metal (sheet) | Weight (g) before the test | Test back weight (g) | Erosion rate (g) |
| The stainless steel and carbon steel aluminum bronze | 3.4339 3.4395 1.1568 3.6825 | 3.4335 3.4178 1.1565 3.6739 | 0.0064 0.3454 0.0138 0.0127 |
| The stainless steel contrast | There is not corrosion | ||
This disinfectant detergent powder available chlorine content 294.1mg/L (0.34% diluent), erosion rate to stainless steel, carbon steel, aluminium, copper is 0.0064mm/a, 0.3454mm/a, 0.0138mm/a, 0.0127mm/a, and extent of corrosion is respectively does not have burn into moderate burn into mild corrosion, mild corrosion substantially.
4, acute oral toxicity test
After the contamination, do not find that in the observation period mouse has poisoning manifestations and death, observations sees the following form.
| Sex | Dosage (mg/kg BW) | Number of animals (only) | Death toll (only) | Mortality ratio (%) |
| Female | 5500 | 10 | 0 | 0 |
| Male | 5500 | 10 | 0 | 0 |
This disinfectant detergent powder is to the nontoxic level in acute oral toxicity LD50＞true border of 5000mg/kg BW. of female male NIH mouse.
5, to clothing cloth sterilisation effect test in place conclusion
This disinfectant detergent powder available chlorine content is 294.1mg/L (0.34% diluent), and effect 10min is 2.68 to the logarithmic value of on average killing of the cloth of clothing surface natural bacteria, the killing logarithmic value and be of each test＞1.00.
6, intact skin irritant test
In observation period, tried the not abnormal response such as show spot oedema of new zealand rabbit skin, also do not found other symptom, the highest stimulation index=0.0 (seeing the following form).
| An intact skin irritant reaction scoring of rabbit | ||||||||||||||||||||
| Number of animals | Sex | Body weight kg | 1h | 24h | 48h | |||||||||||||||
| Sample | Contrast | Sample | Contrast | Sample | Contrast | |||||||||||||||
| Erythema | Oedema | Total points | Erythema | Oedema | Total points | Erythema | Oedema | Total points | Erythema | Oedema | Total points | Erythema | Oedema | Total points | Erythema | Oedema | Total points | |||
| 1 | Female | 2.5 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| 2 | Female | 2.7 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| 3 | Male | 2.6 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| Integral mean value | 0.0 | 0.0 | 0.0 | |||||||||||||||||
These disinfectant detergent powder working instructions 5 times of concentration solution of high working concentration stimulate the once contact intact skin of new zealand rabbit and belong to nonirritant.
7, to the mouse polychromatic erythrocytes micronucleus test
| Grouping | Dosage (mg/kg BW) | Number of animals (only) | Examined the PCE number | Contain micronucleus PCE number | Micronucleated cell rate (‰) | PCE/NCE |
| Tried thing | 5000 | 10 | 10000 | 21 | 2.1 | 0.82 |
| 2000 | 10 | 10000 | 20 | 2.0 | 0.81 | |
| 500 | 10 | 10000 | 25 | 2.5 | 0.85 | |
| Negative control | 0 | 10 | 10000 | 23 | 2.3 | 0.80 |
| Positive control | 40 | 10 | 10000 | 369 ** | 36.9 ** | 0.64 |
Annotate: compare with negative control group
*Expression P＜0.01
The result is negative for this disinfectant detergent powder mouse polychromatic erythrocytes micronucleus test, does not find that this given the test agent has mutagenesis to somatocyte.
Above-mentioned experimental data and result show, the disinfectant detergent powder safety that the present invention makes, nontoxic, non-stimulated, have no side effect, the washing machine stainless steel inner bag do not had corrosion substantially; Washing is outstanding, strong detergency, easy to use, can also kill streptococcus aureus, intestinal bacteria and poliovirus.Disinfectant detergent powder of the present invention can be widely used in family, hotel, hospital, railway, airport, passenger steamer, school and almost all trades and professions washing, decontamination and sterilization and disinfection, for preventing disease infects, play immeasurable effect.
The foregoing description is only for the usefulness that the present invention is described; and be not be to the invention restriction; the those of ordinary skill in relevant technologies field; under the situation that does not break away from the spirit and scope of the present invention; can also make various variations and modification; therefore all technical schemes that are equal to also should belong to the category of invention, and scope of patent protection of the present invention should be limited by each claim.
Claims (8)
1, a kind of disinfecting detergent powder, its weight percent content is:
A. tensio-active agent: 5%-50%
B. washing assistant: 5%-80%
C. additive: 0.01%-10%
D. sterilizing agent: 5%-25%
2, disinfecting detergent powder according to claim 1 is characterized in that described tensio-active agent comprises anion surfactant and nonionogenic tenside.
3, disinfecting detergent powder according to claim 2 is characterized in that described anion surfactant is Sodium dodecylbenzene sulfonate or sodium alkyl sulfate or fatty alcohol-polyoxyethylene ether or its two above mixing.
