CN1947974A - Resin coalesced cork wood and rubber composite material, and its mfg. method, and composite plate thereof, and its mfg. method. - Google Patents

Resin coalesced cork wood and rubber composite material, and its mfg. method, and composite plate thereof, and its mfg. method. Download PDF

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Publication number
CN1947974A
CN1947974A CN 200610104840 CN200610104840A CN1947974A CN 1947974 A CN1947974 A CN 1947974A CN 200610104840 CN200610104840 CN 200610104840 CN 200610104840 A CN200610104840 A CN 200610104840A CN 1947974 A CN1947974 A CN 1947974A
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cork
rubber
composite
blank
plate
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郑林义
郑哲
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Abstract

A composite cork-rubber material is proportionally prepared from cork or cork composition, sulfurized rubber particles or strips, and resin adhesive. A composite board made of said composite material is composed of a basic layer made of said composite cork-rubber material, another layer made of high-grade cork, or cork-rubber, or wood or bamboo, an optional sandwich layer made of artificial ply, and a balancing cork layer. It is used as the floor board in kitchen.

Description

Resin coalesced cork-rubber composite and manufacture method and cork-rubber composite plate and manufacture method
Technical field:
The invention belongs to the forest chemical technical field, particularly a kind of cork-rubber goods are made
Technical field.
Technical background:
The composition of existing cork-rubber paper (pad) is that granulated cork, the rubber chemical industry auxiliary material relevant with it mixes, and is smelted into the cork-rubber green compact through rubber mixing machine, its sanction is slit into the big or small and weight of requirement again and puts into mould and vulcanize through vulcanizing autoclave.Though functional, its manufacture process power consumption is big, cost is higher, and smell is big and easily aging; Cork ground cushion, floor consume rare cork in a large number, and the two is used for ground cushion, floor base material function waste, should not be paved on the bedroom, kitchen.China Patent No. is the rubber floor covering of ZL01207974.X, and the surface layer that bottom that it is formed by the crude rubber particle bond and thin rubbery granule bonding form is formed, and the crude rubber granular size is 0.5-5mm, and thin rubbery granule is the 10-40 order.Surface thickness is 1/5th of a underlayer thickness, and the crude rubber particle can be irregular particle, rounded grain or strip particle.Its advantage is the anti-wear performance excellence, be not afraid of to pound and bump, and insulation antistatic, non-skid property excellent strength is low, but its thickness is big, and coarse, pigment figure is single, and rubber easily flavor is big, can only be used on the playing field, and is indoor unsuitable.
Summary of the invention
The present invention seeks to deficiency, propose a kind of resin coalesced cork-rubber composite and its manufacture method and composite product at existing cork-rubber and rubber floor mat, floor composition and processing method.
Specifically, the present invention is achieved in that
Described resin coalesced cork-rubber composite, it consist of: vegetable cork or cork composite material (1) they are the 1-40 weight portion; Vulcanized rubber grain, bar (2) are the 1-50 weight portion; The adhesive of 1-30 weight portion, resin glue (3).
Can in component, add an amount of fiber (4) again.
Obtain the method for above-mentioned cork-rubber composite:
First method: (1) is with cork or composite cork material grain, vulcanized rubber grain or add an amount of fiber again by the intended diameter size, color and luster, shape weight are mixed, add and to require transparent or coloured and the resin glue of proportioning weight on request, in mixer, stir; (2) by designing requirement weight, the mould or be laid in the original mold frame of packing into; (3) band mould vertical compression or take down the charging framed, put thickness-determining gauge; Push hot press; (4) directly be warmed to 80 ℃ of-180 ℃ of curing moldings, reach and want seeking time, blank takes out mould; (5) Bao blank grinding thickness, cross cutting promptly obtains required ground cushion or floor; Thick blank stack binding agent lumps together, and is placed on the fixed thick sheet that cuts open on the flat cutting machine, and the side cut scale directly is processed into the cork-rubber ground cushion of desired thickness or strengthens the cork-rubber ground cushion.
