CN1869130B - Acid dye mixture - Google Patents
Acid dye mixture Download PDFInfo
- Publication number
- CN1869130B CN1869130B CN200610088065A CN200610088065A CN1869130B CN 1869130 B CN1869130 B CN 1869130B CN 200610088065 A CN200610088065 A CN 200610088065A CN 200610088065 A CN200610088065 A CN 200610088065A CN 1869130 B CN1869130 B CN 1869130B
- Authority
- CN
- China
- Prior art keywords
- dyestuff
- dye mixture
- acid
- ammonium salt
- dyestuffs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000000980 acid dye Substances 0.000 title claims description 12
- 239000000975 dye Substances 0.000 claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims description 12
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 claims description 10
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- ZIUSSTSXXLLKKK-KOBPDPAPSA-N (1e,4z,6e)-5-hydroxy-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta-1,4,6-trien-3-one Chemical compound C1=C(O)C(OC)=CC(\C=C\C(\O)=C\C(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 ZIUSSTSXXLLKKK-KOBPDPAPSA-N 0.000 claims description 6
- VFLDPWHFBUODDF-FCXRPNKRSA-N Curcumin Natural products C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 claims description 6
- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 claims description 6
- 229920001353 Dextrin Polymers 0.000 claims description 5
- 239000004375 Dextrin Substances 0.000 claims description 5
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 235000019425 dextrin Nutrition 0.000 claims description 5
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 5
- IURGIPVDZKDLIX-UHFFFAOYSA-M [7-(diethylamino)phenoxazin-3-ylidene]-diethylazanium;chloride Chemical compound [Cl-].C1=CC(=[N+](CC)CC)C=C2OC3=CC(N(CC)CC)=CC=C3N=C21 IURGIPVDZKDLIX-UHFFFAOYSA-M 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- MHHGZCMFNNAVCQ-UHFFFAOYSA-M sodium;1-amino-4-[3-(2-hydroxyethylsulfamoyl)-4,5-dimethylanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].OCCNS(=O)(=O)C1=C(C)C(C)=CC(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)=C1 MHHGZCMFNNAVCQ-UHFFFAOYSA-M 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 abstract description 7
- 150000003839 salts Chemical class 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract 3
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 abstract 2
- 235000019233 fast yellow AB Nutrition 0.000 abstract 1
- 239000000047 product Substances 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 8
- 239000004677 Nylon Substances 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- -1 amine salt Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
The invention relates to an acidity dye mixture that includes three structures of dyes: one, the dye according with the general expression (I), or the metal salt, ammonium salt or organic ammonium salt according with the expression; two: the dye according with the general expression (II), or the metal salt, ammonium salt or organic ammonium salt according with the expression; three, C.I acid orange 67 or C.I acid yellow 242 in international dye index, or the metal salt, ammonium salt or organic ammonium salt of the two dyes. The invention could be used in the weak color coloration in polyamidefiber outside material and could satisfy general clothes outside material product quality index demand.
Description
Technical field
The present invention relates to a kind of dyestuff, be specifically related to a kind of acid dye mixture, this dyestuff is applied to the dyeing of light color in the polyamide fibre lining, can satisfy the index request of general garment material final product quality in the world.
Background technology
As everyone knows, the dyeing quality of weaving face fabric quality is directly relevant with the performance of dyestuff.At present, printing and dyeing mill is in the polyamide fibre lining during light-colored dyeing, and employed gray dyes is to mix the A-BL ashes of piecing together by C.I. Basic Blue 3 24, C.I. turmeric yellow 199, C.I. Xylene Red 337.Although this gray dyes has selected for use the reasonable acid blue of application performance, turmeric yellow and Xylene Red three-primary colours to mix assembly, actual dyeing quality that obtains and effect do not resemble people's imagination good.State gray dyes with regard to taking, its application performance: 2 grades of nylon staining, former state change 3 grades of 2 grades, light fastness, and variable color during heat setting type.And the index request of general in the world garment material final product quality is: nylon staining 3.5-4 level, former state change more than 3 grades, and light fastness is more than 3.5 grades and do not contain heavy metal and meet the ecological safety requirement.This shows, adopt above-mentioned gray dyes mixture, still do not reach international general requirement the polyamide fibre dyeing fabric.For this reason, how to improve above-mentioned dyeing quality has become the present invention to solve with index problem.
Summary of the invention
The invention provides a kind of acid dye mixture, its objective is will solve the polyamide fibre lining when middle light color (particularly grey) dyes, dyeing quality and index do not reach the general in the world problem that requires.
