CN1942425B - 在含有镍、锰和溴原子的催化剂***存在下,对二甲苯液相氧化成对苯二甲酸 - Google Patents
在含有镍、锰和溴原子的催化剂***存在下,对二甲苯液相氧化成对苯二甲酸 Download PDFInfo
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- CN1942425B CN1942425B CN2005800115875A CN200580011587A CN1942425B CN 1942425 B CN1942425 B CN 1942425B CN 2005800115875 A CN2005800115875 A CN 2005800115875A CN 200580011587 A CN200580011587 A CN 200580011587A CN 1942425 B CN1942425 B CN 1942425B
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/14—Monocyclic dicarboxylic acids
- C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
- C07C63/26—1,4 - Benzenedicarboxylic acid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Ex. | Nippm | Mnppm | Brppm | 摩尔比Ni∶Mn∶Br | Temp℃ | 产量 | COx a(vol%) | COx/TPAdmol/mol | 4-CBA(s)bppm | 4-CBA(t)cppm |
Comp 8 | 920 | 860 | 2500 | 1∶1∶2 | 157 | 1.5 | 0.15 | 1.01 | N/A | 44200 |
Comp 9 | 1750 | 860 | 2500 | 1.9∶1∶2 | 157 | 2.4 | 0.21 | 0.89 | N/A | 54800 |
10 | 1750 | 2500 | 2000 | 0.64;1∶0.55 | 157 | 3.8 | 0.15 | 0.40 | N/A | 7600 |
Comp11 | 850 | 790 | 2300 | 1∶1∶2 | 155 | 1.5 | 0.16 | 1.07 | N/A | 48500 |
Comp12 | 2100 | 790 | 2300 | 1.9∶1∶2 | 155 | 2.6 | 0.16 | 0.62 | N/A | 64500 |
13 | 2100 | 2500 | 2300 | 0.77∶1∶0.63 | 155 | 3.7 | 0.16 | 0.44 | N/A | 20400 |
Comp14 | 800 | 750 | 2200 | 1∶1∶2 | 170 | 1.4 | 0.17 | 1.22 | 52100 | 213000 |
Comp15 | 2050 | 750 | 2200 | 2.5∶1∶2 | 170 | 3.4 | 0.25 | 0.74 | 22200 | 85500 |
16 | 2050 | 750 | 850 | 2.5∶1∶0.78 | 170 | 3.3 | 0.19 | 0.58 | 12100 | 31900 |
Claims (21)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/743,624 | 2004-04-22 | ||
US10/743,624 US7348452B2 (en) | 2004-04-22 | 2004-04-22 | Liquid phase oxidation of P-xylene to terephthalic acid in the presence of a catalyst system containing nickel, manganese, and bromine atoms |
PCT/US2005/011848 WO2005108340A1 (en) | 2004-04-22 | 2005-04-08 | Liquid phase oxidation of p-xylene to terephthalic acid in the presence of a catalyst system containing nickel, manganese, and bromine atoms |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1942425A CN1942425A (zh) | 2007-04-04 |
CN1942425B true CN1942425B (zh) | 2011-01-26 |
Family
ID=35137403
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2005800115875A Active CN1942425B (zh) | 2004-04-22 | 2005-04-08 | 在含有镍、锰和溴原子的催化剂***存在下,对二甲苯液相氧化成对苯二甲酸 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7348452B2 (zh) |
EP (1) | EP1756031A4 (zh) |
KR (1) | KR101214664B1 (zh) |
CN (1) | CN1942425B (zh) |
BR (1) | BRPI0509215A (zh) |
MX (1) | MXPA06012058A (zh) |
TW (1) | TW200613263A (zh) |
WO (1) | WO2005108340A1 (zh) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070155987A1 (en) * | 2006-01-04 | 2007-07-05 | O'meadhra Ruairi S | Oxidative digestion with optimized agitation |
US7772424B2 (en) * | 2006-03-01 | 2010-08-10 | Eastman Chemical Company | Polycarboxylic acid production system employing enhanced evaporative concentration downstream of oxidative digestion |
US7816556B2 (en) * | 2006-03-01 | 2010-10-19 | Eastman Chemical Company | Polycarboxylic acid production system employing enhanced multistage oxidative digestion |
US20070208194A1 (en) * | 2006-03-01 | 2007-09-06 | Woodruff Thomas E | Oxidation system with sidedraw secondary reactor |
US7393973B2 (en) * | 2006-03-01 | 2008-07-01 | Eastman Chemical Company | Polycarboxylic acid production system with enhanced residence time distribution for oxidative digestion |
US7420082B2 (en) * | 2006-03-01 | 2008-09-02 | Eastman Chemical Company | Polycarboxylic acid production system employing hot liquor removal downstream of oxidative digestion |
US7326808B2 (en) * | 2006-03-01 | 2008-02-05 | Eastman Chemical Company | Polycarboxylic acid production system employing cooled mother liquor from oxidative digestion as feed to impurity purge system |
US7501537B2 (en) * | 2006-03-01 | 2009-03-10 | Eastman Chemical Company | Polycarboxylic acid production system employing oxidative digestion with reduced or eliminated upstream liquor exchange |
US7326807B2 (en) * | 2006-03-01 | 2008-02-05 | Eastman Chemical Company | Polycarboxylic acid production system with enhanced heating for oxidative digestion |
