CN1803928A - Plastic alloy composite material - Google Patents
Plastic alloy composite material Download PDFInfo
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- CN1803928A CN1803928A CN 200610032783 CN200610032783A CN1803928A CN 1803928 A CN1803928 A CN 1803928A CN 200610032783 CN200610032783 CN 200610032783 CN 200610032783 A CN200610032783 A CN 200610032783A CN 1803928 A CN1803928 A CN 1803928A
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Abstract
Disclosed is a plastic and alloy composite material which comprises the following raw materials (by weight ratio): plastic 30-60, bulking agent 15-30, coupling agent 1-5, modifier 2-10, activating agent 2-8, reinforcing agent 10-40, wherein the bulking agent is selected from resin fiber powder or paper fabric powder, the coupling agent is titanate, the modifier is aluminum hydroxide, the activating agent is zinc oxide or urea, the reinforcing agent is nano calcium carbonate or ethylene-acetic acid ethyenyl ester copolymer.
Description
Technical field
The present invention relates to plastic alloy composite material manufacturing technology field, is a kind of new prescription that utilizes waste or used plastics to make plastic alloy material as main raw material specifically.
Background technology
At present, along with socioeconomic continuous development, the different people life level of people improves constantly, the quick growth of market comsupton, disposable product is also more and more, the flourishing country of many in the world industry also is faced with the problem of waste products, waste or used plastics particularly, it is difficult to degraded under field conditions (factors) as a kind of high molecular polymer, being embedded in underground centuries even several thousand can not be decomposed, so just brought very big difficulty to environmental improvement, it has been brought for social development, the eubiosis and people's life and health and seriously influences.The report that the patent documentation that utilizes for the research and development of waste or used plastics was abroad just arranged as far back as the seventies in 20th century, as american documentation literature " US5088910 ", this patent documentation has been reported the technology of useless ethene with lumber fibre blend system plastic wood board material of utilizing, but there is very big difficulty in this patent aspect the waste or used plastics selection, because the fusing point difference of various waste or used plastics, be difficult to multiple waste or used plastics mixing congruent melting is got up, thereby this patent utilizes face very narrow to waste or used plastics, be difficult to this patent be generalized to utilize wide, reclaim and be easy to above the various waste or used plastics.
Summary of the invention
The present invention is the shortcoming that overcomes above-mentioned prior art, and a kind of new formula technique that utilizes various waste or used plastics to make plastic alloy material is provided.
The present invention can be achieved through the following technical solutions:
A kind of plastic alloy composite material, it comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is one or more in resin fibre powder, the paper fiber powder, coupling agent is a titanic acid ester, described properties-correcting agent is aluminium hydroxide, and activator is one or more in zinc oxide, the urea, and toughener is one or more in nano-calcium carbonate, the vinyl-vinyl acetate copolymer.
Described plastics are the material concurrent mixture after various waste or used plastics processes are pulverized, and comprise PE, PP, PS, PVC, ABS or the like.
To enumerate the embodiment an of the best below and realize that the present invention conceives:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a zinc oxide, and toughener is a nano-calcium carbonate.
In the foregoing invention conception plans, the weight percent of each raw material is plastics 60, paper fiber powder 15, titanic acid ester 1, aluminium hydroxide 10, zinc oxide 4, nano-calcium carbonate 10.
In the present embodiment, be main raw material with the waste or used plastics, paper fiber powder is an auxiliary material in addition again, two kinds of raw materials are thorough mixing again after the dryings respectively, absorb fillers paper fiber powder again, the coupling agent titanic acid ester, properties-correcting agent aluminium hydroxide, activator zinc oxide, the toughener nano-calcium carbonate, add behind each powder thorough mixing again, place twin screw extruder to heat blend then and extrude, this moment twin screw extruder working conditions will under 30K～50Kpa pressure, temperature is between 160 ℃～180 ℃.The powder that forcing machine is extruded enters into mould and becomes tool, can form the product of different shapes as required.Product after the moulding is owing to adopted weighting agent paper fiber powder, the coupling agent titanic acid ester, properties-correcting agent aluminium hydroxide, activator zinc oxide, toughener nano-calcium carbonate etc., take into account flexible and keep higher hardness simultaneously thereby improved plastics composite significantly, have more water-repellancy after utilizing plastics to be insoluble in the finished product of characteristic compacting of water, thereby embody the high-performance of integral composite product.
When die forming, can be various articles for use such as sheet material, furniture, outdoor field article with product shaping, its range of application is extremely extensive.
In the present embodiment, also the composition of each raw material can be prepared burden by weight percentage to reach effect preferably:
One, the weight percent of each raw material is: plastics 30, weighting agent 21, coupling agent 2, properties-correcting agent 5, activator 2, toughener 40;
Its two, the weight percent of each raw material is: plastics 50, weighting agent 20, coupling agent 5, properties-correcting agent 2, activator 3, toughener 20;
More than the described weighting agent of two schemes be paper fiber powder, coupling agent is a titanic acid ester, properties-correcting agent is aluminium hydroxide, activator is a zinc oxide, toughener is a nano-calcium carbonate.Its production method is identical with the production method of most preferred embodiment.
