CN1950565A - Textile benefit compositions - Google Patents
Textile benefit compositions Download PDFInfo
- Publication number
- CN1950565A CN1950565A CNA2005800144897A CN200580014489A CN1950565A CN 1950565 A CN1950565 A CN 1950565A CN A2005800144897 A CNA2005800144897 A CN A2005800144897A CN 200580014489 A CN200580014489 A CN 200580014489A CN 1950565 A CN1950565 A CN 1950565A
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- Prior art keywords
- alkyl
- textiles
- composition
- independently selected
- carboxymethyl cellulose
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/07—Cellulose esters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/419—Amides having nitrogen atoms of amide groups substituted by hydroxyalkyl or by etherified or esterified hydroxyalkyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to textile benefit compositions comprising a cellulosic based polymer component; a material selected from the group consisting of a dispersible polyolefin, a chlorine inhibitor, a dye fixative and mixtures thereof; a cross-linking agent; a carrier and an optional wetting agent or, alternatively, a chlorine inhibitor; a material selected from the group consisting of a dispersible polyolefin, a cellulosic based polymer component, a dye fixative and mixtures thereof; a cross-linking agent; a carrier and an optional wetting agent. The present invention also relates to processes for making and using the aforementioned compositions and textiles treated with such compositions.
Description
Invention field
The present invention relates to textile benefit compositions, and the method that is used to prepare and use above-mentioned composition.
Background of invention
Goods that are made of fiber such as clothes and linen are owing to use and cleaning can be faded, wearing and tearing and/or shrinkage.In order to reduce above-mentioned damage, some beneficial agent is incorporated in the cleaning compositions.Yet, owing to following one or more reasons, weaken and/or limited the validity of above-mentioned composition: some beneficial agent is incompatible with the cleaning substance that is present in the above-mentioned composition, owing to washing methods has limited the content of beneficial agent in the above-mentioned composition, and the beneficial effect that above-mentioned composition is given can not be lasting.
Therefore, need to give to textiles and strengthen and/or lasting anti-ly fade, resistance to wear and the textile benefit compositions of shrink-resistant matter.
Summary of the invention
Textile benefit compositions comprises based on cellulosic polymers compositions; But be selected from the material of dispersible polyolefin, chlorine inhibitor, dye-fixing agent and their mixtures; Crosslinking agent; Carrier and optional wetting agent; Or alternatively comprise: the chlorine inhibitor; But be selected from dispersible polyolefin, based on the material of cellulosic polymers compositions, dye-fixing agent and their mixtures; Crosslinking agent; Carrier and optional wetting agent.
The invention still further relates to preparation and use the method for above-mentioned composition, and with the method for above-mentioned compositions-treated textiles.
Detailed Description Of The Invention
Definition
Except as otherwise noted, term used herein " textiles " comprises fiber, yarn, fabric and/or clothes, or comprises the goods of above-mentioned substance.
When being used for claim, article used herein " " is understood to mean one or more things that is subjected to claims protection or describes.
Except as otherwise noted, all components or composition levels all are the activity substance contents about that component or composition, and do not comprise the impurity that may be present in the commercially available source, for example residual solvent or accessory substance.
Except as otherwise noted, all percentages and ratio are all calculated by weight.Except as otherwise noted, all percentages and ratio all calculate based on total composition.
Should be appreciated that each higher limit that provides in this manual comprises each lower limit, is also conclusivelyed show in this article as this lower limit.Each lower limit that provides in this manual will comprise each higher limit, promptly as this higher limit clear and definite expression be arranged also in this explanation.Each number range that provides in this manual will comprise all less number ranges that are contained in this bigger numerical scope, promptly as this less number range clear and definite expression be arranged also in this explanation.
The relevant part of all references is incorporated herein by reference; Quoting of any document all may not be interpreted as its approval as prior art of the present invention.
Textile benefit compositions
Applicant's textile benefit compositions comprises based on cellulosic polymers compositions; But be selected from the material of dispersible polyolefin, chlorine inhibitor, dye-fixing agent and their mixtures; Crosslinking agent; Carrier and optional wetting agent; Or alternatively comprise: the chlorine inhibitor; But be selected from dispersible polyolefin, based on the material of cellulosic polymers compositions, dye-fixing agent and their mixtures; Crosslinking agent; Carrier and optional wetting agent.
