CN1891195B - Surfactant composition - Google Patents
Surfactant composition Download PDFInfo
- Publication number
- CN1891195B CN1891195B CN2006100917069A CN200610091706A CN1891195B CN 1891195 B CN1891195 B CN 1891195B CN 2006100917069 A CN2006100917069 A CN 2006100917069A CN 200610091706 A CN200610091706 A CN 200610091706A CN 1891195 B CN1891195 B CN 1891195B
- Authority
- CN
- China
- Prior art keywords
- composition
- surface activator
- salt
- carbon number
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a surfactant composition exhibiting good fluidity over a wide temperature range even if containing a polyoxyethylene alkyl ether sulfate salt or alkyl sulfate salt in high concentrations, with no occurrence of viscosity rise or gelation when diluted, and free of decline in the performance inherent in surfactant, and useful for producing skin cleansers or hair cleansers including shampooes and body shampooes. The surfactant composition comprises (A) the polyoxyethylene alkyl ether sulfate salt of the general formula(1): R<SP>1</SP>O(CH<SB>2</SB>CH<SB>2</SB>O)<SB>n</SB>SO<SB>3</SB>M, (B) an alcohol alkylene oxide adduct of the general formula(2):R<SP>2</SP>O-(AO)<SB>m</SB>-R<SP>3</SP>and (C) a water-soluble salt. In this surfactant composition, the content of the component A is 40 wt.% or greater.
Description
Technical field
The present invention relates to can be used for making the surface activator composition of skin detergents such as shampoo, bath foam or hair detergent, even its high concentration ground contains polyoxyethylene alkyl ether sulfate salt or alkyl sulfate, also can under the temperature of relative broad range, have good flowability, viscosity can not take place during dilution rise and gelation, and can not reduce surfactant performance originally.
Background technology
Normally used polyoxyethylene alkyl ether sulfate salt or alkyl sulfate are in the non-constant of high concentration current downflow, difficult treatment.For it is handled easily, in being the very low range of 30 weight % or following or viscosity, concentration handle.Therefore, attempt the 3rd composition (viscosity reductant) that purposes influenced that various interpolation performances can not be used polyoxyethylene alkyl ether sulfate salt or alkyl sulfate, carried out the method for high concentrationization and lowering viscousity.For example, the sulfonate of unsaturated fatty acid polyalkylene Arrcostab and the method (the flat 10-17898 communique of Japanese Patent Application Laid-Open) of α-sulfonic acid polyalkylene alkyl ester salt, the method several different methods such as (WO91/04313) of adding alkyl polyglucoside and alkali metal salt have been proposed to add.Yet, thereby different and produce bad influence at aspect of performance and be subjected to the restriction that can't be suitable for according to purposes, and mobile variation during low temperature, must heat when cooperating detergent and use, can not fully satisfy the demand.
In addition, put down in writing in the method for flat 10-17898 communique of Japanese Patent Application Laid-Open or 2WO91/04313, do not improved but be documented near the flowability of low temperature (5 ℃) from improving effect to 70 ℃ flowability near the room temperature (20 ℃).
On the other hand, disclose in the Japanese Patent Application Laid-Open 2004-277685 communique and in anionic surfactants such as polyoxyethylene alkyl ether sulfate salt, be added with: R with formula
1O-(CH
2CH
2O)
n-R
2(R
1Be that carbon number is 8～12 straight chained alkyl, R
2Be 1～3 integer for hydrogen atom or methyl, n) polyethyleneglycol of expression or dialkyl ether and as electrolytical liquid detergent compositions such as the Sal of composition arbitrarily, sodium sulfate.But, in Japanese Patent Application Laid-Open 2004-277685 communique, only related to the effect of tackify foam enhancing specially, and the visbreaking effect that is brought about the polyoxyethylene alkyl ether sulfate salt of high concentration or the mentioned component of alkyl sulfate (polyethyleneglycol or dialkyl ether) to the raising of flowability without any record.
In addition, in Japanese Patent Application Laid-Open 2004-352943 communique, put down in writing anionic surfactants such as being combined with polyoxyethylene alkyl ether sulfate salt, the liquid detergent composition of water soluble magnesium chemical compounds such as the alkylene oxide addition product of 2-Ethylhexyl Alcohol and magnesium chloride, but the liquid detergent composition that uses polyoxyethylene alkyl ether sulfate salt or alkyl sulfate with low concentration is in fact only disclosed, only know that the viscosity of this compositions in the time of 20 ℃ is 10～1000mPas, for low viscous compositions, as shampoo, usability variation when skin detergent such as bath foam or hair detergent use.