Enclose and state outside several embodiments, the present invention's design can also realize by following enforcement side example:
Embodiment one
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a resin fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 50, resin fibre powder 20, titanic acid ester 5, aluminium hydroxide 7, urea 3, nano-calcium carbonate 15.
In the present embodiment, also the composition of each raw material can be prepared burden by weight percentage to reach effect preferably:
One, the weight percent of each raw material is:
Plastics 30, resin fibre powder 30, titanic acid ester 5, aluminium hydroxide 5, urea 10, nano-calcium carbonate 20.
Its two, the weight percent of each raw material is:
Plastics 60, resin fibre powder 15, titanic acid ester 1, aluminium hydroxide 2, urea 2, nano-calcium carbonate 20.
Because the resin fibre powder belongs to the blend composition of epoxy polyester powder and staple glass fibre, its physical property and endurance are all very good, use the product that composition proportion is produced among the above embodiment can high temperature resistantly reach, flame retardant properties and waterproof, anticorrosion, fungicidal properties are preferably arranged simultaneously to 200 ℃.
The production method of this embodiment is identical with the production method of most preferred embodiment.
Embodiment two
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is resin fibre powder and paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is zinc oxide and urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 50, resin fibre powder 10, paper fiber powder 10, titanic acid ester 3, aluminium hydroxide 4, zinc oxide 2, urea 2, nano-calcium carbonate 19.
In the present embodiment, also the composition of each raw material can be prepared burden by weight percentage to reach effect preferably:
One, the weight percent of each raw material is:
Plastics 60, resin fibre powder 8, paper fiber powder 8, titanic acid ester 2, aluminium hydroxide 2, zinc oxide 4, urea 4, nano-calcium carbonate 12.
Its two, the weight percent of each raw material is:
Plastics 30, resin fibre powder 10, paper fiber powder 10, titanic acid ester 5, aluminium hydroxide 10, zinc oxide 4, urea 4, nano-calcium carbonate 27.
The production method of this embodiment is identical with the production method of most preferred embodiment.
The present invention mainly adopts such scheme to realize that the present invention conceives, but is not limited to above-mentioned several scheme, among the scope that all schemes that uses main design of the present invention all belong to the present invention to be protected.
The present invention compared with prior art has following advantage:
The present invention mainly utilizes waste or used plastics as main raw material, suitably add weighting agent, coupling agent, properties-correcting agent, activator, toughener again as auxiliary material, make the product that utilizes material of the present invention to produce various, this product is had can be high temperature resistant and have flame retardant properties and waterproof, anticorrosion a, fungicidal properties, also have good stretch-resistance and wear resistance, can be suitable for all trades and professions and use, this invention will be discarded industrial material and will be converted into available resources, the health of beautifying the environment greatly.
Description of drawings
Accompanying drawing 1 is Production Flow Chart synoptic diagram of the present invention.
Embodiment
Come the present invention is further described below in conjunction with accompanying drawing:
A kind of plastic alloy composite material, it comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is one or more in resin fibre powder, the paper fiber powder, coupling agent is a titanic acid ester, described properties-correcting agent is aluminium hydroxide, activator is one or more in zinc oxide, the urea, and toughener is one or more in nano-calcium carbonate, the ethylene-vinyl acetate ester copolymer.
To explain the present invention's innovation by following embodiment below:
Embodiment one:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a zinc oxide, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 60, paper fiber powder 15, titanic acid ester 1, aluminium hydroxide 10, zinc oxide 4, nano-calcium carbonate 10.
Embodiment two:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent: plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a zinc oxide, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is: plastics 30, weighting agent 21, coupling agent 2, properties-correcting agent 5, activator 2, toughener 40;
Embodiment three:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent: plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a zinc oxide, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is: plastics 50, weighting agent 20, coupling agent 5, properties-correcting agent 2, activator 3, toughener 20;
Embodiment four:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a resin fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 50, resin fibre powder 20, titanic acid ester 5, aluminium hydroxide 7, urea 3, nano-calcium carbonate 15.
Embodiment five:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a resin fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 30, resin fibre powder 30, titanic acid ester 5, aluminium hydroxide 5, urea 10, nano-calcium carbonate 20.
Embodiment six:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a resin fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 60, resin fibre powder 15, titanic acid ester 1, aluminium hydroxide 2, urea 2, nano-calcium carbonate 20.
Embodiment seven:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is resin fibre powder and paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is zinc oxide and urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 50, resin fibre powder 10, paper fiber powder 10, titanic acid ester 3, aluminium hydroxide 4, zinc oxide 2, urea 2, nano-calcium carbonate 19.
Embodiment eight:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is resin fibre powder and paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is zinc oxide and urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 60, resin fibre powder 8, paper fiber powder 8, titanic acid ester 2, aluminium hydroxide 2, zinc oxide 4, urea 4, nano-calcium carbonate 12.
Embodiment nine:
Plastic alloy composite material of the present invention comprises following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is resin fibre powder and paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is zinc oxide and urea, and toughener is a nano-calcium carbonate.