In aspect of applicant invention, the pH that applicant's textile benefit compositions has is about 2 to about 11, about 3 to about 9, or alternative about 3 to about 5, and comprises:
A.) about by weight 0.005% to about 10%, about 0.01% to about 5% or alternative about 0.05% to about 2% based on cellulosic polymers compositions;
B.) about 0.005% to about 20%, about 0.01% to about 10% or alternative material of about 0.05% to about 5%, but described material is selected from dispersible polyolefin, chlorine inhibitor, dye-fixing agent, and their mixture;
C.) about 0.01% to about 15%, about 0.01% to about 12% or alternative crosslinking agent of about 0.1% to about 10%; With
D.) Ren Xuan wetting agent;
The surplus of described composition is a carrier.
In aspect of applicant invention, the pH that applicant's textile benefit compositions has is about 2 to about 11, about 3 to about 9, or alternative about 3 to about 5, and comprises:
A.) about by weight 0.01% to about 10%, about 0.05% to about 5% or alternative chlorine inhibitor of about 0.1% to about 3%;
B.) about 0.005% to about 20%, about 0.01% to about 10% or alternative material of about 0.05% to about 5%, but described material is selected from dispersible polyolefin, based on cellulosic polymers compositions, dye-fixing agent, and their mixture;
C.) about 0.01% to about 15%, about 0.01% to about 12% or alternative crosslinking agent of about 0.1% to about 10%; With
D.) Ren Xuan wetting agent;
The surplus of described composition is a carrier.
In aspect of applicant's invention, above-mentioned textile benefit compositions can be given lasting beneficial effect to the textiles of crossing with described compositions-treated.
In aspect of applicant's invention, above-mentioned textile benefit compositions does not comprise optional wetting agent.
In aspect of applicant's invention, above-mentioned textile benefit compositions does not comprise following one or more auxiliary materials: bleach-activating, surfactant, builder, chelating agent, dye transfer inhibitor, dispersant, enzyme and enzyme stabilizers, catalytic metal complexes, polymeric dispersant, earth and dirt remove/resist again precipitating agent, brightening agent, foam inhibitor, dyestuff, spices, structural elasticity agent, fabric softener, carrier, hydrotropic agent, processing aid and/or pigment.
Available comprises those components that contain the hydrophobically modified carboxy methyl cellulose polymer based on cellulosic polymers compositions, and the weight average molecular weight that the carboxymethyl cellulose polymer of described hydrophobically modified has is that about 0.016ag (10,000 dalton) is to about 3.32ag (2,000,000 dalton), about 0.049ag (30,000 dalton) is to about 2.49ag (1,500,000 dalton), or alternative about 0.16ag (100,000 dalton) to about 1.66ag (1,000,000 dalton).The carboxymethyl cellulose polymer of described hydrophobically modified comprises the repetitive with following formula structure:
Wherein:
A.) n is enough big integer, so that the weight average molecular weight that the carboxymethyl cellulose polymer of described hydrophobically modified has is that about 0.016ag (10,000 dalton) is to about 3.32ag (2,000,000 dalton), about 0.049ag (30,000 dalton) is to about 2.49ag (1,500,000 dalton), or alternative about 0.16ag (100,000 dalton) to about 1.66ag (1,000,000 dalton);
B.) each R is independently selected from R
H, R
CAnd H;
Wherein:
(i) each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aralkyl, replacement, hydroxyalkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
Each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aralkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidyl alkyl, morpholinyl alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
Each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aralkyl, replacement, hydroxy alkyl, (R
6)
2N-alkyl and (R
6)
3The N-alkyl;
Each R
6Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aralkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidyl alkyl, morpholinyl alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
Two R on the wherein identical nitrogen-atoms
4Or R
6Part can lump together, and forms ring structure, and described ring structure is selected from piperidines and morpholine;
M is the CATION that suits, and it is selected from Na, K, 1/2Ca and 1/2Mg; With
Precondition is:
If any R
HHave positive charge, then can come balance by suitable anion; With
R
HSubstitution value be about 0.0001 to 0.1;
(ii) each R
CFor
Wherein each Z is independently selected from M, R
2And R
HWherein:
Each M as above defines;
Each R
HAs above definition;
Each R
2Be independently selected from H and C
1-C
4Alkyl;
Each y is about 1 to about 5; With
Precondition is:
When Z is H or M, radicals R
CSubstitution value be about 0.1 to 2.0.