4, disinfecting detergent powder according to claim 2 is characterized in that described nonionogenic tenside is fatty alcohol-polyoxyethylene ether (n=9) or nonyl phenol polyethenoxy ether.
5, disinfecting detergent powder according to claim 1 is characterized in that described washing assistant is SPC-D or Sodium peroxoborate or yellow soda ash or water glass or sodium sulfate or tripoly phosphate sodium STPP or its two above mixing.
6, disinfecting detergent powder according to claim 1 is characterized in that described additive is Xylo-Mucine or Sumizyme MP or amylase or essence or its two above mixing.
7, disinfecting detergent powder according to claim 1 is characterized in that described sterilizing agent is trichloroisocyanuric acid or Surchlor GR 60 or its both combination.
8, a kind of method for preparing disinfecting detergent powder is characterized in that at first solid material difference riddler in tensio-active agent, washing assistant, the additive being screened, and the block raw material that will sift out is then sent into pulverizer and pulverized; Secondly, take by weighing each raw material for standby successively by formula ratio; Once more standby anion surfactant, washing assistant, additive are mixed and stir; At last, through aging, more standby nonionogenic tenside added stirrer mixing stirring and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101017246A CN100552011C (en) | 2005-12-01 | 2005-12-01 | A kind of disinfectant detergent powder and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101017246A CN100552011C (en) | 2005-12-01 | 2005-12-01 | A kind of disinfectant detergent powder and preparation method thereof |
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| Publication Number | Publication Date |
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| CN1978612A true CN1978612A (en) | 2007-06-13 |
| CN100552011C CN100552011C (en) | 2009-10-21 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796625A (en) * | 2012-07-13 | 2012-11-28 | 湖北海力化工科技有限公司 | Water-based cleaning agent used before coating of optical glass |
| CN101831363B (en) * | 2009-03-13 | 2012-11-28 | 龙振海 | Washing powder expanded additive and preparation method thereof |
| CN102876470A (en) * | 2012-09-11 | 2013-01-16 | 启东市万隆电气光源有限公司 | Sterile bacteriostatic washing powder |
| CN103275817A (en) * | 2013-06-05 | 2013-09-04 | 衡阳县利群日用化工厂 | Preparation method for washing powder with strong permeability, degreasing and wettability |
| CN103695201A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Disinfectant washing powder for fabric and preparation method thereof |
| CN103937624A (en) * | 2014-04-11 | 2014-07-23 | 广州立白企业集团有限公司 | Pipeline dredging agent with stable oxygenation effect and preparation method of pipeline dredging agent |
| CN104946412A (en) * | 2015-05-26 | 2015-09-30 | 柳州市亿廷贸易有限责任公司 | Sterilizing washing powder |
| CN115119849A (en) * | 2022-07-02 | 2022-09-30 | 厦门迈诺泰医疗科技有限公司 | Decontamination disinfectant for appliances and preparation method thereof |
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2005
- 2005-12-01 CN CNB2005101017246A patent/CN100552011C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831363B (en) * | 2009-03-13 | 2012-11-28 | 龙振海 | Washing powder expanded additive and preparation method thereof |
| CN102796625A (en) * | 2012-07-13 | 2012-11-28 | 湖北海力化工科技有限公司 | Water-based cleaning agent used before coating of optical glass |
| CN102796625B (en) * | 2012-07-13 | 2013-09-11 | 湖北海力化工科技有限公司 | Water-based cleaning agent used before coating of optical glass |
| CN102876470A (en) * | 2012-09-11 | 2013-01-16 | 启东市万隆电气光源有限公司 | Sterile bacteriostatic washing powder |
| CN103275817A (en) * | 2013-06-05 | 2013-09-04 | 衡阳县利群日用化工厂 | Preparation method for washing powder with strong permeability, degreasing and wettability |
| CN103695201A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Disinfectant washing powder for fabric and preparation method thereof |
| CN103937624A (en) * | 2014-04-11 | 2014-07-23 | 广州立白企业集团有限公司 | Pipeline dredging agent with stable oxygenation effect and preparation method of pipeline dredging agent |
| CN103937624B (en) * | 2014-04-11 | 2017-10-10 | 广州立白企业集团有限公司 | It is a kind of have stablize pipe-dredging agent of ozone effect and preparation method thereof |
| CN104946412A (en) * | 2015-05-26 | 2015-09-30 | 柳州市亿廷贸易有限责任公司 | Sterilizing washing powder |
| CN115119849A (en) * | 2022-07-02 | 2022-09-30 | 厦门迈诺泰医疗科技有限公司 | Decontamination disinfectant for appliances and preparation method thereof |
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|---|---|
| CN100552011C (en) | 2009-10-21 |
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Effective date of registration: 20090417 Address after: Seven Guangdong Road, Shunde District of Beijiao city of Foshan province Shunde Bi Gui Yuan Nan nine G03 post encoding: 528312 Applicant after: Zhang Kai Yu Co-applicant after: Zhang Wanjing Address before: Seven Guangdong Road, Shunde District of Beijiao city of Foshan province Shunde Bi Gui Yuan Nan nine G03 post encoding: 528312 Applicant before: Zhang Jieyu |
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