CN1876750A - High intensity elastic water-proofing material - Google Patents
High intensity elastic water-proofing material Download PDFInfo
- Publication number
- CN1876750A CN1876750A CN 200610091189 CN200610091189A CN1876750A CN 1876750 A CN1876750 A CN 1876750A CN 200610091189 CN200610091189 CN 200610091189 CN 200610091189 A CN200610091189 A CN 200610091189A CN 1876750 A CN1876750 A CN 1876750A
- Authority
- CN
- China
- Prior art keywords
- water
- high intensity
- proofing material
- elastic water
- intensity elastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention relates the elastomeric water-proofing material. The material comprises 30-40wt% acrylic ester emulsion, 12-22wt% silicon rubber, 0.5-1.0wt% polycarboxylate, 0.5-1.5wt% defoaming agent SP-3, 0.1-0.3wt% preservative agent LXE, 0.2-0.4wt% 40% potassium hydrate, 1.2-2.2wt% acrylic acid series polycarboxylic acids, 1.2-2.4wt% nanometer silica dioxide, 0.8-1.8wt% nanometer titanium dioxide, 26-45wt% heavy calcium carbonate and 3-5wt% water. The material has the advantages of improving the strength for extension, impermeability, ageing resistance and water resistance.
Description
Technical field
The invention belongs to the water-proof material technical field between roof waterproof for building, basement waterproofing and Kitchen hygiene, relate in particular to a kind of high intensity elastic water-proofing material with excellent waterproof effect with and preparation technology.
Background technology
The processing of waterproof adopts organic polymer material to carry out blade coating or brushing operation more between waterproof, basement waterproofing and the Kitchen hygiene of building roof at present.The material that is used for roof waterproof mainly is based on SBS (modified bituminous pitch coiled material), and its main shortcoming is that this material is the solvent-borne type material, and not environmental protection, elasticity are little, easy to crack, loss of properties on aging, construction wants heat seal bonding, and after the construction seam is arranged, and construction technology is more complicated also.Be used for the waterproof paint that indoor waterproof materials mainly is the Polyurethane material, its main drawback is not environmental protection, and such waterproof is the solvent borne two-pack, and production and use are polluted big, a little less than the water resistance, because product is a two-pack, so be not easy to transportation and storage.
Summary of the invention
The purpose of this invention is to provide a kind of high intensity elastic water-proofing material with high-strength elastic, tensile strength and good watertightness, it also has anti-aging and the excellent in water resistance energy simultaneously.
The technical solution used in the present invention is as follows:
A kind of high intensity elastic water-proofing material, it is characterized in that this high intensity elastic water-proofing material is made up of following materials of weight proportions: elastomeric propylene yogurt liquid 30～40, liquid silastic 12～22, polycarboxylate type dispersion agent 0.5～1.0, defoamer SP-3 0.5～1.5, sanitas LXE 0.1～0.3,40% potassium hydroxide solution 0.2～0.4, acrylic acid series polyocarboxy acid type thickening material 1.2～2.2, nanometer grade silica 1.2～2.4, Nano titanium dioxide 0.8～1.8, water-ground limestone 26～45, water 3～5.
This high intensity elastic water-proofing material is made up of following concrete materials of weight proportions:
Elastomeric propylene yogurt liquid 35, liquid silastic 17, polycarboxylate type dispersion agent 0.7, defoamer SP-30.9, sanitas LXE 0.2,40% potassium hydroxide solution 0.3, acrylic acid series polyocarboxy acid type thickening material 1.7, nanometer grade silica 1.8, Nano titanium dioxide 1.3, water-ground limestone 37, water 4.
It is the elastomeric propylene yogurt liquid of 2438M that described elastomeric propylene yogurt liquid is selected the trade mark for use.
It is the liquid silastic of AP-268 that the liquid silastic of stating is selected the trade mark for use.
Described polycarboxylate type dispersion agent can be selected from dispersion agent DA-01, dispersion agent 5040 or dispersion agent DA-40.
Described 40% potassium hydroxide solution can replace with 40% sodium hydroxide solution.
Described acrylic acid series polyocarboxy acid type thickening material is thickening material AT-06.
Described water-ground limestone is that the fineness of 300～400 purpose water-ground limestones and 10-20 weight part is that the above water-ground limestone of 600 orders is formed by the fineness of 16～25 weight parts.
