CN1861730A - Rod shaped single parked epoxy adhesive and preparation process - Google Patents
Rod shaped single parked epoxy adhesive and preparation process Download PDFInfo
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- CN1861730A CN1861730A CN 200610070990 CN200610070990A CN1861730A CN 1861730 A CN1861730 A CN 1861730A CN 200610070990 CN200610070990 CN 200610070990 CN 200610070990 A CN200610070990 A CN 200610070990A CN 1861730 A CN1861730 A CN 1861730A
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- 229920006332 epoxy adhesive Polymers 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000000843 powder Substances 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- 238000011049 filling Methods 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 12
- 239000000853 adhesive Substances 0.000 claims abstract description 6
- 230000001070 adhesive effect Effects 0.000 claims abstract description 6
- 229920001558 organosilicon polymer Polymers 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 54
- 239000000377 silicon dioxide Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000004593 Epoxy Substances 0.000 claims description 15
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 239000007822 coupling agent Substances 0.000 claims description 12
- 229920000459 Nitrile rubber Polymers 0.000 claims description 8
- 239000004327 boric acid Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- -1 mercaptan compound Chemical class 0.000 claims description 8
- 229940059574 pentaerithrityl Drugs 0.000 claims description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical class CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 5
- 238000007872 degassing Methods 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000003981 vehicle Substances 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 3
- 125000005619 boric acid group Chemical group 0.000 claims 1
- 229920002050 silicone resin Polymers 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 150000001450 anions Chemical class 0.000 abstract description 2
- 239000000975 dye Substances 0.000 abstract 2
- 239000000546 pharmaceutical excipient Substances 0.000 abstract 2
- 239000011162 core material Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 229920000768 polyamine Polymers 0.000 description 6
- 150000003512 tertiary amines Chemical class 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001404 mediated effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WGRQANOPCQRCME-PMACEKPBSA-N teneligliptin Chemical compound O=C([C@H]1NC[C@H](C1)N1CCN(CC1)C1=CC(=NN1C=1C=CC=CC=1)C)N1CCSC1 WGRQANOPCQRCME-PMACEKPBSA-N 0.000 description 2
- FWQHRZXEQNUCSY-UHFFFAOYSA-N tert-butyl N-[2-(ethoxycarbonylamino)-5-[(4-fluorophenyl)methyl-prop-2-ynylamino]phenyl]carbamate Chemical compound CCOC(=O)NC1=C(C=C(C=C1)N(CC#C)CC2=CC=C(C=C2)F)NC(=O)OC(C)(C)C FWQHRZXEQNUCSY-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QBTROWHSMGZXCV-RQURQNPSSA-N (6r,7r)-1-[(4s,5r)-4-acetyloxy-5-methyl-3-methylidene-6-phenylhexyl]-4,7-dihydroxy-6-(11-phenoxyundecoxy)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylic acid Chemical compound C([C@@H](C)[C@H](OC(C)=O)C(=C)CCC12[C@@H]([C@@H](OCCCCCCCCCCCOC=3C=CC=CC=3)C(O1)(C(O)=O)C(O)(C(O2)C(O)=O)C(O)=O)O)C1=CC=CC=C1 QBTROWHSMGZXCV-RQURQNPSSA-N 0.000 description 1
- 241000283730 Bos primigenius Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229940125761 Compound 6g Drugs 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a rod one package epoxy adhesive. The A component of the adhesive is made up of the epikote 25-35%, the reactive diluent 0-5%, the elasticizer 1-4%, the filling dyestuff 50-64%, the excipient 3-7%; the B component is made up of the firming agent 26-34%, the accelerator 1.5-4%, the resin acceptor 1-3%, the filling dyestuff 52-64%, the excipient 3-8%; the separant is made up of the organosiliconpolymer 75-83%, the glass scale powder 15-22%, the anion trapper 1.5-3%. The A component is made to sheet and the B is made to cylindrical core material, after the surface of the B is covered with the separant, the B component is rolled by the A to form the product. The adhesive can solidify quickly in the room temperature.
Description
Technical field
The present invention relates to a kind of bar-shaped single packaging adhesive, relate in particular to the response type epoxy adhesive that a kind of semi-solid, two component are separated by separant.