Summary of the invention
Like this, the polyoxyethylene alkyl ether sulfate salt of high concentration or alkyl sulfate are relatively poor in the high viscosity current downflow.Thus, exist the problem that the property handled is poor, gelation takes place when the high concentration material is used in dilution.
The object of the present invention is to provide the surface activator composition that can be used for making skin detergents such as shampoo, bath foam or hair detergent, even its high concentration ground contains polyoxyethylene alkyl ether sulfate salt or alkyl sulfate, also can under the temperature of relative broad range, have good flowability, viscosity can not take place during dilution rise and gelation, and can not reduce surfactant performance originally.
Discoveries such as the inventor, by in polyoxyethylene alkyl ether sulfate salt or alkyl sulfate, adding the alkylene oxide addition product of specific alcohol, and then combination water soluble salt, can access the surface activator composition that can be used for making skin detergents such as shampoo, bath foam or hair detergent, it has good flowability under the temperature of relative broad range, viscosity can not take place during dilution rise and gelation, and can not reduce surfactant performance originally.
That is, the invention provides a kind of surface activator composition, said composition contains following composition (A), (B) and (C), and the content of composition (A) be 40 weight % or more than, the viscosity of said composition in the time of 30 ℃ is 1000～70,000 mPas,
(A) with the polyoxyethylene alkyl ether sulfate salt of general formula (1) expression or alkyl sulfate [below be also referred to as composition (A)];
R
1O(CH
2CH
2O)
nSO
3M (1)
(in the formula, R
1The expression carbon number is that 8～18 saturated or undersaturated alkyl, average addition molal quantity n represent that 0～5 number, M represent alkali metal atom, alkanolamine or ammonium)
(B) with the alkylene oxide addition product of the alcohol of general formula (2) expression [below be also referred to as composition (B)];
R
2O-(AO)
m-R
3 (2)
(in the formula, R
2The expression carbon number is that the alkyl of 6～10 straight or branched or alkenyl, AO represent that carbon number is that 2～4 oxyalkylene group, average addition molal quantity m represent 1～3 number, R
3Expression hydrogen atom or methyl)
(C) water soluble salt [below be also referred to as composition (C)].
The specific embodiment
The present invention can provide the surface activator composition that can be used for making skin detergents such as shampoo, bath foam or hair detergent, even its high concentration ground contains polyoxyethylene alkyl ether sulfate salt or alkyl sulfate, also can under the temperature of relative broad range, have good flowability, viscosity can not take place during dilution rise and gelation, and can not reduce surfactants such as foaming characteristic, usability performance originally.
Below, the present invention is described in further detail.
In the present invention in the polyoxyethylene alkyl ether sulfate salt or alkyl sulfate with above-mentioned general formula (1) expression of the composition of Shi Yonging (A), R
1Be that carbon number is 8～18 saturated or undersaturated alkyl, carbon number is preferably 10～16, more preferably 12～14, is preferably saturated hydrocarbyl.R
1Alkyl can be straight chain and also can be side chain, be preferably straight chain.Average addition molal quantity n represents 0～5 number, is preferably 0.5～5, more preferably 1～3, more preferably 1～2.M represents alkali metal atom, alkanolamine or ammonium.As alkali metal atom, can list sodium, potassium etc., be preferably sodium.As alkanolamine, be preferably triethanolamine.Composition (A) is the composition of performance surfactant script performance.
Viewpoint from flowability, preferred component (A) in surface activator composition, contain 40～70 weight %, more preferably 45～70 weight %, more preferably 45～65 weight %, be preferably and surpass 50 weight % but especially smaller or equal to 70 weight %, be preferably more especially and surpass 50 weight % but smaller or equal to 65 weight %.
In the alkylene oxide addition product with the alcohol of above-mentioned general formula (2) expression of composition (B), from the viewpoint of foaming characteristic, usability, R
2Be carbon number be the alkyl of 6～10 straight or branched or alkenyl, preferred carbon number be 6～10 branched alkyl or straight or branched alkenyl, more preferably carbon number is that 6～10 branched alkyl, further preferred carbon number are 8～10, particularly carbon number is 8 alkyl.