The preparation technology of this high intensity elastic water-proofing material is characterized in that preparation process is as follows:
In water, drop into polycarboxylate type dispersion agent, defoamer SP-3, sanitas LXE, 40% potassium hydroxide solution and film coalescence aid alcohol ester-12, and to mix under 200～300 rev/mins the stirring velocity; Add elastomeric propylene yogurt liquid then, mix, add nanometer grade silica, Nano titanium dioxide and water-ground limestone again, under 600～800 rev/mins high-speed stirring condition, mix; And then the adjustment stirring velocity is 200～300 rev/mins, add liquid silastic to being uniformly dispersed, add acrylic acid series polyocarboxy acid type thickening material at last slowly and stir 10～15 minutes to thorough mixing, the emulsion that obtains is filtered, standing and reacting under vacuum condition obtains this high intensity elastic water-proofing material.
Employed each raw material of this efficient elastic water-proofing material is the commercially available prod among the present invention.Elastomeric propylene yogurt liquid is self-cross linking type pure acrylic acid emulsion, even still can keep its permanent elasticity and snappiness under 0 ℃ condition, it also has excellent mechanical stability in addition, can effectively stop moisture and carbonic acid gas.Liquid silastic is the versatility liquid silastic, and it has the good transparency and rebound resilience, anti-ozone and ultraviolet ray ageing, and high and low temperature resistance strong (60～250 ℃), chemical-resistant resistance, outstanding moistureproofness, mildew resistance, heat insulating ability is good, and electrical insulation capability is reliable.
Polycarboxylate type dispersion agent can effectively carry out homodisperse with mineral filler and pigment, and the improvement system is to the wettability of color stuffing, shorten milling time, stablize color stuffing dispersion system, prevent color stuffing flocculation, reduction loose colour, tendency such as grow dim.DA is a kind of dispersion agent that is widely used in water-borne coatings, is the polymer aqueous solution of polycarboxylate type, and it has splendid molecular weight and the molecular weight distribution that is rather narrow, and is in the emulsion paint manufacturing processed, fine with the consistency of whole coating system.Select for use the DA dispersion agent can obtain best system lacquer viscosity.After adding the DA dispersion agent, can improve the mud jacking efficient of coating, effectively suppress returning of color stuffing and slightly reach the viscosity knock-on that face is filled out slurry, thereby improve the stability in storage of coating.The dispersion agent that the present invention uses can be dispersion agent DA-01, dispersion agent 5040 or the dispersion agent DA-40 in the dispersion agent of commercial goods.Defoamer SP-3 belongs to the broad spectrum type paint antifoaming agent, has efficient froth breaking, the long-acting function that presses down bubble.
Sanitas LXE to phenylpropyl alcohol, vinegar third, pure third and other multipolymer fabulous preservative efficacy is arranged, and fabulous compatible conformability is arranged with organic and inorganics composition in these products.Sanitas LXE used in the present invention can be that the trade name that Rhom and Hass produces is the sanitas of Kathon LXE, also can be the sanitas LXE that Shenzhen Haichuan Company is produced.40% potassium hydroxide solution is used to regulate the pH value of this highly effective rainproof paint, and the pH value of rainproof paint finished product is adjusted between 7～9.Acrylic acid series polyocarboxy acid type thickening material AT-06 can give moderate levelling of coating system and sagging performance, has excellent compatibility with various Emulsion Adhesives, thickening efficiency height, good rheological property.Storage and stability in use through the latex after its thickening are all good, and can satisfy the requirement of the multiple form of construction work course of processing.Nanometer grade silica has higher surface activity, and it utilizes its surface effects, can effectively improve the hydrophobicity and the contamination resistance of paint film.Nano titanium dioxide can utilize its photocatalytic effect, thereby the anti-uv-ray that improves paint film improves the resistance to deterioration of coating with lacquer.
This high intensity elastic water-proofing material utilizes the combination of elastomeric propylene acid and liquid silastic, the tensile strength and the watertightness of product have been significantly improved, the adding of nanometer grade silica and Nano titanium dioxide simultaneously, a nearly step has been improved the ageing resistance and the water tolerance of water-proof material.
Embodiment
The present invention is further elaborated below in conjunction with embodiment.