Second method is: (1) is with cork or composite cork material grain, rubber grain, add an amount of fiber again by the intended diameter size, color and luster, shape weight mix, and add to require transparent or coloured and the resin glue of proportioning weight on request, stir in mixer; (2) compound that will mix glue is incorporated with the rectangle of going to the bottom in the activity, and square or cylinder installs according to required weight to the folding steel mold, and the dress back requires to add upper cover plate, will lock loam cake after the pressurization; (3) mould that locks is pushed baker, drying room is heated to 80 ℃-180 ℃, makes its solidifying and setting insulation 2-3 hour; (4) mould is pulled out outside the stove, temperature drops to normal temperature, and rectangle, square, hollow cylinder cork-rubber blank are taken out in die sinking; (5) thickness cuts the cork-rubber sheet material of designing requirement less than the rectangle below the 15cm, square cork-rubber blank with fish gutting machine; Circular blanks, the force plane both ends of the surface are also sprayed glue, and stack is contained on the rotary-cut axle, locks by length dimension requirement pressurization, waits to solidify the back and is peeled into cork-rubber or strengthens the cork-rubber coiled material with the cork peeler.
The third method is: (1) is with cork or composite cork material grain, rubber grain, add an amount of fiber again by the intended diameter size, color and luster, shape weight mix, and add to require transparent or coloured and the resin glue of proportioning weight on request, stir in mixer; (2) cork-rubber glue mixing compound is packed into nonmetal mould or nonmetally strengthen mould with metal; On go to the bottom and be false bottom, the base plate medial surface has pole plate; Add after the charging and in forcing press, be forced into the inboard band of upper cover plate pole plate and require height; To go up bottom crown and be connected, close a switch with the positive consequent pole of high-frequency heating; (3) adopt high-frequency dielectric to be heated to the temperature-time of solidification temperature time requirement; (4) mould is opened in the low-density release, takes out blank and gets final product; High density locks cover plate, treats that temperature reduces to the normal temperature form removal; (5) take out blank; The rectangle blank dissects thickness requirement sheet material cork-rubber ground cushion, floor with the cork splitting machine; Cylindrical blank, the force plane both ends of the surface, spray glue, stack is in layer executed the cork-rubber coiled material that cutter is peeled into required thickness with cork after being contained in and compressing stickup curing on the stamen axle, plate, pad.
Described cork-rubber composite plate comprises with above-mentioned three kinds or four kinds of raw materials strand mixes resin coalesced cork-rubber plate, the pad that is mixed and made into or strengthens the cork-rubber material substrate layer (b) that cork-rubber, cork sheet, plate, pad, floor are made, with this substrate layer and senior cork or veneer, bamboo layer (a), two-layer compound and compound one deck cork suspension balance layer (c) in the bottom surface.
The method for production of above-mentioned cork-rubber composite plate is:
One, (1), in mould, spread cork sheet on the bottom surface at when filling with substance, rubbery cork paper or mat formation and go up double-colored different size particles cork-rubber material is loaded onto base material in the above with cork-rubber glue mixing material, obtains two-layer compound cork rubber clad plate blank; (2) after completing bilayer, on the cork-rubber layer, put granulated cork or cork sheet, promptly get three layers of cork-rubber composite; (3) after completing two layers, on the cork-rubber granulosa, put wood-based plate, put one deck cork sheet or shop one deck cork glue mixing pellet or cork-rubber paper or glue mixing cork-rubber pellet again, put the upper cover plate one-shot forming of heating, promptly obtain four layers of cork-rubber composite plate blank that is compounded with suspension balance cork layer; (4) sanding of above cork composite plate blank is decided gauge and required and fineness, the cross cutting floor, wallboard, the wall paper waxing gets final product.
Two, cut open sheet or coiled material with cork-rubber, paste thereon and go up cork, cork composite, cork-rubber, bamboo and wood, thin skin lining, promptly get two layers of composite and floor blank; At its upper berth, end one deck cork sheet, promptly get three layers compound, on two layers, add wood-based plate, sticking again one deck cork sheet or rubbery cork paper promptly get four layers of composite and floor blank.
Scale thickness floor surface is coated with photosensitive " UV " or PU, pastes the PVCU film.
This composite board also can adopt following method preparation: double-colored different size particles cork-rubber material when filling with substance is spread cork sheet or cork glue mixing material, rubbery cork paper or mated formation on the bottom surface in mould on, load onto base material cork-rubber glue mixing material in the above; (2) wood-based plate is put the cover plate one-shot forming of heating, and obtains two-layer compound cork rubber clad plate blank; (3) put one deck cork sheet or shop one deck cork glue mixing pellet again, promptly obtain three layers of cork-rubber composite plate blank that is compounded with suspension balance cork layer; (4) sanding of above cork composite plate blank is decided gauge and required and fineness, the cross cutting floor, wallboard, the wall paper waxing gets final product.