AO is that carbon number is 2～4 oxyalkylene group, and preferred carbon number is 2～3, particularly 3 oxyalkylene group.Specifically, can list oxyethylene group, oxypropylene group and butylene oxide base etc., preferred oxyethylene group and oxypropylene group, preferred especially oxypropylene group.The viewpoint of the visbreaking effect under the low temperature, average addition molal quantity m represents 1～3 number, more preferably 1.5～3, more preferably 2～3, be preferably 2～2.8 especially.
The maximum component list of addition molal quantity of AO is shown AO in composition (B)
MaxThe time, thereby harsh feeling disappears and improves the viewpoint of usability, AO after such economical point of the load that alleviates manufacturing cost such as refining and the towel
MaxBe preferably 70 whole weight % or following of composition (B), more preferably 60 weight % or following are preferably 50 weight % or following especially.Particularly AO be the oxyalkylene group of carbon number 2, when being oxyethylene group, preferred AO
MaxBe 60 whole weight % or following of composition (B), more preferably 50 weight % or following are preferably 40 weight % or following especially.In addition, particularly AO be the oxyalkylene group of carbon number 3, when being oxypropylene group, preferred AO
MaxBe 70 whole weight % or following of composition (B), more preferably 60 weight % or following are preferably 50 weight % or following especially.
R
3Expression hydrogen atom or methyl are preferably hydrogen atom especially.
Composition (B) can easily obtain by addition AO (alkylene oxide) in alcohol.Carry out separation and purification by alkylene oxide addition product, can adjust AO resulting alcohol
Max
Composition (B) is to suppressing composition (A) thereby tackify at low temperatures improves the mobile composition of bringing into play effect.That is, composition (B) plays a role as the viscosity reductant under the low temperature of composition (A).
Composition (B) can use a kind or multiple, from improving the viewpoint that concentration is the effect of 40 weight % or the flowability when above, composition (A) and (B) match ratio in surface activator composition of the present invention count (A)/(B)=99/1～75/25 with weight ratio, be preferably 98/2～85/15, more preferably 97/3～90/10.If in this scope, then can bring into play the sufficient mobile effect that improves.
From improving flowability, particularly improve the viewpoint of fluidity at low temperature, composition (B) preferably in surface activator composition, contain 0.5～15 weight %, more preferably 1～10 weight %, be preferably 2～8 weight % especially.
As the water soluble salt of composition (C), be preferably in the water solublity organic salt that is selected from beyond water-soluble inorganic salt and the surfactant one or more.As listing the salt of mineral acids such as organic acid such as citric acid, malic acid, succinic acid, lactic acid or hydrochloric acid, sulphuric acid, nitric acid, carbonic acid, phosphoric acid, in addition,, can list alkali metal such as sodium, potassium or ammonium, aluminum etc. as the cation that forms this salt.As the preferred concrete example of these salts, can list the alkali metal salt of mineral acids such as sodium chloride, sodium sulfate; The ammonium salt of mineral acids such as ammonium chloride, ammonium sulfate, ammonium nitrate; The ammonium salt of the alkali metal salt of organic acid such as trisodium citrate (special preferred aliphat organic acid) and organic acid (special preferred aliphat organic acid) etc., the viewpoint of the usability when using as skin detergent or hair detergent, the alkali metal salt of preferred especially mineral acid or the ammonium salt of mineral acid can use a kind or multiple.Composition (C) improves the composition of effect for performance composition (A) flowability at room temperature.If with composition (B) and (C) combination, then can under the temperature of relative broad range, improve the flowability of composition (A) exponentially.
From improving the viewpoint that composition (A) concentration is the effect of 40 weight % or the flowability when above, composition (A) and (C) match ratio in surface activator composition of the present invention in weight ratio, be preferably (A)/(C)=99/1～85/15, more preferably 99/1～90/10, be preferably 98/2～95/5 especially.If in this scope, then can bring into play the sufficient mobile effect that improves.
From the viewpoint of flowability, composition (C) preferably contains 0.1～10 weight %, is more preferably 0.2～8 weight % in surface activator composition, more preferably 0.5～5 weight %, be preferably 1～4 weight % especially.
Viewpoint from flowability raising and operability excellence, surface activator composition of the present invention preferably the viscosity in the time of 30 ℃ be 1000～70,000 mPas, more preferably 1000～50,000 mPas, be preferably 3000～50,000 mPas especially, preferably the viscosity in the time of 5 ℃ be 90,000 mPas or following, more preferably 1000～70,000 mPas, be preferably 5000～50,000 mPas especially.
Among the present invention, the dissolubility when making the flowability of compositions in wide temperature range that contain 40 weight % or above high concentration composition (A) and dilution improves by using composition (B) and composition (C) to reach simultaneously.
