CN1961968A - Deodorant containing natural botanical deodorizing ingredient - Google Patents
Deodorant containing natural botanical deodorizing ingredient Download PDFInfo
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- CN1961968A CN1961968A CN 200610118547 CN200610118547A CN1961968A CN 1961968 A CN1961968 A CN 1961968A CN 200610118547 CN200610118547 CN 200610118547 CN 200610118547 A CN200610118547 A CN 200610118547A CN 1961968 A CN1961968 A CN 1961968A
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Abstract
The invention provides a deodorant containing natural plant constituents, wherein the compositions include 0.001-5% of plant extracts for deodorization, 0.01-10% of surface active agent, 0.001-1% of antibacterial agent, 1-70% of dissolvent and balancing deionized water. The deodorant is produced through steps of mixing constituents homogeneously, and injecting into atomizing tanks.
Description
Technical field
The present invention relates to the household chemicals field, especially natural plant deodorant.
Background technology
Along with growth in the living standard, people more and more need the environment of living clean, clean and tidy.In life staying idle at home, kitchen, room, parlor, toilet, wardrobe can produce abnormal flavour at any time, and also can there be the abnormal flavour of formaldehyde sometimes in the house behind the finishing.These foul smell not only affect people's mood, and also are deleterious to human body, and long-term life wherein must cause various diseases.Be defined as carcinogenic and teratogenesis shape material by World Health Organization (WHO) at present as formaldehyde.Traditional air freshener can only be used the essence covering smell, smell substance can not be decomposed and remove.The deodorizer that can remove abnormal flavour is presenting the situation that increases always on market, be an active market, has increased by 6.6% in the 02-03 world market.The deodorizer market of Japan in 2004 reaches 1.2 hundred million dollars.According to the information that national departments concerned provides, the domestic market is also constantly increasing the deodorizer demand, and market potential is huge.The deodorizer kind that relates to people's daily life is a lot, and as automobile, aircraft deodorizer, room, lavatory, dining room deodorizer etc. are used quite extensive.And the deodorizer kind of domestic production at present is comparatively single, and employed deodoring materials mostly is chemical constituent, simultaneously environment is easily caused secondary pollution at deodorant.Chinese patent CN1096964A discloses a kind of deodorant madefrom natural material and preparation method thereof October 4 nineteen ninety-five.Although this technology has also been used plant component, mainly still rely on the adsorption deodorization of powdery solid granules, the effect of plant extract is not fully exerted, and does not more carry out selected to plant extract.At this, we have proposed the effective ingredient in the extraction plant, with its deodorant method.The method is harmless, and to the environment non-secondary pollution, raw material sources are extensive, is easy to processing, and is economical and practical.
Summary of the invention
The objective of the invention is to disclose a kind of deodorizer that contains natural botanical deodorizing ingredient, owing to select for use plant extract to reach deodorizing effect, therefore non-toxic efficient, the advantage little to environmental effect are arranged.Present deodorizer is with chemical constituent, reaches the deodorant purpose as aldehydes, slaine and the reaction of airborne odorant.These products easily cause secondary pollution simultaneously at deodorant.Cause minimal irritation easily as aldehydes to the human respiratory tract; The slaine composition sucks human body, also be deleterious to health, and its deodorizing effect is comparatively single, and is relatively poor to the compound deodorising effect of some complexity.The present invention effectively extract and purification the deodorization composition in the plant, proposed to adopt the method for various plant component composite deodurizings, can extensively effectively remove the various abnormal flavour in the domestic environment.
Odorant in the environment has three classes substantially: a class nitrogen-containing compound is mainly ammonia, trimethylamine, carbamide, nicotine etc.; Two classes are sulfur-containing compounds, are mainly hydrogen sulfide, mercaptan and sulfur ether; Oxygenatedchemicalss such as the acids of being exactly and aldehydes are arranged again, mainly contain low carbon organic acid and formaldehyde such as acetic acid, butanoic acid.In the present invention, the various deodorization characteristics of different plants are assessed, filtered out the three kind of plant extracts that different foul smell had better effects, carry out compositely, become the deodorizer that the smelly effect that extensively disappears is arranged.