For achieving the above object, the technical solution used in the present invention is: a kind of acid dye mixture, this dye mixture mainly are made of the dyestuff mixing of following three kinds of structures:
One is for meeting dyestuff C.I. acid blue 277, C.I. acid blue 225, C.I. Basic Blue 3 50, the C.I. acid blue 264 of chemical general formula (I), and content is calculated as 3～90% of gross weight with the dyestuff dry product;
It is two for meeting dyestuff C.I. Xylene Red 336, the C.I. Xylene Red 361 of chemical general formula (II), and content is calculated as 3～90% of gross weight with the dyestuff dry product:
It three is C.I. von Muller's indicator 67 dyestuffs or C.I. turmeric yellow 242 dyestuffs in the international Colour Index, and content is calculated as 3～90% of gross weight with the dyestuff dry product.
Related content in the such scheme is explained as follows:
1, in the such scheme, the metal-salt of dyestuff specifically can refer to sodium salt, sylvite and the lithium salts of dyestuff; During the ammonium salt of dyestuff promptly refers to come with ammonia and acidic-group such as the sulfonic group on the dye structure and the salt that forms; During the organic amine salt of dyestuff promptly refers to come with organic amines such as ethamine, quadrol, thanomin, diethanolamine or trolamines and acidic-group such as the sulfonic group on the dye structure and the salt that forms.
2, in the such scheme, also comprise auxiliary agent 3～60% weight in the described dye mixture, described auxiliary agent is selected in the following material at least a:
Urea, its effect is a solubility promoter;
Dextrin, its effect is a weighting agent;
Tripoly phosphate sodium STPP, its effect is a solubility promoter.
The present invention considers the international garment material final product quality index request of general middle light color: nylon staining 3.5-4 level, former state changes more than 3 grades, light fastness reaches more than 3.5 grades and does not contain heavy metal and meet the ecological safety requirement, consider the needs of dyeing and finishing technology typing arrangement workshop section in addition, through analytical test repeatedly, success research has been allocated a kind of grey acid dye mixture, the more employed related dye performance of this dye mixture obviously improves, under ISO GB testing method, record: nylon staining 3.5-4 level, former state changes 3 grades, 4 grades of light fastnesss, the thermo-sensitivity excellence can obviously improve the quality of garment material in application.
Embodiment
Below in conjunction with embodiment the present invention is further described:
Embodiment one: a kind of grey acid dye mixture and preparation thereof
1, prescription
Form content
(1) meets C.I. acid blue 277 dyestuffs 36% of chemical general formula (I);
(2) meet C.I. Xylene Red 336 dyestuffs 10% of chemical general formula (II);
(3) C.I. turmeric yellow 242 dyestuffs 16%;
(4) urea 10%;
(5) dextrin 28%.
Above-mentioned content calculates with the weight percentage of dyestuff dry product.
2, dye mixture preparation
By prescription each composition is closed in aqueous solution state downward modulation compounding, obtain finished product through spraying drying.
Embodiment two: a kind of grey acid dye mixture and preparation thereof
1, prescription
Form content
(1) meets C.I. acid blue 225 dyestuffs 40% of chemical general formula (I);
(2) meet C.I. Xylene Red 336 dyestuffs 15% of chemical general formula (II);
(3) C.I. von Muller's indicator 67 dyestuffs 10%;
(4) urea 15%;
(5) tripoly phosphate sodium STPP 20%.
Above-mentioned content calculates with the weight percentage of dyestuff dry product.
2, dye mixture preparation
By prescription each composition is closed in aqueous solution state downward modulation compounding, obtain finished product through spraying drying.
Embodiment three: a kind of grey acid dye mixture and preparation thereof
1, prescription
Form content
(1) meets C.I. Basic Blue 3 50 dyestuffs 50% of chemical general formula (I);
(2) meet C.I. Xylene Red 361 dyestuffs 10% of chemical general formula (II);
(3) C.I. von Muller's indicator 67 dyestuffs 15%;
(4) dextrin 15%;
(5) tripoly phosphate sodium STPP 10%.
Above-mentioned content calculates with the weight percentage of dyestuff dry product.
2, dye mixture preparation
By prescription each composition is closed in aqueous solution state downward modulation compounding, obtain finished product through spraying drying.
Embodiment four: a kind of grey acid dye mixture and preparation thereof
1, prescription
Form content
(1) meets C.I. acid blue 264 dyestuffs 55% of chemical general formula (I);
(2) meet C.I. Xylene Red 361 dyestuffs 10% of chemical general formula (II);
(3) C.I. turmeric yellow 242 dyestuffs 13%;
(4) urea 8%;
(5) dextrin 9%;
(5) tripoly phosphate sodium STPP 5%.