The embodiment of the available categories of the carboxymethyl cellulose polymer of hydrophobically modified comprises the carboxymethyl cellulose polymer of ether modification, ester modified carboxymethyl cellulose polymer, and their mixture.Available hydrophobically modified carboxy methyl cellulose polymer can derive from Noviant Oy of nekoski, Finland.
But available dispersible polyolefin comprises high density or low-density Tissuemat E, and described Tissuemat E has about 30 ℃ to about 180 ℃, about 45 ℃ to about 160 ℃, or alternative about 60 ℃ to about 150 ℃ fusing point.Above-mentioned wax can be the Tissuemat E of oxidation.Above-mentioned wax can derive from Honeywell Corp., Morristown New Jersey, and U.S.A., and the typical case provides as the polythene wax emulsion that comprises non-ionic surface active agent, anion surfactant or their mixtures.The specific embodiment of available polyethylene wax emulsion comprises Michem emulsion 39235, Michem emulsion 68725, and their mixture.Above-mentioned emulsion can derive from Michelman Inc.Cincinnati, OH, USA.
Available carrier can comprise water.For example, available carrier is a water.
Available chlorine inhibitor comprises those chlorine inhibitor that contain polyamine component.Available polyamine component comprises those polyamine components that contain the polyamines of being made up of primary amine, secondary amine and tertiary amine.Above-mentioned polyamines can be by ethoxylation.The specific embodiment of available polyamine component comprises those polyamine components that contain following material, and described material is selected from ethoxylation tetraethylenepentamine, polymine, ethoxylation polymine, polyvinylpyrrolidone, polyvinylamine, polylysine; Two hexamethylene diamines, and their mixture.Available chlorine inhibitor can derive from BASF Corp., Ludwingshafen, Germany.
Available dye-fixing agent comprises cationic hydroxyethyl cellulose, and it supplies from DowChemicals, Piscataway, New Jersey, USA.
Available crosslinking agent comprises those crosslinking agents that contain following material, and described material is selected from the methylol and the (alkoxymethyl)-2 radical derivative of urea, ethylene urea and propylene urea, and the polyfunctional group carboxylic acid.The non-limiting example of the methylol of urea, ethylene urea and propylene urea and (alkoxymethyl)-2 radical derivative comprises hydroxymethyl-2 dihydroxy-ethylene urea.The non-limiting example of polyfunctional group carboxylic acid comprises BTCA and poly.Available crosslinking agent can derive from Noveon Inc., Brecksville, Ohio, U.S.A..
Though unnecessary, textile benefit compositions disclosed herein can comprise wetting agent.Available wetting agent comprises non-ionic surface active agent and anion surfactant.Available wetting agent can derive from BASF Corp., Ludwingshafen, Germany.
The applicant recognizes, can overcome to hinder to reduce the textiles problem, as fade, balling-up, rough hand, shrinkage and wearing and tearing because the washing application process that has its source in of above-mentioned obstruction, the flexibility that it has limited prescription and has handled.In addition, the applicant recognizes, by the combination of lasting beneficial effect is provided, only can make the problems referred to above be reduced to required degree, and the applicant recognizes, the application of above-mentioned beneficial effect, need the processing stage such as textile mills the processing stage in obtain above-mentioned beneficial effect.Not bound by theory, it is believed that when the textile treatment composition with the applicant is applied to textiles, the beneficial agent that is contained in the above-mentioned composition will be chemically bound in described textiles, thereby obtain the textiles of high-quality, it has following one or more enhancings and/or lasting beneficial effect: resist and fade, prevent balling-up, the feel of improvement, the crease-resistant ABRASION RESISTANCE that contracts and increase.
Auxiliary substance
Though since the listed auxiliary agent of this paper for the object of the invention not necessarily, some embodiment of applicant's textile benefit compositions does not comprise one or more above-mentioned auxiliary materials, but other embodiment can comprise one or more auxiliary agents that hereinafter illustrate.Above-mentioned auxiliary agent can be incorporated in the textile benefit compositions disclosed herein, with for example auxiliary or strengthen clean-up performance, or improves the aesthetic property of above-mentioned composition, as roles such as spices, colouring agent, dyestuff.The definite character and the incorporation thereof of these annexing ingredients, the physical form that will depend on textile benefit compositions with and the character of operation used or that use.Useful auxiliary material can include but not limited to, bleach-activating, surfactant, builder, chelating agent, dye transfer inhibitor, dispersant, enzyme and enzyme stabilizers, catalytic metal complexes, polymeric dispersant, earth and dirt remove/resist again precipitating agent, brightening agent, foam inhibitor, dyestuff, spices, structural elasticity agent, fabric softener, carrier, hydrotropic agent, processing aid and/or pigment.
