CN1930973A - 一种含咪鲜胺或其锰盐和丙环唑的杀菌组合物及其应用 - Google Patents
一种含咪鲜胺或其锰盐和丙环唑的杀菌组合物及其应用 Download PDFInfo
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- CN1930973A CN1930973A CN 200510094391 CN200510094391A CN1930973A CN 1930973 A CN1930973 A CN 1930973A CN 200510094391 CN200510094391 CN 200510094391 CN 200510094391 A CN200510094391 A CN 200510094391A CN 1930973 A CN1930973 A CN 1930973A
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- Prior art keywords
- prochloraz
- propiconazole
- manganese salt
- bactericidal composition
- propiconazol
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000005820 Prochloraz Substances 0.000 title claims abstract description 23
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 150000002696 manganese Chemical class 0.000 title claims abstract description 11
- 230000002070 germicidal effect Effects 0.000 title abstract 2
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- 229940099607 manganese chloride Drugs 0.000 description 5
- OXOKTPUZOHPXSA-UHFFFAOYSA-L manganese(2+);n-propyl-n-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide;dichloride Chemical compound Cl[Mn]Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl OXOKTPUZOHPXSA-UHFFFAOYSA-L 0.000 description 5
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了一种含咪鲜胺或其锰盐和丙环唑的杀菌组合物及其应用。该组合物含有咪鲜胺或其锰盐和丙环唑，其中咪鲜胺或其锰盐与丙环唑的重量比为5～45∶1～40。该组合物可应用于防治禾谷类、瓜果或蔬菜作物病害。该组合物适用范围广、成本低、效果好。
Description
技术领域
本发明涉及一种杀菌组合物及其用途，尤其是一种以咪鲜胺或其锰盐和丙环唑为主要活性成分的杀菌组合物及其应用。
背景技术
咪鲜胺(prochloraz)(或其锰盐prochloraz-manganese chloride complex)是一种高效、广谱性咪唑类杀菌剂和水果蔬菜保鲜剂，用于谷类作物防治假尾孢属、核腔菌属、孢属及壳针孢属真菌，对早期的眼点病、叶斑病、和白粉病、有防效。用于油籽、葡萄可防治链格孢属、葡萄孢属、假尾孢属、埋核盘菌属、核盘菌属真菌。防治豆科植物上的壳二孢属、葡萄孢属、甜菜上的生尾孢属和白粉菌属，对于谷类作物上的旋孢腔菌属、镰孢属、核腔菌属、壳针孢属真菌引起的病害有防治作用。此外，可防治花椰菜叶斑病，水稻稻瘟病。
咪鲜胺已经在中国农作物，尤其是保鲜方面应用广泛，在水稻稻瘟病上使用取得良好效果还没有相关文献说明。
丙环唑(propiconazol)是具有保护和治疗作用的内吸性杀菌剂。可被根、茎、叶部吸收，并能很快地在植物株体内向上传导，防治子囊菌，担子菌和半知菌引起的病害，属麦角甾醇生物合成的抑制剂。麦角甾醇在真菌细胞膜的构成中起重要作用，丙环唑通过干扰C14-去甲基化而妨碍真菌体内麦角甾醇的生物合成，从而破坏真菌的生长繁殖，起到保护和治疗作用。丙环唑除对藻菌病害无效外，对子囊菌属、担子菌数、半知菌属真菌在粮食作物、蔬菜、水果以及观赏植物上引起的多种病害有效。
丙环唑对于水稻稻瘟病的病原菌有一定的治疗作用，但是单一使用丙环唑不能达到防治水稻稻瘟病的作用。
发明内容
本发明的目的是争对上述技术问题提供一种适用范围广、成本低、效果好含咪鲜胺或其锰盐与丙环唑的植物杀菌组合物。
本发明还有一个目的是提供该杀菌组合物的用途。
本发明的目的是通过下列措施来实现的：
一种杀菌组合物，它含有咪鲜胺(或其锰盐)与丙环唑，其中咪鲜胺(或其锰盐)与丙环唑的重量比为5～45∶1～40。
所述的杀菌组合物，其中咪鲜胺(或其锰盐)与丙环唑重量比为10～45∶2～30。
所述的杀菌组合物，其中咪鲜胺(或其锰盐)和丙环唑与已知的助剂和赋形剂复配成农药上允许的任意一种制剂。这些已知的助剂、赋形剂有分散剂、扩散剂、消泡剂、湿润剂、崩解剂等。
所述的杀菌组合物，其剂型是粉剂、可湿性粉剂、悬乳剂或乳油。
所述的杀菌组合物在防治禾谷类、瓜果或蔬菜作物病害方面的应用，尤其用于防治水稻稻瘟病。
本发明的有益效果：
1、本发明所用的咪鲜胺(或其锰盐)和丙环唑都是唑类杀菌剂，因此具有相同的作用机制，相互混配不会产生低触，可协同增效，减少用药量，降低成本。
2、本发明组合物适用范围增加，适用于防治禾谷类、各种瓜果、蔬菜的作物病害，特别是防治水稻、小麦、辣椒、香蕉、芒果、菠萝、黄瓜、番茄等作物病害，尤其用于防治水稻稻瘟病有较好的效果。
具体实施方式
