CN1926205B - 装饰性层压安全玻璃 - Google Patents
装饰性层压安全玻璃 Download PDFInfo
- Publication number
- CN1926205B CN1926205B CN200580006582.3A CN200580006582A CN1926205B CN 1926205 B CN1926205 B CN 1926205B CN 200580006582 A CN200580006582 A CN 200580006582A CN 1926205 B CN1926205 B CN 1926205B
- Authority
- CN
- China
- Prior art keywords
- polyvinyl butyral
- ink
- image
- butyral film
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10688—Adjustment of the adherence to the glass layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/40—Ink-sets specially adapted for multi-colour inkjet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0064—Digital printing on surfaces other than ordinary paper on plastics, horn, rubber, or other organic polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Textile Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
本发明是包括带有图像的热塑性中间层的装饰性层压制品,其中使用喷墨印刷方法将图像印刷到中间层上,其中图像包括在热塑性中间层表面上的白色颜料。本发明也是在热塑性聚合物上喷墨印刷白色颜料油墨以获得具有良好粘合质量的带有图像的层压材料的方法。
Description
交叉参者部分
本申请要求2004年3月2日提交的美国临时申请No.60/549,607的权益。
发明背景
本发明涉及带有由喷墨印刷工艺在中间层上印刷的图像的装饰性层压材料。本发明特别涉及装饰性层压材料,其中将图像印刷到包括聚乙烯醇缩丁醛(PVB)的中间层上。本发明也涉及用于制备本发明的层压材料的油墨配制剂。
装饰性层压材料是已知的并由各种方法获得。DE 29706880、US4,968,553、US 5,914,178、EP1129844A1和DE 20100717公开了通过丝网印刷工艺制备装饰性玻璃层压材料。丝网印刷图像到中间层上是制备装饰性层压安全玻璃的非常耗时和昂贵的工艺。制备装饰性玻璃层压材料的方法也描述于US4,173,672。此专利描述了转印层压方法,其中将在纸上印刷的图像转印到热塑性膜上,并然后在玻璃片之间层压带有转印图像的膜。
对于层压安全玻璃″喷墨″技术在PVB和聚氨酯上印刷的用途公开于WO 0218154。喷墨印刷是已知的并且是常规的印刷工艺,其中将油墨小滴通过打印头以高速推进到印刷衬底。由于可以将任何数字图像印刷到衬底上,所述喷墨技术是非常灵活的。
然而,使用喷墨印刷工艺直接在PVB上印刷的一个缺点在于PVB中间层具有粗糙的表面图案(Rz为30-60μm),它在印刷图像中引起差的图像质量。粗糙的表面图案在PVB层压工艺中是必须的以获得没有空气泡和由夹带空气的存在在层压工艺期间引起的其它缺陷的层压材料。然而,当喷墨印刷到PVB上时,粗糙表面图案可在斑点和分辨率方面影响图像质量。
由于油墨用于常规喷墨工艺,遇到采用常规喷墨印刷工艺的其它问题。在常规喷墨印刷工艺中要求低粘度油墨以减轻喷墨打印机的打印头中的高压累积,和随后对头的损害和/或印刷图像中差的质量。喷墨印刷通常由(a)按需滴落(DOD)工艺,如压电印刷或热喷墨印刷工艺,或(b)连续滴落喷墨印刷进行。也存在使低粘度油墨在喷墨印刷工艺中是必须和优选的其它因素。然而,适于喷墨印刷的常规油墨的使用可导致热塑性中间层上差的图像质量。由于在中间层表面上油墨从高点向低点移动,当将低粘度油墨喷淋到为层压而制备的粗糙表面如PVB表面上时,结果是差的图像质量。
在层压到另一个衬底之前在中间层上印刷图像的另一个潜在问题在于在中间层和衬底之间的粘合剂结合可由于在中间层表面上的着色剂而显著弱化,这可降低在衬底和中间层之间的″有效″粘合表面积。在此使用的″有效粘合表面″描述其中中间层和衬底彼此直接接触而没有***着色剂层的表面积。层压材料的粘合力的降低可导致作为安全玻璃,或在希望的应用中性能差的层压材料。
当印刷的图像要求白色和透明(即其中没有油墨喷射到衬底上的区域)部分两者时,喷墨印刷到热塑性聚合物中间层上可能仍然遇到进一步的问题。为获得白色在印刷的图像中出现的区域,目前的实践要求印刷着色油墨到白色热塑性片上。在以此方式获得的图像中出现的白色来自片中的添加剂,而不是来自印刷白色颜料到其中在印刷的图像中需要白色的区域上。当要求清楚(透明)区域与白色部分一起在相同的图像中时,这不是实用的解决方案。
喷墨印刷白色颜料不是已知的工艺。更特别地,没有适于喷墨印刷到中间层材料上的白色油墨体系是已知的。各种因素使白色油墨体系对于喷墨印刷是有问题的,但一个问题可能是用于油墨分散体的白色颜料的粒度对于喷墨印刷可能太大。
可以在层压之前在用于在热塑性中间层上印刷的方法中具有喷墨印刷白色油墨到热塑性中间层上的方法,使得除其中没有油墨印刷到衬底上的清楚或透明的区域以外,在图像或文本中可以观察到白色区域。
可能特别需要具有这样的方法并保持层压材料强度和抗断裂的回弹性,而同时在中间层衬底上产生优质图像。
发明概述
在一方面,本发明是一种喷墨印刷白色颜料油墨到热塑性聚合物衬底材料上的方法,其中白色颜料油墨是包括在载体中的白色颜料粒子的非含水分散体,所述载体包括至少一种有机液体和至少一种用于白色颜料的分散剂。
在另一方面,本发明是适于喷墨印刷到热塑性聚合物衬底材料上的非含水白色颜料油墨分散体,其中白色颜料油墨是包括在载体中的白色颜料粒子的非含水分散体,所述载体包括至少一种有机液体和至少一种用于白色颜料的分散剂。
在另一方面,本发明是包括带有图像的中间层衬底的层压材料制品,其中图像包括使用喷墨印刷方法通过印刷白色油墨分散体到衬底的至少一个表面上施加的白色颜料粒子。
在另一方面,本发明是一种获得带有图像的层压材料的方法,该层压材料的层压材料粘合强度为至少约1000psi,该方法包括如下步骤:喷墨印刷非含水白色着色油墨到热塑性中间层的至少一个表面上;和在两片合适层压衬底的透明片之间层压带有图像的中间层,其中白色颜料油墨是包括在载体中的白色颜料粒子的非含水分散体,所述载体包括至少一种有机液体和至少一种用于白色颜料的分散剂。
发明详述
在一个实施方案中,本发明是一种由喷墨印刷方法印刷图像到热塑性中间层材料上的方法。用于本发明目的的合适热塑性中间层材料可以是任何通常已知或市售的热塑性材料,该材料足够柔韧还足够刚硬以通过喷墨打印机。在本发明的实践中用作印刷衬底的合适热塑性材料包括例如聚氨酯(PUR)、聚酯如聚对苯二甲酸乙二醇酯(PET)、聚氯乙烯(PVC)、和聚乙烯醇缩丁醛(PVB)、聚烯烃如聚乙烯和/或聚丙烯。优选用于本发明的目的的是聚乙烯醇缩丁醛(PVB)。PVB例如从E.I.DuPont de Nemours&Co.以商品名Butacite购得。
本发明的在中间层材料上的喷墨印刷优选使用着色油墨进行。由于它们的色牢度、热稳定性、边缘清晰度、和在印刷衬底上的低扩散性,优选着色油墨。在常规实践中,将颜料悬浮在液体介质中,该介质通常称为″载体″。通常,载体可包括有机液体(有机溶剂)和/或水,它们单独或组合用于分散颜料。适用于本发明实践的颜料可以分散在非含水载体中。在此适用的″非含水″载体不严格是非含水的,这是由于当使用特定的有机溶剂时,作为在此使用的术语,″非含水″载体可包括少部分(不大于16wt%)的水。各种常规溶剂是已知的并可以单独或与其它合适的溶剂组合使用。有用但较不优选的溶剂包括例如甲基异丁基酮(MIBK)、甲乙酮(MEK)、丁内酯和环己酮。优选的溶剂包括例如丙二醇醚、丙二醇醚乙酸酯如二丙二醇单甲基醚乙酸酯,和乙二醇丁基醚、或任何这些的混合物。在特别优选的实施方案中,二丙二醇单甲基醚乙酸酯(DPMA)可用于分散着色油墨。也可以优选是DPMA在至多约50wt%的浓度下与二醇醚和/或其它有机溶剂的混合物。更优选,DPMA在溶剂混合物中的浓度可以为约5wt%-约50wt%,和最优选约15wt%-约45wt%。
本发明的油墨具有足够低的粘度使得它们可以通过喷墨打印机的打印头喷射,而不必须加热打印头以降低油墨的粘度。在本发明的实践中,在25℃测量的油墨粘度小于约30厘泊(cps)。优选在25℃的油墨粘度小于约20cps。更优选在25℃的油墨粘度小于约15cps,和最优选小于约12cps。
不受理论约束,申请人相信使用喷墨印刷***的图像质量问题可能产生,这是由于用于喷墨印刷的油墨体系的粘度比例如用于丝网印刷的油墨的粘度低得多。低粘度油墨可由重力″移动″入粗糙PVB表面的凹处。因此,油墨可以在PVB表面上的低区域中形成胶泥,并且不均匀粘合到高点。因此,尽管优选低粘度油墨,但粘度应当不太低使得在层压材料中的图像质量差,或在印刷工艺期间变模糊。优选油墨的粘度大于约1cps。对于DOD印刷工艺,在25℃测量的油墨粘度优选大于约1.5cps,更优选大于约1.7,和最优选大于约1.8cps。油墨的粘度根据DuPont标准测试方法测量。
用于本发明实践的优选油墨是提供具有令人满意的如下性能的组合的印刷图像的那些:图像质量、耐光性和耐候性。此外,引入本发明的带有图像的中间层的层压材料应当具有在此所述的粘合性能。由于用于根据本发明实践的印刷的聚合物中间层衬底的性质,和对于安全玻璃中粘合性的要求,合适油墨的选择是没问题的。适用于本发明实践的油墨应当与衬底相容以得到令人满意的结果。
传统上,颜料由分散剂如聚合物分散剂或表面活性剂稳定成载体中的分散体。更近来,已开发了所谓的″可自分散″或″自分散″颜料(以下″SDP″),它们适用于本发明实践。SDP可以在含水载体中分散而不使用传统的分散剂。本发明的颜料粒子可以根据几种方法稳定。颜料粒子可以由例如WO01/94476中描述的表面处理而变成自分散的,为所有目的在此引入如同完整所列的该文献作为参考,或颜料粒子可以由采用传统方式的分散剂处理稳定,或可以由表面处理和传统处理的一些组合分散颜料。
优选,当采用传统分散剂时,分散剂可以是无规或结构化聚合物分散剂。优选的无规聚合物包括丙烯酸类聚合物和苯乙烯-丙烯酸类聚合物。然而,最优选的是包括AB、BAB和ABC嵌段共聚物、支化聚合物和接枝聚合物的结构化分散剂。一些有用的结构化聚合物公开于US 5,085,698、EP-A-0556649和US 5,231,131中,为所有目的在此引入如同完整所列的这些文献作为参考。例如可以使用市售分散剂如Dispersbyk2000和Dispersbyk2001。
本发明实践中的重要参数是要印刷图像到其上的粗糙中间层表面的频率。粗糙表面的频率可以使用从表面光度仪数据获得的数据计算。在本发明的实践中,合适的频率大于约0.60次循环/mm。优选频率为约0.60次循环/mm-约3次循环/mm。更优选,频率为约0.75-约2.9,和最优选频率为约0.85-约2.5次循环/mm。在上限以上可能观察不到图像质量的显著改进。在下限以下,图像质量可能差。
在另一个实施方案中,本发明是包括本发明的带有图像的热塑性中间层的层压材料。中间层可以与各种透明衬底如玻璃或聚碳酸酯一起层压。优选,带有图像的中间层片在至少两片玻璃之间层压。中间层的其它层可以布置在带有图像的中间层和玻璃之间,例如在玻璃/″常规PVB″/″印刷的PVB″/玻璃层压材料中,其中印刷的PVB表面与常规PVB中间层表面接触。带有图像的中间层也可以直接层压到玻璃。常规层压技术在获得本发明的层压材料中是有用的和有效的。
在任何情况下,本发明的层压材料的粘合强度可以与常规或非装饰性层压材料相比。由压缩剪切测试测量的本发明的层压材料中的粘合力是至少1000psi。优选压缩剪切强度是约1400-约2600psi。更优选,本发明的层压材料的粘合力是约1450psi-约2575psi,且甚至更优选约1740-约2540psi。最优选层压材料的粘合强度为约1800psi-约2520psi。本发明的层压材料可用于其中使用常规(即非装饰性)层压玻璃的任何应用。然而,除作为安全玻璃的通常用途以外,本发明的层压材料可以用作装饰性制品如图画窗、装饰性工作台面、形象艺术、带图像的仓库前窗、带有公司标识的显示器、广告介质、和/或任何其它用途,其中带有图像的透明层压材料可能是所需的。在本发明的实践中,图像可以定义为任何视觉可看清的图案,它可以数字化和喷墨印刷到衬底上,例如绘图、照片、文本、图形设计、颜色图案、符号和/或相似例子。
本发明的层压材料可以例如从带有图像的中间层和用于生产安全玻璃或窗户的已知材料如玻璃或聚碳酸酯获得。中间层对其它组件的层压可以使用常规层压技术完成。例如,可以在高温和压力下在可以除去或防止在层压制品中夹带的空气泡的条件下,在两片玻璃之间通过挤压中间层而将带有图像的中间层层压到玻璃。
在另一个实施方案中,本发明是带有图像的中间层片,该片根据在此所述的方法印刷上去。本发明的印刷中间层片可以与其它合适的中间层材料如PET、PUR和/或PVB层压以获得堆迭的中间层,该堆迭的中间层反过来又可以与本发明的合适衬底如玻璃或聚碳酸酯层压。
在本发明的另一个实施方案中,将第二中间层片放置在主携带图像的层和层压衬底之间,其中第二层可例如携带印刷的图像或是任何实心、半透明的颜色如红色、绿色、蓝色或白色。
本发明的白色颜料油墨可以是任何可分散的白色颜料,可以将该颜料碾磨到充分小的粒度以使用常规喷墨印刷设备喷墨印刷。例如,可以使用二氧化钛,条件是将它充分碾磨并然后分散在载体中,它提供用于喷墨印刷的稳定白色颜料油墨。在本发明的优选实施方案中,可以将干燥二氧化钛粉末直接分散入油墨载体而不向油墨体系中加入水。
优选将合适数量的白色颜料分散入载体以当在喷墨印刷工艺期间时在衬底表面上提供足够的颜料。如果颜料水平太低,则覆盖的深度不足以覆盖衬底,并且衬底可通过衬底表面上的颜料显示。如果颜料浓度太高,则油墨的粘度可能太高而不能用于喷墨印刷工艺。优选以约1份每一百份(pph)-约40pph的数量分散颜料。更优选采用约5pph-约35pph的数量,甚至更优选采用约10pph-约30pph的数量分散颜料。
使用本发明的油墨喷墨印刷的图像可以使用常规喷墨印刷设备,最显著地是用打印头获得。适用于本发明实践的打印头包括例如用于压电印刷、热喷墨印刷和连续滴落印刷的打印头。用于压电印刷工艺的打印头例如购自Epson、Seiko-Epson、Spectra、XAAR和XAAR-Hitachi,并且可适用于本发明的实践。用于热喷墨印刷的打印头例如购自Hewlitt-Packard和Canon并且可适用于本发明的实践。适用于连续滴落印刷的打印头例如购自Iris和Video Jet并且可适用于本发明的实践。
实施例
给出如下实施例以举例说明本发明。实施例不拟以任何方式限制本发明的范围。
测试方法
粘度在BrookfieldDV-II+粘度计上测量。样品使用小样品适配器(保持样品的带夹套容器)和00定子处理。水浴用于再循环在25℃下通过小样品适配器的夹套的水。将每个样品在60rpm下处理和保持至少5分钟以允许样品在25℃下平衡并为定子的旋转提供足够的时间能驱出可能在样品中存在的任何空气泡。用于分析的样品尺寸大约是18mL。
表面粗糙度Rz由10点平均粗糙度确定,如在ISO-R468中所述并以微米表示。表面粗糙度使用Mahr Federal(Providence,RI)表面分析仪测量。表面图案频率由表面分析仪数据通过将自动关联函数对表面光度仪数据的距离作图而计算。自动关联数据由快速付里叶转变分析。表面图案的报导频率是中值频率。
压缩剪切粘合测试:层压材料粘合力(以压缩剪切强度给出)由压缩剪切测试测定。通过将层压材料锯成六个2.54cm×2.54cm的小片而确定压缩剪切强度。将小片在夹具中以45°保持并且压缩测试仪器用于在0.25cm/min的速率下在小片上施加力。引起玻璃-PVB粘合的内聚故障的力的数量是层压材料的压缩剪切强度。
通用油墨制备方法
如下制备100克油墨样品:
向250-ml瓶子中加入溶剂和分散剂,并混合组分直到分散剂在溶剂中完全溶解。将白色颜料缓慢加入到容器中并充分混合。向混合物中加入锆介质(0.8-1.0密耳)。然后将容器放置在辊炼机上并将辊炼机的速度调节到200rpm。将油墨辊炼规定的时间。通过使用1微米滤纸过滤将油墨与介质分离。然后分析油墨的物理性能。溶剂(油墨载体)缩写如下:二丙二醇甲基醚(DPM);二丙二醇甲基醚乙酸酯(DPMA);三丙二醇丙基醚(TPnP);二丙二醇丙基醚(DPnP);三丙二醇甲基醚(TPM)。
实施例1-5
根据通用方法,使用表1中的组分以所示的数量制备油墨。将每个实施例中的混合物辊炼12小时。实施例1和3-5显示良好的可过滤性,而实施例2具有差的可过滤性。油墨具有适度到良好的稳定性,并且当测试喷射性时每个都是优异的,即从打印头喷射出的优异能力。
实施例6-13
根据通用方法,使用表1中的组分以所示的数量制备油墨。将每个实施例中的混合物辊炼24小时。实施例6和8-13显示良好的可过滤性,而实施例7具有差的可过滤性。油墨具有适度到良好的稳定性,且每个都具有优异的喷射性。
表1
实施例 | 颜料(pph) | 油墨载体(pph) | 分散剂(pph) | 粘度(CPS) |
1 | R700(25) | DPM(65) | D2001(10) | 7.05 |
2 | R700(25) | DPM(65) | D2000(10) | 7.88 |
3 | R700(25) | PPE(16.25)/DPM(48.75) | D2001(10) | 10.30 |
4 | TS-6200 | DPM(65) | D2001(10) | 6.83 |
5 | TS-6200 | DPM(65) | D2001(10) | 7.00 |
6 | R700(25) | DPM(73) | D2001(2) | 4.88 |
7 | R700(25) | DPMA(73) | D2001(2) | 4.53 |
8 | R700(25) | TPnP(73) | D2001(2) | 9.20 |
9 | R700(25) | DPnP(73) | D2001(2) | 5.53 |
10 | R700(25) | DPnP(54.8)/DPMA(18.3) | D2001(2) | 4.52 |
11 | R700(25) | DPM(58.5)/TPM(6.5) | D2001(10) | 7.35 |
12 | R700(25) | DPM(58.5)/PPH(6.5) | D2001(10) | 8.22 |
13 | R700(25) | DPM(65) | D2001(10) | 6.84 |
R700是TiO2,采用氧化铝处理,含有0.3%三羟甲基丙烷(TMP),是市购的。
TS-6200是TiO2,采用氧化铝处理和二氧化硅湿处理,含有柠檬酸和TMP,是市购的。
D2000是Dispersbyk2000。
D2001是Dispersbyk2001。
表2
实施例 | 颜料(pph) | 油墨载体(pph) | 分散剂(pph) | 粘度(CPS) | 粒度(nm) | 油墨稳定性 |
14 | R700(20)P-25(5) | DPM(72.8)DPMA(0.0) | D2001(2.2) | 6.7 | 289.4 | Good |
15 | R700(20)P-25(5) | DPM(63.5)DPMA(9.1) | D2001(2.2) | 5.5 | 276.0 | Good |
16 | R700(20)P-25(5) | DPM(54.6)DPMA(18.2) | D2001(2.2) | 5 | 256.2 | Good |
17 | R700(20)P-25(5) | DPM(45.5)DPMA(27.3) | D2001(2.2) | 4.8 | 249.8 | Good |
18 | R700(20)P-25(5) | DPM(36.4)DPMA(36.4) | D2001(2.2) | 4.8 | 257.7 | Good |
19 | R700(20)P-25(5) | DPM(18.2)DPMA(54.6) | D2001(2.2) | EEE | 336.0 | Poor |
20 | R700(20)P-25(5) | DPM(9.1)DPMA(63.5) | D2001(2.2) | EEE | 343 | Poor |
21 | R700(20)P-25(5) | DPM(0)DPMA(72.8) | D2001(2.2) | EEE | 494.8 | Poor |
P-25TiO2是购自Degussa的纳米TiO2。
*粘度太高(>10cps)而不能在使用的测试条件下测定。
实施例14是0%DPMA和100%DPM(溶剂比)
实施例21是100%DPMA和0%DPM。
使用JV3打印机将实施例16的油墨打印在PVB上。将白色油墨单色和与其它颜色组合以两种不同的模式打印。
模式1:首先打印白色油墨然后将色料(CMYK)在它的顶部打印(套印)
模式2:将白色油墨与其它色料(CMYK)同时打印。
测量粘合力(psi)并将结果总结于表3。
表3
颜色 | 单色 | 模式1 | 模式2 |
白色(50%覆盖率) | 2920 | ||
白色(100%覆盖率) | 2511 | ||
青色 | 2285 | 2330 | 2031 |
品红色 | 2375 | 2024 | 1881 |
黄色 | 2247 | 2177 | 2039 |
黑色 | 2589 | 2400 | 2249 |
表4-不同TiO2粒度的粘度比较
实施例 | 颜料(pph) | 油墨载体(pph) | 分散剂(pph) | 初始粘度(cPS) | 初始粒度(nm) |
22 | R700 | DPM(54.6)DPMA(18.2) | D2001(2.2) | 5.0 | 256.2 |
23 | R796 | DPM(54.6)DPMA(18.2) | D2001(2.2) | 4.8 | 274.8 |
24 | TS6200 | DPM(54.6)DPMA(18.2) | D2001(2.2) | 5.0 | 305.3 |
不管表4中不同TiO2粒子的初始粘度数据的相似性,R700由于更小的粒度是优选的。
油墨根据通用方法制备并测量TiO2的粘度和粒度。将油墨在第二次测量物理性能之前放入70℃的烘箱中14天。结果见表5。由于DPMA小于油墨溶剂含量的50%,所以油墨的稳定性良好。
表5-白色油墨稳定性
实施例 | 颜料(pph) | 油墨载体(pph) | 分散剂(pph) | 初始粘度(CPS) | 初始粒度(nm) | 在烘箱老化之后的粘度 | 在烘箱老化之后的粒度 |
22 | R700(35) | DPM(26.2)DPMA(6.2) | D2001(2.6) | 5.71 | 160 | 4.9 | 219.8 |
23 | TS6200(35) | DPM(56.2)DPMA(6.2) | D2001(2.6)) | 5.76 | 207.7 | 5.71 | 254.1 |
24 | R706(35) | DPM(56.2)DPMA(6.2) | D2001(2.6) | 5.8 | 208.3 | 5.78 | 225.4 |
25 | R700(35) | DPM (62.4) | D2001(2.6) | 6.26 | 209.5 | 6.04 | 206.0 |
26 | R700(35) | DPM(56.2)TPnP(6.2) | D2001(2.6) | 6.7 | 220.1 | 5.72 | 210.1 |
27 | TS6200(35) | DPM(56.2)TPnP (6.2) | D2001(2.6) | 6.6 | 228.4 | 6.39 | 227.7 |
28 | R706(35) | DPM(56.2)TPnP(6.2) | D2001(2.6) | 6.49 | 227.6 | 6.56 | 218.8 |
29 | R700(35) | DPM(50.0)DPMA(6.2)TPnP(6.2) | D2001(2.6) | 6.11 | 212.1 | 5.96 | 212.9 |
实施例30和31及时比例C1
将实施例11的油墨在100%覆盖率及50%覆盖率下印刷到PVB的片上,并将该片层压到玻璃上。对比例由白色油墨的覆盖率为0%。测量并在表6中提供粘合力。
实施例32和33及时比例C2
将实施例12的油墨在100%覆盖率及50%覆盖率下印刷到PVB的片上,并将该片层压到玻璃上。对比例由白色颜油墨的覆盖率为0%。测量并在表6中提供粘合力。
实施例34和35及对比例C3
将实施例13的油墨在100%覆盖率及50%覆盖率下印刷到PVB的片上,并将该片层压到玻璃上。对比例由白色颜油墨的覆盖率为0%。测量并在表6中提供粘合力。
表6
实施例 | 覆盖率(%) | 粘合力(psi) |
30 | 100 | 1440 |
31 | 50 | 2468 |
C1 | 0 | 2355 |
32 | 100 | 1345 |
33 | 50 | 2340 |
C2 | 0 | 2325 |
34 | 100 | 1491 |
35 | 50 | 2354 |
C3 | 0 | 2397 |
Claims (8)
1.一种喷墨印刷油墨到聚乙烯醇缩丁醛片上的方法,包括提供聚乙烯醇缩丁醛片,该聚乙烯醇缩丁醛片具有粗糙表面图案并且喷墨印刷油墨到聚乙烯醇缩丁醛片的粗糙表面上,其中油墨是在25℃测量的粘度大于1.7到小于15厘泊的白色颜料油墨并且白色颜料油墨是包括在载体中5份每一百份(pph)-35pph白色颜料二氧化钛粒子的非含水分散体,所述二氧化钛粒子为100nm-400nm,所述载体包括至少一种有机液体和至少一种用于白色颜料的分散剂。
2.权利要求1的方法,其中聚乙烯醇缩丁醛片的粗糙表面具有Rz为30-60μm的粗糙表面图案。
3.权利要求1-2任一项的方法,其中载体包括作为有机液体浓度为载体的5-50wt%的二丙二醇单甲基醚乙酸酯(DPMA)。
4.由权利要求1-3任一项的方法制备的带有图像的聚乙烯醇缩丁醛片,其中图像包括由喷墨印刷施加到聚乙烯醇缩丁醛片上的白色颜料粒子。
5.权利要求4的带有图像的聚乙烯醇缩丁醛片,其中图像包括白色区域和其中在片上没有油墨的透明区域,所述白色区域包括由喷墨印刷施加到聚乙烯醇缩丁醛片上的白色颜料粒子。
6.一种层压材料制品,包括权利要求4或5的带有图像的聚乙烯醇缩丁醛片。
7.权利要求6的层压材料制品,其中将带有图像的聚乙烯醇缩丁醛片层压到两片玻璃上。
8.权利要求6的层压材料制品,其中层压带有图像的聚乙烯醇缩丁醛片、不带有图像的第二聚乙烯醇缩丁醛片和两片玻璃以形成具有如下顺序的层压材料:玻璃/带有图像的聚乙烯醇缩丁醛片/第二聚乙烯醇缩丁醛片/玻璃;并且其中带有图像的聚乙烯醇缩丁醛片的带图像的表面与第二聚乙烯醇缩丁醛片的表面接触。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US54960704P | 2004-03-02 | 2004-03-02 | |
US60/549,607 | 2004-03-02 | ||
PCT/US2005/006653 WO2005085371A1 (en) | 2004-03-02 | 2005-03-02 | Decorative laminated safety glass |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1926205A CN1926205A (zh) | 2007-03-07 |
CN1926205B true CN1926205B (zh) | 2013-08-28 |
Family
ID=34919514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200580006582.3A Expired - Fee Related CN1926205B (zh) | 2004-03-02 | 2005-03-02 | 装饰性层压安全玻璃 |
Country Status (10)
Country | Link |
---|---|
US (2) | US20050215664A1 (zh) |
EP (1) | EP1730244B1 (zh) |
JP (1) | JP4852031B2 (zh) |
CN (1) | CN1926205B (zh) |
AT (1) | ATE443739T1 (zh) |
AU (1) | AU2005219867B2 (zh) |
DE (1) | DE602005016785D1 (zh) |
ES (1) | ES2330654T3 (zh) |
PT (1) | PT1730244E (zh) |
WO (1) | WO2005085371A1 (zh) |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070087137A9 (en) * | 2003-06-26 | 2007-04-19 | Elwakil Hamdy A | Decorative laminated safety glass |
DE602004030188D1 (de) * | 2003-06-27 | 2011-01-05 | Toyo Ink Mfg Co | Nichtwässrige Tintenstrahldruckertinte |
JP4852031B2 (ja) | 2004-03-02 | 2012-01-11 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 装飾性積層安全ガラス |
US20050282928A1 (en) * | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Ink jet ink |
US20050282946A1 (en) * | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Titanium dioxide slurries for ink applications |
US20060099356A1 (en) * | 2004-11-08 | 2006-05-11 | Pray Eric T | Decorative laminated safety glass |
EP1852477B1 (en) * | 2005-02-21 | 2013-11-13 | Konica Minolta Medical & Graphic, Inc. | Ink set for inkjet recording and image forming method by use thereof |
US20060223909A1 (en) * | 2005-03-31 | 2006-10-05 | Illinois Tool Works Inc. | Faster drying inkjet ink for porous and non-porous printing |
US7393400B2 (en) * | 2005-07-26 | 2008-07-01 | Toshiba Tec Kabushiki Kaisha | Non-aqueous ink composition for ink jet |
US20070172636A1 (en) * | 2005-12-30 | 2007-07-26 | Smith Rebecca L | Decorative sheets having enhanced adhesion and laminates prepared therefrom |
ES2289916B1 (es) * | 2006-01-23 | 2008-12-16 | Ferro Spain, S.A. | Dispersion coloidal de pigmentos ceramicos. |
US20070188535A1 (en) * | 2006-02-14 | 2007-08-16 | Elwakil Hamdy A | Method for printing on clear or translucent substrates |
US7311371B2 (en) * | 2006-04-26 | 2007-12-25 | Toshiba Tec Kabushiki Kaisha | Method for inkjet recording |
US7645332B2 (en) * | 2006-04-28 | 2010-01-12 | Toshiba Tec Kabushiki Kaisha | Non-aqueous ink composition for inkjet |
US7635504B2 (en) * | 2006-05-05 | 2009-12-22 | E. I. Du Pont De Nemours And Company | Curable white inkjet ink |
US20080014414A1 (en) * | 2006-07-13 | 2008-01-17 | Vincent James Yacovone | Windshield Interlayer Having a Gradient Region Having a White Coloration |
US8158221B2 (en) * | 2006-11-22 | 2012-04-17 | Hewlett-Packard Development Company, L.P. | Reactive ink and ink-media system for reduced air fade on porous media |
ES2342189T3 (es) * | 2006-12-21 | 2010-07-02 | Agfa Graphics N.V. | Metodo de impresion por chorro de tinta y cartuchos de tinta. |
US20080233352A1 (en) * | 2007-03-19 | 2008-09-25 | Smith Rebecca L | High contrast decorative sheets and laminates |
US10040216B2 (en) * | 2007-04-04 | 2018-08-07 | The Exone Company | Powder particle layerwise three-dimensional printing process |
US20080280076A1 (en) * | 2007-05-11 | 2008-11-13 | Richard Allen Hayes | Decorative safety glass |
US20090012195A1 (en) * | 2007-07-05 | 2009-01-08 | Neff Raymond A | Resin composition for use in forming a polyurethane article with increased comfort |
WO2009017648A1 (en) * | 2007-07-26 | 2009-02-05 | The Ex One Company, Llc | Nanoparticle suspensions for use in the three-dimensional printing process |
EP2210922B1 (en) * | 2007-11-14 | 2016-02-17 | Konica Minolta IJ Technologies, Inc. | Nonaqueous ink-jet ink and ink-jet recording method |
JP2009132847A (ja) * | 2007-12-03 | 2009-06-18 | Mimaki Engineering Co Ltd | インクジェット用インク |
FR2925483B1 (fr) * | 2007-12-20 | 2010-01-08 | Saint Gobain | Vitrage decoratif. |
US8351100B2 (en) * | 2008-05-28 | 2013-01-08 | Xerox Corporation | Method to create spot colors with white and CMYK toner and achieve color consistency |
JP5489126B2 (ja) * | 2009-09-30 | 2014-05-14 | 大日本印刷株式会社 | インク組成物 |
FR2964447B1 (fr) | 2010-09-02 | 2012-08-24 | Saint Gobain | Vitrage feuillete eclairant a diodes electroluminescentes et sa fabrication |
WO2012060060A1 (ja) * | 2010-11-01 | 2012-05-10 | 理想科学工業株式会社 | 非水系顔料インク |
DE102011004500A1 (de) | 2011-02-22 | 2012-08-23 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Herstellung einer bedruckten Fahrzeug-Verbundscheibe |
US8926079B2 (en) * | 2011-07-13 | 2015-01-06 | Hewlett-Packard Development Company, L.P. | Ink set |
CN103059641B (zh) * | 2011-10-21 | 2014-12-24 | 武汉泓锦旭隆新材料有限公司 | 一种多彩pvb中间膜及其制备方法 |
JP2013129708A (ja) * | 2011-12-20 | 2013-07-04 | Seiko Epson Corp | インクジェット記録用白色系インク、記録装置 |
CN103184411A (zh) * | 2011-12-29 | 2013-07-03 | 深圳富泰宏精密工业有限公司 | 镀膜件及镀膜件的制作方法 |
US9441123B2 (en) | 2012-08-15 | 2016-09-13 | Penn Color, Inc. | Cationic water based polymers for ink, coating, and film applications |
EP2711346A1 (en) | 2012-09-25 | 2014-03-26 | Falco Technologies BVBA | Multi-layered panel and method for manufacturing a multi-layered panel |
US9434849B2 (en) | 2012-10-19 | 2016-09-06 | Penn Color, Inc. | Water based anionic polymers for ink, coating, and film applications |
US9336473B2 (en) * | 2014-09-11 | 2016-05-10 | Electronics For Imaging, Inc. | Virtual ink channels |
EP3034312A1 (en) | 2014-12-18 | 2016-06-22 | Agfa Graphics Nv | Radiation curable compositions for printing on glass |
US10710340B2 (en) | 2015-02-19 | 2020-07-14 | Agp America S.A. | Obscuration having superior strength and optical quality for an automotive laminate |
US9623634B2 (en) | 2015-02-19 | 2017-04-18 | Agp America S.A. | Obscuration having superior strength and optical quality for a laminated automotive windshield |
US10780674B2 (en) | 2015-02-19 | 2020-09-22 | Agp America S.A. | Obscuration having superior strength and optical quality for an automotive laminate |
JPWO2017051668A1 (ja) * | 2015-09-25 | 2018-03-01 | 富士フイルム株式会社 | 水性顔料分散液及びその製造方法、着色組成物、インク組成物、インクジェット記録用インク組成物、並びに、インクジェット記録方法 |
CO2017008445A1 (es) | 2016-12-29 | 2018-01-31 | Agp America Sa | Oscurecimiento con resistencia y calidad óptica superiores para un laminado para automotores |
EP3625051A1 (en) * | 2017-05-15 | 2020-03-25 | Corning Incorporated | Laminate having organic ink decoration and high impact resistance |
CN107190532A (zh) * | 2017-06-28 | 2017-09-22 | 常州武城服饰有限公司 | 一种防沉淀剂 |
US11034613B2 (en) * | 2017-11-21 | 2021-06-15 | Corning Incorporated | Methods for ion exchanging glass articles |
US11338588B2 (en) * | 2018-12-20 | 2022-05-24 | Kateeva, Inc. | Print material feed system |
FR3118026B1 (fr) * | 2020-12-22 | 2023-08-18 | Saint Gobain | Vitrage de toit pour véhicule automobile |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4680058A (en) * | 1982-08-04 | 1987-07-14 | Hitachi, Ltd. | White ink composition for ink-jet printing |
EP1421139B1 (en) * | 2001-08-30 | 2009-10-21 | Chemtura Corporation | Higher alkylated triaryl phosphate ester flame retardants |
Family Cites Families (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4173672A (en) * | 1977-09-06 | 1979-11-06 | Mannheim Jose R | Decorated safety glass |
US4230775A (en) * | 1977-12-16 | 1980-10-28 | E. I. Du Pont De Nemours And Company | Polyvinyl butyral ink formulation |
US4303718A (en) * | 1980-06-09 | 1981-12-01 | Monsanto Company | Printing ink formulations |
JPS58144888A (ja) | 1982-02-23 | 1983-08-29 | セイコーインスツルメンツ株式会社 | 行列形液晶表示装置 |
JPS59113073A (ja) * | 1982-12-18 | 1984-06-29 | Pilot Ink Co Ltd | マ−キングペン用インキ |
JPS59115853A (ja) * | 1982-12-23 | 1984-07-04 | Sharp Corp | インクジエツト記録装置 |
JPS6092368A (ja) * | 1983-10-26 | 1985-05-23 | Hitachi Ltd | インクジエツト記録用白色インク |
JPS60118767A (ja) * | 1983-11-30 | 1985-06-26 | Tokyo Ohka Kogyo Co Ltd | ジエツト印刷用白色インク組成物 |
US4680352A (en) * | 1985-03-01 | 1987-07-14 | E. I. Du Pont De Nemours And Company | Cobalt (II) chelates as chain transfer agents in free radical polymerizations |
US4656226A (en) | 1985-09-30 | 1987-04-07 | E. I. Du Pont De Nemours And Company | Acrylic pigment dispersants made by group transfer polymerization |
US4722984A (en) | 1985-12-03 | 1988-02-02 | E. I. Du Pont De Nemours And Company | Pentacyanocobaltate(II) catalytic chain transfer agents for molecular weight control in free radical polymerization |
EP0254187A3 (de) | 1986-07-21 | 1989-07-26 | Siemens Aktiengesellschaft | Pigmentierter Lack für Schreibsysteme |
US4968553A (en) * | 1988-09-16 | 1990-11-06 | Claudio Cesar | Graphic architectural glass |
US5026427A (en) | 1988-10-12 | 1991-06-25 | E. I. Dupont De Nemours And Company | Process for making pigmented ink jet inks |
DE3920730A1 (de) * | 1989-06-24 | 1991-01-10 | Heidelberger Druckmasch Ag | Vorrichtung zur bogenglaettung am druckzylinder in einer bogenrotationsdruckmaschine |
US5085698A (en) * | 1990-04-11 | 1992-02-04 | E. I. Du Pont De Nemours And Company | Aqueous pigmented inks for ink jet printers |
US5141556A (en) | 1991-06-13 | 1992-08-25 | E. I. Du Pont De Nemours And Company | Penetrants for aqueous ink jet inks |
US5231131A (en) * | 1991-12-24 | 1993-07-27 | E. I. Du Pont De Nemours And Company | Aqueous graft copolymer pigment dispersants |
EP0556649B1 (en) | 1992-02-20 | 1999-06-23 | E.I. Du Pont De Nemours & Company Incorporated | Aqueous dispersions containing ABC triblock polymer dispersants |
US5169436A (en) * | 1992-05-13 | 1992-12-08 | E. I. Du Pont De Nemours And Company | Sulfur-containing penetrants for ink jet inks |
JP3397365B2 (ja) * | 1993-04-01 | 2003-04-14 | キヤノン株式会社 | インク、インクの製造方法、インクジェット記録方法、記録ユニット、インクカートリッジおよびインクジェット記録装置 |
FR2706446B1 (fr) * | 1993-06-18 | 1995-08-25 | Saint Gobain Vitrage Int | Vitrage feuilleté comportant un motif apparent. |
US6852156B2 (en) | 2000-06-05 | 2005-02-08 | E.I. Du Pont De Nemours And Company | Self-dispersing pigment and process of making and use of same |
US6037405A (en) * | 1995-12-25 | 2000-03-14 | Sakata Inx Corp. | Pigment dispersion and offset printing ink composition using the same |
US5698016A (en) | 1996-06-14 | 1997-12-16 | Cabot Corporation | Compositions of modified carbon products and amphiphilic ions and methods of using the same |
DE29706880U1 (de) | 1997-04-16 | 1997-05-28 | Vegla Vereinigte Glaswerke Gmbh, 52066 Aachen | Dekoratives Verbundglas |
EP1066352B2 (en) | 1998-04-03 | 2008-10-01 | Cabot Corporation | Modified pigments having improved dispersing properties |
JPH11334359A (ja) * | 1998-05-26 | 1999-12-07 | Oki Electric Ind Co Ltd | 電動式パワーウインドウの安全装置 |
AU3210000A (en) | 1999-02-19 | 2000-09-04 | Markem Corporation | Stable titanium dioxide containing ink jet ink composition |
US6433038B1 (en) | 1999-03-16 | 2002-08-13 | Seiko Epson Corporation | Photocurable ink composition for ink jet recording and ink jet recording method using the same |
DE20100717U1 (de) | 2000-02-18 | 2001-04-05 | Glas Engels Gmbh | Verbundkörper aus einer mehrschichtigen Anordnung |
EP1129844A1 (en) | 2000-02-29 | 2001-09-05 | Brevet 2000 Holding S.A. | Composite stratified decorated panel from glass and/or transparent plastics |
JP2001246767A (ja) * | 2000-03-07 | 2001-09-11 | Sharp Corp | インクジェット画像形成方法及びインクジェット画像形成装置 |
DE60124287T3 (de) | 2000-09-01 | 2015-03-19 | Digiglass Pty. Ltd. | Laminiertes Bildträgermaterial |
DE10050345C1 (de) | 2000-10-11 | 2002-05-08 | Andreas Peter Galac | Verfahren zur Herstellung von Verbundglas mit einer Mattierung |
WO2002046322A2 (en) | 2000-12-06 | 2002-06-13 | Printar Ltd. | Heat curable ink-jet ink for printing on printed circuit boards |
JP3915554B2 (ja) | 2001-03-14 | 2007-05-16 | セイコーエプソン株式会社 | インクジェット用白色インクおよびそれに用いる二酸化チタンスラリー |
GB0113093D0 (en) | 2001-05-30 | 2001-07-18 | 3M Innovative Properties Co | Inkjet printing |
US20040246319A1 (en) | 2001-10-04 | 2004-12-09 | Akio Ito | White inkjet ink and inkjet recording method |
US7368487B2 (en) * | 2001-11-15 | 2008-05-06 | 3M Innovative Properties Company | Aqueous ink jet printable compositions |
US20030149130A1 (en) | 2001-12-21 | 2003-08-07 | Ai Kondo | Ink composition and a method for ink jet recording |
US6769766B2 (en) * | 2001-12-28 | 2004-08-03 | Konica Corporation | Inkjet printer utilizing white ink |
US6824868B2 (en) * | 2002-04-30 | 2004-11-30 | Solutia, Inc. | Digital color-design composite for use in laminated glass |
JP2004002055A (ja) * | 2002-05-29 | 2004-01-08 | Shijo Sozo Kk | 中間接着剤に塗装した熱線吸収合わせガラス |
US6881458B2 (en) * | 2002-06-03 | 2005-04-19 | 3M Innovative Properties Company | Ink jet receptive coating |
JP4214729B2 (ja) * | 2002-07-25 | 2009-01-28 | コニカミノルタホールディングス株式会社 | 硬化性白インク組成物 |
JP2004059395A (ja) * | 2002-07-31 | 2004-02-26 | Dainippon Toryo Co Ltd | 装飾用合わせガラス |
AU2003257995B2 (en) * | 2002-07-31 | 2008-05-22 | Kuraray America, Inc. | Ink-jet printed rigid interlayer and a process for preparing same |
US7026368B2 (en) | 2002-07-31 | 2006-04-11 | Dainippon Ink And Chemicals, Inc. | Ultraviolet-curable ink composition for ink jet recording |
US20070071955A9 (en) * | 2002-08-20 | 2007-03-29 | Elwakil Hamdy A | Decorative laminated safety glass |
CA2495946A1 (en) | 2002-08-20 | 2004-03-04 | E.I. Du Pont De Nemours And Company | Decorative laminated safety glass |
US20070087137A9 (en) * | 2003-06-26 | 2007-04-19 | Elwakil Hamdy A | Decorative laminated safety glass |
US7041163B2 (en) * | 2003-03-28 | 2006-05-09 | E.I. Du Pont De Nemours And Company | Non-aqueous inkjet ink set |
US7279511B2 (en) * | 2002-12-09 | 2007-10-09 | Videojet Technologies Inc. | Opaque ink jet ink composition |
EP1651434A1 (en) * | 2003-08-07 | 2006-05-03 | E.I. Dupont De Nemours And Company | Decorative laminated safety glass utilizing a rigid interlayer and a process for preparing same |
JP4852031B2 (ja) | 2004-03-02 | 2012-01-11 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 装飾性積層安全ガラス |
US20050282946A1 (en) * | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Titanium dioxide slurries for ink applications |
US20050282928A1 (en) | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Ink jet ink |
US20060099356A1 (en) * | 2004-11-08 | 2006-05-11 | Pray Eric T | Decorative laminated safety glass |
-
2005
- 2005-03-02 JP JP2007501912A patent/JP4852031B2/ja not_active Expired - Fee Related
- 2005-03-02 ES ES05724240T patent/ES2330654T3/es active Active
- 2005-03-02 AT AT05724240T patent/ATE443739T1/de not_active IP Right Cessation
- 2005-03-02 DE DE602005016785T patent/DE602005016785D1/de active Active
- 2005-03-02 US US11/070,714 patent/US20050215664A1/en not_active Abandoned
- 2005-03-02 EP EP05724240A patent/EP1730244B1/en not_active Not-in-force
- 2005-03-02 PT PT05724240T patent/PT1730244E/pt unknown
- 2005-03-02 WO PCT/US2005/006653 patent/WO2005085371A1/en not_active Application Discontinuation
- 2005-03-02 AU AU2005219867A patent/AU2005219867B2/en not_active Ceased
- 2005-03-02 CN CN200580006582.3A patent/CN1926205B/zh not_active Expired - Fee Related
- 2005-03-02 US US11/070,687 patent/US7278730B2/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4680058A (en) * | 1982-08-04 | 1987-07-14 | Hitachi, Ltd. | White ink composition for ink-jet printing |
EP1421139B1 (en) * | 2001-08-30 | 2009-10-21 | Chemtura Corporation | Higher alkylated triaryl phosphate ester flame retardants |
Also Published As
Publication number | Publication date |
---|---|
JP4852031B2 (ja) | 2012-01-11 |
AU2005219867B2 (en) | 2009-10-08 |
CN1926205A (zh) | 2007-03-07 |
US7278730B2 (en) | 2007-10-09 |
EP1730244B1 (en) | 2009-09-23 |
EP1730244A1 (en) | 2006-12-13 |
PT1730244E (pt) | 2009-11-16 |
DE602005016785D1 (de) | 2009-11-05 |
ATE443739T1 (de) | 2009-10-15 |
ES2330654T3 (es) | 2009-12-14 |
US20050196560A1 (en) | 2005-09-08 |
JP2007526389A (ja) | 2007-09-13 |
US20050215664A1 (en) | 2005-09-29 |
AU2005219867A1 (en) | 2005-09-15 |
WO2005085371A1 (en) | 2005-09-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1926205B (zh) | 装饰性层压安全玻璃 | |
CN100457444C (zh) | 热塑性中间层片材、含有其的层合材料和该层合材料的制备方法 | |
US11512216B2 (en) | Pretreatment liquid and ink set | |
US8002938B2 (en) | Decorative laminated safety glass | |
KR0173328B1 (ko) | 적층 구조체용 착색 열가소성 복합체 시이팅의 제조방법 | |
TWI573842B (zh) | A glass substrate, a printing material for printing an ink composition printed with a high-quality, high-quality screen printing ink, and a method for manufacturing the printed matter | |
US20060099356A1 (en) | Decorative laminated safety glass | |
US20050271865A1 (en) | Decorative laminated safety glass | |
US20230030249A1 (en) | Pretreatment liquid, ink set and printed matter | |
EP3956410B1 (en) | Fast drying inkjet ink compositions | |
US20240218198A1 (en) | Recording liquid set, printed matter producing method, and printed matter |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: KURARAY AMERICA INC. Free format text: FORMER OWNER: E.I. DU PONT DE NEMOURS AND CO. Effective date: 20141011 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20141011 Address after: Texas, USA Patentee after: KURARAY AMERICA Inc. Address before: Delaware, USA Patentee before: E. I. du Pont de Nemours and Co. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130828 |
|
CF01 | Termination of patent right due to non-payment of annual fee |