CN1943350B - Composition with sterilizing function containing difenoconazole and thiophanate-methyl - Google Patents
Composition with sterilizing function containing difenoconazole and thiophanate-methyl Download PDFInfo
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- CN1943350B CN1943350B CN2006101471229A CN200610147122A CN1943350B CN 1943350 B CN1943350 B CN 1943350B CN 2006101471229 A CN2006101471229 A CN 2006101471229A CN 200610147122 A CN200610147122 A CN 200610147122A CN 1943350 B CN1943350 B CN 1943350B
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- thiophanate
- methyl
- difenoconazole
- powdery mildew
- composition
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- 239000005760 Difenoconazole Substances 0.000 title claims abstract description 35
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 239000005842 Thiophanate-methyl Substances 0.000 title claims abstract description 34
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000000203 mixture Substances 0.000 title claims abstract description 7
- 230000001954 sterilising effect Effects 0.000 title 1
- 239000000575 pesticide Substances 0.000 claims abstract description 3
- 239000000375 suspending agent Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 241000221785 Erysiphales Species 0.000 abstract description 25
- 241000209140 Triticum Species 0.000 abstract description 12
- 235000021307 Triticum Nutrition 0.000 abstract description 12
- 201000010099 disease Diseases 0.000 abstract description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 6
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 abstract description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 abstract description 2
- 244000241257 Cucumis melo Species 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- 240000008067 Cucumis sativus Species 0.000 description 10
- 230000003902 lesion Effects 0.000 description 10
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 9
- 239000002131 composite material Substances 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 206010039509 Scab Diseases 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000001225 therapeutic effect Effects 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000205 computational method Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000009545 invasion Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007619 statistical method Methods 0.000 description 2
- 239000008223 sterile water Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000011278 mitosis Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide composition; it comprises difenoconazole and thiophanate-methyl, and is used in preventing and controlling agricultural disease. It is especially suitable for preventing and controlling melon powdery mildew and wheat powdery mildew.
Description
Technical field
This invention relates to a kind of composition pesticide, is made up of Difenoconazole and thiophanate-methyl, is used to prevent and treat the disease on the agricultural.Especially be suitable for preventing and treating cucurbits powdery mildew and powdery mildew of wheat and barley.
Technical background
Difenoconazole is a kind of systemic fungicide with protection and therapeutic action, is table angle sterol biosynthesis inhibitor.It has strong interior absorption, drug effect height, to crop safety, and long characteristics of lasting period.Have prevention and therapeutic action.
Thiophanate-methyl is a kind of bactericide of wide spectrum, high-efficiency low-toxicity.The mechanism of action is the formation of imitative hammer body in the mitosis of disturbing bacterium, thereby influences cell division.Have protection and therapeutic action.
In the real process of agricultural production, preventing and treating the problem that disease is easy to generate most is the drug-fast generation of germ.Important powdery mildew on the agricultural often takes place in the melon crop growth later stage because its spread speed is fast, and host range is wide, is easy to generate resistance especially.In some powdery mildews serious place of causing harm, common bactericide such as tpn, carbendazim, use has not had any effect separately.Triazolones etc. have also caused very serious resistance, and have been easy to generate poisoning owing to large-area application.
Go up the powdery mildew that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But, the development cost height of new active ingredient, the construction cycle is long, and all produces the speed of resistance forever less than germ.Other method such as crop allocation adjustment, different agricultural chemicals are rotated etc., in the process of practical operation, are difficult to really play obvious effects.
The composition of different cultivars carries out composite, is to prevent and treat the very common way of resistance germ.Heterogeneity is carried out composite, according to the effect of practical application, judge certain composite be synergy, add and or antagonism.Compound synergic is well filled a prescription, owing to obviously improved actual control efficiency, reduced the usage amount of agricultural chemicals, thereby delayed the generation of pest resistance to insecticide greatly, and be the important means of integrated control insect.Still nobody reported in the composite and application of Difenoconazole and thiophanate-methyl at present.