Above-mentioned content calculates with the weight percentage of dyestuff dry product.
2, dye mixture preparation
By prescription each composition is closed in aqueous solution state downward modulation compounding, obtain finished product through spraying drying.
The foregoing description only is explanation technical conceive of the present invention and characteristics, and its purpose is to allow the personage who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (2)
1. acid dye mixture is characterized in that: this dye mixture is mainly mixed by the dyestuff of following three kinds of structures and constitutes:
One is for meeting dyestuff C.I. acid blue 277, C.I. acid blue 225, C.I. Basic Blue 3 50, the C.I. acid blue 264 of chemical general formula (I), and content is calculated as 3～90% of gross weight with the dyestuff dry product;
It is two for meeting dyestuff C.I. Xylene Red 336, the C.I. Xylene Red 361 of chemical general formula (II), and content is calculated as 3～90% of gross weight with the dyestuff dry product:
It three is C.I. von Muller's indicator 67 dyestuffs or C.I. turmeric yellow 242 dyestuffs in the international Colour Index, and content is calculated as 3～90% of gross weight with the dyestuff dry product.
2. acid dye mixture according to claim 1 is characterized in that: also comprise auxiliary agent 3～60% weight in the described dye mixture, described auxiliary agent is selected in the following material at least a:
Urea;
Dextrin;
Tripoly phosphate sodium STPP.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610088065A CN1869130B (en) | 2006-06-20 | 2006-06-20 | Acid dye mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610088065A CN1869130B (en) | 2006-06-20 | 2006-06-20 | Acid dye mixture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1869130A CN1869130A (en) | 2006-11-29 |
| CN1869130B true CN1869130B (en) | 2010-05-12 |
Family
ID=37442914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610088065A Expired - Fee Related CN1869130B (en) | 2006-06-20 | 2006-06-20 | Acid dye mixture |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1869130B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI659138B (en) * | 2017-10-25 | 2019-05-11 | Everlight Chemical Industrial Corporation | Acid dye composition and use thereof on dying nylon texture |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462293A (en) * | 2015-12-18 | 2016-04-06 | 安徽宜民服饰有限公司 | Acid dye |
| CN105462291A (en) * | 2015-12-18 | 2016-04-06 | 安徽宜民服饰有限公司 | Bacteriostatic acid dye |
| CN105968876A (en) * | 2016-06-30 | 2016-09-28 | 叶文佳 | Compound type reactive dye formula |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0083299A1 (en) * | 1981-12-29 | 1983-07-06 | Ciba-Geigy Ag | Process for trichromatic dyeing or printing |
| CN1136056A (en) * | 1994-12-21 | 1996-11-20 | 希巴-盖吉股份公司 | Dye mixtures comprising 1:2 chromium complex dyes, and 1:2 chromium complex dyes |
| US6063137A (en) * | 1997-12-11 | 2000-05-16 | Ciba Specialty Chemicals Corporation | Process for dyeing or printing and novel reactive dyes |
| CN1594444A (en) * | 2004-06-18 | 2005-03-16 | 吴江市绿洲染料化工有限公司 | Dye mixtures |
| CN1626582A (en) * | 2003-12-11 | 2005-06-15 | 美国永光公司 | Dye compsns. and its applications |
| CN1667051A (en) * | 2005-03-30 | 2005-09-14 | 吴江市绿洲染料化工有限公司 | Disperse dye mixtures |
-
2006
- 2006-06-20 CN CN200610088065A patent/CN1869130B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0083299A1 (en) * | 1981-12-29 | 1983-07-06 | Ciba-Geigy Ag | Process for trichromatic dyeing or printing |
| CN1136056A (en) * | 1994-12-21 | 1996-11-20 | 希巴-盖吉股份公司 | Dye mixtures comprising 1:2 chromium complex dyes, and 1:2 chromium complex dyes |
| US6063137A (en) * | 1997-12-11 | 2000-05-16 | Ciba Specialty Chemicals Corporation | Process for dyeing or printing and novel reactive dyes |
| CN1626582A (en) * | 2003-12-11 | 2005-06-15 | 美国永光公司 | Dye compsns. and its applications |
| CN1594444A (en) * | 2004-06-18 | 2005-03-16 | 吴江市绿洲染料化工有限公司 | Dye mixtures |
| CN1667051A (en) * | 2005-03-30 | 2005-09-14 | 吴江市绿洲染料化工有限公司 | Disperse dye mixtures |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI659138B (en) * | 2017-10-25 | 2019-05-11 | Everlight Chemical Industrial Corporation | Acid dye composition and use thereof on dying nylon texture |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1869130A (en) | 2006-11-29 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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Granted publication date: 20100512 |