The invention has the advantages that the asepsis environment-protecting that has kept cork-rubber, elastic shock attenuation, moistureproof water-fast, thermal insulation sound-absorbing, insulation, anlistatig superperformance.Eliminated not ageing-resistantly, the rubber smell deficiency has been arranged, solved floor for kitchen use, improved decorative effect.Strengthen cork-rubber intensity and improve, reduced rare cork consumption of raw materials, the reclaimed rubber circulation utilizes fully efficiently.Production method has simply reduced raw material, energy manpower consumption.Realized the saving of natural resources.Renewable recycling, enlarged range of application, therefore be used for senior cork-rubber ground cushion, floor and multiple color and luster thereof, the cork-rubber composite floor board of wood grain, the manufacturing of carpet.Can be used for indoor, objective with car and boat, sports ground, gymnasium, machine room, the long-pending furniture in kitchen, sole exterior trim.、
Description of drawings:
Fig. 1 is resin cork-rubber composite composition and structure cross-sectional schematic.
Fig. 2 strengthens cork-rubber composite composition and structure cross-sectional schematic for resin.
Fig. 3 is a resin cork-rubber two-layer compound sheet material cross-sectional schematic.
Fig. 4 is a resin cork-rubber three-layer composite board material cross-sectional schematic.
The figure number explanation:
Label among Fig. 1, Fig. 2:
1, cork, softening, expanded cork diameter, color and luster, shape particle, sheet, bar arbitrarily; The coalescent granulated cork bar of color resin, sheet, diameter, color and luster, shape are any.
2, through the rubber of over cure, reclaim colorful rubber arbitrary dimension particle, bar, sheet, CF.
3, sizing material, elastic resin, EVA, polypropylene, neoprene etc.
4, fiber or screen cloths such as plant (wood, bamboo, grass, stalk, linen-cotton), mineral (asbestos, glass), chemical fibre.
Fig. 3 to Fig. 4:
A, decorative fabric, resin cork, cork composite material, cork-rubber material, wood, bamboo, thin skin, birch-bark, cotton, fiber crops, chemical fabric, calico paper.Iron, seal, gold stamping printing ink charing pattern.
B, substrate layer resin rubber, resin cork-rubber, fortified resin cork-rubber, the various wood of b1 enhancement Layer, bamboo, stalk, wood-based plate, cardboard, hollow aluminium sheet, plastic plate.
C, suspension balance confining bed; Cork, cork composite material, cork-rubber material, elastoplast.
D, surface waterproofing wearing layer; Wallboard, wall paper move, plant wax or mineral tallow with natural.The floor is with photosensitive " UV " coating, PU, PVCU veneer, elastic polyurethane.
The specific embodiment
Resin coalesced cork-rubber composite, it consist of: vegetable cork or cork composite material (1) they are the 1-40 weight portion; Vulcanized rubber grain, bar (2) are the 1-50 weight portion; The adhesive of 1-30 weight portion, resin glue (3).Can in component, add an amount of fiber (4) again.
Obtain the method for above-mentioned cork-rubber composite:
First method: (1) is with cork or composite cork material grain, vulcanized rubber grain or add an amount of fiber again by the intended diameter size, color and luster, shape weight are mixed, add and to require transparent or coloured and the resin glue of proportioning weight on request, in mixer, stir; (2) by designing requirement weight, the mould or be laid in the original mold frame of packing into; (3) band mould vertical compression or take down the charging framed, put thickness-determining gauge; Push hot press; (4) directly be warmed to 80 ℃ of-180 ℃ of curing moldings, reach and want seeking time, blank takes out mould; (5) Bao blank grinding thickness, cross cutting promptly obtains required ground cushion or floor; Thick blank stack binding agent lumps together, and is placed on the fixed thick sheet that cuts open on the flat cutting machine, and the side cut scale directly is processed into the cork-rubber ground cushion of desired thickness or strengthens the cork-rubber ground cushion.
Second method is: (1) is with cork or composite cork material grain, rubber grain, add an amount of fiber again by the intended diameter size, color and luster, shape weight mix, and add to require transparent or coloured and the resin glue of proportioning weight on request, stir in mixer; (2) compound that will mix glue is incorporated with the rectangle of going to the bottom in the activity, and square or cylinder installs according to required weight to the folding steel mold, and the dress back requires to add upper cover plate, will lock loam cake after the pressurization; (3) mould that locks is pushed baker, drying room is heated to 80 ℃-180 ℃, makes its solidifying and setting insulation 2-3 hour; (4) mould is pulled out outside the stove, temperature drops to normal temperature, and rectangle, square, hollow cylinder cork-rubber blank are taken out in die sinking; (5) thickness cuts the cork-rubber sheet material of designing requirement less than the rectangle below the 15cm, square cork-rubber blank with fish gutting machine; Circular blanks, the force plane both ends of the surface are also sprayed glue, and stack is contained on the rotary-cut axle, locks by length dimension requirement pressurization, waits to solidify the back and is peeled into cork-rubber or strengthens the cork-rubber coiled material with the cork peeler.