Background technology
Characteristics such as epoxy adhesive possesses the bonding strength height, and ageing-resistant performance is good, and shrinking percentage is little, and is applied widely are used in national economy all departments and people's daily life widely, and its description has reached thousands of kinds.Rod shaped single parked epoxy adhesive is fast because of its curing speed, good mechanical property, easy to usely also arises at the historic moment.This tackiness agent, Fixmater metal magic steel series as the rapid-result series of U.S. Polymeric systems inc (rapid-result steel, rapid-result aluminium etc.), happy safe (Nordbak) company, Holland " wild ox " repairs clay steel series and has sold for some time in the China's Mainland, and good product quality, price are very expensive.Through looking into, this series products is not applied for People's Republic of China's patent of invention, does not reveal the technology relevant with product.
The preparation rod shaped single parked epoxy adhesive, A component and B component are made circular top layer and cylindric sandwich layer respectively, also have and make two semi-cylindrical situations respectively, both are combined packing tightly, the product shelf life general requirement is more than 2 years, thereby the necessary problem that solves formability, the effective isolation between two components, the mixed rapid reaction curing of two components and the bonding strength of A, B two components.
Summary of the invention
The objective of the invention is to address the above problem, provide a kind of and be easy to shape, shelf lives length, room temperature fast-curing, bonding quality is good, cost is moderate rod shaped single parked epoxy adhesive and preparation method thereof, concrete technical scheme is as follows: rod shaped single parked epoxy adhesive is made up of the separant that constitutes between bar-shaped annular A component and cylindrical sandwich layer and A, B two components.The A component is made of raw material epoxy resin, reactive thinner, toughner, filler, pigment, vehicle.Resins, epoxy selects E-51, E-44 type Resins, epoxy or their mixture, reactive thinner to select the butylglycidyl ether compounds for use, to adjust the viscosity of A component, consider that the filling material amount is bigger, the character of Resins, epoxy own is more crisp, make toughner so add a certain amount of liquid nitrile rubber, liquid nitrile rubber preferably and Resins, epoxy be used further to the preparation of A component under certain condition after reacting.Do not select calcium oxide and carbonate in filler, the pigment for use, and select the more stable silica powder of chemical property, talcum powder, titanium dioxide etc. for use, prevent the stability that unnecessary reaction influences quality product.Gas-phase silica can improve the cohesive strength of tackiness agent, can also give tackiness agent certain shape, so select it to make vehicle.The B component is made up of solidifying agent, promotor, filling material, coupling agent, vehicle.For satisfying tackiness agent room temperature, the quick-setting requirement of low temperature (about 5 ℃), solidifying agent uses the mixture of low molecular polyamides, modified fat amine polyamines, sulfur alcohol compound, reaches reactive behavior, the unification of viscosity, cost many index.Promotor is selected tertiary amine for use at sulfur alcohol compound, makes the solidifying agent at low temperatures can rapid reaction.Filler is selected silica powder, talcum powder, titanium dioxide for use, and pigment is selected Graphite Powder 99, phthalocyanine for use, and coupling agent is selected KH-550, KH-560 silicoorganic compound for use, and vehicle is selected gas-phase silica for use.
Separant between A, B two components is vital for the purpose of the present invention.For guaranteeing adhesive bar steady quality in the shelf lives, from physics, chemical two aspect design isolated agent.The separant main body is selected the medium viscosity methyl-silicone oil for use, adding a small amount of glass flake strengthens stifled every effect, the glass flake specification is the 100-500 order, purpose is to stop A component, B component to interpenetrate, add boric acid, tetramethylolmethane combination or phosphine piperazine compound, Resorcinol combination in the separant main part simultaneously, catch the anion active group that goes out, stop between A component, the B component curing reaction takes place.
The present invention also provides a kind of preparation method of rod shaped single parked epoxy adhesive.A component starting material dispersing and mixing in the equipment with powerful kneading ability obtains white mud shape thing, is pressed into certain thickness sheet material again in molding device.The B component materials is dispersing and mixing in the equipment with powerful kneading ability also, adds small amounts of pigment and obtains respective color such as grey, black, suppresses and cut into the right cylinder of certain diameter again through screw extrusion press, and at the even coating in its surface separant.On custom-built machine, the core that sheet material that the A component is made and B component make rolls into core and is bar-shaped epoxy adhesive in interior, sheet material profile outside, this tackiness agent is two components, also is simultaneously single packing.