Summary of the invention
In order to prevent and treat the disease on the agricultural, we have carried out mutual composite synergy research with compositions such as Difenoconazole, thiophanate-methyls.It is tested object that powdery mildew and wheat powdery mildew on the cucumber are adopted in test, and concrete grammar is:
1) powdery mildew of cucumber.Test medicine provides former medicine for producer, is mixed with the preparation that needs by my research department of company.Take back the powdery mildew of cucumber leaf that adopt back in the field indoor, the cultivation 24h that preserves moisture about 21 ℃ impels and forms more spore on the scab, wash with sterile water then, be diluted under low power lens in (10 * 15) each visual field 3-5 spore and be advisable, and in spore suspension, add 0.25% gelatin to improve the adhesivity of spore on the blade face.
The test method that test adopts blade to preserve moisture and inoculate.Select growing way prosperous after long the to the 3rd to the four true leaf expansion of potted plant cucumber, growth is used (every basin field planting 5 young plants) for connecing the bacterium test uniformly, and every processing repeats 8 times.On pretreated basis series concentration is set, each handles earlier constant spray medicine routinely then, connects bacterium behind the 24h, every basin spray bacterium liquid 5ml, and inoculation back insulation (21-24 ℃) is preserved moisture (relative moisture is greater than 90%) to guarantee the invasion of germ.After morbidity is stable, investigates disease index according to powdery mildew of cucumber grade scale complete stool, and make evaluating drug effect with blank.Ratio is mass ratio.
Statistical analysis technique:
1, state of an illness grade scale:
0 grade: blade does not have scab
1 grade: lesion area accounts for below 5% of whole blade area;
3 grades: lesion area accounts for the 6-10% of whole blade area;
5 grades: lesion area accounts for the 11-25% of whole blade area;
7 grades: lesion area accounts for the 26-50% of whole blade area;
9 grades: lesion area accounts for more than 50% of whole blade area.
2, computational methods:
Calculate concentration EC in virulence equation and the inhibition with method of least squares
50, calculate the toxicity index of medicament and the co-toxicity coefficient of using with (CTC value) according to the abundant method of Sun Yun, CTC value greater than 100 be synergistic effect, equaling 100 is addition, is antagonism less than 100.
2) wheat powdery mildew.Test medicine provides former medicine for producer, is mixed with the preparation that needs by my research department of company.Take back the wheat powdery mildew leaf that adopt back in the field indoor, the cultivation 24h that preserves moisture about 21 ℃ impels and forms more spore on the scab, wash with sterile water then, be diluted under low power lens in (10 * 15) each visual field 3-5 spore and be advisable, and in spore suspension, add 0.25% gelatin to improve the adhesivity of spore on the blade face.
The leaf test method of preserving moisture is adopted in test.It is consistent to get size earlier, the wheat leaf blade that growth is consistent, and each handles 10 leaves, and every processing repeats 8 times.On pretreated basis series concentration is set, each handles earlier constant spray medicine routinely then, connects bacterium behind the 24h, and each handles spray bacterium liquid 5ml, and the insulation (21-24 ℃) in box of inoculation back is preserved moisture (relative moisture is greater than 90%) to guarantee the invasion of germ.After morbidity is stable, investigates disease index according to wheat leaf blade powdery mildew grade scale complete stool, and make evaluating drug effect with blank.Ratio is mass ratio.
Statistical analysis technique:
2, state of an illness grade scale:
0 grade: blade does not have scab
1 grade: lesion area accounts for below 5% of whole blade area;
3 grades: lesion area accounts for the 6-10% of whole blade area;
5 grades: lesion area accounts for the 11-25% of whole blade area;
7 grades: lesion area accounts for the 26-50% of whole blade area;
9 grades: lesion area accounts for more than 50% of whole blade area.
2, computational methods:
Calculate concentration EC in virulence equation and the inhibition with method of least squares
50, calculate the toxicity index of medicament and the co-toxicity coefficient of using with (CTC value) according to the abundant method of Sun Yun, CTC value greater than 100 be synergistic effect, equaling 100 is addition, is antagonism less than 100.