The third method is: (1) is with cork or composite cork material grain, rubber grain, add an amount of fiber again by the intended diameter size, color and luster, shape weight mix, and add to require transparent or coloured and the resin glue of proportioning weight on request, stir in mixer; (2) cork-rubber glue mixing compound is packed into nonmetal mould or nonmetally strengthen mould with metal; On go to the bottom and be false bottom, the base plate medial surface has pole plate; Add after the charging and in forcing press, be forced into the inboard band of upper cover plate pole plate and require height; To go up bottom crown and be connected, close a switch with the positive consequent pole of high-frequency heating; (3) adopt high-frequency dielectric to be heated to the temperature-time of solidification temperature time requirement; (4) mould is opened in the low-density release, takes out blank and gets final product; High density locks cover plate, treats that temperature reduces to the normal temperature form removal; (5) take out blank; The rectangle blank dissects thickness requirement sheet material cork-rubber ground cushion, floor with the cork splitting machine; Cylindrical blank, the force plane both ends of the surface, spray glue, stack is in layer executed the cork-rubber coiled material that cutter is peeled into required thickness with cork after being contained in and compressing stickup curing on the stamen axle, plate, pad.
Described cork-rubber composite plate comprises with above-mentioned three kinds or four kinds of raw materials strand mixes resin coalesced cork-rubber plate, the pad that is mixed and made into or strengthens the cork-rubber material substrate layer (b) that cork-rubber, cork sheet, plate, pad, floor are made, with this substrate layer and senior cork or veneer, bamboo layer (a), two-layer compound and compound one deck cork suspension balance layer (c) in the bottom surface.
The method for production of above-mentioned cork-rubber composite plate is:
One, (1), in mould, spread cork sheet on the bottom surface at when filling with substance, rubbery cork paper or mat formation and go up double-colored different size particles cork-rubber material is loaded onto base material in the above with cork-rubber glue mixing material, obtains two-layer compound cork rubber clad plate blank; (2) after completing bilayer, on the cork-rubber layer, put granulated cork or cork sheet, promptly get three layers of cork-rubber composite; (3) after completing two layers, on the cork-rubber granulosa, put wood-based plate, put one deck cork sheet or shop one deck cork glue mixing pellet or cork-rubber paper or glue mixing cork-rubber pellet again, put the upper cover plate one-shot forming of heating, promptly obtain four layers of cork-rubber composite plate blank that is compounded with suspension balance cork layer; (4) sanding of above cork composite plate blank is decided gauge and required and fineness, the cross cutting floor, wallboard, the wall paper waxing gets final product.Cut open sheet or coiled material with cork-rubber, paste thereon and go up cork, cork composite, cork-rubber, bamboo and wood, thin skin lining, promptly get two layers of composite and floor blank; At its upper berth, end one deck cork sheet, promptly get three layers compound, on two layers, add wood-based plate, sticking again one deck cork sheet or rubbery cork paper promptly get four layers of composite and floor blank.Scale thickness floor surface is coated with photosensitive " UV " or PU, pastes the PVCU film.
This composite board also can adopt following method preparation: double-colored different size particles cork-rubber material when filling with substance is spread cork sheet or cork glue mixing material, rubbery cork paper or mated formation on the bottom surface in mould on, load onto base material cork-rubber glue mixing material in the above; (2) wood-based plate is put the cover plate one-shot forming of heating, and obtains two-layer compound cork rubber clad plate blank; (3) put one deck cork sheet or shop one deck cork glue mixing pellet again, promptly obtain three layers of cork-rubber composite plate blank that is compounded with suspension balance cork layer; (4) sanding of above cork composite plate blank is decided gauge and required and fineness, the cross cutting floor, wallboard, the wall paper waxing gets final product.