The method for preparing textile benefit compositions
The technical staff can prepare textile benefit compositions of the present invention according to the guidance that is contained in herein, and in an embodiment, can prepare above-mentioned composition by mixing desired substance.
Use various reaction vessels and method (comprising batch method, half batch method and continuity method), can prepare the above-mentioned textile benefit compositions of commercial quantities.The said equipment can derive from multiple source, as Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Kentucky, U.S.A.), Forberg AS (Larvik, Norway), GlattIngenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex (Minneapolis, Minnesota, USA).
Using method
By following steps,, handle textiles with applicant's any textile benefit compositions or its mixture:
A.) at least a portion textiles is contacted with applicant's any textile benefit compositions or its mixture;
B.) remove the described composition of capacity from described textiles, obtaining about 10% to about 200%, about 15% to about 150%, or alternative wet absorption of about 20% to about 120%; With
C.) dry and curing and the described textiles of the contacted at least a portion of described composition.
Typically, described textiles was handled before the end user uses.Typically, described processing is carried out in textile mills.Typically, described contact procedure comprises and is selected from following operation: soak into, spray, pad, discharge, and their combination.When the contact procedure in the described processing comprises when padding, the typical case removes the described textile treatment composition of capacity from described textiles, obtaining about 30% to about 200%, about 50% to about 150%, or alternative wet absorption of about 60% to about 120%.When the contact procedure in the described processing comprises when spraying, the typical case removes the described textile treatment composition of capacity from described textiles, obtaining about 10% to about 150%, about 15% to about 100%, or alternative wet absorption of about 20% to about 80%.
Be used to realize that the available devices of method disclosed herein comprises the standard textile product treating apparatus, it includes but not limited to, batch process equipment, semicontinuous treatment facility and continuous processing apparatus, and their combination.
The persistence textiles
By handling described textiles, can make textiles with enhancing and/or lasting beneficial effect with applicant's textile benefit compositions.Processing method comprises disclosed method in the specification of the present invention.When processing was suitable, described textiles comprised following one or more enhancings and/or lasting beneficial effect: resist and fade, prevent balling-up, the feel of improvement, the crease-resistant ABRASION RESISTANCE that contracts and increase.When testing according to applicant's persistence when detecting above-mentioned textiles, textiles is regarded as having one or more above-mentioned persistence beneficial effects, and for the vision hierarchical test that is used for overall appearance, processed textiles is compared with the textiles by water treatment with water treatment, has the difference of positive 2PSU unit or higher score.For the instrument color measuring, Δ E (using the water treatment)-Δ E (handling with advantageous compositions) that has when textiles is when being equal to or greater than 1, and above-mentioned textiles is regarded as having one or more above-mentioned persistence beneficial effects.
Method of testing
1.) persistence test
A.) sample-size: obtain 5 kilograms of textiless to be tested.Two equal portions that above-mentioned substance are divided into each 2.5kg.
B.) handle: handle equal portions with advantageous compositions, only handle another equal portions with distilled water.
C.) washing: following this two equal portions that wash respectively:
(i) equipment: Kenmore Heavy Duty 70 serial washing machines
(ii) wash conditions:
-washing machine is arranged on and is used for the standard weight dirt that cotton is washed journey.
-washing machine is set to 32 ℃.
The hardness that-washing machine is filled with 64L (17 gallons) is that 100ppm and chlorinity are the water of 1ppm.
(iii) handle
-with 100 gram Tide
TMLiquid laundry joins in each washing machine with product.
-stirring/washing 2 minutes.
-in each washing machine, add textiles.
-stirring/washing 12 minutes.
-fast rotational is removed wash liquid.
-rinsed textile in rinse cycle (rinsing is 4 minutes in 16 ℃ of washings)
-fast rotational is removed rinsing liquid.