A component among the present invention, B component, separant weight percentage separately are composed as follows:
A component: Resins, epoxy 25-35%
Reactive thinner 0-5%
Toughner 1-4%
Filling material 50-64%
Vehicle 3-7%
B component: solidifying agent 26-34%
Promotor 1.5-4%
Coupling agent 1-3%
Filling material 52-64%
Vehicle 3-8%
Separant: organosilicon polymer 75-83%
Glass flake powder 15-22%
Boric acid and tetramethylolmethane combination or phosphine piperazine compound, Resorcinol combination 1.5-3.0%
These three components raw material weight percentage ratio sum separately is 100%.
The weight percentage of A component, B component, separant is respectively 42-55%, 42-55%, 0.1-5% in the tackiness agent, and three's weight percentage sum is 100%.
Accompanying drawing
The invention provides a kind of rod shaped single parked epoxy adhesive structural representation, see Fig. 1
1, A component
2, separant
3, B component
Embodiment
Implementation method of the present invention is described below
Take by weighing Resins, epoxy E-51 25g, E-44 8g, butylglycidyl ether 1g puts into miniature kneader, transmission operation adds liquid nitrile rubber 2g respectively, silica powder 26g, talcum powder 28g, titanium dioxide 7g, gas-phase silica 4g, mediated 30 minutes, vacuumize degassing 15 minutes changes mud shape thing over to tabletting machine, make thickness 2mm layer material, be cut into long 90mm again, wide 88mm material piece, weigh 28g, be the A component of rod shaped single parked epoxy adhesive.
Take by weighing Versamid 650 12g, modified aliphatic polyamines 8g, sulfur alcohol compound 10g, put into miniature kneader, transmission operation adds silica powder 22.8g successively, talcum powder 21g, greenstone powder 8g, promotor tertiary amines 3g, KH-550 organo-silicon coupling agent 1g, Graphite Powder 99 10g, pthalocyanine blue 0.2g, gas-phase silica 4g, mediated vacuumize degassing 15 minutes 30 minutes.Above-mentioned material is sent into screw extruder, from squeezing head ejection φ 14.9mmB component charge bar.Bar is cut into the long right cylinder of 90mm, weighs 28g, be the B component of rod shaped single parked epoxy adhesive.
Take by weighing medium-viscosity silicone oil 80g, add 18g glass flake powder, 2g boric acid and tetramethylolmethane mixture, thorough mixing promptly obtains separant of the present invention.
On operator's console, complete plastics film, and brushing separant, cylindrical shape B component is placed on rolling 3-5 week on the film, make its surface evenly apply separant, the B component that will apply separant then places the correct position of A component material piece, is axle with the B component, with A component volume thereon, obtain bar-shaped single pack epoxy resin tackiness agent of long 90mm, diameter 21-22mm, heavy 57g.
With the long sample (heavily about 10g) of the about 2em of scissors clip, about 1 minute of finger kneading, from color whether unanimity whether evenly can find out, make stretching, compression, tensile shear strength test sample immediately.Sample solidified 16 hours under 23 ℃.The strength test method is seen GB/T6329-1996 " mensuration of tackiness agent opposite joint tensile strength " respectively, GB11177-89 " inorganic adhesive socket compression shear strength test method ", GB/T7124-86 " tackiness agent tensile shear strength measuring method (metal-metal) ".Press GB/T7751-87 " tackiness agent storage period mensuration " simultaneously, measure the shelf lives of tackiness agent.
The prescription of A component is Resins, epoxy E-51 22g, E-44 10g, butylglycidyl ether 2g, liquid nitrile rubber 2.5g, silica powder 20g, talcum powder 36g, titanium dioxide 6g, gas-phase silica 3.5g.
The prescription of B component is Versamid 65014g, modified aliphatic polyamines 6g, sulfur alcohol compound 8g, silica powder 18g, talcum powder 24g, greenstone powder 8g, promotor tertiary amines 3g, KH-550 organo-silicon coupling agent 1.2g, Graphite Powder 99 10g, pthalocyanine blue 0.2g, gas-phase silica 3g.
The separant prescription is medium-viscosity silicone oil 78g, glass flake powder 20g, 2.5g boric acid and tetramethylolmethane mixture.
All the other conditions are with embodiment 1.
The prescription of A component is Resins, epoxy E-51 28g, E-44 7g, butylglycidyl ether 3g, liquid nitrile rubber 3.5g, silica powder 18g, talcum powder 40g, titanium dioxide 5g, gas-phase silica 4.5g.
The prescription of B component is Versamid 650 10g, modified aliphatic polyamines 12g, sulfur alcohol compound 6g, silica powder 26g, talcum powder 15g, greenstone powder 12g, promotor tertiary amines 2.5g, KH-550 organo-silicon coupling agent 1.8g, Graphite Powder 99 8g, pthalocyanine blue 0.2g, gas-phase silica 6g.
The separant prescription is medium-viscosity silicone oil 82g, glass flake powder 16g, 1.8g boric acid and tetramethylolmethane mixture.
All the other conditions are with embodiment 1.
Embodiment 4
The prescription of A component is Resins, epoxy E-51 20g, E-44 12g, butylglycidyl ether 4g, liquid nitrile rubber 3g, silica powder 26g, talcum powder 20g, titanium dioxide 8g, gas-phase silica 5.5g.
The prescription of B component is Versamid 650 8g, modified aliphatic polyamines 14g, sulfur alcohol compound 10g, silica powder 12g, talcum powder 30g, greenstone powder 14g, promotor tertiary amines 2.5g, KH-550 organo-silicon coupling agent 2.1g, Graphite Powder 99 6g, pthalocyanine blue 0.2g, gas-phase silica 7g.
The separant prescription is medium-viscosity silicone oil 76g, glass flake powder 21g, 1.8g boric acid and tetramethylolmethane mixture.
All the other conditions are with embodiment 1.
Embodiment 5
The prescription of A component is Resins, epoxy E-51 26g, E-44 8g, butylglycidyl ether 3.5g, liquid nitrile rubber 1.5g, silica powder 15g, talcum powder 30g, titanium dioxide 10g, gas-phase silica 6g.
The prescription of B component is Versamid 650 16g, modified aliphatic polyamines 6g, sulfur alcohol compound 8g, silica powder 14g, talcum powder 25g, greenstone powder 11g, promotor tertiary amines 3.5g, KH-550 organo-silicon coupling agent 2.8g, Graphite Powder 99 9g, pthalocyanine blue 0.2g, gas-phase silica 5g.
The separant prescription is medium-viscosity silicone oil 81g, glass flake powder 17g, 2.2g boric acid and tetramethylolmethane mixture.
All the other conditions are with embodiment 1.
The embodiment sample testing the results are shown in following table:
Claims (3)
1, a kind of rod shaped single parked epoxy adhesive comprises the A component of being made up of Resins, epoxy, reactive thinner, toughner, filling material, vehicle; The B component of forming by solidifying agent, promotor, filling material, coupling agent, vehicle; Form by the separant that silicone resin, glass powder, anionic trapping agent are formed, it is characterized in that:
1. the A component is the Resins, epoxy of 25-35% by weight percentage, the 0-5% reactive thinner, and 1-4% toughner, the 50-64% filling material, the 3-7% vehicle is formed, and the weight percentage sum of various raw materials is 100%;
2. the B component is by the 26-34% solidifying agent, 1.5-4% promotor, and the 1-3% coupling agent, the 52-64% filling material, the 3-8% vehicle is formed, and the weight percentage sum of various raw materials is 100%;
3. separant is by the 75-83% organosilicon polymer, 15-22% glass flake powder, and the 1.5-3% anionic trapping agent is formed, and the weight percentage sum of various raw materials is 100%;
4. the weight percentage of A component, B component, separant is respectively 42-55%, 42-55%, 0.1-5% in the tackiness agent, and three's weight percentage sum is 100%
2, rod shaped single parked epoxy adhesive according to claim 1, it is characterized in that the Resins, epoxy in the A component is E-44 type, E-51 type Resins, epoxy or their mixture, reactive thinner is the butylglycidyl ether compounds, toughner is liquid nitrile rubber, filling material is silica powder, talcum powder, titanium dioxide and their mixture, and vehicle is a gas-phase silica; Solidifying agent in the B component is low molecular polyamides, modified fatty amine, mercaptan compound, their mixture preferably, promotor is tertiary amine compounds, filling material is silica powder, talcum powder, Graphite Powder 99, phthalocyanine and their mixture, coupling agent is KH-550, KH-560 silicoorganic compound, vehicle are gas-phase silicas; Organosilicon polymer is the medium viscosity methyl-silicone oil in the separant, and the glass flake fineness of powder is in 100-500 order scope, and anionic trapping agent is boric acid, tetramethylolmethane combination or phosphine piperazine compound, Resorcinol combination.
3, a kind of bar-shaped single pack epoxy resin adhesive preparation method is characterized in that may further comprise the steps:
1. Resins, epoxy, reactive thinner, toughner, filling material, vehicle composition mix through kneader, and the degassing is handled, and is pressed into sheet material through forming mill again;
2. solidifying agent, promotor, coupling agent, filling material, vehicle are handled through the kneader degassing that stirs, and are squeezed into bar-shaped and cut into the right cylinder core through screw extruder again;
3. after the coating of the periphery in the 2. separant, with 1. made sheet material the right cylinder core is rolled, acquisition right cylinder core is the B component, and cylindric top layer is bar-shaped single pack epoxy resin tackiness agent of the certain size of A component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100709901A CN100497513C (en) | 2006-03-29 | 2006-03-29 | Rod shaped single parked epoxy adhesive and preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100709901A CN100497513C (en) | 2006-03-29 | 2006-03-29 | Rod shaped single parked epoxy adhesive and preparation process |
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| Publication Number | Publication Date |
|---|---|
| CN1861730A true CN1861730A (en) | 2006-11-15 |
| CN100497513C CN100497513C (en) | 2009-06-10 |
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| CNB2006100709901A Expired - Fee Related CN100497513C (en) | 2006-03-29 | 2006-03-29 | Rod shaped single parked epoxy adhesive and preparation process |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101948667A (en) * | 2010-10-13 | 2011-01-19 | 湖南神力铃胶粘剂制造有限公司 | Adhesive for compounding marble veneer with base material and preparation method thereof |
| CN102618199A (en) * | 2011-01-30 | 2012-08-01 | 厦门潞邦材料科技有限公司 | Anti-cracking green adhesive for ceiling decoration seams |
| CN103184022A (en) * | 2011-12-30 | 2013-07-03 | 汉高股份有限公司 | Adhesive composition used for temporary adhesion in wafer preparation |
| CN106497489A (en) * | 2016-10-26 | 2017-03-15 | 沈阳万合胶业股份有限公司 | A kind of porous type pressure sensitive adhesive and preparation method thereof |
| CN110325589A (en) * | 2017-02-28 | 2019-10-11 | 味之素株式会社 | Resin combination |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85100135A (en) * | 1985-04-01 | 1986-08-13 | 清华大学 | The intermediate temperature setting high strength epoxy adhesive |
| CN100341969C (en) * | 2004-01-02 | 2007-10-10 | 湖南神力实业有限公司 | Fast-setting two-component epoxy adhesive and its preparing method |
-
2006
- 2006-03-29 CN CNB2006100709901A patent/CN100497513C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948667A (en) * | 2010-10-13 | 2011-01-19 | 湖南神力铃胶粘剂制造有限公司 | Adhesive for compounding marble veneer with base material and preparation method thereof |
| CN101948667B (en) * | 2010-10-13 | 2012-10-03 | 湖南神力铃胶粘剂制造有限公司 | Adhesive for compounding marble veneer with base material and preparation method thereof |
| CN102618199A (en) * | 2011-01-30 | 2012-08-01 | 厦门潞邦材料科技有限公司 | Anti-cracking green adhesive for ceiling decoration seams |
| CN102618199B (en) * | 2011-01-30 | 2013-11-06 | 厦门潞邦材料科技有限公司 | Anti-cracking green adhesive for ceiling decoration seams |
| CN103184022A (en) * | 2011-12-30 | 2013-07-03 | 汉高股份有限公司 | Adhesive composition used for temporary adhesion in wafer preparation |
| CN106497489A (en) * | 2016-10-26 | 2017-03-15 | 沈阳万合胶业股份有限公司 | A kind of porous type pressure sensitive adhesive and preparation method thereof |
| CN110325589A (en) * | 2017-02-28 | 2019-10-11 | 味之素株式会社 | Resin combination |
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| CN100497513C (en) | 2009-06-10 |
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Assignee: HUNAN YIXIANG TECHNOLOGY Corp.,Ltd. Assignor: Hunan Shenli Industrial Co.,Ltd. Contract record no.: 2011430000169 Denomination of invention: Rod shaped single parked epoxy adhesive and preparation process Granted publication date: 20090610 License type: Exclusive License Open date: 20061115 Record date: 20110909 |
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