Claims (8)

1, resin coalesced cork-rubber composite is characterized in that consisting of of it: vegetable cork or cork composite material (1) are the 1-40 weight portion; Vulcanized rubber grain, bar (2) are the 1-50 weight portion; The adhesive of 1-30 weight portion, resin glue (3).
2, resin coalesced cork-rubber composite according to claim 1 is characterized in that adding an amount of fiber (4) again in component.
3, resin coalesced cork-rubber composite according to claim 1 is characterized in that described vegetable cork is granulated cork, bar, sheet; Cork composite material is resin coalesced granulated cork, bar.
4, the preparation method of cork-rubber composite is characterized in that may further comprise the steps:
(1) with cork or composite cork material grain, vulcanized rubber grain, add an amount of fiber again by the intended diameter size, color and luster, shape weight are mixed, and add to require transparent or coloured and the resin glue of proportioning weight on request, stir in mixer; (2) by designing requirement weight, the mould or be laid on of packing into adorn framed in; (3) the direct pressure of band mould, or it is framed to remove charging, and blank takes out mould, puts thickness-determining gauge; Push hot press; (4) directly be warmed to 80 ℃ of-180 ℃ of curing moldings, reach and want seeking time, blank takes out mould; (5) Bao blank grinding thickness, cross cutting promptly obtains required ground cushion or floor; Thick blank stack binding agent lumps together, and is placed on the fixed thick sheet that cuts open on the flat cutting machine, and the side cut scale directly is processed into the cork-rubber ground cushion of desired thickness or strengthens the cork-rubber ground cushion.
5, the preparation method of cork-rubber composite is characterized in that may further comprise the steps:
(1) with cork or composite cork material grain, vulcanized rubber grain, add an amount of fiber again by the intended diameter size, color and luster, shape weight are mixed, and add to require transparent or coloured and the resin glue of proportioning weight on request, stir in mixer; (2) compound that will mix glue is incorporated with the rectangle of going to the bottom in the activity, and square or cylinder installs according to required weight to the folding steel mold, is filled to require to add upper cover plate, will lock loam cake after the pressurization; (3) mould that locks is pushed baker, drying room is heated to 80 ℃-180 ℃, makes its solidifying and setting insulation 2-3 hour; (4) mould is pulled out outside the stove, temperature drops to normal temperature, and rectangle, square, solid cylindrical cork-rubber blank are taken out in die sinking; (5) thickness cuts the cork-rubber sheet material of designing requirement less than the rectangle below the 15cm, square cork-rubber blank with fish gutting machine; The direct rotary-cut of circular blanks, the force plane both ends of the surface that thickness is little are also sprayed glue, and stack is contained on the rotary-cut axle, locks by length dimension requirement pressurization, waits to solidify the back and is peeled into cork-rubber or strengthens the cork-rubber coiled material with the cork peeler.
6, the preparation method of cork-rubber composite is characterized in that may further comprise the steps:
(1) with cork or composite cork material grain, vulcanized rubber grain, add an amount of fiber again by the intended diameter size, color and luster, shape weight are mixed, and add to require transparent or coloured and the resin glue of proportioning weight on request, stir in mixer; (2) cork-rubber glue mixing compound is packed into nonmetal mould or nonmetally strengthen mould with metal; On go to the bottom and be false bottom, the base plate medial surface has pole plate; Add after the charging and in forcing press, be forced into the inboard band of upper cover plate pole plate and require height; To go up bottom crown and be connected, close a switch with the positive consequent pole of high-frequency heating; (3) adopt high-frequency dielectric to be heated to the temperature-time of solidification temperature time requirement; (4) mould is opened in the low-density release, takes out blank and gets final product; High density locks cover plate, treats that temperature reduces to the normal temperature form removal; (5) take out blank; The rectangle blank dissects thickness requirement sheet material cork-rubber ground cushion, floor with the cork splitting machine; The direct rotary-cut of cylindrical blank, the force plane both ends of the surface spray glue that thickness is little, one deck stack is executed the cork-rubber coiled material that cutter is peeled into required thickness with cork after being contained in and compressing stickup curing on the stamen axle, plate, pad.
7, a kind of cork-rubber composite plate, it is characterized in that comprising with above-mentioned three kinds or four kinds of raw material strands and mix the cork-rubber material substrate layer (b) that make on resin coalesced cork-rubber plate, pad or the reinforcement, cork-rubber, cork sheet, plate, pad, the floor that are mixed and made into, with this substrate layer with senior cork, cork-rubber or veneer, bamboo layer (a) is double-deck or the centre is with three layers of wood-based plate to be incorporated in bottom surface compound one deck cork suspension balance layer (c) again.
8,, it is characterized in that comprising following steps according to the manufacture method of the described cork-rubber composite plate of claim 7:
(1), when filling with substance is spread cork sheet or cork glue mixing material, rubbery cork paper or is mated formation on the bottom surface in mould on double-colored different size particles cork-rubber material, load onto base material in the above with cork-rubber glue mixing material; (2) wood-based plate is put the cover plate one-shot forming of heating, and obtains two-layer compound cork rubber clad plate blank; (3) put one deck cork sheet or shop one deck cork glue mixing pellet again, promptly obtain three layers of cork-rubber composite plate blank that is compounded with suspension balance cork layer; (4) sanding of above cork composite plate blank is decided gauge and required and fineness, the cross cutting floor, wallboard, the wall paper waxing gets final product.
CN 200610104840 2006-10-31 2006-10-31 Resin coalesced cork wood and rubber composite material, and its mfg. method, and composite plate thereof, and its mfg. method. Pending CN1947974A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200610104840 CN1947974A (en) 2006-10-31 2006-10-31 Resin coalesced cork wood and rubber composite material, and its mfg. method, and composite plate thereof, and its mfg. method.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200610104840 CN1947974A (en) 2006-10-31 2006-10-31 Resin coalesced cork wood and rubber composite material, and its mfg. method, and composite plate thereof, and its mfg. method.