For the composition (A) of high concentration, by adding ingredient (B), the flowability of (5 ℃) is enhanced under the low temperature, and by adding ingredient (C), the flowability of (30 ℃) is enhanced under the room temperature.And, by being used in combination composition (B) and composition (C), can in the wider temperature range of room temperature, improve mobile exponentially from low temperature.And the surface activator composition that obtains like this viscosity when dilution can not rise, and can not cause gelation, therefore can easily cooperate.Cooperating the composition of detergent that obtains is the compositions that foaming characteristic is good and usability is excellent.
Surface activator composition of the present invention can be by mixing composition (A), (B) and (C) making under 15～60 ℃ temperature.And its dosage form is not particularly limited, and preferably makes liquid, pasty state, paste.Preferably use solvent during manufacturing, as solvent, special preferred water.
Surface activator composition of the present invention can be used for the manufacturing of composition of detergent.Can further cooperate other surfactant and/or water during fabrication.In addition, surface activator composition of the present invention, can be used as composition of detergent behind the dilute with water uses, can also cooperate as the composition of detergent composition that is used for skin detergent such as cleansing milk, bath foam or is used for hair detergent such as shampoo, in the composition of detergent that has cooperated these surface activator compositions, can cooperate any composition according to its purpose.Here, as any composition, can list the composition (A) that is engaged in usually in these detergents anionic surfactant, nonionic surfactant, amphoteric surfactant, cationic surfactant and being adjusted in addition and grade.
As composition (A) anionic surfactant in addition, can list soap, phosphate ester salt, sulfosuccinic acids surfactant, polyoxyalkylene alkylamide ether sulfate, monoglyceride sulfate, alkene sulfonate, paraffin sulfonate, acidylate isethionate, acylated amino salt, polyoxyalkylene alkyl phosphate, polyoxyalkylene alkyl acetate etc.
As nonionic surfactant, can list APG, sucrose fatty acid ester, polyglyceryl fatty acid ester, polyoxyalkylene alkyl, fatty acid alkanol amides, oxidation of alkyl amine, polyol esters of fatty acids etc.
As amphoteric surfactant, can list amide betaine class surfactant, amidoamino acid class surfactant, carbobetaine class surfactant, sulfobetaines class surfactant, amide sulfo betaine class surfactant, imidazolinium betaine class surfactant, phosphoric acid betaine class surfactant etc.
As cationic surfactant, can list with following general formula (3)
[in the formula, R
4, R
5, R
6And R
7In at least one expression total carbon atom number be 8～28 and alkoxyl, alkenyloxy, alkanol amino or commutable alkyl of chain enamino or alkenyl, all the other expression benzyls, carbon number are 1～5 alkyl, hydroxyalkyl or to add up to the addition molal quantity be 10 or following polyoxyethylene thiazolinyl; Z
-Expression halide ion or organic anion] quaternary ammonium salt of expression.
As regulating composition, can list higher alcohols such as lauryl alcohol, myristyl alcohol, spermol, stearyl alcohol, silicone and silicone derivative, the surfactants such as fatty acid ester of lanoline, Squalene, hydrocarbon, protein derivatives, Polyethylene Glycol, Poise C-80M, JR-125, マ one コ one ト 550 cationic polymers such as (productions of Merck company), Sofcare KG-301W[flower king (strain) produces] etc. contain the copolymer etc. of cationic group.
Normally used other composition can cooperate in the scope of not damaging effect of the present invention as required in the composition of detergent, and above-mentioned other composition is water soluble polymers such as polysaccharide such as methylcellulose, hydroxyethyl-cellulose, CVP Carbopol ETD2050, xanthan gum for example; Viscosity modifiers such as polyoxyalkylene sorbitan ester, polyoxygenated glycol distearate, ethanol; Chelating agen such as ethylenediaminetetraacetic acid (EDTA), phosphoric acid salt; Antiseptic such as methyl parahydroxybenzoate, butyl p-hydroxybenzoate; Effective ingredient such as vitamin or its precursor; Animals and plants such as lecithin, gelatin extract or derivatives thereof; Micro polymer such as nylon or polyethylene powder body; Antiinflammatory such as glycyrrhizic acid dipotassium; Antibacterial, antidandruff agent such as triclosan (triclosan), trichlorine diphenylurea (trichlorocarban), octopirox (octopirox), Zinc Pyrithione; Antioxidants such as dibenzylatiooluene; Pearling agent, UV absorbent, pH adjust agent, pigment, spice, water.