US7385081B1 (en) | 2007-11-14 | 2008-06-10 | Bp Corporation North America Inc. | Terephthalic acid composition and process for the production thereof |
KR100907168B1 (ko) * | 2007-12-20 | 2009-07-09 | 호남석유화학 주식회사 | 우레아 유도체를 포함한 복합 금속 촉매를 이용한 방향족카르복시산의 제조방법 |
KR100988684B1 (ko) * | 2008-04-16 | 2010-10-18 | 삼남석유화학 주식회사 | 조테레프탈산 제조를 위한 산화 반응기 |
US8314267B2 (en) * | 2009-06-26 | 2012-11-20 | Uop Llc | Carbohydrate route to para-xylene and terephthalic acid |
US8466312B2 (en) * | 2010-08-20 | 2013-06-18 | Grupo Petrotemex, S.A. De C.V. | Terephthalic acid purge filtration rate by controlling % water in filter feed slurry |
CN103601638B (zh) * | 2013-11-08 | 2015-06-24 | 天津东大化工集团有限公司 | 苯甲酸连续生产工艺及其装置 |
TWI720948B (zh) * | 2014-09-26 | 2021-03-11 | 美商卡福科學公司 | 伸二甲苯類型共聚物、嵌段聚合物及混合組成物材料之形成 |
CN105688988B (zh) * | 2014-12-16 | 2018-11-27 | 财团法人工业技术研究院 | 糠醛化合物的氧化反应催化剂及糠醛化合物的氧化方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4160108A (en) * | 1976-02-24 | 1979-07-03 | Matsuyama Petrochemicals Inc. | Process for producing terephthalic acid |
EP0041784A1 (en) * | 1980-06-10 | 1981-12-16 | Imperial Chemical Industries Plc | Oxidation of substituted aromatic compounds to aromatic carboxylic acids |
US4786753A (en) * | 1987-05-18 | 1988-11-22 | Amoco Corporation | Oxidation process for the manufacture of aromatic acids from alkylaromatic compounds |
US6476257B1 (en) * | 1972-03-31 | 2002-11-05 | Korea Institute Of Chemical Technology | Method for preparing aromatic carboxylic acids from alkylaromatics by liquid-phase oxidation |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2833816A (en) | 1954-05-03 | 1958-05-06 | Mid Century Corp | Preparation of aromatic polycarboxylic acids |
JPS54119427A (en) * | 1978-03-07 | 1979-09-17 | Teijin Ltd | Preparation of benzenecarboxylic acid |
KR970000136B1 (ko) | 1993-09-28 | 1997-01-04 | 브이.피. 유리예프 | 고순도 벤젠디카르복실산 이성질체의 제조방법 |
US6486257B1 (en) | 2001-04-10 | 2002-11-26 | University Of Akron | Block copolymers of lactone and lactam, compatabilizing agents, and compatibilized polymer blends |
-
2004
- 2004-04-22 US US10/743,624 patent/US7348452B2/en active Active
-
2005
- 2005-04-08 EP EP05740331A patent/EP1756031A4/en not_active Withdrawn
- 2005-04-08 CN CN2005800115875A patent/CN1942425B/zh active Active
- 2005-04-08 MX MXPA06012058A patent/MXPA06012058A/es active IP Right Grant
- 2005-04-08 BR BRPI0509215-9A patent/BRPI0509215A/pt not_active IP Right Cessation
- 2005-04-08 WO PCT/US2005/011848 patent/WO2005108340A1/en not_active Application Discontinuation
- 2005-04-21 TW TW094112707A patent/TW200613263A/zh unknown
-
2006
- 2006-10-18 KR KR1020067021573A patent/KR101214664B1/ko active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6476257B1 (en) * | 1972-03-31 | 2002-11-05 | Korea Institute Of Chemical Technology | Method for preparing aromatic carboxylic acids from alkylaromatics by liquid-phase oxidation |
US4160108A (en) * | 1976-02-24 | 1979-07-03 | Matsuyama Petrochemicals Inc. | Process for producing terephthalic acid |
EP0041784A1 (en) * | 1980-06-10 | 1981-12-16 | Imperial Chemical Industries Plc | Oxidation of substituted aromatic compounds to aromatic carboxylic acids |
US4786753A (en) * | 1987-05-18 | 1988-11-22 | Amoco Corporation | Oxidation process for the manufacture of aromatic acids from alkylaromatic compounds |
Also Published As
Publication number | Publication date |
---|---|
EP1756031A4 (en) | 2008-05-28 |
WO2005108340A1 (en) | 2005-11-17 |
EP1756031A1 (en) | 2007-02-28 |
KR101214664B1 (ko) | 2012-12-21 |
CN1942425A (zh) | 2007-04-04 |
BRPI0509215A (pt) | 2007-09-04 |
TW200613263A (en) | 2006-05-01 |
US20050240055A1 (en) | 2005-10-27 |
US7348452B2 (en) | 2008-03-25 |
MXPA06012058A (es) | 2007-01-25 |
KR20060135889A (ko) | 2006-12-29 |
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Assignee: Jiaxing Petrochemical Co., Ltd. Assignor: Eastman Chemical Company Contract record no.: 2012990000015 Denomination of invention: Liquid phase oxidation of p-xylene to terephthalic acid in the presence of a catalyst system containing nickel, manganese, and bromine atoms Granted publication date: 20110126 License type: Common License Open date: 20070404 Record date: 20120113 |