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CN1947974A true CN1947974A (en) 2007-04-18

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010148630A1 (en) * 2009-06-25 2010-12-29 Yang Xujiang Cork carpet
CN105971233A (en) * 2016-06-25 2016-09-28 安徽省申运木业有限公司 Luminous cork and rubber composite floor and production process thereof
CN106592921A (en) * 2016-11-17 2017-04-26 安徽韩华建材科技股份有限公司 Production technique of shrinkage prevention glue-free floor made of novel combined material
CN111267201A (en) * 2020-01-19 2020-06-12 郑林义 Cork wood composite material and preparation method thereof
CN111364315A (en) * 2020-03-13 2020-07-03 宝力科技(宁国)有限公司 Environment-friendly prefabricated plastic track

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010148630A1 (en) * 2009-06-25 2010-12-29 Yang Xujiang Cork carpet
CN105971233A (en) * 2016-06-25 2016-09-28 安徽省申运木业有限公司 Luminous cork and rubber composite floor and production process thereof
CN106592921A (en) * 2016-11-17 2017-04-26 安徽韩华建材科技股份有限公司 Production technique of shrinkage prevention glue-free floor made of novel combined material
CN111267201A (en) * 2020-01-19 2020-06-12 郑林义 Cork wood composite material and preparation method thereof
CN111364315A (en) * 2020-03-13 2020-07-03 宝力科技(宁国)有限公司 Environment-friendly prefabricated plastic track

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Open date: 20070418