Composition of detergent of the present invention can be by cooperate other surfactant and/or water in surface activator composition of the present invention, according to the well-established law manufacturing.Its dosage form is not particularly limited, and can be liquid, pasty state, paste, solid, shaped, dosage form arbitrarily such as Powdered, preferably makes liquid, pasty state, paste, especially preferably makes liquid.Make when liquid,, preferably make water as liquid medium.
Embodiment
Below, enumerate embodiment and be described in detail.
Embodiment 1～48, comparative example 1～17
Prepare the surface activator composition shown in table 1～6 according to well-established law, by following method to the viscosity of surface-active compositions when 30 ℃ and 5 ℃ and mobile and estimate as the foaming power of 15 weight % aqueous solutions of composition (A).The result is shown in table 1～6 in the lump.The composition of embodiment 1～48, comparative example 12～13 (B) can followingly be made, and promptly by in the presence of base catalyst, is made by alcohol (being specially capryl alcohol, decanol or hexanol) addition alkylene oxide (being specially expoxy propane or oxirane).Dipropylene glycol list ether in the last of the ten Heavenly stems be (table 1～6
*5), ethylene glycol monooctyl ether (table 1～6
*7), diethylene glycol list-2-ethyl hexyl ether (table 1～6
*10), glycol monomethyl-2-ethyl hexyl ether (table 1～6
*11) and dipropylene glycol list-2-ethyl hexyl ether (table 1～6
*13) after neutralization, directly use.The dipropylene glycol monohexyl ether be (table 1～6
*6), propylene glycol list octyl ether (table 1～6
*8) and propylene glycol list octyl ether (table 1～6
*9) after the reaction neutralization, by distilling under reduced pressure the back is removed in unreacted alcohol distillation and use.Dipropylene glycol list octyl ether be (table 1～6
*3), propylene glycol list octyl ether (table 1～6
*4) and diethylene glycol list isodecyl ester (table 1～6
*12) obtain the distillation product in reaction neutralization back by distilling under reduced pressure.Table 1～6
*5～
*11 and
*13 pass through GC AO as can be known
MaxBe 50 whole weight % or following of composition (B).
In addition, under the state when being diluted to 15 weight % as the composition (A) of the surface activator composition of embodiment 1～48, can be in dilution (in 5 minutes) easily at room temperature under the situation that produces gel hardly.And under the state the when composition of 1～6,9,12,13,15 and 17 surface activator composition (A) is diluted to 15 weight % as a comparative example, produce gel, and the dilution under the room temperature needs (about 1 hour) for a long time.Under the state when composition of 7,8,10,14 and 16 surface activator composition (A) is diluted to 15 weight % as a comparative example, produced some gels, and the dilution under the room temperature needs some times (15～30 minutes).
(1) viscosimetric analysis
The condition determination of viscosity is as described below.
Use viscometer B shape viscometer (production of (strain) Tokyo metrical instrument)
Rotor No./rotation number No.4/6rpm minute 1 minute
30 ℃ of temperature: the vial of the sample of will packing in 30 ℃ ± 1 temperature chamber keeps measuring after 1 hour
5 ℃ of temperature: in 5 ℃ ± 1 thermostat, keep measuring after 24 hours
(2) flowability
To pack into vial (diameter be 4cm, highly for 10cm) 90 degree that tilt of 50g surface activator composition, the naked eyes evaluation.
30 ℃ of temperature: the vial of the sample of will packing in 30 ℃ ± 1 temperature chamber keeps post-evaluation in 1 hour
5 ℃ of temperature: in 5 ℃ ± 1 thermostat, keep post-evaluation in 24 hours
(flowability)
A: good fluidity
B: flowability is arranged slightly
C: do not have flowability
(3) foaming characteristics test
Be dropped in the palm according to following evaluation criterion to the surface activator composition that 1ml is diluted to 15 weight % as composition (A) and wash hands and rapid foaming characteristic and bubble amount during wrist carried out and the comparative evaluation that does not add product [15% aqueous solution of polyoxyethylene alkyl ether sodium sulfate (n=2)] by the evaluation group member of 10 specialties.