To removing nitrogen is that Folium Bambusae, Herba Oxalidis Corniculatae, Semen Ginkgo plant extract can be adopted in smelly source; To removing sulfur is that Flos Lonicerae, Semen Vitis viniferae, Flos Sophorae extract can be adopted in smelly source; To smelly Semen Vitis viniferae, the Semen Ginkgo extrac of adopting of acid.
According to the deodorization characteristics of various plant extracts, adopt composite between the plant extract to reach best deodorizing effect.Deodorant mechanism is that the phenol hydroxyl of flavonoids can carry out condensation, neutralization reaction with groups such as sulfydryl, amido, ammonia, eliminates the smell substance that is free in the environment.
As liquid deodorant of the present invention, in prescription, add antimicrobial component, this is because microbial decomposition Organic substances such as antibacterial cause, as ubiquitous Ammonification in the environment and sulfur mineralization because of some foul smell.In addition, actinomycetes and algae also can produce musty.They are killed or suppress to help to control from the source generation of abnormal flavour.In the present invention, preferred antibacterial be hexamethylene biguan-ide, quaternary ammonium salts cationic compound one or more.The general 0.01%-2.0% of the content of antibacterial, preferred 0.02%-1.0%, preferred especially 0.05%-0.5%.
In the present invention, as a kind of liquid spray deodorizer.In order to obtain even droplet spray, to enlarge the contact area of drop and foul smell, deodorizing effect is better brought into play, generally add surfactant.Surfactant comprises one or more in non-ionic surface active agent, the zwitterionic surfactant.For preventing to cause having a large amount of foams to appear at the floor at home when spraying, metope etc. surface and influence is used, non-foaming or the frangible fast non-ionic surface active agent that looses of foam during preferred itself spraying is as alkyl polyglucoside, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, Polyoxyethylene Sorbitol Fatty Acid Esters.Preferred especially Polyoxyethylene Sorbitol Fatty Acid Esters.Surface-active contents content is 0.01%-10%, preferred 0.05%-5.0%, more preferably 0.1%-2.0%, especially preferably 0.5%-1.5%.
As deodorizer of the present invention,, add solvent for reaching spraying rapid exsiccant effect afterwards from the surface.The solvent that adds comprises one or more in ethanol, isopropyl alcohol, propylene glycol, ethylene glycol, ethylene glycol, butyl glycol ether, diethylene glycol dimethyl ether, the diethylene glycol ether.Preferred alcohol, propylene glycol, diethylene glycol dimethyl ether, special preferred alcohol.The preferred 1%-25% of the amount of contained solvent, more preferably 3%-10%.
Consider masking action, using fragrance component becomes preferred modification.As perfume composition, be selected from the chemical compound that is not subjected to other components influence, the consumption of essence is at 0.001%-5%.
In the present invention, selecting citric acid as the deodorization synergist, is the removal effect in smelly source to strengthen to the seizure of foul smell molecule with to nitrogen.The content of citric acid is 0.01%-3%, preferred 0.05%-1.0%.
In the present invention, select EDTA, to strengthen the antibacterial effect of antimicrobial component as Trimethoprim.The content of EDTA is 0.02%-1.0%, preferred 0.05%-0.1%.
Water in the liquid deodorant of the present invention is deionized water, and content is 30%-95%, and is preferred 75%95%, so that liquid deodorant has gratifying deodorizing capability, and the sensation of the fabric in the domestic environment do not degenerated.
The specific embodiment
Embodiment 1
| Component | Content (%) |
| Herba Oxalidis Corniculatae extract | 0.3 |
| Semen Ginkgo extrac | 0.3 |
| Semen Vitis viniferae extract | 0.3 |
| Citric acid | 0.1 |
| Polyoxyethylene Sorbitol Fatty Acid Esters | 1.0 |
| The quaternary ammonium salts antibacterial | 0.15 |
| EDTA | 0.05 |
| Ethanol | 5 |
| Deionized water | Surplus |
The preparation of Semen Vitis viniferae extract: with Semen Vitis viniferae drying, pulverizing, the ethanol water of employing 50% is an extractant, extracts 8 hours down at 70 ℃.Filtrate is distilling under reduced pressure and concentrated on rotary evaporator, gets Semen Vitis viniferae extract.Get highly finished product through column chromatography.