D.) following respectively dry these two equal portions:
(i) equipment
-standard U.S. the roller dryer that provides by Kenmore
(ii) condition:
-drying time and setting:, carry out suitable setting according to the control explanation of dryer about type of textiles
(iii) handle:
-the textiles equal portions are positioned in the dryer respectively.
-make dryer move complete dry cycle.
When finishing ,-dry cycle takes out textiles
E.), estimate described textiles according to the method among the step f hereinafter then to each textiles equal portions repeating step c and d10 time.
F.) evaluation of textiles
(i) overall appearance is carried out vision classification (scoring unit of appraisal group)
-arrange that under the D50 illumination textiles is to carry out classification.
-use water treatment and washed textiles thing in contrast, following will the processing with washed textiles carried out classification:
Use+4/-4 vision scale
0=does not have difference
I think that difference is arranged 1=
I be sure of that difference is arranged 2=
I be sure of 3=to have than big difference
I be sure of that dramatic difference is arranged 4=
-use and mark for three times.Grade is the digital average of three scorings of gained.
(ii) instrument classification
-U.S. textile dyes chemical work NAB National Association 0f Broadcasters (AATCC) assessment process 7: the instrument assessment of sample change color.The 391st page of 2004 " technical manual " the 79th volume.
The use washed textiles thing in contrast that is untreated
Equipment: Hunter Color Quest 45/0
Δ E is the aberration index with tester
Color scale: CIEL
*a
*b
*
Instrument geometric system: 45/0 circumference illumination
Light source: D65 (daylight at high noon)
Observer: 10
Ultraviolet sees through (comprising ultraviolet ray)
For textiles, 2.54cm (1 inch) aperture
Example I is to IV
According to following method, preparation has the textile benefit compositions of following prescription.
| Raw material | Commodity/supplier | Embodiment 1 prescription % | Embodiment 2 prescription % | Embodiment 3 prescription % | Embodiment 4 prescription % |
| Ester modified carboxymethyl cellulose | Finnefix/Noviant, Finland | 0.10% | 0.75% | 0.10% | 0.10% |
| Polyethylene emulsion | PE 39725/Michleman, Ohio | 1.00% | 1.00% | 1.00% | 1.00% |
| Cationic hydroxyethyl cellulose | LK400/Dow Chemicals | 0.20% | 0.00% | 0.20% | 0.20% |
| The ethoxylation tetraethylenepentamine | PG105/BASF | 1.00% | 0.00% | 1.00% | 1.00% |
| Dihydroxymethyl-4, the 5-dihydroxy ethylene urea | Freerez 845/Noveon, Ohio | 2.00% | 2.00% | 0.00% | 0.00% |
| BTCA | Aldrich | 0.00% | 0.00% | 2.00% | 0.00% |
| Polymalic acid | Derive from the monomer of Aldrich.Internal pair production | 0.00% | 0.00% | 0.00% | 2.00% |
| Sodium hypophosphite | Aldrich | 0.00% | 0.00% | 1.00% | 1.00% |
| Wetting agent | LEOPHEN TMN-AM/BASF | 0.10% | 0.10% | 0.10% | 0.10% |
| Water | Surplus | Surplus | Surplus | Surplus | |
| PH value of solution (regulating) with acetate | 4 | 4 | 3 | 3 |
To IV, required component is dissolving in advance all, mixes in standard batch of material mixer then for each example I.
Fabric treating
Obtain four parts of fabric samples, and with a kind of composition of above-mentioned example I to the IV, soak every increment this.Under the pressure of 300kPa (3 crust),, pad fabric then via Mathis padder (model #HVF 52200) with the speed of 0.6m/min (2 feet of per minutes).By the weight of described fabric, wet being absorbed in 75% to 100% the scope.Before curing, that fabric is following dry 2 hours at 50 ℃ then.Under 170 ℃ of baking oven regional temperatures, these fabrics were solidified 4 minutes in the continuous feed dryer.
Although illustrated and described the present invention with specific embodiments, it will be apparent to those skilled in the art that and to make many other variation and modifications in the case of without departing from the spirit and scope of protection of the present invention.Therefore in additional claims, comprise all such changes and modifications that belong in the scope of the invention consciously.