Embodiment 1 presses each feed composition that column weight amount proportioning is got this high intensity elastic water-proofing material:
U.S. Rhom and Hass produces elastomeric propylene yogurt liquid 2438M 35kg, Shenzhen peace product organosilicon material production fluid body silicon rubber AP-268 17kg of company, Shenzhen Haichuan Company produces polycarboxylate type dispersion agent 50400.7kg, the Beijing Orient acrylic is produced defoamer SP-3 0.9kg, Shenzhen Haichuan Company produces sanitas LXE0.2kg, 40% potassium hydroxide solution 0.3kg, Shanghai Bo Dao auxiliary agent company produces acrylic acid series polyocarboxy acid type thickening material AT-06 1.7kg, Haihe River, Jiangsu nanosecond science and technology company limited produces nanometer grade silica 1.8kg, Nano titanium dioxide 1.3kg, fineness is 325 purpose water-ground limestone 21kg, fineness is 600 purpose water-ground limestone 16kg, tap water 4kg.
Tap water is added in the agitator, stirring velocity with 200～300 rev/mins stirs, in water, drop into polycarboxylate type dispersion agent, defoamer SP-3, sanitas LXE, 40% potassium hydroxide solution and film coalescence aid alcohol ester-12 in order successively, stir and mixed in 10 minutes.Add elastomeric propylene yogurt liquid then, stirred 5 minutes, add nanometer grade silica, Nano titanium dioxide and water-ground limestone again, under 600～800 rev/mins high-speed stirring condition, mixed 20 minutes, and then the adjustment stirring velocity is 200～300 rev/mins, add liquid silastic to being uniformly dispersed, dropwise addition of acrylic acid is that the polyocarboxy acid type thickening material stirs 10～15 minutes to thorough mixing slowly at last, the emulsion that obtains is filtered, standing and reacting is 24 hours under vacuum condition, obtains this high intensity elastic water-proofing material.
This high intensity elastic water-proofing material is the oyster white uniform liquid, this highly effective rainproof paint finished product is carried out every index detect, and testing conditions is 23 ± 2 ℃ of temperature, humidity 50 ± 5%.Detect data and see Table 1.
Every performance index of table 1 high intensity elastic water-proofing material and GB contrast information slip
| Test event | Unit | The value of limiting the quantity of | Test result | |
| Volatile organic compounds | g/L | ≤200 | 57 | |
| Free formaldehyde | g/kg | ≤0.1 | 0.018 | |
| Heavy metal | Dissoluble lead | mg/kg | ≤90 | 5.27 |
| Soluble cadmium | mg/kg | ≤75 | 1.63 | |
| Soluble chromium | mg/kg | ≤60 | 3.34 | |
| Soluble mercury | mg/kg | ≤60 | 0.87 | |
As can be seen from the above table, high intensity elastic water-proofing material provided by the invention is tested the every performance index that obtain according to standard GB 18582-2001 and is all satisfied this standard-required.
Elastomeric propylene yogurt liquid and liquid silastic are given this water-proof material with higher elasticity simultaneously, make this water-proof material not easy to crack in the process of using, through WATER REPELLENT between Kitchen hygiene is tested, be more than 5 times of polyurethane waterproofing coating the work-ing life of high intensity elastic water-proofing material provided by the invention.Through its elasticity and watertightness are detected obtain the results are shown in Table 2.
The elasticity of table 2 water-proof material of the present invention and watertightness detected result
| Test event | Technical requirements (II class) | Test result |
| Tensile strength, Mpa | ≥1.5 | 2.13 |
| Elongation at break, % | ≥300 | 324 |
| Low temperature flexibility (around φ 10mm rod) | -20 ℃, flawless | By |
| Watertightness (0.3Mpa, 0.5h) | Waterproof | By |
Embodiment 2 presses each feed composition that column weight amount proportioning is got this high intensity elastic water-proofing material:
U.S. Rhom and Hass produces elastomeric propylene yogurt liquid 2438M 30kg, Shenzhen peace product organosilicon material production fluid body silicon rubber AP-268 22kg of company, Shenzhen Haichuan Company produces polycarboxylate type dispersion agent DA-010.5kg, the Beijing Orient acrylic is produced defoamer SP-3 1.5kg, Shenzhen Haichuan Company produces sanitas LXE0.3kg, 40% sodium hydroxide solution 0.2kg, acrylic acid series polyocarboxy acid type thickening material AT-06 2.2kg, Haihe River, Jiangsu nanosecond science and technology company limited produces nanometer grade silica 1.2kg, Nano titanium dioxide 1.8kg, fineness is 400 purpose water-ground limestone 16kg, fineness is 600 purpose water-ground limestone 20kg, tap water 3kg.