3) measurement result of powdery mildew of cucumber, wheat powdery mildew sees Table 1 and table 2 respectively
Table 1 different disposal is to the Toxicity Determination result of wheat powdery mildew
| Handle | EC 50(PPM) | Co-toxicity coefficient |
| Difenoconazole 1+ thiophanate-methyl 1 | 6.89 | 299.34 |
| Difenoconazole 1+ thiophanate-methyl 2 | 7.25 | 366.52 |
| Difenoconazole 1+ thiophanate-methyl 4 | 7.15 | 482.67 |
| Difenoconazole 1+ thiophanate-methyl 8 | 7.09 | 607.38 |
| Difenoconazole 1+ thiophanate-methyl 12 | 5.36 | 889.17 |
| Difenoconazole 1+ thiophanate-methyl 16 | 7.65 | 659.08 |
| Difenoconazole 1+ thiophanate-methyl 20 | 8.40 | 623.26 |
| Difenoconazole | 12.36 | |
| Thiophanate-methyl | 62.46 |
Table 1 different disposal is to the Toxicity Determination result of powdery mildew of cucumber
| Handle | EC 50(PPM) | Co-toxicity coefficient |
| Difenoconazole 1+ thiophanate-methyl 1 | 7.10 | 287.21 |
| Difenoconazole 1+ thiophanate-methyl 2 | 5.71 | 472.79 |
| Difenoconazole 1+ thiophanate-methyl 4 | 5.82 | 627.49 |
| Difenoconazole 1+ thiophanate-methyl 8 | 5.66 | 841.3 |
| Difenoconazole 1+ thiophanate-methyl 12 | 5.37 | 1005.2 |
| Difenoconazole 1+ thiophanate-methyl 16 | 6.10 | 951.26 |
| Difenoconazole 1+ thiophanate-methyl 20 | 6.27 | 971.21 |
| Difenoconazole | 11.75 | |
| Thiophanate-methyl | 76.99 |
As seen from Table 1, Difenoconazole and thiophanate-methyl are composite, and wheat powdery mildew is had very high synergistic effect.Its co-toxicity coefficient reached 229.34-889.17 the proportioning of (by quality) from 1: 1 to 1: 20.Show that both synergistic effects under this proportioning are obvious.
As seen from Table 2, Difenoconazole and thiophanate-methyl are composite, and powdery mildew of cucumber is had very high synergistic effect.Its co-toxicity coefficient reached 287.21-1005.2 the proportioning of (by quality) from 1: 1 to 1: 20.Show that both synergistic effects under this proportioning are obvious.
Embodiment
Application example one: powdery mildew of cucumber
Press Difenoconazole 5%, thiophanate-methyl 25% is filler and dispersant with white carbon and sodium lignin sulfonate, breaks into 800 order pulvis.This prescription is by 1000 times of dilution sprayings, behind the medicine 7 days control efficiency be 91.3%, 10% Difenoconazole pulvis and 50% thiophanate-methyl pulvis according to using with quadrat method, 7 days preventive effects are respectively 61.3% and 72.0% behind the medicine.
Application example two: powdery mildew of cucumber
Press Difenoconazole 10%, thiophanate-methyl 40% is filler and dispersant with white carbon and sodium lignin sulfonate, breaks into 800 order pulvis.This prescription is by 2000 times of dilution sprayings, and 7 days control efficiency are 97.3%, 10% Difenoconazole pulvis and 25% thiophanate-methyl pulvis according to 1000 times of uses of quadrat method behind the medicine, and 7 days preventive effects are respectively 63..3% and 58.2% behind the medicine.
Application example three: wheat powdery mildew
Press Difenoconazole 5%, thiophanate-methyl 25% is filler and dispersant with white carbon and sodium lignin sulfonate, breaks into 800 order pulvis.This prescription is by 1000 times of dilution sprayings, and 7 days control efficiency are that 88.0%, 10% Difenoconazole pulvis and 25% thiophanate-methyl pulvis are respectively 72..5% and 61.0% according to 7 days preventive effects after making medication with 1000 times of quadrat methods behind the medicine.
