CN1908026A - 丙烯酰胺交联共聚物乳液及其制备方法 - Google Patents
丙烯酰胺交联共聚物乳液及其制备方法 Download PDFInfo
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- crosslinking copolymer
- acrylamide
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- acrylamide crosslinking
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起始物料 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | |
水相 | 丙烯酰胺,g | 155.0 | 208.0 | 228.0 | 112.0 | 94.0 | 208.0 | 208.0 |
2-丙烯酰胺基-2-甲基丙磺酸,g | 453.0 | 405.0 | 300.2 | 491.0 | 548.64 | 405.0 | 405.0 | |
H2O,g | 316.0 | 345.0 | 369 | 334.0 | 300 | 355.0 | 347.0 | |
NaOH(45%),g | 218.0 | 195.0 | 181.0 | 236.0 | 245.0 | 195.0 | 195.0 | |
N’N-亚甲基双丙烯酰胺,g | 0.16 | 0.16 | 0.16 | 0.16 | 0.44 | 0.08 | 0.8 | |
乙二撑三胺五乙酸五钠盐,g | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.066 | 0.288 | |
油相 | 脱水山梨醇单油酸酯,g | 32.0 | 56.3 | 32.0 | 48.0 | 25.6 | 41.3 | 32 |
异十六烷烃,g | 354.0 | 354.0 | 454.0 | 400.0 | 300.0 | 363.3 | 354.0 | |
氧化剂 | 叔丁基过氧化氢,g | 0.131 | 0.131 | 0.162 | 0.032 | 0.32 | 0.131 | 0.131 |
2%水溶液 | 焦亚硫酸钠,g | 0.33 | 0.33 | 0.33 | 0.066 | 0.66 | 0.33 | 0.49 |
H2O,g | 16 | 16 | 17 | 3.2 | 32 | 16.0 | 24.0 | |
氧化剂 | 叔丁基过氧化氢,g | 0.66 | 0.197 | 0.066 | 0.197 | 0.197 | 0.197 | 0.197 |
30%水溶液 | 焦亚硫酸钠,g | 3.29 | 0.982 | 0.329 | 2.459 | 1.262 | 0.982 | 0.982 |
H2O,g | 7.7 | 4.2 | 0.8 | 5.7 | 3 | 2.3 | 2.3 | |
水包油型乳化剂 | 脂肪醇聚氧乙烯(9)醚,g | 48.3 | 80.5 | 53.1 | 65.2 | 40.0 | 48.3 | 48.3 |
测试项目 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 |
0.8%聚合物水溶液粘度(cps) | 76000 | 80000 | 65000 | 65000 | 52000 | 40000 | 10000 |
MgCl2粘度保留值 | 0.40 | 0.35 | 0.30 | 0.45 | 0.50 | 0.40 | 0.20 |
NaCl粘度保留值 | 0.51 | 0.45 | 0.40 | 0.56 | 0.52 | 0.46 | 0.25 |
残留单体含量(ppm) | 50 | 41 | 40 | 39 | 43 | 48 | 55 |
反相速度(秒) | 15 | 22 | 14 | 19 | 14 | 16 | 25 |
指标名称 | 实施例1 | EP 0503853 |
乳液粘度@30rpm | 3200 | 3600 |
2%水溶液粘度@5rpm | 76000 | 78000 |
残留单体含量,% | 0.005 | 0.02 |
反相速度,秒 | 15 | 25 |
MgCl2粘度保留值 | 0.4 | 0.35 |
NaCl粘度保留值 | 0.51 | 0.2 |
测试项目 | 实施例8 | 实施例9 | 实施例10 | 实施例11 | 实施例12 | 实施例13 | 实施例14 | 实施例15 | 实施例16 | 实施例17 | 实施例18 | 实施例19 | 实施例20 | 实施例21 |
2%水溶液粘度,cps | 70000 | 64000 | 65000 | 60000 | 75000 | 68000 | 67000 | 64000 | 73000 | 65000 | 65000 | 64000 | 66000 | 65000 |
MgCl2粘度保留值 | 0.35 | 0.26 | 0.3 | 0.3 | 0.4 | 0.32 | 0.38 | 0.32 | 0.36 | 0.3 | 0.32 | 0.28 | 0.28 | 0.26 |
NaCl粘度保留值 | 0.45 | 0.30 | 0.4 | 0.35 | 0.5 | 0.40 | 0.48 | 0.41 | 0.48 | 0.4 | 0.40 | 0.42 | 0.35 | 0.35 |
反相速度(秒) | 15 | 13 | 14 | 18 | 20 | 18 | 18 | 15 | 14 | 15 | 15 | 15 | 20 | 18 |
残留单体含量ppm | 28 | 27 | 30 | 43 | 24 | 26 | 34 | 33 | 26 | 37 | 40 | 35 | 30 | 32 |
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CN1908026A true CN1908026A (zh) | 2007-02-07 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103819606A (zh) * | 2014-03-28 | 2014-05-28 | 杜海兵 | 一种耐盐型超高分子量增稠剂的制备方法 |
CN104449649A (zh) * | 2014-11-28 | 2015-03-25 | 中国石油化工股份有限公司胜利油田分公司采油工艺研究院 | 一种高浓度油包水乳液态缔合聚合物压裂液及其制备方法 |
CN113354774A (zh) * | 2021-06-28 | 2021-09-07 | 万华化学集团股份有限公司 | 一种丙烯酸酯-丙烯酰胺共聚物乳液及其制备方法与应用 |
CN114349908A (zh) * | 2022-01-21 | 2022-04-15 | 万华化学集团股份有限公司 | 一种反相乳液的制备方法及一种增稠剂、乳化剂 |
CN114569496A (zh) * | 2021-12-06 | 2022-06-03 | 广州百孚润化工有限公司 | 一种高分子增稠剂及其制备方法与应用 |
CN115785726A (zh) * | 2022-12-06 | 2023-03-14 | 万华化学集团股份有限公司 | 一种高耐沾污水性丙烯酸消光剂及制备方法与应用 |
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EP0186361B2 (en) * | 1984-12-10 | 1994-04-27 | Scott Bader Company Limited | Thickeners for thickening aqueous media |
GB9104878D0 (en) * | 1991-03-08 | 1991-04-24 | Scott Bader Co | Thickeners for personal care products |
FR2709982B1 (fr) * | 1993-09-15 | 1995-12-08 | Oreal | Emulsions acides stables de type huile-dans-eau et compositions les contenant. |
DE69932648T2 (de) * | 1998-01-16 | 2007-08-09 | Société d'Exploitation de Produits pour les Industries Chimiques S.E.P.P.I.C. | Verdickend wirkendes Latex, Verfahren zu dessen Herstellung und Anwendungen in der Kosmetik |
US6586094B1 (en) * | 1998-11-24 | 2003-07-01 | E. I. Du Pont De Nemours And Company | Fiber coated with water blocking material |
JP2005534749A (ja) * | 2002-07-29 | 2005-11-17 | アプレラ コーポレイション | グラフト共重合体、それらの調製、およびキャピラリー電気泳動での使用 |
JP4711633B2 (ja) * | 2003-06-17 | 2011-06-29 | ローム アンド ハース カンパニー | ポリマー組成物およびポリマーの調製法 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103819606A (zh) * | 2014-03-28 | 2014-05-28 | 杜海兵 | 一种耐盐型超高分子量增稠剂的制备方法 |
CN104449649A (zh) * | 2014-11-28 | 2015-03-25 | 中国石油化工股份有限公司胜利油田分公司采油工艺研究院 | 一种高浓度油包水乳液态缔合聚合物压裂液及其制备方法 |
CN104449649B (zh) * | 2014-11-28 | 2017-10-13 | 中国石油化工股份有限公司胜利油田分公司采油工艺研究院 | 一种高浓度油包水乳液态缔合聚合物压裂液及其制备方法 |
CN113354774A (zh) * | 2021-06-28 | 2021-09-07 | 万华化学集团股份有限公司 | 一种丙烯酸酯-丙烯酰胺共聚物乳液及其制备方法与应用 |
CN114569496A (zh) * | 2021-12-06 | 2022-06-03 | 广州百孚润化工有限公司 | 一种高分子增稠剂及其制备方法与应用 |
CN114569496B (zh) * | 2021-12-06 | 2024-02-27 | 广州百孚润化工有限公司 | 一种高分子增稠剂及其制备方法与应用 |
CN114349908A (zh) * | 2022-01-21 | 2022-04-15 | 万华化学集团股份有限公司 | 一种反相乳液的制备方法及一种增稠剂、乳化剂 |
CN115785726A (zh) * | 2022-12-06 | 2023-03-14 | 万华化学集团股份有限公司 | 一种高耐沾污水性丙烯酸消光剂及制备方法与应用 |
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