Tap water is added in the agitator, stirring velocity with 200～300 rev/mins stirs, in water, drop into polycarboxylate type dispersion agent, defoamer SP-3, sanitas LXE, 40% sodium hydroxide solution and film coalescence aid alcohol ester-12 in order successively, stir and mixed in 10 minutes.Add elastomeric propylene yogurt liquid then, stirred 5 minutes, add nanometer grade silica, Nano titanium dioxide and water-ground limestone again, under 600～800 rev/mins high-speed stirring condition, mixed 20 minutes, and then the adjustment stirring velocity is 200～300 rev/mins, add liquid silastic to being uniformly dispersed, dropwise addition of acrylic acid is that the polyocarboxy acid type thickening material stirs 15 minutes to thorough mixing slowly at last, the emulsion that obtains is filtered, standing and reacting is 24 hours under vacuum condition, obtains this high intensity elastic water-proofing material.
This high intensity elastic water-proofing material is the oyster white uniform liquid, this highly effective rainproof paint finished product is carried out every index to be detected, the every performance index of gained all are far superior to national standard, utilize this high intensity elastic water-proofing material to carry out the test of buildings interlayer WATER REPELLENT, its ageing resistance and water tolerance are higher than existing polyurethane waterproof material far away.
Embodiment 3 presses each marketable material component that column weight amount proportioning is got this high intensity elastic water-proofing material:
Elastomeric propylene yogurt liquid 2438M 40kg, universal liquid silastic AP-268 12kg, polycarboxylate type dispersion agent DA-40 1.0kg, defoamer SP-3 0.5kg, sanitas LXE 0.1kg, 40% potassium hydroxide solution 0.4kg, acrylic acid series polyocarboxy acid type thickening material AT-06 1.2kg, nanometer grade silica 2.4kg, Nano titanium dioxide 0.8kg, fineness is 300 purpose water-ground limestone 25kg, fineness is 800 purpose water-ground limestone 10kg, tap water 5kg.
Tap water is added in the agitator, stirring velocity with 200～300 rev/mins stirs, in water, drop into polycarboxylate type dispersion agent, defoamer SP-3, sanitas LXE, 40% potassium hydroxide solution and film coalescence aid alcohol ester-12 in order successively, stir and mixed in 10 minutes.Add elastomeric propylene yogurt liquid then, stirred 5 minutes, add nanometer grade silica, Nano titanium dioxide and water-ground limestone again, under 600～800 rev/mins high-speed stirring condition, mixed 20 minutes, and then the adjustment stirring velocity is 200～300 rev/mins, add liquid silastic to being uniformly dispersed, dropwise addition of acrylic acid is that the polyocarboxy acid type thickening material stirs 15 minutes to thorough mixing slowly at last, the emulsion that obtains is filtered, standing and reacting is 24 hours under vacuum condition, obtains this high intensity elastic water-proofing material.
This high intensity elastic water-proofing material is the oyster white uniform liquid, this highly effective rainproof paint finished product is carried out every index to be detected, the every performance index of gained all are far superior to national standard, utilize this high intensity elastic water-proofing material to carry out the test of buildings interlayer WATER REPELLENT, its ageing resistance and water tolerance are higher than existing polyurethane waterproof material far away.
Claims (9)
1. high intensity elastic water-proofing material, it is characterized in that this high intensity elastic water-proofing material is made up of following materials of weight proportions: elastomeric propylene yogurt liquid 30～40, liquid silastic 12～22, polycarboxylate type dispersion agent 0.5～1.0, defoamer SP-3 0.5～1.5, sanitas LXE 0.1～0.3,40% potassium hydroxide solution 0.2～0.4, acrylic acid series polyocarboxy acid type thickening material 1.2～2.2, nanometer grade silica 1.2～2.4, Nano titanium dioxide 0.8～1.8, water-ground limestone 26～45, water 3～5.