Application example four: wheat powdery mildew
Press Difenoconazole 5%, thiophanate-methyl 30% is made suspending agent.This prescription is by 1000 times of dilution sprayings, and 7 days control efficiency are that 96.0%, 10% difenoconazole suspending agent and 50% thiophanate-methyl suspending agent are respectively 68..3% and 52.8% according to 7 days preventive effects after making medication with 1000 times of quadrat methods behind the medicine.
Claims (1)
1. composition pesticide is characterized in that its active component is made up of Difenoconazole and thiophanate-methyl, and the ratio of Difenoconazole and thiophanate-methyl (by quality) is 1: 1-1: between 20, make suspending agent, wetting powder during practical application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006101471229A CN1943350B (en) | 2006-11-07 | 2006-11-07 | Composition with sterilizing function containing difenoconazole and thiophanate-methyl |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006101471229A CN1943350B (en) | 2006-11-07 | 2006-11-07 | Composition with sterilizing function containing difenoconazole and thiophanate-methyl |
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| Publication Number | Publication Date |
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| CN1943350A CN1943350A (en) | 2007-04-11 |
| CN1943350B true CN1943350B (en) | 2011-08-31 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009098230A2 (en) * | 2008-02-05 | 2009-08-13 | Basf Se | Pesticidal mixtures |
| CN103563955B (en) * | 2012-08-08 | 2015-08-19 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bromuconazole |
| BR102013030596A2 (en) * | 2013-11-28 | 2015-09-22 | Rotam Agrochem Int Co Ltd | method of treating fungicidal infections, fungicidal compositions and their use |
| CN107018986A (en) * | 2017-05-15 | 2017-08-08 | 李军民 | A kind of Difenoconazole and thiophanate methyl compounding suspending agent and preparation method thereof |
| CN111084189A (en) * | 2019-12-25 | 2020-05-01 | 山东省绿士农药有限公司 | Pesticide bactericide composition, preparation method and application |
| CN115777721A (en) * | 2022-11-26 | 2023-03-14 | 江西田友生化有限公司 | Suspending agent containing difenoconazole and thiophanate-methyl and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1751474A (en) * | 2003-12-22 | 2006-03-22 | 国际商业机器公司 | Utilization method and system within a communication network |
| CN1833503A (en) * | 2006-04-19 | 2006-09-20 | 江苏龙灯化学有限公司 | Bactericide compsns, with synergistic effect |
| WO2006104742A2 (en) * | 2005-03-28 | 2006-10-05 | Honeywell International Inc. | Methane and methyl chloride as selective reducing agent in the transformation of hydrochlorofluorocarbons or chlorofluorcarbons to hydrochlorofluorocarbons |
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2006
- 2006-11-07 CN CN2006101471229A patent/CN1943350B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1751474A (en) * | 2003-12-22 | 2006-03-22 | 国际商业机器公司 | Utilization method and system within a communication network |
| WO2006104742A2 (en) * | 2005-03-28 | 2006-10-05 | Honeywell International Inc. | Methane and methyl chloride as selective reducing agent in the transformation of hydrochlorofluorocarbons or chlorofluorcarbons to hydrochlorofluorocarbons |
| CN1833503A (en) * | 2006-04-19 | 2006-09-20 | 江苏龙灯化学有限公司 | Bactericide compsns, with synergistic effect |
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Application publication date: 20070411 Assignee: Shandong Zhaofengnian Bio-Technology Co.,Ltd. Assignor: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Contract record no.: 2013440020364 Denomination of invention: Composition with sterilizing function containing difenoconazole and thiophanate-methyl Granted publication date: 20110831 License type: Exclusive License Record date: 20131206 |
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Address after: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee after: Shenzhen Novozon Crop Science Co.,Ltd. Country or region after: China Address before: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Country or region before: China |