(foaming characteristic rapidly)
4: foaming characteristic is very good rapidly
3: foaming characteristic is good rapidly
2: foaming characteristic is poor slightly rapidly
1: foaming characteristic is poor rapidly
(bubble amount)
4: compare with not adding product, the bubble amount is very many
3: compare with not adding product, the bubble amount is many
2: compare with not adding product, the bubble amount is identical
1: compare with not adding product, the bubble amount is few
(sensation during washing)
4: compare with not adding product, feel good
3: compare with not adding product, feel good slightly
2: compare with not adding product, feel identical
1: with do not add product and compare perceptual difference
(sensation during cleaning)
4: compare with not adding product, feel good
3: compare with not adding product, feel good slightly
2: compare with not adding product, feel identical
1: with do not add product and compare perceptual difference
(sensation after the towel)
4: compare with not adding product, feel good
3: compare with not adding product, feel good slightly
2: compare with not adding product, feel identical
1: with do not add product and compare perceptual difference
Obtain the meansigma methods that 10 personnel estimate, 3.6 or above be designated as A, 2.6～3.5 be designated as B, 1.6～2.5 be designated as C, 1.5 or the following D that is designated as.
Embodiment 49
Make the bath foam of following composition.
Composition weight %
The surface activator composition 5.0 of embodiment 5
Sodium laurate 6.0
Sodium myristate 3.0
Sodium palmitate 1.0
2-ethylhexyl glycerin ether 1.0
Glycerol 3.0
Methyl parahydroxybenzoate is an amount of
Spice is an amount of
The Purified Water amount of supplying
Meter 100.0
This bath foam does not have viscosity to rise when the dilution of the surface activator composition of embodiment 5, can easily cooperate, and foaming characteristic is good, and the usability excellence.
Embodiment 50
Make the shampoo of following composition.
Composition weight %
The surface activator composition 15.0 of embodiment 2
Amido propyl betaine
*2.0
Myristyl alcohol 1.0
JR-125
*0.5
Ethanol 3.0
Spice is an amount of
The Purified Water amount of supplying
Meter 100.0
*: Amphitol 20AB (flower king (strain) produces)
*: JAGUAR C-13S (production of Rhodia company)
This shampoo does not have viscosity to rise when the dilution of the surface activator composition of embodiment 2, can easily cooperate, and foaming characteristic is good, and the usability excellence.
Embodiment 51
Make the shampoo of following composition.
Composition weight %
The surface activator composition 16.0 of embodiment 14
Coco-nut oil fatty acid N-methyl ethanol amide
*1.0
Myristyl alcohol 1.0
JR-125
*0.5
Ethanol 3.0
Spice is an amount of
The Purified Water amount of supplying
Meter 100.0
*: Aminon C-11S (flower king (strain) produces)
*: JAGUAR C-13S (production of Rhodia company)
This shampoo does not have viscosity to rise when the dilution of the surface activator composition of embodiment 14, can easily cooperate, and foaming characteristic is good, and the usability excellence.
Embodiment 52
Make the bath foam of following composition.
Composition weight %
The surface activator composition 5.0 of embodiment 29
Sodium laurate 6.0
Sodium myristate 3.0
Sodium palmitate 1.0
2-ethylhexyl glycerin ether 1.0
Glycerol 3.0
Methyl parahydroxybenzoate is an amount of
Spice is an amount of
The Purified Water amount of supplying
Meter 100.0
This bath foam does not have viscosity to rise when the dilution of the surface activator composition of embodiment 29, can easily cooperate, and foaming characteristic is good, and the usability excellence.
Embodiment 53
Make the shampoo of following composition.
Composition weight %
The surface activator composition 15.0 of embodiment 36
Amido propyl betaine
*2.0
Myristyl alcohol 1.0
The copolymer that contains the cationic group
*0.2
Ethanol 3.0
Spice is an amount of
The Purified Water amount of supplying
Meter 100.0
*: Amphitol 20AB (flower king (strain) produces)
*: Sofcare KG-301W (the flower king produces)
This shampoo does not have viscosity to rise when the dilution of the surface activator composition of embodiment 36, can easily cooperate, and foaming characteristic is good, and the usability excellence.