2. high intensity elastic water-proofing material according to claim 1 is characterized in that this high intensity elastic water-proofing material is made up of following concrete materials of weight proportions:
Elastomeric propylene yogurt liquid 35, liquid silastic 17, polycarboxylate type dispersion agent 0.7, defoamer SP-30.9, sanitas LXE 0.2,40% potassium hydroxide solution 0.3, acrylic acid series polyocarboxy acid type thickening material 1.7, nanometer grade silica 1.8, Nano titanium dioxide 1.3, water-ground limestone 37, water 4.
3. high intensity elastic water-proofing material according to claim 1 is characterized in that it is the elastomeric propylene yogurt liquid of 2438M that described elastomeric propylene yogurt liquid is selected the trade mark for use.
4. high intensity elastic water-proofing material according to claim 1 is characterized in that it is the liquid silastic of AP-268 that described liquid silastic is selected the trade mark for use.
5. high intensity elastic water-proofing material according to claim 1 is characterized in that described polycarboxylate type dispersion agent can be selected from dispersion agent DA-01, dispersion agent 5040 or dispersion agent DA-40.
6. high intensity elastic water-proofing material according to claim 1 is characterized in that described 40% potassium hydroxide solution can replace with 40% sodium hydroxide solution.
7. high intensity elastic water-proofing material according to claim 1 is characterized in that described acrylic acid series polyocarboxy acid type thickening material is thickening material AT-06.
8. high intensity elastic water-proofing material according to claim 1 is characterized in that described water-ground limestone is that the fineness of 300～400 purpose water-ground limestones and 10-20 weight part is that the above water-ground limestone of 600 orders is formed by the fineness of 16～25 weight parts.
9. the preparation technology of the described high intensity elastic water-proofing material of claim 1 is characterized in that preparation process is as follows:
In water, drop into polycarboxylate type dispersion agent, defoamer SP-3, sanitas LXE, 40% potassium hydroxide solution and film coalescence aid alcohol ester-12, and to mix under 200～300 rev/mins the stirring velocity; Add elastomeric propylene yogurt liquid then, mix, add nanometer grade silica, Nano titanium dioxide and water-ground limestone again, under 600～800 rev/mins high-speed stirring condition, mix; And then the adjustment stirring velocity is 200～300 rev/mins, add liquid silastic to being uniformly dispersed, add acrylic acid series polyocarboxy acid type thickening material at last slowly and stir 10～15 minutes to thorough mixing, the emulsion that obtains is filtered, standing and reacting under vacuum condition obtains this high intensity elastic water-proofing material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100911895A CN100489049C (en) | 2006-07-06 | 2006-07-06 | Elastic water-proof material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100911895A CN100489049C (en) | 2006-07-06 | 2006-07-06 | Elastic water-proof material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1876750A true CN1876750A (en) | 2006-12-13 |
| CN100489049C CN100489049C (en) | 2009-05-20 |
Family
ID=37509312
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100911895A Expired - Fee Related CN100489049C (en) | 2006-07-06 | 2006-07-06 | Elastic water-proof material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100489049C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787260A (en) * | 2010-03-19 | 2010-07-28 | 江苏明昊新材料科技有限公司 | Water vapor permeance resistant silicone sealant and manufacture method thereof |
| CN101792653A (en) * | 2010-03-19 | 2010-08-04 | 江苏明昊新材料科技有限公司 | Sealant for acrylic ester modified solar photovoltaic module and preparation method thereof |
| CN102189598A (en) * | 2010-03-05 | 2011-09-21 | 上海耐齐建材有限公司 | Water-based non-absorptive interface agent |
| CN102278549A (en) * | 2011-06-03 | 2011-12-14 | 嘉兴市大成电气新材料有限公司 | Method for preparing heat-resisting elastic insulating pipe |
| CN104293178A (en) * | 2014-04-28 | 2015-01-21 | 南昌奥倍克纳米技术有限公司 | Long-lasting and anti-bacterial water-proofing agent for concrete product, and preparation method thereof |