In this inventive concept scheme, the weight percent of each raw material is plastics 30, resin fibre powder 10, paper fiber powder 10, titanic acid ester 5, aluminium hydroxide 10, zinc oxide 4, urea 4, nano-calcium carbonate 27.
Be raw material in the above-described embodiment with the waste or used plastics, weighting agent in addition again, coupling agent, properties-correcting agent, activator, toughener adds behind each powder thorough mixing again, place twin screw extruder to heat blend then and extrude, this moment twin screw extruder working conditions will under 30K～50Kpa pressure, temperature is between 160 ℃～180 ℃.The powder that forcing machine is extruded enters into mould and becomes tool, can form the product of different shapes as required.Product after the moulding is owing to adopted weighting agent, coupling agent, properties-correcting agent, activator, toughener etc., take into account flexible and keep higher hardness simultaneously thereby improved plastics composite significantly, have more water-repellancy after utilizing plastics to be insoluble in the finished product of characteristic compacting of water, thereby embody the high-performance of integral composite product.
When die forming, can be various articles for use such as sheet material, furniture, outdoor field article with product shaping, its range of application is extremely extensive.
The present invention mainly adopts such scheme to realize that the present invention conceives, but is not limited to above-mentioned several scheme, among the scope that all schemes that uses main design of the present invention all belong to the present invention to be protected.
Claims (3)
1, a kind of plastic alloy composite material is characterized in that comprising following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is one or more in resin fibre powder, the paper fiber powder, coupling agent is a titanic acid ester, described properties-correcting agent is aluminium hydroxide, activator is one or more in zinc oxide, the urea, and toughener is one or more in nano-calcium carbonate, the ethylene-vinyl acetate ester copolymer.
2, plastic alloy composite material according to claim 1 is characterized in that comprising following raw materials by weight percent:
Plastics 30～60, weighting agent 15～30, coupling agent 1～5, properties-correcting agent 2～10, activator 2～8, toughener 10～40;
Described weighting agent is a paper fiber powder, and coupling agent is a titanic acid ester, and properties-correcting agent is aluminium hydroxide, and activator is a zinc oxide, and toughener is a nano-calcium carbonate.
3, plastic alloy composite material according to claim 2 is characterized in that comprising following raw materials by weight percent:
Plastics 60, paper fiber powder 15, titanic acid ester 1, aluminium hydroxide 10, zinc oxide 4, nano-calcium carbonate 10.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610032783 CN1803928A (en) | 2006-01-10 | 2006-01-10 | Plastic alloy composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610032783 CN1803928A (en) | 2006-01-10 | 2006-01-10 | Plastic alloy composite material |
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| CN1803928A true CN1803928A (en) | 2006-07-19 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845159A (en) * | 2010-05-17 | 2010-09-29 | 河南久通电缆有限公司 | Regenerated polyolefin blending modified nano-aluminum hydroxide flame retardant, environment-friendly and insulating composite material |
| CN101705006B (en) * | 2009-11-12 | 2011-07-06 | 严志龙 | Glass plastic product with composite material resin circular fiber power |
| CN102898112A (en) * | 2011-07-29 | 2013-01-30 | 上海圣济国际贸易有限公司 | Novel environmentally friendly material of composite calcium carbonate |
| CN103044772A (en) * | 2012-12-19 | 2013-04-17 | 清远市宏保环保科技有限公司 | Resin glass fiber formula and resin glass fiber type tile prepared by same |
| CN105670290A (en) * | 2016-01-23 | 2016-06-15 | 中山百鸥医药科技有限公司 | Pill making machine roller bearing for processing omega-3 fish-oil soft capsules |
| CN109968775A (en) * | 2019-04-10 | 2019-07-05 | 大连路安建材有限公司 | A kind of compound antiglare shield of Nano self-cleaning PVC |
-
2006
- 2006-01-10 CN CN 200610032783 patent/CN1803928A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705006B (en) * | 2009-11-12 | 2011-07-06 | 严志龙 | Glass plastic product with composite material resin circular fiber power |
| CN101845159A (en) * | 2010-05-17 | 2010-09-29 | 河南久通电缆有限公司 | Regenerated polyolefin blending modified nano-aluminum hydroxide flame retardant, environment-friendly and insulating composite material |
| CN101845159B (en) * | 2010-05-17 | 2012-03-28 | 河南久通电缆有限公司 | Regenerated polyolefin blending modified nano-aluminum hydroxide flame retardant, environment-friendly and insulating composite material |
| CN102898112A (en) * | 2011-07-29 | 2013-01-30 | 上海圣济国际贸易有限公司 | Novel environmentally friendly material of composite calcium carbonate |
| CN103044772A (en) * | 2012-12-19 | 2013-04-17 | 清远市宏保环保科技有限公司 | Resin glass fiber formula and resin glass fiber type tile prepared by same |
| CN105670290A (en) * | 2016-01-23 | 2016-06-15 | 中山百鸥医药科技有限公司 | Pill making machine roller bearing for processing omega-3 fish-oil soft capsules |
| CN109968775A (en) * | 2019-04-10 | 2019-07-05 | 大连路安建材有限公司 | A kind of compound antiglare shield of Nano self-cleaning PVC |
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Open date: 20060719 |