Claims (11)
1. surface activator composition, said composition contains following composition (A), (B) and (C), and the content of composition (A) in surface activator composition be 40 weight % or more than, composition (A) and ratio (B) (A)/(B) count 99/1～75/25 with weight ratio, the ratio (A) of composition (A) and composition (C)/(C) count 99/1～85/15 with weight ratio, the viscosity of said composition in the time of 30 ℃ is 1000～70,000 mPas
(A) polyoxyethylene alkyl ether sulfate salt or the alkyl sulfate of representing with general formula (1),
R
1O(CH
2CH
2O)
nSO
3M (1)
Wherein, R
1The expression carbon number is 8～18 saturated or undersaturated alkyl, and average addition molal quantity n represents 0～5 number, and M represents alkali metal atom, alkanolamine or ammonium;
(B) with the alkylene oxide addition product of the alcohol of general formula (2) expression,
R
2O-(AO)
m-R
3 (2)
Wherein, R
2The expression carbon number is that the alkyl of 6～10 straight or branched or alkenyl, AO represent that carbon number is that 2～4 oxyalkylene group, average addition molal quantity m represent 1～3 number, R
3Expression hydrogen atom or methyl;
(C) water soluble salt, it is the ammonium salt of the alkali metal salt that is selected from mineral acid, mineral acid and in the organic acid alkali metal salt one or more.
2. surface activator composition as claimed in claim 1, wherein the AO of composition (B) is that carbon number is 3～4 oxyalkylene group.
3. surface activator composition as claimed in claim 1 is wherein when the maximum component list of addition molal quantity among the AO of composition (B) is shown AO
MaxThe time, AO
MaxBe 70 whole weight % or following of composition (B).
4. surface activator composition as claimed in claim 1, the R of its formula of (2)
2Be that carbon number is 6～10 the branched alkyl or the alkenyl of straight or branched.
5. surface activator composition as claimed in claim 1, the R of its formula of (2)
2Be that carbon number is 6～10 branched alkyl.
6. as each described surface activator composition of claim 1～5, its viscosity in the time of 5 ℃ is 90,000 mPas or following.
7. as each described surface activator composition of claim 1～5, wherein composition (C) is in the ammonium salt of the alkali metal salt that is selected from mineral acid and mineral acid one or more.
8. the composition of detergent that in each described surface activator composition of claim 1～5, cooperates other surfactant and/or water and obtain.
9. the manufacture method of a composition of detergent is characterized in that, cooperates other surfactant and/or water in each described surface activator composition of claim 1～5.
10. each described surface activator composition of claim 1～5 is used to make the purposes of composition of detergent.
11. purposes as claimed in claim 10 wherein further cooperates other surfactant and/or water.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP167943/2005 | 2005-06-08 | ||
| JP2005167943A JP4965821B2 (en) | 2005-06-08 | 2005-06-08 | Surfactant composition |
| JP2005219226 | 2005-07-28 | ||
| JP219226/2005 | 2005-07-28 | ||
| JP378367/2005 | 2005-12-28 | ||
| JP2005378367A JP4915720B2 (en) | 2005-07-28 | 2005-12-28 | Surfactant composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1891195A CN1891195A (en) | 2007-01-10 |
| CN1891195B true CN1891195B (en) | 2011-04-13 |
Family
ID=37596560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100917069A Active CN1891195B (en) | 2005-06-08 | 2006-06-08 | Surfactant composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4965821B2 (en) |
| CN (1) | CN1891195B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2039340B2 (en) | 2006-07-04 | 2020-04-01 | Kao Corporation | Skin cleansing composition |
| CN104382750A (en) * | 2014-11-27 | 2015-03-04 | 青岛厚科信息工程有限公司 | Liquid shampoo containing cationic protein |
| CN104382792A (en) * | 2014-11-27 | 2015-03-04 | 青岛厚科信息工程有限公司 | Liquid shampoo incapable of generating excessive hair degreasing and dryness phenomena |
| CN104473811A (en) * | 2014-11-27 | 2015-04-01 | 青岛厚科信息工程有限公司 | Shampoo liquid with good fluidity in wide temperature range |
| CN104490655A (en) * | 2014-11-27 | 2015-04-08 | 青岛市市南区隆德中医药研究所 | Nerve-soothing liquid shampoo |