以下结合实施例对本发明作进一步说明。实施例中剂型的制备方法均为常规方法。
实施例1：
将咪鲜胺5g、丙环唑20g、十二烷基苯磺酸钙3g、苯乙基酚聚氧乙烯醚2g，二甲苯加之100g，混合至均相液，制得组合物乳油。
实施例2：
将咪鲜胺锰盐12.5g、丙环唑12.5g、净洗剂LS(对甲氧基脂肪酸胺基苯磺酸钠)3g、扩散剂NNO(亚甲基双萘磺酸钠)2g、白炭黑5g，高岭土加至100g混合物进行气流粉碎，制得可湿性粉剂。
实施例3：
将咪鲜胺15g、丙环唑15g、苯乙基酚聚氧乙烯醚膦酸酯3g，壬基酚聚氧乙烯醚2g，丙二醇5g、去离子水加至100g，利用高速均质机搅拌均匀，制得水乳剂。
实施例4：
将咪鲜胺锰盐25g、丙环唑25g，滑石粉50g混合均匀，制得粉剂。
实施例5：
将将咪鲜胺锰盐25g、丙环唑10g、净洗剂LS 5g、羧甲基纤维素5g、轻质碳酸钙29.5g混合，制得可湿性粉剂。
实施例6：
将将咪鲜胺锰盐20g、丙环唑5g、净洗剂LS(对甲氧基脂肪酸胺基苯磺酸钠)3g、扩散剂NNO(亚甲基双萘磺酸钠)2g，高岭土加至100g混合均匀，制得可湿性粉剂。
应用实施例：
用上述实施例制得的制剂防治水稻稻瘟病试验。
1、试验处理：本试验药剂用量根据各个成分的不同分别设三个处理浓度，对照药剂分别是市售农药45％咪鲜胺乳油(EC)和25％丙环唑乳油(EC)及空白清水试验。
2、试验方法：每个小区面积为66.7m2，重复3次；施药前调查及防治后的检查药效方法为：在试验处理区内随机取样5点，每点50穗，检查稻瘟病发生程度。
3、试验结果见下表：
| 处理(g/亩) | 药前病情指数(％) | 防效(％) | |||
| 药后5天 | 药后10天 | 药后14天 | |||
| 实施例1 | 60 | 72.0 | 72.3ab | 79.2ab | 73.4ab |
| 80 | 78.6 | 86.4a | 90.5a | 81.3a | |
| 100 | 69.4 | 88.3a | 92.4a | 83.2a | |
| 实施例2 | 60 | 72.9 | 69.7ab | 77.4b | 70.5b |
| 80 | 50.8 | 79.6a | 83.2a | 80.4a | |
| 90 | 59.3 | 83.1a | 93.4a | 89.9a | |
| 实施例3 | 60 | 61.0 | 63.2ab | 71.9b | 69.3b |
| 80 | 57.3 | 79.5a | 85.2a | 84.2ab | |
| 100 | 56.6 | 83.3a | 89.4a | 86.9a | |
| 45％咪鲜胺乳油 | 120 | 62.3 | 62.2c | 65.2c | 49.1c |
| 25％丙环唑乳油 | 170 | 60.3 | 63.7c | 65.8c | 59.9c |
| 空白清水对照 | 63.2 | - | - | - | |
注：a表示在α＝0.05水平上显著，b表示在α＝0.05水平上有差异，c表示在α＝0.05水平上不显著。
田间药效结果表明，咪鲜胺与丙环唑组合物对水稻稻瘟病具有优良的防治效果，防治效果均好于单剂品种。
Claims (5)
1、一种杀菌组合物，其特征在于含有咪鲜胺或其锰盐与丙环唑，其中咪鲜胺或其锰盐与丙环唑的重量比为5～45∶1～40。
2、根据权利要求1所述的杀菌组合物，其特征在于咪鲜胺或其锰盐与丙环唑的重量比为10～45∶2～30。
3、根据权利要求1或2所述的杀菌组合物，其特征在于咪鲜胺或其锰盐和丙环唑与已知的助剂和赋形剂复配成农药上允许的任意一种制剂。
4、根据权利要求3所述的杀菌组合物，其特征在于剂型是粉剂、可湿性粉剂、悬乳剂或乳油。
5、权利要求1所述的杀菌组合物在防治禾谷类、瓜果或蔬菜作物病害方面的应用。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101971850A (zh) * | 2010-11-21 | 2011-02-16 | 陕西美邦农药有限公司 | 一种含环唑醇的杀菌组合物 |
| CN102503678A (zh) * | 2011-10-27 | 2012-06-20 | 吉林农业大学 | 一种防治盐碱地水稻秆腐病的复合农药 |
| CN102805104A (zh) * | 2011-05-31 | 2012-12-05 | 通州正大农药化工有限公司 | 一种含有咪鲜胺锰盐和嘧菌酯的杀菌组合物 |
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| TW286264B (zh) * | 1994-05-20 | 1996-09-21 | Ciba Geigy Ag | |
| CN1288663A (zh) * | 2000-06-22 | 2001-03-28 | 张长兴 | 防治蔬菜灰霉病用杀菌剂农药 |
| CN1399883A (zh) * | 2001-07-30 | 2003-03-05 | 江苏辉丰农化股份有限公司 | 一种植物杀菌剂 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101971850A (zh) * | 2010-11-21 | 2011-02-16 | 陕西美邦农药有限公司 | 一种含环唑醇的杀菌组合物 |
| CN101971850B (zh) * | 2010-11-21 | 2013-03-13 | 陕西美邦农药有限公司 | 一种含环唑醇的杀菌组合物 |
| CN102805104A (zh) * | 2011-05-31 | 2012-12-05 | 通州正大农药化工有限公司 | 一种含有咪鲜胺锰盐和嘧菌酯的杀菌组合物 |
| CN102503678A (zh) * | 2011-10-27 | 2012-06-20 | 吉林农业大学 | 一种防治盐碱地水稻秆腐病的复合农药 |
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