The preparation of Semen Ginkgo extrac: Folium Ginkgo is drying, pulverizing is an extractant with water, and lixiviate is 12 hours under 65 ℃ of temperature.Centrifugal filtration, filtrate is through microfiltration, reverse osmosis concentration, and lyophilization gets Semen Ginkgo extrac.
The preparation of Herba Oxalidis Corniculatae extract: Herba Oxalidis Corniculatae is drying, pulverizing, with 70% ethanol is extractant, adopt heating in water bath to 70 ℃, extracted 3 hours, insulation is extracted 3 times, behind the merge extractive liquid,, use isopyknic chloroform extraction, tell chloroform and use ethyl acetate extraction instead 3 times after mutually, with the ethyl acetate distilling under reduced pressure, after concentrating Herba Oxalidis Corniculatae extract.
In deionized water, add Semen Vitis viniferae extract, Semen Ginkgo extrac, Herba Oxalidis Corniculatae extract successively, add citric acid, Polyoxyethylene Sorbitol Fatty Acid Esters, quaternary ammonium salts antibacterial, EDTA, ethanol.Stirring at normal temperature 2 hours fully after the dissolving, is filled into spray bottle.
Embodiment 2
| Composition | Content (%) |
| Herba Oxalidis Corniculatae extract | 0.45 |
| Semen Ginkgo extrac | 0.45 |
| Citric acid | 0.1 |
| Polyoxyethylene Sorbitol Fatty Acid Esters | 1.0 |
| The quaternary ammonium salts antibacterial | 0.15 |
| EDTA | 0.05 |
| Ethanol | 5 |
| Deionized water | Surplus |
The preparation method of plant extract and the compound method of deodorizer are all same with embodiment 1.
Embodiment 3
| Composition | Content (%) |
| Herba Oxalidis Corniculatae extract | 0.45 |
| Semen Vitis viniferae extract | 0.45 |
| Citric acid | 0.1 |
| Polyoxyethylene Sorbitol Fatty Acid Esters | 1.0 |
| The quaternary ammonium salts antibacterial | 0.15 |
| EDTA | 0.05 |
| Ethanol | 5 |
| Deionized water | Surplus |
The preparation method of plant extract and the compound method of deodorizer are all same with embodiment 1.
Embodiment 4
| Composition | Content (%) |
| Semen Ginkgo extrac | 0.45 |
| Semen Vitis viniferae extract | 0.45 |
| Citric acid | 0.1 |
| Polyoxyethylene Sorbitol Fatty Acid Esters | 1.0 |
| The quaternary ammonium salts antibacterial | 0.15 |
| EDTA | 0.05 |
| Ethanol | 5 |
| Deionized water | Surplus |
The preparation method of plant extract and the compound method of deodorizer are all same with embodiment 1.
Embodiment 5
| Composition | Content (%) |
| Citric acid | 0.1 |
| Polyoxyethylene Sorbitol Fatty Acid Esters | 1.0 |
| The quaternary ammonium salts antibacterial | 0.15 |
| EDTA | 0.05 |
| Ethanol | 5 |
| Deionized water | Surplus |
The preparation method of plant extract and the compound method of deodorizer are all same with embodiment 1.
Prepare 1000ppm ammonia, 450ppm stink damp, 1000mg/m respectively in airtight space
3Acetic acid gas, 0.40mg/m
3Formaldehyde is tested the deodorizing effect of above embodiment; Measure the deodorizing effect of each embodiment simultaneously to toilet, garbage, medicated clothing musty.
The deodorizing effect of each embodiment sees Table 1.
The deodorizing effect of each prescription of table 1
| Deodorizing effect | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Ammonia | 90％ | 90％ | 80％ | 80％ | 30％ |
| Hydrogen sulfide | 85％ | 50％ | 85％ | 85％ | 0％ |
| Acetic acid | 99％ | 99％ | 95％ | 99％ | 40％ |
| Formaldehyde | 80％ | - | 80％ | - | - |
| Toilet | Good | Good | Generally | Generally | Difference |
| Garbage | Good | Generally | Good | Good | Difference |
| The medicated clothing musty | Good | Good | Good | Good | Generally |
By example 1 preparation deodorizer, carry out the user and try out, send out 16 parts in sample.Table 2 has shown user's trial state.
Table 2 user trial state
| The user is on probation to be estimated | Fabric | Toilet | Garbage |
| Good | 12 | 11 | 13 |
| Generally | 4 | 5 | 3 |
| Difference | 0 | 0 | 0 |
Claims (10)
1. a deodorizer that contains natural botanical deodorizing ingredient is characterized in that, the weight percentage of each component is:
Plant deodorization composition 0.001%-5%
Surfactant 0.01%-10%
Antibacterial 0.001%-1%
Solvent 1%-70%
The deionized water surplus
Wherein:
Plant deodorization composition is: Semen Vitis viniferae extract, or Semen Ginkgo extrac, or Herba Oxalidis Corniculatae extract;
Surfactant is: non-ionic surface active agent, or zwitterionic surfactant;
Solvent is: any one in ethanol, isopropyl alcohol, propylene glycol, ethylene glycol, ethylene glycol, butyl glycol ether, diethylene glycol dimethyl ether and the diethylene glycol ether or several mixing with arbitrary proportion arbitrarily;
Antibacterial is: hexamethylene biguan-ide, or quaternary ammonium salts cationic compound.
2. a kind of deodorizer that contains natural botanical deodorizing ingredient as claimed in claim 1, it is characterized in that: plant deodorization composition is selected any two or three in Semen Vitis viniferae extract, Semen Ginkgo extrac and the Herba Oxalidis Corniculatae extract for use, the weight percent concentration of Semen Vitis viniferae extract is 0.001%-5%, the weight percent concentration of Semen Ginkgo is 0.01%-5%, and the weight percent concentration of Herba Oxalidis Corniculatae extract is 0.01%-5%.
3. as any described a kind of deodorizer that contains natural botanical deodorizing ingredient in claim 1 or 2, it is characterized in that: non-ionic surface active agent is selected alkyl androstanediol for use, or Polyoxyethylene Sorbitol Fatty Acid Esters, or fatty alcohol-polyoxyethylene ether, or alkylphenol polyoxyethylene, or aforementioned several mixing arbitrarily with arbitrary proportion; Zwitterionic surfactant is selected betanin or amine oxide for use.
4. as any described a kind of deodorizer that contains natural botanical deodorizing ingredient in claim 1 or 2, it is characterized in that: also contain citric acid and EDTA as auxiliary agent, the weight percent concentration of citric acid and EDTA all is 0.01%-10%.
5. as claimed in claim 3 any one contains the deodorizer of natural botanical deodorizing ingredient, it is characterized in that: also contain citric acid and EDTA as auxiliary agent, the weight percent concentration of citric acid and EDTA all is 0.01%-10%.
6. as any described a kind of deodorizer that contains natural botanical deodorizing ingredient in claim 1 or 2, it is characterized in that: also contain the essence that weight percent concentration is 0.001%-5%.
7. a kind of deodorizer that contains natural botanical deodorizing ingredient as claimed in claim 3 is characterized in that: also contain the essence that weight percent concentration is 0.001%-5%.
8. a kind of deodorizer that contains natural botanical deodorizing ingredient as claimed in claim 4 is characterized in that: also contain the essence that weight percent concentration is 0.001%-5%.
9. a kind of deodorizer that contains natural botanical deodorizing ingredient as claimed in claim 5 is characterized in that: also contain the essence that weight percent concentration is 0.001%-5%.
10. one kind natural plant extracts removed the application of airborne abnormal flavour, after any described a kind of deodorizer that contains natural botanical deodorizing ingredient stirs in the claim 1 to 9, be filled into aerosol can, in indoor even sprinkling, with airborne abnormal flavour in the decontamination chamber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610118547 CN1961968A (en) | 2006-11-21 | 2006-11-21 | Deodorant containing natural botanical deodorizing ingredient |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610118547 CN1961968A (en) | 2006-11-21 | 2006-11-21 | Deodorant containing natural botanical deodorizing ingredient |
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| CN1961968A true CN1961968A (en) | 2007-05-16 |
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| CN 200610118547 Pending CN1961968A (en) | 2006-11-21 | 2006-11-21 | Deodorant containing natural botanical deodorizing ingredient |
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