Claims (9)
1. a pH is 2 to 11 composition, and described composition comprises:
(a) by weight 0.005% to 10% based on cellulosic polymers compositions; 0.005% to 20% material, but described material is selected from dispersible polyolefin, chlorine inhibitor; Dye-fixing agent and their mixture; Or 0.01% to 10% chlorine inhibitor by weight; 0.005% to 20% material, but described material is selected from dispersible polyolefin, based on cellulosic polymers compositions, dye-fixing agent and their mixture;
(b) 0.1% to 10% crosslinking agent by weight
(c) Ren Xuan wetting agent
The surplus of described composition is a carrier.
2. composition as claimed in claim 1, the wherein said carboxymethyl cellulose polymer that comprises hydrophobically modified based on cellulosic polymers compositions, the carboxymethyl cellulose polymer of described hydrophobically modified has 10,000 dalton to 2,000,000 daltonian weight average molecular weight, the carboxymethyl cellulose polymer of described hydrophobically modified comprises the repetitive with following formula:
Wherein:
A.) n is enough big integer, so that the carboxymethyl cellulose polymer of described hydrophobically modified has 10,000 dalton to 2, and 000,000 daltonian weight average molecular weight;
B.) each R is independently selected from R
H, R
CAnd H;
Wherein:
(i) each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aralkyl, replacement, hydroxy alkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
Each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aralkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidyl alkyl, morpholinyl alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
Each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aralkyl, replacement, hydroxy alkyl, (R
6)
2N-alkyl and (R
6)
3The N-alkyl;
Each R
6Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aralkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidyl alkyl, morpholinyl alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
Two R on the wherein identical nitrogen-atoms
4Or R
6Part can lump together the formation ring structure, and described ring structure is selected from piperidines and morpholine;
M is the CATION that suits, and it is selected from Na, K, 1/2Ca and 1/2Mg; With
Precondition is:
If any R
HHave positive charge, then can come balance by suitable anion; With
R
HSubstitution value between 0.0001 and 0.1;
(ii) each R
CFor
Wherein each Z is independently selected from M, R
2And R
HWherein:
Each M as above defines;
Each R
HAs above definition;
Each R
2Be independently selected from H and C
1-C
4Alkyl;
Each y is 1 to 5; With
Precondition is:
When Z is H or M, radicals R
CSubstitution value between 0.1 and 2.0.
3. the described composition of each claim as described above wherein saidly comprises a kind of material based on cellulosic polymers compositions, and described material is selected from the carboxymethyl cellulose of ether modification, ester modified carboxymethyl cellulose and their mixture.
4. the described composition of each claim as described above, wherein said crosslinking agent comprises a kind of material, described material is selected from methylol and (alkoxymethyl)-2 radical derivative, polyfunctional group carboxylic acid and their mixture of urea, ethylene urea and propylene urea.
5. the described composition of each claim as described above, but wherein said dispersible polyolefin comprises the Tissuemat E of oxidation.
6. the described composition of each claim as described above, wherein said chlorine inhibitor comprises polyamine component, preferred described polyamine component comprises a kind of material, and described material is selected from ethoxylation tetraethylenepentamine, polymine, ethoxylation polymine, polyvinylpyrrolidone, polyvinylamine, polylysine, two hexamethylene diamine and their mixture.
7. method of handling textiles, described method is characterised in that and said method comprising the steps of:
A.) preferably soak into, spray, pad, discharge and their operation of combination, at least a portion textiles is contacted with the described composition of each claim as described above by being selected from;
B.) remove the described composition of capacity from described textiles, preferred 15% to 150% obtaining 30% to 200%, more preferably 20% to 120% wet absorption; With
C.) described processing was preferably carried out in dry and curing and the described textiles of the contacted at least a portion of described composition before the end user uses described textiles.
As each described composition in the claim 1 to 6 in the application that provides for textiles aspect the lasting beneficial effect.