| CN104830177A (en) * | 2015-05-21 | 2015-08-12 | 田福东 | Novel waterproof coating |
| CN107189300A (en) * | 2017-07-07 | 2017-09-22 | 昆山金有利新材料科技有限公司 | A kind of air-permeable elastic film and preparation method |
| CN108395654A (en) * | 2018-02-27 | 2018-08-14 | 合肥雅克丽新型建材有限公司 | A kind of flame retardant type waterproof material and preparation method thereof |
-
2006
- 2006-07-06 CN CNB2006100911895A patent/CN100489049C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102189598A (en) * | 2010-03-05 | 2011-09-21 | 上海耐齐建材有限公司 | Water-based non-absorptive interface agent |
| CN101787260A (en) * | 2010-03-19 | 2010-07-28 | 江苏明昊新材料科技有限公司 | Water vapor permeance resistant silicone sealant and manufacture method thereof |
| CN101792653A (en) * | 2010-03-19 | 2010-08-04 | 江苏明昊新材料科技有限公司 | Sealant for acrylic ester modified solar photovoltaic module and preparation method thereof |
| CN102278549A (en) * | 2011-06-03 | 2011-12-14 | 嘉兴市大成电气新材料有限公司 | Method for preparing heat-resisting elastic insulating pipe |
| CN102278549B (en) * | 2011-06-03 | 2013-04-24 | 嘉兴市大成电气新材料有限公司 | Method for preparing heat-resisting elastic insulating pipe |
| CN104293178A (en) * | 2014-04-28 | 2015-01-21 | 南昌奥倍克纳米技术有限公司 | Long-lasting and anti-bacterial water-proofing agent for concrete product, and preparation method thereof |
| CN104830177A (en) * | 2015-05-21 | 2015-08-12 | 田福东 | Novel waterproof coating |
| CN107189300A (en) * | 2017-07-07 | 2017-09-22 | 昆山金有利新材料科技有限公司 | A kind of air-permeable elastic film and preparation method |
| CN108395654A (en) * | 2018-02-27 | 2018-08-14 | 合肥雅克丽新型建材有限公司 | A kind of flame retardant type waterproof material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100489049C (en) | 2009-05-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100489049C (en) | Elastic water-proof material | |
| CN101550309B (en) | II-type polymer cement waterproofing coating modified by nano materials and preparation method thereof | |
| EP2603470B1 (en) | Coating agents for producing permanently flexible coatings | |
| EP2558541B1 (en) | Surface treatment of cementitious substrates | |
| CN111320440B (en) | Anticorrosive quick-drying cement-based waterproof coating and preparation method thereof | |
| CN1900187A (en) | Environment friendly emulsion paint | |
| CN110016289A (en) | A kind of high performance polymer modified bitumen water-repellent paint and preparation method thereof | |
| EP2619152B1 (en) | Coating agents for producing permanently flexible coatings | |
| CN108359285B (en) | High-performance green waterproof adhesive cement and preparation method thereof | |
| CN1876736A (en) | Highly effective rainproof paint | |
| CN110590229A (en) | Inorganic nano-silica hybrid bio-based acrylic real stone paint and preparation method and application thereof | |
| KR101916821B1 (en) | SBR modified acryl-urethane waterproof composition including water-soluble urethane polymer and preparation method thereof | |
| CN1876737A (en) | Gold brocade coating material | |
| WO2012038302A1 (en) | Coating agents for producing waterproof infrastructure coatings | |
| EP4214281A1 (en) | Kit for producing a coating compound | |
| CN1546583A (en) | Aqueous synthetic latex heat-insulated waterproof coating and its production method | |
| CN107880763B (en) | Waterproof environment-friendly coating and preparation method thereof | |
| CN114181556B (en) | Water-based EAU high-barrier thick film anticorrosive paint | |
| CN110938336A (en) | Ecological stone coating, preparation method and use method | |
| CN1226364C (en) | Waterproof coating material of macromolecule emulsion | |
| CN112521083B (en) | Anti-aging polymer cement waterproof coating and preparation method thereof | |
| CN108707375B (en) | Polymer cement-based waterproof coating and preparation method thereof | |
| CN109111796A (en) | A kind of metal Roof water-repellent paint and preparation method thereof | |
| CN114989728B (en) | Exposed water-based rubber asphalt waterproof coating and preparation method and application thereof | |
| CN110550907A (en) | Water-based modified polypropylene polymer cement-based waterproof slurry and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090520 Termination date: 20110706 |