| CN104473845A (en) * | 2014-11-27 | 2015-04-01 | 青岛市市南区隆德中医药研究所 | Liquid shampoo with camellia fragrance |
| CN110914215A (en) * | 2017-04-06 | 2020-03-24 | 斯蒂潘公司 | Alkyl sulfate/alkyl ether sulfate gypsum foaming agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050897A (en) * | 1989-09-14 | 1991-04-24 | 亨凯尔公司 | Low viscosity negatively charged ion and amphoteric surfactant compositions |
| CN1246461A (en) * | 1998-09-01 | 2000-03-08 | 花王株式会社 | Surfactant composite |
| CN1291637A (en) * | 1999-10-12 | 2001-04-18 | 花王株式会社 | Aqueous detergent composition |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6032676B2 (en) * | 1980-07-11 | 1985-07-29 | ライオン株式会社 | High concentration surfactant slurry |
| KR900016443A (en) * | 1989-04-26 | 1990-11-13 | 오노 알버어스 | Surface active composition and preparation method thereof |
| IL97805A (en) * | 1990-04-10 | 1995-01-24 | Albright & Wilson | Concentrated aqueous surfactant compositions |
| IN185580B (en) * | 1991-08-30 | 2001-03-03 | Albright & Wilson Uk Ltd | |
| JPH0593199A (en) * | 1991-10-02 | 1993-04-16 | Kao Corp | Aqueous solution or slurry of high-concentration surfactant and preparation thereof |
| JPH07157464A (en) * | 1993-12-06 | 1995-06-20 | Kao Corp | Method for treating aqueous slurry of polyoxypropylene alkyl ether sulfate |
| JP3556806B2 (en) * | 1996-07-24 | 2004-08-25 | サンスター株式会社 | Detergent composition |
| JPH11152497A (en) * | 1997-11-21 | 1999-06-08 | Lion Corp | Detergent composition for washing car |
| JP2002053457A (en) * | 2000-08-07 | 2002-02-19 | Pola Chem Ind Inc | Method for reducing irritation of anionic surfactant by polyhydric alcohol |
| JP4536297B2 (en) * | 2001-08-10 | 2010-09-01 | 花王株式会社 | Surfactant composition and method for producing the same |
| JP2004168951A (en) * | 2002-11-21 | 2004-06-17 | Kao Corp | Detergent composition |
| JP4198530B2 (en) * | 2003-05-30 | 2008-12-17 | 花王株式会社 | Liquid detergent composition |
| JP2005187411A (en) * | 2003-12-26 | 2005-07-14 | Lion Corp | Detergent composition for non-aerosol type foam discharge container |
| JP4629354B2 (en) * | 2004-02-25 | 2011-02-09 | 三洋化成工業株式会社 | Surfactant composition |
| JP4087393B2 (en) * | 2005-05-31 | 2008-05-21 | 第一工業製薬株式会社 | Fiber scouring agent composition |
-
2005
- 2005-06-08 JP JP2005167943A patent/JP4965821B2/en active Active
-
2006
- 2006-06-08 CN CN2006100917069A patent/CN1891195B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050897A (en) * | 1989-09-14 | 1991-04-24 | 亨凯尔公司 | Low viscosity negatively charged ion and amphoteric surfactant compositions |
| CN1246461A (en) * | 1998-09-01 | 2000-03-08 | 花王株式会社 | Surfactant composite |
| CN1291637A (en) * | 1999-10-12 | 2001-04-18 | 花王株式会社 | Aqueous detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4965821B2 (en) | 2012-07-04 |
| CN1891195A (en) | 2007-01-10 |
| JP2006342225A (en) | 2006-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1891195B (en) | Surfactant composition | |
| CN1827759B (en) | Surfactant composition | |
| JP5346574B2 (en) | Surfactant composition | |
| JP4965869B2 (en) | Surfactant composition | |
| JP4915720B2 (en) | Surfactant composition | |
| KR101423802B1 (en) | Detergent composition | |
| KR101394685B1 (en) | Cleansing composition | |
| JP5041894B2 (en) | Cleaning composition | |
| CN102836086B (en) | Thickening/foam boosting agent | |
| CN118078667A (en) | Compositions comprising zwitterionic alkyl-alkanoylamides and/or alkyl alkanoates | |
| CN103491936A (en) | Cleaning agent composition | |
| CN103517704A (en) | Cleaning agent composition | |
| CN101484127B (en) | Skin cleanser composition | |
| CN104717959B (en) | Composition comprising aoxidizing ester modified starch | |
| CN101415401B (en) | Cleansing composition | |
| JP2005336387A (en) | Detergent composition | |
| JP4448373B2 (en) | Cleaning composition | |
| JP2005206804A (en) | Detergent composition | |
| JP2008031162A (en) | Skin cleanser composition | |
| JP2005314615A (en) | Detergent composition | |
| JP4361052B2 (en) | Liquid detergent composition | |
| JP2006022116A (en) | Detergent composition | |
| KR101241791B1 (en) | Surfactant composition | |
| JP5123499B2 (en) | Surfactant mixture and cleaning composition | |
| JP2013082802A (en) | Detergent composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |