CN1807550A - Water-loss reducer of soil and its preparation method - Google Patents

Water-loss reducer of soil and its preparation method Download PDF

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Publication number
CN1807550A
CN1807550A CN 200610003493 CN200610003493A CN1807550A CN 1807550 A CN1807550 A CN 1807550A CN 200610003493 CN200610003493 CN 200610003493 CN 200610003493 A CN200610003493 A CN 200610003493A CN 1807550 A CN1807550 A CN 1807550A
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China
Prior art keywords
water
weight part
soil
loss reducer
weight
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CN 200610003493
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CN100398625C (en
Inventor
杨贵成
郭华荣
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Che Delong
PENG SHUNSHENG
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Che Delong
PENG SHUNSHENG
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Priority to CNB200610003493XA priority Critical patent/CN100398625C/en
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Abstract

The invention discloses a soil water-loss reducer and process for preparation, wherein the water-loss reducer comprises 60-80 weight portions of acrylic acid, 10-15 weight portions of sodium hydroxide, 1-5 weight portions of potassium persulfate, 1-5 weight portions of borax, 5-20 weight portions of starch, 1-5 weight portions of glycocoll, and 10-30 weight portions of conventional fertilizer.

Description

Water-loss reducer of soil and preparation method thereof
Technical field:
The present invention relates to a kind of water-loss reducer of soil, relate to a kind of water-loss reducer of soil and preparation method thereof more specifically.
Background technology:
1,500,000,000 mu of China's total area under cultivations, wherein the nonirrigated farmland area is 5.7 hundred million mu, accounts for 38% of national cultivated area, also have large-area deserted mountain in addition, xerocline afforestation district is because rainfall amount is on the low side, and distributed pole is inhomogeneous, directly affects the raising of agriculture production and the surviving rate of afforestation trees; In addition, China is the country that a water resources lacks, promptly enable the paddy field irrigated, also often suffer from no anti-ly, cause the underproduction because of insufficient water sources, the solution route of the problems referred to above removes develop actively water conservancy construction cause, outside the water saving irrigation agricultural, utilize new high-tech product to solve drought resisting, water conservation, protecting fertile problem, is one of effective way of development agricultural and forestry production.
Water-holding agent at farming, forestry such as water-saving moisturizing, soil improvement, seed pelleting, nursery stock is dipped in aspects such as root, preserving fruit and vegetable utilizing that boundless application prospect is arranged.Because the cost of general water-holding agent is higher, and salt tolerant alkalescence and specific aim are relatively poor, have limited its applying at aspects such as agricultural, gardening.
The inventor discloses a kind of water-loss reducer of soil and manufacture method thereof in the patent ZL97101028.5 of application on January 21st, 1997, it comprises that raw materials such as vinylformic acid, Potassium Persulphate form through reaction, product has water-absorbent preferably, and contains the required nutritive element of crop.Yet, find owing to the factors such as raw material that adopted that its preparation process is complicated through the inventor's practice for many years, the reaction times is very long, and is unfavorable to producing.
More than 8 years, on the basis of applying for a patent January 21 in 1997, the contriver has done improvement test repeatedly to production technique and production method, further refinement production technique, technique manufacturing method after the improvement has strong points such as more simple and efficient, that the production frock is simple, the direct labor is easy to operate, has remedied the defective of former complicate fabrication process, long reaction time.
Summary of the invention
One of purpose of the present invention is to overcome the deficiencies in the prior art, and a kind of water-loss reducer of soil that has both the retaining water conservation and the plant-growth desired nutritional is provided is provided.
Two of purpose of the present invention provides a kind of preparation method of water-loss reducer of soil.
These and other objects of the present invention will further be launched and illustrate by following detailed.
Water-loss reducer of soil of the present invention is that a kind of polymer organic polymer is a main raw material with vinylformic acid, sodium hydroxide, starch, zinc sulfate etc., and the technical process of employing new technology forms through polyreaction.
In the present invention, water-loss reducer of soil comprises:
Vinylformic acid 60-80 weight part
Sodium hydroxide 10-15 weight part
Potassium Persulphate 1-5 weight part
Borax 1-5 weight part
Starch 5-20 weight part
Glycocoll 1-5 weight part
Conventional fertilizer 10-30 weight part.
Further, this water-loss reducer of soil comprises:
Vinylformic acid 65-75 weight part
Sodium hydroxide 11-14 weight part
Potassium Persulphate 1-3 weight part
Borax 1-2 weight part
Starch 8-15 weight part
Glycocoll 1-3 weight part
Conventional fertilizer 10-20 weight part.
Further, this water-loss reducer of soil comprises:
Vinylformic acid 70 weight parts
Sodium hydroxide 13 weight parts
Potassium Persulphate 2 weight parts
Borax 2 weight parts
Starch 13 weight parts
Glycocoll 2 weight parts
Conventional fertilizer 15 weight parts.
Water-loss reducer of soil of the present invention is prepared as follows: raw material propylene acid, starch, glycocoll and borax are carried out polyreaction at normal temperatures, react and add initiator potassium persulfate after 0.5 hour, catalyzer sodium hydroxide, under 70 ℃, proceeded secondary reaction 4 hours, discharging, drying and dewatering, and be crushed to 0.25mm, add conventional fertilizer then, packing is finished product.
In the present invention, the chemical constitution of this water-holding agent and component effect:
Vinylformic acid: the main raw material of polyreaction also is the basis of reaction, and its polymer is a high absorbency material;
Sodium hydroxide: the catalyzer of polyreaction;
Potassium Persulphate: initiator of polyreaction;
Starch: reduce the polymer beads diameter, make molecule refining; Increase the nutritive element of water-retaining capacity and plant;
Glycocoll: the high protein material increases the polymer organic composition;
Conventional fertilizer: i.e. nitrogen phosphorus potassium and trace element fertilizer are the required important nutrients of plant-growth.
Product appearance of the present invention is faint yellow powder shape, and effective component content reaches more than 95%.This product can absorb water rapidly when meeting water, molecule expands and reaches more than 350 times, back receivability natural rainfall or manually water is manured into soil, also can absorb airborne moisture, improve soil suction and water retention capacity, reduce the velocity of evaporation of moisture content in the soil, thereby increase the content of soil available water, moisture content is gradually by plant absorbing when meeting drought, improve water and fertilizer utilization, so it is a kind of more satisfactory plant water keeping agent, through after the scientific experiment under the different condition, this product also has the soil physical chemistry of improvement performance, chessom promotes soil aggregate to form, and reconciles P in soil H value, improve soil mineral and biological activity nutrient, thereby can effectively improve utilization rate of fertilizer, slow down water evaporates speed, reconcile soil humidity.Use this product generally can improve the soil moisture utilization ratio more than 30%, improve utilization rate of fertilizer 10-20%.
The product of the present invention multiple that absorbs water after testing is 350-450 (gram weight), and PH is 6.5~7, particle diameter 0.25~0.4mm, nutritive element content 5-10wt%.
Compared with prior art, water-loss reducer of soil of the present invention has the following advantages:
1, the characteristics that have high-strength absorbing and use repeatedly, after being manured into soil, the receivability natural rainfall manually waters, and can also absorb airborne moisture, and after treating fully to adsorb, volumetric expansion can reach (weight ratio) more than 400 times.
2, improve the water-retaining capacity of soil, and natural precipitation can be kept in the soil securely, reduce the evaporation of moisture content in the soil simultaneously, thereby therefore the effect of playing water saving, preventing erosion has good retaining water retention property.
3, the water-loss reducer of soil structure of improving the soil in addition simultaneously improves soil permeability and water-holding power, can make loosing soil, promotes soil aggregate, and soil is not hardened.
4, have reduction soil salinity and alkalinity (belonging to alkalescence because of northern soil is most of), improve water and fertilizer utilization and reach water collection and keeping, keeping crop seedling from drought, the purpose of increasing both production and income.
5, water-loss reducer of soil of the present invention, the effect that not only has preserve moisture and fertility, and contain the required main nutrient elements of farm crop, field-crop can increase production 10-20% after using, use when cash crop vegetables, flowers turf and Greening Urban Road are planted and can improve surviving rate 30-70%, semiarid land half arid area and barren hill are planted trees to use and can be improved surviving rate 20-70%.
6, have wide range of applications, this product can also be used for oil, chemical industry, medical and health, fruit fresh-keeping and industry dehydration and environment protection aspect.
Using method:
1, broadcast application: make perforated method, ditch excute a law again.Water-holding agent and plant ash, sand, farmland dry ground thorough mixing is even, and using the degree of depth must be at 10-20 centimetre, and about 1.5 kilograms every mu in field crop is planted trees every mu and uses (being that every strain restrains with 30-50) about 2.5 kilograms, and this method is applicable to field crop more.
2, be stained with the root method: with the water of 300 times of water-holding agent addings, after treating fully to absorb water, add thin dry ground again and stir into pasty state during use, be stained with root and get final product.Be applicable to forest, fruit tree flue-cured tobacco, vegetables planted in big canopy, flowers.The water-holding agent of plant is useful in transit to nursery stock transplanting especially.
3, water and excute a law: water-holding agent can be added 500-1000 water doubly, treat fully suction after, pour in the introduced plants hole, field crop is watered and executes by plant, ditching, cave are watered and are executed the back blinding.Fruit tree (degree of depth is 10-20 centimetre) under the tree projection digs the cave, and circulating application all can.
4, seed dressing method: water-holding agent directly can be got final product with the seed uniform mixing.(per kilogram can be mixed 5 mu of left and right sides seeds.Be applicable to cotton, wheat, soybean, corn, Chinese sorghum, kind grass and kind beet etc.
5, mixes with fertile: can be with water-holding agent and urea, anhydrous application of mixed fertilizers such as diamino, can not with the application of mixed fertilizers of high humidity, if use with needing to separate priority.
Below further specify the present invention by specific embodiment, embodiment only be used for the explanation, can not limit the scope of the invention.
In the present invention, all starting material all can be buied from market, can adopt the Beijing Chemical Plant to produce as vinylformic acid; If not refer in particular to all per-cent, part is weight unit.
Example 1:
Earlier take by weighing each article by following weight ratio:
60 kilograms in vinylformic acid, 10 kilograms in sodium hydroxide,
1 kilogram of Potassium Persulphate, 1 kilogram of borax
5 kilograms of starch, 1 kilogram of glycocoll,
30 kilograms in conventional fertilizer.
Prepare according to the following steps then: earlier raw material propylene acid, starch, glycocoll and borax are carried out polyreaction at normal temperatures, react and add initiator potassium persulfate after 0.5 hour, catalyzer sodium hydroxide, under 70 ℃, proceeded secondary reaction 4 hours, discharging, drying and dewatering, and be crushed to 0.25mm, add conventional fertilizer then, packing is finished product.
Example 2:
Earlier take by weighing each article by following weight ratio:
80 kilograms in vinylformic acid, 15 kilograms in sodium hydroxide,
5 kilograms of Potassium Persulphates, 5 kilograms of boraxs
20 kilograms of starch, 5 kilograms of glycocoll,
10 kilograms in conventional fertilizer.
The preparation method is with example 1.
Example 3:
Earlier take by weighing each article by following weight ratio:
70 kilograms in vinylformic acid, 13 kilograms in sodium hydroxide,
2 kilograms of Potassium Persulphates, 2 kilograms of boraxs
13 kilograms of starch, 2 kilograms of glycocoll,
15 kilograms in conventional fertilizer.
The preparation method is with example 1.
Example 4:
Earlier take by weighing each article by following weight ratio:
75 kilograms in vinylformic acid, 11 kilograms in sodium hydroxide,
3 kilograms of Potassium Persulphates, 2 kilograms of boraxs
10 kilograms of starch, 3 kilograms of glycocoll,
20 kilograms in conventional fertilizer.
The preparation method is with example 1, and described packing is thin packing of aluminium of adopting 0.07mm.
After testing: suction multiple: 400
PH value: 7.1
Particle diameter: 0.5-0.25mm
Nutritive element content: 10%.

Claims (5)

1, a kind of water-loss reducer of soil is characterized in that comprising:
Vinylformic acid 60-80 weight part
Sodium hydroxide 10-15 weight part
Potassium Persulphate 1-5 weight part
Borax 1-5 weight part
Starch 5-20 weight part
Glycocoll 1-5 weight part
Conventional fertilizer 10-30 weight part.
2, water-loss reducer of soil according to claim 1 is characterized in that comprising:
Vinylformic acid 65-75 weight part
Sodium hydroxide 11-14 weight part
Potassium Persulphate 1-3 weight part
Borax 1-2 weight part
Starch 8-15 weight part
Glycocoll 1-3 weight part
Conventional fertilizer 10-20 weight part.
3, water-loss reducer of soil according to claim 1 is characterized in that comprising:
Vinylformic acid 70 weight parts
Sodium hydroxide 13 weight parts
Potassium Persulphate 2 weight parts
Borax 2 weight parts
Starch 13 weight parts
Glycocoll 2 weight parts
Conventional fertilizer 15 weight parts.
4, as the preparation method of the described water-loss reducer of soil of claim 1-3, it is characterized in that: raw material propylene acid, starch, glycocoll and borax are carried out polyreaction at normal temperatures, react and add initiator potassium persulfate after 0.5 hour, catalyzer sodium hydroxide was proceeded secondary reaction 4 hours, discharging under 70 ℃, drying and dewatering, and be crushed to 0.25mm, and add conventional fertilizer then, packing is finished product.
5, the preparation method of water-loss reducer of soil as claimed in claim 4 is characterized in that: described packing is thin packing of aluminium of adopting 0.07mm.
CNB200610003493XA 2006-02-10 2006-02-10 Water-loss reducer of soil and its preparation method Expired - Fee Related CN100398625C (en)

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127456A (en) * 2010-01-13 2011-07-20 马海力 Soil water retention agent and preparation method thereof
CN104262539A (en) * 2014-09-19 2015-01-07 广西地源之本肥业有限公司 Preparation method of water-absorbing resin from silkworm litter
CN107118778A (en) * 2017-06-14 2017-09-01 合肥助航生态农业科技有限公司 Water-loss reducer of soil and preparation method thereof
CN107162733A (en) * 2017-05-27 2017-09-15 兰溪市奥而特农业科技有限公司 A kind of gardens chemical fertilizer and preparation method thereof
CN107216191A (en) * 2017-05-25 2017-09-29 兰溪市普润斯水产养殖技术有限公司 A kind of flowers chemical fertilizer and preparation method thereof
CN110373208A (en) * 2019-08-02 2019-10-25 广州中茂园林建设工程有限公司 Water conservation agent material of desert afforestation and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1184839A (en) * 1995-11-21 1998-06-17 贾耀辉 Agent for preserving soil moisture
CN1061677C (en) * 1997-01-21 2001-02-07 夏志富 Soil moisture preserving agent and its preparing method
CN1279075C (en) * 2004-01-09 2006-10-11 中国科学院沈阳应用生态研究所 Method for preparing resin type water-retaining preparation
CN1331983C (en) * 2004-06-15 2007-08-15 西北大学 Water absorbing and preserving polymer soil protecting net film spray agent and its preparation

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127456A (en) * 2010-01-13 2011-07-20 马海力 Soil water retention agent and preparation method thereof
CN104262539A (en) * 2014-09-19 2015-01-07 广西地源之本肥业有限公司 Preparation method of water-absorbing resin from silkworm litter
CN107216191A (en) * 2017-05-25 2017-09-29 兰溪市普润斯水产养殖技术有限公司 A kind of flowers chemical fertilizer and preparation method thereof
CN107162733A (en) * 2017-05-27 2017-09-15 兰溪市奥而特农业科技有限公司 A kind of gardens chemical fertilizer and preparation method thereof
CN107118778A (en) * 2017-06-14 2017-09-01 合肥助航生态农业科技有限公司 Water-loss reducer of soil and preparation method thereof
CN110373208A (en) * 2019-08-02 2019-10-25 广州中茂园林建设工程有限公司 Water conservation agent material of desert afforestation and preparation method thereof

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Granted publication date: 20080702

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