9. textiles, described textiles is characterised in that described textiles comprises lasting beneficial effect.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56833804P | 2004-05-05 | 2004-05-05 | |
| US60/568,338 | 2004-05-05 | ||
| US11/081,490 US20050246841A1 (en) | 2004-05-05 | 2005-03-16 | Textile benefit compositions |
| US11/081,490 | 2005-03-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1950565A true CN1950565A (en) | 2007-04-18 |
Family
ID=34968426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005800144897A Pending CN1950565A (en) | 2004-05-05 | 2005-05-05 | Textile benefit compositions |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20050246841A1 (en) |
| EP (1) | EP1743065A2 (en) |
| JP (1) | JP2007535626A (en) |
| CN (1) | CN1950565A (en) |
| BR (1) | BRPI0509591A (en) |
| CA (1) | CA2564857A1 (en) |
| MX (1) | MXPA06012821A (en) |
| WO (1) | WO2005108670A2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101370919B (en) * | 2006-01-19 | 2013-07-17 | 宝洁公司 | Fabric treatment composition providing stain repellant coating |
| DE102006039873B4 (en) * | 2006-08-25 | 2013-10-31 | Henkel Ag & Co. Kgaa | Reinforcement of the cleaning performance of detergents by cotton-active soil release cellulose derivative |
| US20090014034A1 (en) * | 2006-11-22 | 2009-01-15 | The Procter & Gamble Company | Benefit compositions and formaldehyde scavengers for same |
| EP2089570A1 (en) * | 2006-11-22 | 2009-08-19 | The Procter and Gamble Company | Benefit compositions and methods |
| CN101886338B (en) * | 2010-07-07 | 2015-11-25 | 天津科技大学 | A kind of biological antibiotic cotton fiber or cotton and preparation method thereof |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL269149A (en) * | 1960-09-12 | |||
| ATE382079T1 (en) * | 1999-01-13 | 2008-01-15 | Procter & Gamble | DETERGENT CONTAINING CELLULOSE POLYMER |
| EP1255890A1 (en) * | 2000-02-15 | 2002-11-13 | The Procter & Gamble Company | Method for the application of durable press finishes to textile components via the use of hydrophobic bleaching preparation |
| US6830591B1 (en) * | 2000-02-15 | 2004-12-14 | The Procter & Gamble Company | Method for the use of hydrophobic bleaching systems in textile preparation |
| JP2003525361A (en) * | 2000-02-15 | 2003-08-26 | ザ、プロクター、エンド、ギャンブル、カンパニー | One-step preparation method for textile products |
| DE60104106T2 (en) * | 2000-04-20 | 2005-08-25 | The Board Of Regents Of The University Of Nebraska, Lincoln | PROTECTION SYSTEMS FOR SULFUR POWERS, AND COMPOSITIONS AND METHODS THEREOF THEREOF APPLIED TO |
| JP2004526064A (en) * | 2001-01-25 | 2004-08-26 | ナノテックス， エルエルシー | Method of making a cellulose coating around the fibers of a woven fabric and the woven fabric made thereby |
| US6569209B2 (en) * | 2001-02-27 | 2003-05-27 | The Procter & Gamble Company | Method for the use of hydrophobic bleaching systems in cold batch textile preparation |
| DE60210085T2 (en) * | 2001-06-29 | 2006-11-09 | The Procter & Gamble Company, Cincinnati | STABILITY-RESISTANT PERSONALIZATION SYSTEM SUITABLE FOR TISSUE TREATMENT |
| US20030226213A1 (en) * | 2002-04-16 | 2003-12-11 | The Procter & Gamble Company | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
| US20030226212A1 (en) * | 2002-04-16 | 2003-12-11 | Jiping Wang | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
-
2005
- 2005-03-16 US US11/081,490 patent/US20050246841A1/en not_active Abandoned
- 2005-05-05 JP JP2007511101A patent/JP2007535626A/en not_active Withdrawn
- 2005-05-05 EP EP05744639A patent/EP1743065A2/en not_active Withdrawn
- 2005-05-05 BR BRPI0509591-3A patent/BRPI0509591A/en not_active Application Discontinuation
- 2005-05-05 CN CNA2005800144897A patent/CN1950565A/en active Pending
- 2005-05-05 MX MXPA06012821A patent/MXPA06012821A/en unknown
- 2005-05-05 CA CA002564857A patent/CA2564857A1/en not_active Abandoned
- 2005-05-05 WO PCT/US2005/015744 patent/WO2005108670A2/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2564857A1 (en) | 2005-11-17 |
| BRPI0509591A (en) | 2007-09-25 |
| WO2005108670A3 (en) | 2006-01-05 |
| MXPA06012821A (en) | 2007-01-26 |
| US20050246841A1 (en) | 2005-11-10 |
| WO2005108670A2 (en) | 2005-11-17 |
| EP1743065A2 (en) | 2007-01-17 |
| JP2007535626A (en) | 2007-12-06 |
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